CN105567434A - Production apparatus of high cleanness biodiesel, and method thereof - Google Patents

Production apparatus of high cleanness biodiesel, and method thereof Download PDF

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Publication number
CN105567434A
CN105567434A CN201511016967.XA CN201511016967A CN105567434A CN 105567434 A CN105567434 A CN 105567434A CN 201511016967 A CN201511016967 A CN 201511016967A CN 105567434 A CN105567434 A CN 105567434A
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voice signal
temperature
biofuel
abrasive
power
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车春玲
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SHANDONG TAIDE NEW ENERGY CO Ltd
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SHANDONG TAIDE NEW ENERGY CO Ltd
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Priority to CN201511016967.XA priority Critical patent/CN105567434A/en
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    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11CFATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/04Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fats or fatty oils
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/02Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11BPRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES
    • C11B3/00Refining fats or fatty oils
    • C11B3/10Refining fats or fatty oils by adsorption
    • GPHYSICS
    • G05CONTROLLING; REGULATING
    • G05BCONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
    • G05B19/00Programme-control systems
    • G05B19/02Programme-control systems electric
    • G05B19/04Programme control other than numerical control, i.e. in sequence controllers or logic controllers
    • G05B19/042Programme control other than numerical control, i.e. in sequence controllers or logic controllers using digital processors
    • G05B19/0428Safety, monitoring
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/56Specific details of the apparatus for preparation or upgrading of a fuel
    • C10L2290/562Modular or modular elements containing apparatus
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/58Control or regulation of the fuel preparation of upgrading process
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L2290/00Fuel preparation or upgrading, processes or apparatus therefore, comprising specific process steps or apparatus units
    • C10L2290/60Measuring or analysing fractions, components or impurities or process conditions during preparation or upgrading of a fuel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/10Biofuels, e.g. bio-diesel

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Automation & Control Theory (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Microbiology (AREA)
  • Radiation Pyrometers (AREA)

Abstract

The invention provides a production apparatus of high cleanness biodiesel, and a method thereof. The method comprises the following steps: carrying out foreign water removal and dehydration on lower fatty acid-containing biodiesel raw oil with an adsorbent through generating power by using a power generator, through supplying power by using a power supply substrate and through using cooperation of regulating valve input and a container; heating through using a heating wire and a heat accumulation plate, and carrying out infrared temperature monitoring by adopting a temperature monitoring device; and allowing the hydrated biodiesel raw oil to go through a reaction agent provided with cationic exchange resin and an esterification reaction device after the raw oil is heated to an assigned temperature, adjusting the pH value, and acquiring reaction data and remote control experiment parameters through a real-time online monitoring module. The infrared temperature monitoring is carried out through the temperature monitoring device, and the reaction data and remote control experiment parameters are acquired through the real-time online monitoring module, so real-time optimum reaction parameters are guaranteed, the detection performances of produced biodiesel are excellent, and the consistence of the above product is good.

Description

A kind of production equipment of abrasive biofuel and method
Technical field
The invention belongs to diesel production technical field, particularly relate to a kind of production equipment and method of abrasive biofuel.
Background technology
At present, diesel oil is oils, complicated hydro carbons (carbonatoms about 10 ~ 22) mixture.For diesel-fuel, the diesel oil distillate allotment of producing primarily of processes such as crude distillation, catalytic cracking, thermally splitting, hydrocracking, petroleum cokings forms; Also can be produced by shale oil processing and gelatin liquefaction, be divided into solar oil (boiling spread about 180 ~ 370 DEG C) and the large class of heavy gas oil (boiling spread about 350 ~ 410 DEG C) two, be widely used in oversize vehicle, railway locomotive, ships.But the use that the production equipment of existing abrasive biofuel exists is inconvenient, and of poor quality, function is perfect not, poor safety performance, the problem that manufacturing cost is high.
Summary of the invention
The invention provides a kind of production equipment and method of abrasive biofuel, with solve existing abrasive biofuel production equipment use inconvenient, of poor quality, function is perfect not, the problem that manufacturing cost is high.
