CN105568690A - Novel antistatic water-resistant oil-resistant finishing agent and preparation method thereof - Google Patents
Novel antistatic water-resistant oil-resistant finishing agent and preparation method thereof Download PDFInfo
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- CN105568690A CN105568690A CN201610013945.6A CN201610013945A CN105568690A CN 105568690 A CN105568690 A CN 105568690A CN 201610013945 A CN201610013945 A CN 201610013945A CN 105568690 A CN105568690 A CN 105568690A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F265/00—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00
- C08F265/04—Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/00 on to polymers of esters
- C08F265/06—Polymerisation of acrylate or methacrylate esters on to polymers thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/06—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polyethers, polyoxymethylenes or polyacetals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
- C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
- C08F283/122—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes on to saturated polysiloxanes containing hydrolysable groups, e.g. alkoxy-, thio-, hydroxy-
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/11—Oleophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/10—Repellency against liquids
- D06M2200/12—Hydrophobic properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
The invention discloses a novel antistatic water-resistant oil-resistant finishing agent, which comprises the following components: fatty alcohol polyoxyethylene ether, methacrylate polymer, ammonium persulfate, perfluorooctyl ethyl acrylate, dihydroxy polydimethylsiloxane, 3-propyl-2-enoyloxypropane-1-sodium sulfonate, isopropanol, N-(alkylamidomethyl)diethylamine hydrochloride, monoalkyl phosphate, higher aliphatic alcohol acrylate, and deionized water. The provided antistatic water-resistant oil-resistant finishing agent is applied to the antistatic water-resistant oil resistant treatment of synthesized fibers (terylene, acrylic fibers, chinlon, etc.) and blended fabrics thereof. The surface of fibers, which have been processed by the finishing agent, has a good antistatic, water-resistant, and oil-resistant effect, and also has a performance on resisting contamination, dusts, and pilling.
Description
Technical field
The present invention relates to a kind of finishing agent.More particularly, the present invention relates to a kind of novel antistatic water-refusing oil-refusing finishing agent and preparation method thereof.
Background technology
Textiles is after water and oil repellent finish, the surface tension of fiber declines, and fiber surface becomes hydrophobicity from hydrophily, thus makes COTTON FABRIC easily produce electrostatic, bring adverse influence to clothing performance, just seem be necessary very much so study anlistatig waterproof oil-proof finishing agent.
It is contradiction in essence that water and oil repellent finish and antistatic arrange, antistatic finishing agent is the moisture by absorbing in air, improve the electric conductivity of fabric and eliminate electrostatic, and water-refusing oil-refusing finishing agent is by reducing fiber surface tension force, it is made to reach the finishing effect of water and oil repellant lower than the surface tension of water, greasy dirt.This brings some problems just to imparting fabric water and oil repellant anti-static function simultaneously, mainly contain distribution finishing method at present and process with bath method, but distribution finishing method adds manufacturing procedure, also to consider the viscosity between two kinds of finishing agents and impact simultaneously, greatly can reduce antistatic behaviour and water and oil repellant; Consistency problem is there is between difference in functionality agent, so with in bath method, due to functional agent compatibility and influence each other, also greatly can reduce the effect of antistatic finish and water and oil repellent finish, therefore invention one possesses water and oil repellant antistatic finishing agent simultaneously and is very important.As CN102108638B invents a kind of durable waterproof grease proofing antistatic antibiotic functional form coating adhesive, just possessed the anlistatig effect of water and oil repellant simultaneously, but, because the part of its part and its water and oil repellant effect playing electrostatic interaction works as side base simultaneously, influence each other between them larger, so water and oil repellant antistatic effect is not satisfactory, need the water and oil repellant antistatic finishing agent seeking a kind of better effects if.
