CN105562430A - Method for improving mechanical strength of nonmagnetic textured copper-nickel alloy composite base band - Google Patents

Method for improving mechanical strength of nonmagnetic textured copper-nickel alloy composite base band Download PDF

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Publication number
CN105562430A
CN105562430A CN201510988105.7A CN201510988105A CN105562430A CN 105562430 A CN105562430 A CN 105562430A CN 201510988105 A CN201510988105 A CN 201510988105A CN 105562430 A CN105562430 A CN 105562430A
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billet
corronil
copper
nickel
rolling
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刘志勇
黎文峰
楚庄
杨枫
何庭伟
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Henan Normal University
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Henan Normal University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/02Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling heavy work, e.g. ingots, slabs, blooms, or billets, in which the cross-sectional form is unimportant ; Rolling combined with forging or pressing
    • B21B1/024Forging or pressing
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/02Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling heavy work, e.g. ingots, slabs, blooms, or billets, in which the cross-sectional form is unimportant ; Rolling combined with forging or pressing
    • B21B1/026Rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/38Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling sheets of limited length, e.g. folded sheets, superimposed sheets, pack rolling
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C1/00Making non-ferrous alloys
    • C22C1/02Making non-ferrous alloys by melting
    • C22C1/03Making non-ferrous alloys by melting using master alloys
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/10Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of nickel or cobalt or alloys based thereon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B1/00Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
    • B21B1/02Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling heavy work, e.g. ingots, slabs, blooms, or billets, in which the cross-sectional form is unimportant ; Rolling combined with forging or pressing
    • B21B2001/022Blooms or billets
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B21MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
    • B21BROLLING OF METAL
    • B21B3/00Rolling materials of special alloys so far as the composition of the alloy requires or permits special rolling methods or sequences ; Rolling of aluminium, copper, zinc or other non-ferrous metals
    • B21B2003/005Copper or its alloys

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Metal Rolling (AREA)

Abstract

The invention discloses a method for improving the mechanical strength of a nonmagnetic textured copper-nickel alloy composite base band and belongs to the technical field of textured metal base bands for reinforcing high-temperature coating superconductors. According to the technical scheme, the method for improving the mechanical strength of the nonmagnetic textured copper-nickel alloy composite base band is characterized by mainly comprising the steps of preparation of an initial copper-nickel alloy composite billet, rolling of the initial copper-nickel alloy composite billet and recrystallization heat treatment. The operation method is simple, practical, low in cost and suitable for industrial production, and the copper-nickel alloy composite base band which is nonmagnetic, high in strength and strong in cubic texture is finally prepared.