The object of the present invention is to provide a kind of production method of abrasive biofuel, the production method method of described abrasive biofuel utilizes electrical power generators, power for electric substrate, by variable valve input and the cooperation of container, from the biodiesel raw material oil containing lower fatty acid, remove foreign matter with sorbent material and dewater; By heater strip and heat accumulation plate heating, device for monitoring temperature is adopted to carry out infrared temperature monitoring; Making the biodiesel raw material through dehydration oily by being provided with reagent and the esterification device of Zeo-karb after being heated to assigned temperature, regulating pH, gathering response data and remote control experiment parameter by real time and on line monitoring mould.
Another object of the present invention is to provide a kind of abrasive biodiesel production apparatus, comprise generator, supplementary structure, power generation assembly, temperature control unit, driving circuit, thermovent, filter processor, base device, vane, input terminus, handle and guard shield, described generator is arranged on the bottom position of base device; Described input terminus is arranged on the external right side position of filter processor; Described power generation assembly is arranged on the upper position of temperature control unit; Described driving circuit is arranged on the leftward position of vane; Described thermovent is arranged on the tip position of power generation assembly; Described supplementary structure is arranged on the upper position of thermovent, and described handle is arranged on the leftward position of filter processor; Described guard shield is arranged on temperature control unit external position; Described power generation assembly comprises, acousto-optic electric organ, display screen, resistance, storage batteries, and for electric substrate and wireless IC chip, described acousto-optic electric organ is arranged on the leftward position of resistance;
Described display screen is arranged on the top of resistance by being electrically connected, the described display screen the superiors are panels, and described panel is acrylic material, are LCD plate below described panel, are backlight below described LCD plate; Described storage batteries is arranged on the bottom of display screen by being electrically connected; The described bottom being arranged on display screen for electric substrate by electric connection; Described wireless IC chip is arranged on the leftward position for electric substrate;
Described temperature control unit comprises vertical tube, rotating cylinder, safeguard construction and beam seat structure, and described vertical tube is arranged on the mid-way of rotating cylinder, and described safeguard construction is arranged on the upper position of beam seat structure; Described safeguard construction comprises alarming horn, cancel switch, temperature sensing sheet, cutting type button and warning shell, and described cancel switch is arranged on the leftward position of cutting type button;
Described alarming horn is arranged on the leftward position of cutting type button; Described temperature sensing sheet is arranged on the lower position of alarming horn and cancel switch; Described warning shell is arranged on the external position of cancel switch; Described beam seat structure comprises slide block, electric elements, elevating bracket, guide rail and web plate, and described slide block is arranged on the upper position of guide rail, and described web plate is arranged on the lower position of slide block; Described electric elements are arranged on the upper position of slide block; Described elevating bracket is arranged on the lower position of web plate;
Described base device comprises base frame, bottom tub, fixing buckle, bracket component and Universal wheel structure, and described base frame is arranged on the external position of bottom tub, and described Universal wheel structure is arranged on the bottom position of bracket component; Described fixing buckle is arranged on the external position of base frame;
Described Universal wheel structure comprises setting nut, bearing, universal rolling wheel and support bar, and described setting nut is arranged on support bar external position, and described bearing is arranged on the lower position of support bar;
Described universal rolling wheel is arranged on the external position of bearing; Described supplementary structure comprises variable valve input, power switch button and container, and described variable valve input is arranged on the leftward position of power switch button; Described container is arranged on the bottom of power switch button.
Further, described infrared temperature monitoring obtains the production vessel surface temperature of abrasive biofuel according to infrared spectral radiant, infrared spectra emittance has approximately uniform linear relationship at selected wavelength place and temperature, that is:
ε i2=ε i1[1+k(T 2-T 1)]
In formula, ε i1be wavelength be λ i, spectral emittance when temperature is T1; ε i2be wavelength be λ i, spectral emittance when temperature is T2; T1, T2 are respectively two not temperature in the same time; K is coefficient;
Note V i1be first temperature T 1under the output signal of i-th passage, note V i2be first temperature T 2under the output signal of i-th passage, T 1emissivity ε at temperature i1∈ (0,1), by random selecting one group of ε i1, calculated at parameter ε by following formula i1the lower actual T obtained i1:
T i 1 = 1 1 T ′ + λ i c 2 ln ϵ i 1 V i ′ V i 2
If k is ∈ (-η, η), by random selecting k, at second temperature T 2under emissivity ε i2expression formula be:
ϵ i 2 = ϵ i 1 [ 1 + k ( T i 2 - T i 1 ) ]
Calculated at parameter ε by following formula i1the lower actual T obtained i2:
T i 2 = 1 1 T ′ + λ i c 2 ln ϵ i 1 [ 1 + k ( T i 2 - T i 1 ) ] V i ′ V i 2 .