Summary of the invention
The object of this invention is to provide a kind of antistatic water-refusing oil-refusing finishing agent and preparation method thereof, by selecting suitable raw material, suitable proportioning, obtain a kind of to play antistatic property group for end group or close to terminal portion, with the polymer that fluorine-containing ester derivant and polyoxyethylene kind block polymer are main chain, for terylene, acrylic fibers, the antistatic water and oil repellent finish of the synthetic fiber such as polyamide fibre and BLENDED FABRIC thereof, the fiber surface that wherethrough was managed has the effect of well antistatic and water and oil repellant, also have antifouling simultaneously, dust tightness, anti-fluffing and anti-pilling effect.
To achieve these goals, the technical solution used in the present invention is as follows:
A kind of novel antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion:
Fatty alcohol-polyoxyethylene ether: 5 ~ 10 parts; Methacrylate oligomers: 2 ~ 8 parts;
Ammonium persulfate: 0.5 ~ 2 part; Perfluoroethyl octyl group ethyl ester: 3 ~ 15 parts;
Dialkyl polydimethylsiloxane: 8 ~ 20 parts;
3-third-2-alkene acyloxy propane-1-sodium sulfonate: 4 ~ 8 parts; Isopropyl alcohol: 0.3 ~ 1 part;
N-(alkyl amide methyl) diethylamine hydrochloride: 1 ~ 3 part;
Alkylphosphonate: 0.5 ~ 2 part; Higher aliphatic acrylate: 2 ~ 8 parts;
Deionized water: 30 ~ 60 parts.
Preferably, the molecular formula of described fatty alcohol-polyoxyethylene ether is RO (CH
2cH
2o)
nh, wherein R is the alkyl of undersaturated C7 ~ 9, and the scope of n is 4 ~ 6.
Preferably, the number-average molecular weight of described methacrylate oligomers is 6000 ~ 12000.
Preferably, described higher aliphatic acrylate monomer is selected from dodecyl acrylate, Process Conditions of Cetane Acrylate, octadecyl acrylate or Behenyl acrylate.
Present invention also offers a kind of preparation method of antistatic water-refusing oil-refusing finishing agent, comprise the steps:
Step 1: by the proportioning of claim 1, fatty alcohol-polyoxyethylene ether, dialkyl polydimethylsiloxane, methacrylate oligomers, perfluoroethyl octyl group ethyl ester, higher aliphatic acrylate, deionized water are added in container, stirring and emulsifying, temperature control bit 55 ~ 65 DEG C, obtains emulsion;
Step 2: reaction temperature is reduced to 50 DEG C, alkylphosphonate, N-(alkyl amide methyl) diethylamine hydrochloride is added again in reactor, 3-third-2-alkene acyloxy propane-1-sodium sulfonate, continues stirring reaction 0.5 ~ 1h, obtains copolymer emulsion;
Step 3: the temperature of described copolymer emulsion is maintained 50 DEG C, drip the blended liquid of ammonium persulfate and isopropyl alcohol, time for adding controls at 1 ~ 1.5h, continues stirring reaction 3 ~ 5h, obtains mixing material;
Step 4: by mixing material cool to room temperature, carries out shear treatment with cutter after near room temperature, and cutter rotating speed is 6000rpm, and shear time is 10 ~ 20min, filters, namely obtain antistatic water-refusing oil-refusing finishing agent after shearing.
Beneficial effect of the present invention: antistatic water-refusing oil-refusing finishing agent of the present invention is with perfluoroethyl octyl group ethyl ester, higher aliphatic acrylate, methacrylate oligomers is the monomer of initiated polymerization step, in fatty alcohol-polyoxyethylene ether, under the emulsification of dialkyl polydimethylsiloxane, obtain emulsion, then alkylphosphonate is added, N-(alkyl amide methyl) diethylamine hydrochloride, 3-third-2-alkene acyloxy propane-1-sodium sulfonate and described emulsion react, the blended liquid finally adding ammonium persulfate and isopropyl alcohol obtains fluorinated copolymer emulsion.The most addition of 3-third-2-alkene acyloxy propane-1-sodium sulfonate of the present invention, at end group or close to terminal portion, is worked as the antistatic group of end group.This finishing agent has excellent water and oil repellant performance, and emulsion particle diameter is little, does not affect the original performance of fabric, and when this finishing agent uses, the antistatic group of end group can be distributed in skin, plays good antistatic property; Fluorocarbon group and oxygen ethene are that side base can be distributed in internal layer, play the effect of water and oil repellant, obtain refusing the finish fabric that glassware for drinking water has and antistatic property is good.