Description

A kind of method improving nonmagnetic texture corronil composite baseband mechanical strength
Technical field
The present invention relates to a kind of method improving nonmagnetic texture corronil composite baseband mechanical strength, belong to strengthening high temperature coating superconductor textured metal baseband technology field.
Background technology
From YBa in 1987 2cu 3o 7-δsince high temperature superconducting materia is found, reduce its manufacture difficulty, make it be easy to suitability for industrialized production and become the main research direction of scientists, high temperature coating superconductor material is a kind of functional material with excellent performance, and obtains the basis that high performance ductile metal substrate is the high temperature coating superconductor wire band that processability is excellent.At present, Ni5W alloy base band is commercially produced, but because it has ferromagnetism in liquid nitrogen temperature, can magnetic hystersis loss be caused in the application of alternating current, prepare nonmagnetic, that strength texture metal base band is the development of coating superconducting textured metal base band important directions.Research shows, along with the rising of W atom content, the Curie temperature of nickel-tungsten alloy base-band reduces gradually, and mechanical strength raises gradually, but is difficult to obtain strong cubic texture by traditional textured metal base band preparation method on nickel-tungsten alloy base-band surface when W atomic percentage conc is greater than after 5%.Research finds, the content of copper is when more than 54at.%, copper-nickel alloy base band is without ferromagnetic under liquid nitrogen temperature, and the price of copper relative to nickel and tungsten more cheap, but the yield strength of copper-nickel alloy base band is lower, in order to increase the mechanical strength of copper-nickel alloy base band, publication number is the preparation method that patent discloses a kind of nonmagnetic cubic texture acid bronze alloy composite baseband of CN101786352A, isostatic cool pressing and discharge plasma sintering base route is adopted to prepare nonmagnetic copper nickel composite baseband, its skin is nonmagnetic copper-nickel alloy, sandwich layer is high-strength nickel tungsten alloy, compared with corresponding individual layer copper-nickel alloy base band, copper nickel composite baseband effectively improves the overall mechanical strength of base band, but need the long heat treatment of high temperature after adopting isostatic cool pressing to suppress in this patent, add production cost, and the composite billet ingot surface compactness adopting isostatic cool pressing base route to obtain is poor, be unfavorable for the high performance transition zone of subsequently epitaxial growing and superconducting layer, the equipment of discharge plasma sintering is more complicated, and maintenance cost is higher, is not suitable for suitability for industrialized production, and therefore, the high-performance copper nickel composite baseband how successfully preparing low cost is the new challenge of suitability for industrialized production textured metal base band one of facing.
Summary of the invention
The object of this invention is to provide a kind of method improving nonmagnetic texture corronil composite baseband mechanical strength, the method improve the mechanical strength of individual layer copper-nickel alloy base band, reduce production cost, prepared without ferromagnetism, high strength, strong cubic texture corronil composite baseband.
The present invention adopts following technical scheme for achieving the above object, and a kind of method improving nonmagnetic texture corronil composite baseband mechanical strength, is characterized in that comprising the following steps:
Step S100: the preparation of initial corronil compound billet
Step S101: the weight percentage adopting vacuum induction melting to obtain nickel to be respectively the copper-nickel alloy ingot casting of 55% ~ 57% and the atomic percentage conc of tungsten be 8.2% ~ 8.7% nickel tungsten ingot casting;
Step S102: the copper-nickel alloy ingot casting obtained step S101 respectively and nickel tungsten ingot casting carry out high temperature forging and hot rolling;
Step S103: will be the cuboid of 15mm × 10mm × 1.5mm through the hot-rolled copper Ni alloy ingot of step S102 process and the equal cut growth of nickel tungsten ingot casting × wide × height, then with 200# waterproof abrasive paper, surface finish is carried out to hot-rolled copper Ni alloy ingot and nickel tungsten ingot casting and obtain corronil billet and nickel tungsten billet;
Step S104: be defined as A and B respectively by through the corronil billet of step S103 process and nickel tungsten billet, A and B is stacked together according to the order of A-B-A, finally adopts spot welding or roll welding to be welded together by three-layer alloy billet along the surrounding of alloy billet and obtain initial corronil compound billet;
Step S200: the rolling of initial corronil compound billet and dynamic recrystallization treatment
Step S201: the initial corronil compound billet obtained by step S104 carries out warm-rolling, and warm-rolling technique is: be rolled after 1 hour 350 DEG C of insulations by initial corronil compound billet, rolling only has a time, and deflection is 50%;
Step S202: carry out cold rolling to the compound billet through step S201 process, pass deformation is 10%, and total deformation is 93%;
Step S203: the compound billet through step S202 process is carried out dynamic recrystallization treatment, and Technology for Heating Processing is: 850 DEG C insulation 40 ~ 60min, final obtained without ferromagnetism, high strength, strong cubic texture corronil composite baseband.
The texture corronil composite baseband prepared by method of the present invention has following characteristics:
1, the present invention obtains the cladding material of corronil as compound billet using melting base route, and the composite baseband surface soundness obtained is good;