Further, the described built-in sound identification module of real time and on line monitoring mould, comprises frequency analysis unit, phase curve computing unit, error calculation unit, voice signal recognition unit;
Described frequency analysis unit, analyzes the frequency signal of voice signal;
Described phase curve computing unit, calculates the phase curve carrying out with the time variations of the phase place of described frequency signal being similar to;
Described error calculation unit, calculates the error between described phase curve and the phase place of described frequency signal;
Described voice signal recognition unit, identifies the signal whether described voice signal is periodic sound based on described error.
Further, described sound identification module, for each road voice signal, carries out noise tracking to each the frame voice signal in described voice signal according to the following equation, obtains the noise spectrum N (w, n) of each frame voice signal:
N ( w , n ) = ( 1 - &alpha; u ) | X ( w , n ) | + &alpha; u N ( w , n - 1 ) , | X ( w , n ) | &GreaterEqual; N ( w , n - 1 ) ( 1 - &alpha; d ) | X ( w , n ) | + &alpha; d N ( w , n - 1 ) , | X ( w , n ) | < N ( w , n - 1 ) ;
Wherein, X (w, n) represents the Short Time Fourier Transform of described voice signal; α u, α dfor predetermined coefficient and 0 < α d< α u< 1; W represents the frequency sequence number on frequency domain; N represents the frame number in time domain;
According to the following equation binary conversion treatment is carried out to the Short Time Fourier Transform of each frame voice signal and obtains two-value spectrum Xb (w, n):
X b ( w , n ) = 1 , | X ( w , n ) | - N ( w , n ) > T b 0 , | X ( w , n ) | - N ( w , n ) &le; T b
T bfor preset first threshold value;
Ka corresponding for wherein road voice signal two-value spectrum Kb the two-value corresponding with another road voice signal is composed the coherency between carrying out between two to mate and obtain described first matching result, described first matching result comprises matched position corresponding to one group of the highest two-value spectrum of matching degree and matching degree, and Ka, Kb are positive integer;
For each road voice signal, calculate the power spectrum P (w, n) of each the frame voice signal in described voice signal according to the following equation:
P(w,n)=α pP(w,n-1)+(1-α p)|X(w,n)| 2
Wherein, X (w, n) represents the Short Time Fourier Transform of described voice signal;
α pfor predetermined coefficient and 0 < α p< 1; W represents the frequency sequence number on frequency domain; N represents the frame number in time domain;
Calculate the Spectral correlation DP (w, n) of the power spectrum of each frame voice signal according to the following equation:
DP(w,n)=|P(w+1,n)-P(w,n)|
According to the following equation noise tracking is carried out to described Spectral correlation DP (w, n), obtains the Spectral correlation NDP (w, n) of the noise power spectrum of each frame voice signal:
N D P ( w , n ) = ( 1 - &beta; u ) D P ( w , n ) + &beta; u N D P ( w , n - 1 ) , D P ( w , n ) &GreaterEqual; N D P ( w , n - 1 ) ( 1 - &beta; d ) D P ( w , n ) + &beta; d N D P ( w , n - 1 ) , D P ( w , n ) < N D P ( w , n - 1 )
Wherein, β u, β dfor predetermined coefficient and 0 < β d< β u< 1.
The present invention carries out infrared temperature monitoring by device for monitoring temperature, gathers response data and remote control experiment parameter, can ensure that reaction parameter is in the best in real time by real time and on line monitoring mould, and the biofuel detection perform of production is excellent, good product consistency.
Accompanying drawing explanation
Fig. 1 is the production equipment structural representation of the abrasive biofuel that the embodiment of the present invention provides;
Fig. 2 is the generating device structure schematic diagram that the embodiment of the present invention provides;
Fig. 3 is the temperature control unit structural representation that the embodiment of the present invention provides;
Fig. 4 is the base device structural representation that the embodiment of the present invention provides.