Detailed description of the invention
Describe embodiments of the present invention in detail below with reference to specific embodiment, to the present invention, how application technology means solve technical problem whereby, and the implementation procedure reaching technique effect can fully understand and implement according to this.
If do not specialize, the conventional means that the technological means adopted in embodiment is well known to those skilled in the art, the raw material adopted also be can business obtain.The various process do not described in detail and method are conventional methods as known in the art.
Embodiment 1
Antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion: fatty alcohol-polyoxyethylene ether 5 parts; The amount that number all divides is the methacrylate polymers 2 parts of 20000; Ammonium persulfate 0.5 part; Perfluoroethyl octyl group ethyl ester 3 parts; Dialkyl polydimethylsiloxane 8 parts; 3-third-2-alkene acyloxy propane-1-sodium sulfonate 4 parts; Isopropyl alcohol 0.3 part; N-(alkyl amide methyl) diethylamine hydrochloride 1 part; Alkylphosphonate 0.5 part; Higher aliphatic acrylate 2 parts; Deionized water 30 parts.
Embodiment 2
Antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion: fatty alcohol-polyoxyethylene ether 7 parts; The amount that number all divides is the methacrylate polymers 6 parts of 30000; Ammonium persulfate 1 part; Perfluoroethyl octyl group ethyl ester 6 parts; Dialkyl polydimethylsiloxane 12 parts; 3-third-2-alkene acyloxy propane-1-sodium sulfonate 6 parts; Isopropyl alcohol 0.6 part; N-(alkyl amide methyl) diethylamine hydrochloride 2 parts; Alkylphosphonate 1.5 parts; Higher aliphatic acrylate 5 parts; Deionized water 50 parts.
Embodiment 3
Antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion: fatty alcohol-polyoxyethylene ether 10 parts; The amount that number all divides is the methacrylate polymers 8 parts of 40000; Ammonium persulfate 2 parts; Perfluoroethyl octyl group ethyl ester 15 parts; Dialkyl polydimethylsiloxane 20 parts; 3-third-2-alkene acyloxy propane-1-sodium sulfonate 8 parts; Isopropyl alcohol 1 part; N-(alkyl amide methyl) diethylamine hydrochloride 3 parts; Alkylphosphonate 2 parts; Higher aliphatic acrylate 8 parts; Deionized water 60 parts.
Comparative example 1
Antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion: fatty alcohol-polyoxyethylene ether 2 parts; The amount that number all divides is the methacrylate polymers 1 part of 30000; Ammonium persulfate 0.1 part; Perfluoroethyl octyl group ethyl ester 2 parts; Dialkyl polydimethylsiloxane 5 parts; 3-third-2-alkene acyloxy propane-1-sodium sulfonate 3 parts; Isopropyl alcohol 0.1 part; N-(alkyl amide methyl) diethylamine hydrochloride 0.4 part; Alkylphosphonate 0.1 part; Higher aliphatic acrylate 1 part; Deionized water 10 parts.
Comparative example 2
Antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion: fatty alcohol-polyoxyethylene ether 12 parts; The amount that number all divides is the methacrylate polymers 10 parts of 30000; Ammonium persulfate 3 parts; Perfluoroethyl octyl group ethyl ester 20 parts; Dialkyl polydimethylsiloxane 22 parts; 3-third-2-alkene acyloxy propane-1-sodium sulfonate 9 parts; Isopropyl alcohol 2 parts; N-(alkyl amide methyl) diethylamine hydrochloride 5 parts; Alkylphosphonate 4 parts; Higher aliphatic acrylate 10 parts; Deionized water 80 parts.