2, polish in initial for ectonexine billet surface by the present invention, increases the roughness on ectonexine billet surface, in warm-rolling process, enhance inter-layer bonding force, avoids cracking or layering;
3, adopt the method for spot welding or roll welding to be welded together by three-layer alloy billet and obtain initial corronil compound billet, method of operating is simple, practical and with low cost, is applicable to suitability for industrialized production;
4, adopt warm-rolling to carry out large pass deformation, realize larger roll-force rolling, easier rolling success, adds lumber recovery;
5, the recrystallization technique that the present invention adopts makes ectonexine atom carry out counterdiffusion and then obtains overall non-magnetic strong cubic texture copper nickel composite baseband.
Accompanying drawing explanation
Fig. 1 is (001) pole, face figure on the corronil composite baseband surface that the embodiment of the present invention 1 obtains;
Fig. 2 is (001) pole, face figure on the corronil composite baseband surface that the embodiment of the present invention 2 obtains.
Detailed description of the invention
The present invention is further described below in conjunction with embodiment.It is noted that the present invention is not limited to following each embodiment.
Embodiment 1
Step S100: the preparation of initial copper nickel compound billet
Step S101: the weight percentage adopting vacuum induction melting to obtain nickel to be respectively the copper-nickel alloy ingot casting of 56% and the atomic percentage conc of tungsten be 8.3% nickel tungsten ingot casting;
Step S102: respectively high temperature forging and hot rolling are carried out to the two kinds of alloy cast ingots obtained in step S101;
Step S103: the cuboid by two kinds of equal cut growths of the hot rolled alloy ingot casting × wide × height through step S102 process being 15mm × 10mm × 1.5mm, obtains corronil billet and nickel tungsten billet with 200# waterproof abrasive paper to after two kinds of hot rolled alloy ingot casting surface finish;
Step S104: be defined as A and B respectively by through the corronil billet of step S103 process and nickel tungsten billet, A and B is stacked together according to the order of A-B-A, finally adopts spot welding or roll welding to be welded together by three-layer alloy billet along the surrounding of alloy billet and obtain initial corronil compound billet;
Step S200: the rolling of initial corronil compound billet and dynamic recrystallization treatment
Step S201: the initial corronil compound billet obtained by step S104 carries out warm-rolling, and warm-rolling technique is: be rolled after 1 hour 350 DEG C of insulations by initial corronil compound billet, rolling only has a time, and deflection is 50%;
Step S202: carry out cold rolling to the compound billet through step S201 process, pass deformation is 10%, and total deformation is 93%;
Step S203: the compound billet through step S202 process is carried out dynamic recrystallization treatment, and Technology for Heating Processing is: 850 DEG C insulation 45min, final obtained without ferromagnetism, high strength, strong cubic texture corronil composite baseband.
As shown in Figure 1, obtained corronil composite baseband yield strength is at room temperature 225MPa to (001) pole, face figure on this corronil composite baseband surface, and yield strength obtains obvious improvement compared with corresponding individual layer copper-nickel alloy base band.
Embodiment 2
Step S100: the preparation of initial corronil compound billet
Step S101: the weight percentage adopting vacuum induction melting to obtain nickel to be respectively the copper-nickel alloy ingot casting of 57% and the atomic percentage conc of tungsten be 8.7% nickel tungsten ingot casting;
Step S102: respectively high temperature forging and hot rolling are carried out to two kinds of alloy cast ingots that step S101 obtains;
Step S103: the cuboid by two kinds of equal cut growths of the hot rolled alloy ingot casting × wide × height through step S102 process being 15mm × 10mm × 1.5mm, obtains corronil billet and nickel tungsten billet with 200# waterproof abrasive paper to after two kinds of hot rolling ingot surface finish;
Step S104: be defined as A and B respectively by through the corronil billet of step S103 process and nickel tungsten billet, A and B is stacked together according to the order of A-B-A, finally adopts spot welding or roll welding to be welded together by three-layer alloy billet along the surrounding of alloy billet and obtain initial corronil compound billet;
Step S200: the rolling of initial corronil compound billet and dynamic recrystallization treatment
Step S201: the initial corronil compound billet obtained by step S104 carries out warm-rolling, and warm-rolling technique is: be rolled after 1 hour 350 DEG C of insulations by initial corronil compound billet, rolling only has a time, and deflection is 50%;
Step S202: carry out cold rolling to the compound billet through step S201 process, pass deformation is 10%, and total deformation is 93%;
Step S203: the compound billet through step S202 process is carried out dynamic recrystallization treatment, and Technology for Heating Processing is: 850 DEG C insulation 60min, final obtained without ferromagnetism, high strength, strong cubic texture corronil composite baseband.
As shown in Figure 2, obtained corronil composite baseband yield strength is at room temperature 237MPa to (001) pole, face figure on this corronil composite baseband surface, and yield strength obtains obvious improvement compared with corresponding individual layer copper-nickel alloy base band.
Embodiment above describes general principle of the present invention, principal character and advantage; the technical staff of the industry should understand; the present invention is not restricted to the described embodiments; what describe in above-described embodiment and description just illustrates principle of the present invention; under the scope not departing from the principle of the invention; the present invention also has various changes and modifications, and these changes and improvements all fall in the scope of protection of the invention.