In figure: 1, generator; 2, supplementary structure; 2-1, variable valve input; 2-2, power switch button; 2-3, container; 3, power generation assembly; 3-1 acousto-optic electric organ; 3-2, display screen; 3-3, resistance; 3-4, storage batteries; 3-5, confession electric substrate; 3-6, wireless IC chip; 4, temperature control unit; 4-1, muff; 4-2, store battery; 4-3, heater strip; 4-4, heat accumulation plate; 4-5, thermophore; 4-6, thermostatted; 5, driving circuit; 6, thermovent; 7, filter processor; 8, base device; 9, vane; 10, input terminus; 11, shake hands; 12, guard shield.
Embodiment
Below in conjunction with accompanying drawing, the present invention is described further:
The production method of abrasive biofuel utilizes an electrical power generators, powers for electric substrate, by variable valve input and the cooperation of container, removes foreign matter and dewater with sorbent material from the biodiesel raw material oil containing lower fatty acid; By heater strip and heat accumulation plate heating, device for monitoring temperature is adopted to carry out infrared temperature monitoring; Making the biodiesel raw material through dehydration oily by being provided with reagent and the esterification device of Zeo-karb after being heated to assigned temperature, regulating pH, gathering response data and remote control experiment parameter by real time and on line monitoring mould.
Biodiesel raw material oil through dehydration protects bed to remove metallic cation by solid acid catalyst reaction, methyl alcohol is mixed with the described biodiesel raw material oil passed through, then at 70-120 DEG C, with the flow velocity of 0.5-1.5SV, described mixture is reacted main bed there is esterification by the solid acid catalyst being provided with solid acid catalyst, the final acid number of described biodiesel raw material oil is adjusted to 5mgKOH/g or lower; And the biodiesel raw material oil described in making under basic catalyst exists with the final acid number of 5mgKOH/g or lower reacts.
As shown in accompanying drawing 1 to accompanying drawing 4:
A production equipment for abrasive biofuel, comprises generator 1, supplementary structure 2, power generation assembly 3, temperature control unit 4, driving circuit 5, thermovent 6, filter processor 7, base device 8, vane 9, input terminus 10, handle 11 and guard shield 12, described generator 1 is arranged on the bottom position of base device 8; Described input terminus 2 is arranged on the external right side position of filter processor 7; Described power generation assembly 3 is arranged on the upper position of temperature control unit 4; Described driving circuit 5 is arranged on the leftward position of vane 9; Described thermovent 6 is arranged on the tip position of power generation assembly 3; Described supplementary structure 2 is arranged on the upper position of thermovent 6, and described handle 11 is arranged on the leftward position of filter processor 7; Described guard shield 12 is arranged on temperature control unit 4 external position; Described power generation assembly 3 comprises, acousto-optic electric organ 3-1, display screen 3-2, resistance 3-3, storage batteries 3-4, and for electric substrate 3-5 and wireless IC chip 3-6, described acousto-optic electric organ 3-1 is arranged on the leftward position of resistance 3-3.
Described display screen 3-1 is arranged on the top of resistance 3-3 by being electrically connected, the described display screen 3-1 the superiors are panels, described panel is acrylic material, it is LCD plate below described panel, backlight below described LCD plate, described display screen 3-1 specifically adopts multipoint mode capacitance touch screen, is conducive to easy to use, thus improves intelligence degree.
Described storage batteries 3-4 is arranged on the bottom of display screen 3-1 by being electrically connected, the series of cells that described storage batteries 3-4 specifically adopts multiple lithium ion battery to form, is conducive to accumulate convenient and reliable, thus consummating function diversity.
The described bottom being arranged on display screen 3-1 for electric substrate 3-5 by electric connection, the described duplexer formation specifically adopting dielectric layer or magnetosphere to be laminated for electric substrate 3-5, is conducive to electricity consumption convenient, improves work quality.
Described wireless IC chip 3-6 is arranged on the leftward position for electric substrate 3-5, and described wireless IC chip 3-6 specifically adopts the miniature IC chipset of concrete employing voice, is conducive to easy to operate, improves intelligence degree, reduces manufacturing cost.
Described temperature control unit 4 comprises muff 4-1, store battery 4-2, heater strip 4-3, heat accumulation plate 4-4, thermophore 4-5 and thermostatted 4-6, and described muff 4-1 is arranged on the mid-way of thermostatted 4-6 and store battery 4-2; Described heater strip 4-3 is arranged on the interior location of heat accumulation plate 4-4; Described thermophore 4-5 is arranged on the external position of heat accumulation plate 4-4.