Comparative example 3
Antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion: fatty alcohol-polyoxyethylene ether 5 parts; The amount that number all divides is the methacrylate polymers 2 parts of 8000; Ammonium persulfate 0.5 part; Perfluoroethyl octyl group ethyl ester 3 parts; Dialkyl polydimethylsiloxane 8 parts; 3-third-2-alkene acyloxy propane-1-sodium sulfonate 4 parts; Isopropyl alcohol 0.3 part; N-(alkyl amide methyl) diethylamine hydrochloride 1 part; Alkylphosphonate 0.5 part; Higher aliphatic acrylate 2 parts; Deionized water 30 parts.
Comparative example 4
Antistatic water-refusing oil-refusing finishing agent, comprises the component of following weight portion: fatty alcohol-polyoxyethylene ether 5 parts; The amount that number all divides is the methacrylate polymers 2 parts of 60000; Ammonium persulfate 0.5 part; Perfluoroethyl octyl group ethyl ester 3 parts; Dialkyl polydimethylsiloxane 8 parts; 3-third-2-alkene acyloxy propane-1-sodium sulfonate 4 parts; Isopropyl alcohol 0.3 part; N-(alkyl amide methyl) diethylamine hydrochloride 1 part; Alkylphosphonate 0.5 part; Higher aliphatic acrylate 2 parts; Deionized water 30 parts.
The preparation method of the antistatic water-refusing oil-refusing finishing agent of embodiment 1 ~ 3 and comparative example 1 ~ 4, comprises the steps:
Step 1: by the proportioning of claim 1, fatty alcohol-polyoxyethylene ether, dialkyl polydimethylsiloxane, methacrylate oligomers, perfluoroethyl octyl group ethyl ester, higher aliphatic acrylate, deionized water are added in container, stirring and emulsifying, temperature control bit 55 ~ 65 DEG C, obtains emulsion;
Step 2: reaction temperature is reduced to 50 DEG C, alkylphosphonate, N-(alkyl amide methyl) diethylamine hydrochloride is added again in reactor, 3-third-2-alkene acyloxy propane-1-sodium sulfonate, continues stirring reaction 0.5 ~ 1h, obtains copolymer emulsion;
Step 3: the temperature of described copolymer emulsion is maintained 50 DEG C, drip the blended liquid of ammonium persulfate and isopropyl alcohol, time for adding controls at 1 ~ 1.5h, continues stirring reaction 3 ~ 5h, obtains mixing material;
Step 4: by mixing material cool to room temperature, carries out shear treatment with cutter after near room temperature, and cutter rotating speed is 6000rpm, and shear time is 10 ~ 20min, filters, namely obtain antistatic water-refusing oil-refusing finishing agent after shearing.
Add water above-mentioned finishing agent the work bath being configured to 5g/l, dacron carried out a leaching one and roll, pad liquid level 70%.Cure 90S at 160 DEG C, then refuse water respectively to its washing 20 front and back, refuse oil and anlistatig test, result is as table 1.
Table 1 test result
Although embodiment of the present invention are open as above, but it is not restricted to listed in description and embodiment utilization, it can be applied to various applicable the field of the invention completely, for those skilled in the art, can easily realize other amendment, therefore do not deviating under the universal that claim and equivalency range limit, the present invention is not limited to specific details.
Claims (5)
1. a novel antistatic water-refusing oil-refusing finishing agent, is characterized in that, comprises the component of following weight portion:
Fatty alcohol-polyoxyethylene ether: 5 ~ 10 parts; Ammonium persulfate: 0.5 ~ 2 part;
Methacrylate polymers: 2 ~ 8 parts; Perfluoroethyl octyl group ethyl ester: 3 ~ 15 parts;
Dialkyl polydimethylsiloxane: 8 ~ 20 parts;
3-third-2-alkene acyloxy propane-1-sodium sulfonate: 4 ~ 8 parts; Isopropyl alcohol: 0.3 ~ 1 part;
N-(alkyl amide methyl) diethylamine hydrochloride: 1 ~ 3 part;
Alkylphosphonate: 0.5 ~ 2 part; Higher aliphatic acrylate: 2 ~ 8 parts;
Deionized water: 30 ~ 60 parts.