Claims (1)

1. improve a method for nonmagnetic texture corronil composite baseband mechanical strength, it is characterized in that comprising the following steps:
Step S100: the preparation of initial corronil compound billet
Step S101: the weight percentage adopting vacuum induction melting to obtain nickel to be respectively the copper-nickel alloy ingot casting of 55% ~ 57% and the atomic percentage conc of tungsten be 8.2% ~ 8.7% nickel tungsten ingot casting;
Step S102: the copper-nickel alloy ingot casting obtained step S101 respectively and nickel tungsten ingot casting carry out high temperature forging and hot rolling;
Step S103: will be the cuboid of 15mm × 10mm × 1.5mm through the hot-rolled copper Ni alloy ingot of step S102 process and the equal cut growth of nickel tungsten ingot casting × wide × height, then with 200# waterproof abrasive paper, surface finish is carried out to hot-rolled copper Ni alloy ingot and nickel tungsten ingot casting and obtain corronil billet and nickel tungsten billet;
Step S104: be defined as A and B respectively by through the corronil billet of step S103 process and nickel tungsten billet, A and B is stacked together according to the order of A-B-A, finally adopts spot welding or roll welding to be welded together by three-layer alloy billet along the surrounding of alloy billet and obtain initial corronil compound billet;
Step S200: the rolling of initial corronil compound billet and dynamic recrystallization treatment
Step S201: the initial corronil compound billet obtained by step S104 carries out warm-rolling, and warm-rolling technique is: be rolled after 1 hour 350 DEG C of insulations by initial corronil compound billet, rolling only has a time, and deflection is 50%;
Step S202: carry out cold rolling to the compound billet through step S201 process, pass deformation is 10%, and total deformation is 93%;
Step S203: the compound billet through step S202 process is carried out dynamic recrystallization treatment, and Technology for Heating Processing is: 850 DEG C insulation 40 ~ 60min, final obtained without ferromagnetism, high strength, strong cubic texture corronil composite baseband.
CN201510988105.7A 2015-12-28 2015-12-28 Method for improving mechanical strength of nonmagnetic textured copper-nickel alloy composite base band Pending CN105562430A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107068316A (en) * 2017-04-14 2017-08-18 河北工业大学 Cupro-nickel permendur strip and preparation method thereof
CN109531067A (en) * 2018-12-17 2019-03-29 河南师范大学 A kind of no ferromagnetism texture cupro-nickel/nickel tungsten composite baseband and preparation method thereof
CN111101007A (en) * 2020-01-13 2020-05-05 周口师范学院 Preparation method of high-performance nickel-based alloy composite strip

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050026788A1 (en) * 2002-01-02 2005-02-03 Jutta Kloewer Metal strip for epitaxial coatings and method for production thereof
CN101786352A (en) * 2010-01-15 2010-07-28 北京工业大学 Non-magnetic cube texture Cu-based alloy composite base band and preparation method thereof
CN102644003A (en) * 2011-02-16 2012-08-22 宋东升 High-strength high-conductivity corrosion-resistant rare earth-copper alloy and manufacturing method thereof
CN103008372A (en) * 2012-12-29 2013-04-03 北京工业大学 Method for preparing nonmagnetic cube-textured NiV alloy composite baseband
CN103924108A (en) * 2014-05-05 2014-07-16 河南师范大学 Nonmagnetic high-cube texture copper-base alloy composite base band and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20050026788A1 (en) * 2002-01-02 2005-02-03 Jutta Kloewer Metal strip for epitaxial coatings and method for production thereof
CN101786352A (en) * 2010-01-15 2010-07-28 北京工业大学 Non-magnetic cube texture Cu-based alloy composite base band and preparation method thereof
CN102644003A (en) * 2011-02-16 2012-08-22 宋东升 High-strength high-conductivity corrosion-resistant rare earth-copper alloy and manufacturing method thereof
CN103008372A (en) * 2012-12-29 2013-04-03 北京工业大学 Method for preparing nonmagnetic cube-textured NiV alloy composite baseband
CN103924108A (en) * 2014-05-05 2014-07-16 河南师范大学 Nonmagnetic high-cube texture copper-base alloy composite base band and preparation method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107068316A (en) * 2017-04-14 2017-08-18 河北工业大学 Cupro-nickel permendur strip and preparation method thereof
CN107068316B (en) * 2017-04-14 2018-11-16 河北工业大学 Cupro-nickel permendur strip and preparation method thereof
CN109531067A (en) * 2018-12-17 2019-03-29 河南师范大学 A kind of no ferromagnetism texture cupro-nickel/nickel tungsten composite baseband and preparation method thereof
CN111101007A (en) * 2020-01-13 2020-05-05 周口师范学院 Preparation method of high-performance nickel-based alloy composite strip
CN111101007B (en) * 2020-01-13 2022-02-25 周口师范学院 Preparation method of high-performance nickel-based alloy composite strip

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