Described thermostatted 4-6 specifically adopts two adjustable fixed thermostat of gold plaque, is conducive to keeping certain temperature, makes practical and convenient, safe and reliable.
Described heater strip 4-3 specifically adopts 1 Aludirome nichrome wire, is conducive to heating convenient, safety durable, thus improves heat insulation effect.
Described store battery 4-2 specifically adopts chargeable lithium cell group, is conducive to store electrical energy, provides power supply, makes safe and reliable.
Described base 8 comprises base frame 8-1, bottom tub 8-2, fixing buckle 8-3, bracket component 8-4 and Universal wheel structure 8-5, described base frame 8-1 is arranged on the external position of bottom tub 8-2, and described Universal wheel structure 8-5 is arranged on the bottom position of bracket component 8-4.
Described fixing buckle 8-3 is arranged on the external position of base frame 8-1, the buckle that described fixing buckle 8-3 specifically adopts multiple stainless material to make, and is conducive to easy to use, fixed.
Described Universal wheel structure 8-5 comprises setting nut 8-5-1, bearing 8-5-2, universal rolling wheel 8-5-3 and support bar 8-5-4, described setting nut 8-5-1 is arranged on support bar 8-5-4 external position, and described bearing 8-5-2 is arranged on the lower position of support bar 8-5-4.
Described universal rolling wheel 8-5-3 is arranged on the external position of bearing 8-5-2, and described universal rolling wheel 8-5-3 specifically adopts urethane universal wheel, and be conducive to easy for installation, structure is simple, makes safe and reliable.
Described supplementary structure 2 comprises variable valve input 2-1, power switch button 2-2 and container 2-3, and described variable valve input 2-1 is arranged on the leftward position of power switch button 2-2.
Described container 2-3 is arranged on the bottom of power switch button 2-2, the tubular shape container that described container 2-3 specifically adopts PE plastics to make, and is conducive to easy to use, long service life, thus consummating function diversity.
Described handle 11 comprises set screw nut, and described handle 7 specifically adopts the belt that can stretch to make, and described set screw nut specifically adopts 2 adjustable nuts, is arranged on the two ends of handle, is conducive to fixing stretching conveniently, thus consummating function diversity.
The shell that described guard shield 12 specifically adopts PE plastics to make, be conducive to playing protective effect, demolition and maintenance are convenient.
Described infrared temperature monitoring obtains the production vessel surface temperature of abrasive biofuel according to infrared spectral radiant, infrared spectra emittance has approximately uniform linear relationship at selected wavelength place and temperature, that is:
ε i2=ε i1[1+k(T 2-T 1)]
In formula, ε i1be wavelength be λ i, spectral emittance when temperature is T1; ε i2be wavelength be λ i, spectral emittance when temperature is T2; T1, T2 are respectively two not temperature in the same time; K is coefficient;
Note V i1be first temperature T 1under the output signal of i-th passage, note V i2be first temperature T 2under the output signal of i-th passage, T 1emissivity ε at temperature i1∈ (0,1), by random selecting one group of ε i1, calculated at parameter ε by following formula i1the lower actual T obtained i1:
T i 1 = 1 1 T &prime; + &lambda; i c 2 ln &epsiv; i 1 V i &prime; V i 2
If k is ∈ (-η, η), by random selecting k, at second temperature T 2under emissivity ε i2expression formula be:
&epsiv; i 2 = &epsiv; i 1 &lsqb; 1 + k ( T 2 i - T i 1 ) &rsqb;
Calculated at parameter ε by following formula i1the lower actual T obtained i2:
T i 2 = 1 1 T &prime; + &lambda; i c 2 ln &epsiv; i 1 &lsqb; 1 + k ( T i 2 - T i 1 ) &rsqb; V i &prime; V i 2 .
The described built-in sound identification module of real time and on line monitoring mould, comprises frequency analysis unit, phase curve computing unit, error calculation unit, voice signal recognition unit;
Described frequency analysis unit, analyzes the frequency signal of voice signal;
Described phase curve computing unit, calculates the phase curve carrying out with the time variations of the phase place of described frequency signal being similar to;
Described error calculation unit, calculates the error between described phase curve and the phase place of described frequency signal;
Described voice signal recognition unit, identifies the signal whether described voice signal is periodic sound based on described error.