2. antistatic water-refusing oil-refusing finishing agent as claimed in claim 1, is characterized in that, the molecular formula of described fatty alcohol-polyoxyethylene ether is RO (CH
2cH
2o)
nh, wherein R is the alkyl of undersaturated C7 ~ 9, and the scope of n is 4 ~ 6.
3. antistatic water-refusing oil-refusing finishing agent as claimed in claim 1, is characterized in that, the number-average molecular weight of described methacrylate polymers is 20000 ~ 40000.
4. antistatic water-refusing oil-refusing finishing agent as claimed in claim 1, is characterized in that, described higher aliphatic acrylate monomer is selected from dodecyl acrylate, Process Conditions of Cetane Acrylate, octadecyl acrylate or Behenyl acrylate.
5. a preparation method for the antistatic water-refusing oil-refusing finishing agent as described in any one of Claims 1 to 4, is characterized in that, comprise the steps:
Step 1: by the proportioning of claim 1, fatty alcohol-polyoxyethylene ether, dialkyl polydimethylsiloxane, methacrylate oligomers, perfluoroethyl octyl group ethyl ester, higher aliphatic acrylate, deionized water are added in container, stirring and emulsifying, temperature control bit 55 ~ 65 DEG C, obtains emulsion;
Step 2: reaction temperature is reduced to 50 DEG C, alkylphosphonate, N-(alkyl amide methyl) diethylamine hydrochloride is added again in reactor, 3-third-2-alkene acyloxy propane-1-sodium sulfonate, continues stirring reaction 0.5 ~ 1h, obtains copolymer emulsion;
Step 3: the temperature of described copolymer emulsion is maintained 50 DEG C, drip the blended liquid of ammonium persulfate and isopropyl alcohol, time for adding controls at 1 ~ 1.5h, continues stirring reaction 3 ~ 5h, obtains mixing material;
Step 4: by mixing material cool to room temperature, carries out shear treatment with cutter after near room temperature, and cutter rotating speed is 6000rpm, and shear time is 10 ~ 20min, filters, namely obtain antistatic water-refusing oil-refusing finishing agent after shearing.
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| CN201610013945.6A CN105568690A (en) | 2016-01-08 | 2016-01-08 | Novel antistatic water-resistant oil-resistant finishing agent and preparation method thereof |
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| CN201610013945.6A CN105568690A (en) | 2016-01-08 | 2016-01-08 | Novel antistatic water-resistant oil-resistant finishing agent and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486898A (en) * | 2018-04-18 | 2018-09-04 | 佛山慧创正元新材料科技有限公司 | A kind of crease-resistant water-proof finish method of environment-friendlytype type fabric |
| CN108951154A (en) * | 2018-05-23 | 2018-12-07 | 绍兴柯桥德美精细化工有限公司 | A kind of environment-friendly type terylene soft fabric, water repellent, anti-static multifunctional method for sorting |
| CN110130114A (en) * | 2019-04-25 | 2019-08-16 | 王兵兵 | A kind of biomass graphene fabric and preparation method thereof |
| CN111548462A (en) * | 2020-05-18 | 2020-08-18 | 广东健玺表面工程技术有限公司 | Organic fluorine-silicon copolymer and synthesis and application methods thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108486898A (en) * | 2018-04-18 | 2018-09-04 | 佛山慧创正元新材料科技有限公司 | A kind of crease-resistant water-proof finish method of environment-friendlytype type fabric |
| CN108951154A (en) * | 2018-05-23 | 2018-12-07 | 绍兴柯桥德美精细化工有限公司 | A kind of environment-friendly type terylene soft fabric, water repellent, anti-static multifunctional method for sorting |
| CN110130114A (en) * | 2019-04-25 | 2019-08-16 | 王兵兵 | A kind of biomass graphene fabric and preparation method thereof |
| CN111548462A (en) * | 2020-05-18 | 2020-08-18 | 广东健玺表面工程技术有限公司 | Organic fluorine-silicon copolymer and synthesis and application methods thereof |
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