Described sound identification module, for each road voice signal, carries out noise tracking to each the frame voice signal in described voice signal according to the following equation, obtains the noise spectrum N (w, n) of each frame voice signal:
N ( w , n ) = ( 1 - &alpha; u ) | X ( w , n ) | + &alpha; u N ( w , n - 1 ) , | X ( w , n ) | &GreaterEqual; N ( w , n - 1 ) ( 1 - &alpha; d ) | X ( w , n ) | + &alpha; d N ( w , n - 1 ) , | X ( w , n ) | < N ( w , n - 1 ) ;
Wherein, X (w, n) represents the Short Time Fourier Transform of described voice signal; α u, α dfor predetermined coefficient and 0 < α d< α u< 1; W represents the frequency sequence number on frequency domain; N represents the frame number in time domain;
According to the following equation binary conversion treatment is carried out to the Short Time Fourier Transform of each frame voice signal and obtains two-value spectrum Xb (w, n):
X b ( w , n ) = 1 , | X ( w , n ) | - N ( w , n ) > T b 0 , | X ( w , n ) | - N ( w , n ) &le; T b
T bfor preset first threshold value;
Ka corresponding for wherein road voice signal two-value spectrum Kb the two-value corresponding with another road voice signal is composed the coherency between carrying out between two to mate and obtain described first matching result, described first matching result comprises matched position corresponding to one group of the highest two-value spectrum of matching degree and matching degree, and Ka, Kb are positive integer;
For each road voice signal, calculate the power spectrum P (w, n) of each the frame voice signal in described voice signal according to the following equation:
P(w,n)=α pP(w,n-1)+(1-α p)|X(w,n)| 2
Wherein, X (w, n) represents the Short Time Fourier Transform of described voice signal;
α pfor predetermined coefficient and 0 < α p< 1; W represents the frequency sequence number on frequency domain; N represents the frame number in time domain;
Calculate the Spectral correlation DP (w, n) of the power spectrum of each frame voice signal according to the following equation:
DP(w,n)=|P(w+1,n)-P(w,n)|
According to the following equation noise tracking is carried out to described Spectral correlation DP (w, n), obtains the Spectral correlation NDP (w, n) of the noise power spectrum of each frame voice signal:
N D P ( w , n ) = ( 1 - &beta; u ) D P ( w , n ) + &beta; u N D P ( w , n - 1 ) , D P ( w , n ) &GreaterEqual; N D P ( w , n - 1 ) ( 1 - &beta; d ) D P ( w , n ) + &beta; d N D P ( w , n - 1 ) , D P ( w , n ) < N D P ( w , n - 1 )
Wherein, β u, β dfor predetermined coefficient and 0 < β d< β u< 1.
The present invention utilizes generator 1 to generate electricity, power for electric substrate 3-5, electricity consumption is convenient, by variable valve input 2-1 and container 2-3 be combined be beneficial to easy to use, long service life, it is convenient to be heated by heater strip 4-3 and heat accumulation plate 4-4, safety durable, thus raising heats, display screen 3-1 is utilized to improve intelligence degree transmission signal, by being arranged on the two ends adjustable nut of handle 7, be conducive to fixing stretching convenient, Universal wheel structure 8-5 is utilized to move, be conducive to playing protective effect under the cooperation of guard shield 12, complete be conducive to easy to use, reduce power consumption, increase work efficiency, reduce work degree, safe and reliable, long service life, thus consummating function diversity, and then reduction maintenance cost, carry out infrared temperature monitoring by device for monitoring temperature, gather response data and remote control experiment parameter, can ensure that reaction parameter is in the best in real time by real time and on line monitoring mould, the biofuel detection perform of production is excellent, good product consistency.
Utilize technical solutions according to the invention, or those skilled in the art being under the inspiration of technical solution of the present invention, designing similar technical scheme, and reach above-mentioned technique effect, is all fall into protection scope of the present invention.

Claims (5)

1. the production method of an abrasive biofuel, it is characterized in that, the production method of described abrasive biofuel utilizes electrical power generators, power for electric substrate, by variable valve input and the cooperation of container, from the biodiesel raw material oil containing lower fatty acid, remove foreign matter with sorbent material and dewater; By heater strip and heat accumulation plate heating, device for monitoring temperature is adopted to carry out infrared temperature monitoring; Making the biodiesel raw material through dehydration oily by being provided with reagent and the esterification device of Zeo-karb after being heated to assigned temperature, regulating pH, gathering response data and remote control experiment parameter by real time and on line monitoring mould.
2. the production method of abrasive biofuel as claimed in claim 1, is characterized in that, the production equipment that the method adopts comprises generator, supplementary structure, power generation assembly, temperature control unit, driving circuit, thermovent, filter processor, base device, vane, input terminus, handle and guard shield, described generator is arranged on the bottom position of base device; Described input terminus is arranged on the external right side position of filter processor; Described power generation assembly is arranged on the upper position of temperature control unit; Described driving circuit is arranged on the leftward position of vane; Described thermovent is arranged on the tip position of power generation assembly; Described supplementary structure is arranged on the upper position of thermovent, and described handle is arranged on the leftward position of filter processor; Described guard shield is arranged on temperature control unit external position; Described power generation assembly comprises, acousto-optic electric organ, display screen, resistance, storage batteries, and for electric substrate and wireless IC chip, described acousto-optic electric organ is arranged on the leftward position of resistance;
Described display screen is arranged on the top of resistance by being electrically connected, the described display screen the superiors are panels, and described panel is acrylic material, are LCD plate below described panel, are backlight below described LCD plate; Described storage batteries is arranged on the bottom of display screen by being electrically connected; The described bottom being arranged on display screen for electric substrate by electric connection; Described wireless IC chip is arranged on the leftward position for electric substrate;
Described temperature control unit comprises vertical tube, rotating cylinder, safeguard construction and beam seat structure, and described vertical tube is arranged on the mid-way of rotating cylinder, and described safeguard construction is arranged on the upper position of beam seat structure; Described safeguard construction comprises alarming horn, cancel switch, temperature sensing sheet, cutting type button and warning shell, and described cancel switch is arranged on the leftward position of cutting type button;
Described alarming horn is arranged on the leftward position of cutting type button; Described temperature sensing sheet is arranged on the lower position of alarming horn and cancel switch; Described warning shell is arranged on the external position of cancel switch; Described beam seat structure comprises slide block, electric elements, elevating bracket, guide rail and web plate, and described slide block is arranged on the upper position of guide rail, and described web plate is arranged on the lower position of slide block; Described electric elements are arranged on the upper position of slide block; Described elevating bracket is arranged on the lower position of web plate;
Described base device comprises base frame, bottom tub, fixing buckle, bracket component and Universal wheel structure, and described base frame is arranged on the external position of bottom tub, and described Universal wheel structure is arranged on the bottom position of bracket component; Described fixing buckle is arranged on the external position of base frame;
Described Universal wheel structure comprises setting nut, bearing, universal rolling wheel and support bar, and described setting nut is arranged on support bar external position, and described bearing is arranged on the lower position of support bar;
Described universal rolling wheel is arranged on the external position of bearing; Described supplementary structure comprises variable valve input, power switch button and container, and described variable valve input is arranged on the leftward position of power switch button; Described container is arranged on the bottom of power switch button.
3. the production method of abrasive biofuel as claimed in claim 1, it is characterized in that, described infrared temperature monitoring obtains the production vessel surface temperature of abrasive biofuel according to infrared spectral radiant, infrared spectra emittance has approximately uniform linear relationship at selected wavelength place and temperature, that is:
ε i2=ε i1[1+k(T 2-T 1)]
In formula, ε i1be wavelength be λ i, spectral emittance when temperature is T1; ε i2be wavelength be λ i, spectral emittance when temperature is T2; T1, T2 are respectively two not temperature in the same time; K is coefficient;
Note V i1be first temperature T 1under the output signal of i-th passage, note V i2be first temperature T 2under the output signal of i-th passage, T 1emissivity ε at temperature i1∈ (0,1), by random selecting one group of ε i1, calculated at parameter ε by following formula i1the lower actual T obtained i1:
T i 1 = 1 1 T &prime; + &lambda; t c 2 ln &epsiv; i 1 V i &prime; V i 2
If k is ∈ (-η, η), by random selecting k, at second temperature T 2under emissivity ε i2expression formula be:
&epsiv; i 2 = &epsiv; i 1 &lsqb; 1 + k ( T i 2 - T i 1 ) &rsqb;
Calculated at parameter ε by following formula i1the lower actual T obtained i2:
T i 2 = 1 1 T &prime; + &lambda; i c 2 ln &epsiv; i 1 &lsqb; 1 + k ( T i 2 - T i 1 ) &rsqb; V i &prime; V i 2 .
4. the production method of abrasive biofuel as claimed in claim 1, it is characterized in that, the described built-in sound identification module of real time and on line monitoring mould, comprises frequency analysis unit, phase curve computing unit, error calculation unit, voice signal recognition unit;
Described frequency analysis unit, analyzes the frequency signal of voice signal;
Described phase curve computing unit, calculates the phase curve carrying out with the time variations of the phase place of described frequency signal being similar to;
Described error calculation unit, calculates the error between described phase curve and the phase place of described frequency signal;
Described voice signal recognition unit, identifies the signal whether described voice signal is periodic sound based on described error.
5. the production method of abrasive biofuel as claimed in claim 1, it is characterized in that, described sound identification module is for each road voice signal, according to the following equation noise tracking is carried out to each the frame voice signal in described voice signal, obtain the noise spectrum N (w, n) of each frame voice signal:
N ( w , n ) = ( 1 - &alpha; u ) | X ( w , n ) | + &alpha; u N ( w , n - 1 ) , | X ( w , n ) | &GreaterEqual; N ( w , n - 1 ) ( 1 - &alpha; d ) | X ( w , n ) | + &alpha; d N ( w , n - 1 ) , | X ( w , n ) | < N ( w , n - 1 ) ;
Wherein, X (w, n) represents the Short Time Fourier Transform of described voice signal; α u, α dfor predetermined coefficient and 0 < α d< α u< 1; W represents the frequency sequence number on frequency domain; N represents the frame number in time domain;
According to the following equation binary conversion treatment is carried out to the Short Time Fourier Transform of each frame voice signal and obtains two-value spectrum Xb (w, n):
X b ( w , n ) = 1 , | X ( w , n ) | - N ( w , n ) > T b 0 , | X ( w , n ) | - N ( w , n ) &le; T b
T bfor preset first threshold value;
Ka corresponding for wherein road voice signal two-value spectrum Kb the two-value corresponding with another road voice signal is composed the coherency between carrying out between two to mate and obtain described first matching result, described first matching result comprises matched position corresponding to one group of the highest two-value spectrum of matching degree and matching degree, and Ka, Kb are positive integer;
For each road voice signal, calculate the power spectrum P (w, n) of each the frame voice signal in described voice signal according to the following equation:
P(w,n)=α pP(w,n-1)+(1-α p)|X(w,n)| 2
Wherein, X (w, n) represents the Short Time Fourier Transform of described voice signal;
α pfor predetermined coefficient and 0 < α p< 1; W represents the frequency sequence number on frequency domain; N represents the frame number in time domain;
Calculate the Spectral correlation DP (w, n) of the power spectrum of each frame voice signal according to the following equation:
DP(w,n)=|P(w+1,n)-P(w,n)|
According to the following equation noise tracking is carried out to described Spectral correlation DP (w, n), obtains the Spectral correlation NDP (w, n) of the noise power spectrum of each frame voice signal:
N D P ( w , n ) = ( 1 - &beta; u ) D P ( w , n ) + &beta; u N D P ( w , n - 1 ) , D P ( w , n ) &GreaterEqual; N D P ( w , n - 1 ) ( 1 - &beta; d ) D P ( w , n ) + &beta; d N D P ( w , n - 1 ) , D P ( w , n ) < N D P ( w , n - 1 )
Wherein, β u, β dfor predetermined coefficient and 0 < β d< β u< 1.
CN201511016967.XA 2015-12-31 2015-12-31 Production apparatus of high cleanness biodiesel, and method thereof Pending CN105567434A (en)

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CN107037838A (en) * 2017-06-16 2017-08-11 内蒙古工业大学 A kind of temperature control HVAC with detection means and its control method

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CN104321415A (en) * 2013-03-20 2015-01-28 株式会社Menergy Method for preparing biodiesel
CN104700842A (en) * 2015-02-13 2015-06-10 广州市百果园网络科技有限公司 Sound signal time delay estimation method and device
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