CN105561951A - Preparation method of composite resin having oil smoke adsorption and air filtering performance - Google Patents
Preparation method of composite resin having oil smoke adsorption and air filtering performance Download PDFInfo
- Publication number
- CN105561951A CN105561951A CN201510952186.5A CN201510952186A CN105561951A CN 105561951 A CN105561951 A CN 105561951A CN 201510952186 A CN201510952186 A CN 201510952186A CN 105561951 A CN105561951 A CN 105561951A
- Authority
- CN
- China
- Prior art keywords
- parts
- oil smoke
- preparation
- resin
- compound resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/02—Loose filtering material, e.g. loose fibres
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/02—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
- B01J20/10—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
- B01J20/12—Naturally occurring clays or bleaching earth
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/24—Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
- B01J20/26—Synthetic macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
- B01J20/28—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties
- B01J20/28014—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof characterised by their form or physical properties characterised by their form
- B01J20/28042—Shaped bodies; Monolithic structures
- B01J20/28045—Honeycomb or cellular structures; Solid foams or sponges
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Analytical Chemistry (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Dispersion Chemistry (AREA)
- Geochemistry & Mineralogy (AREA)
- Inorganic Chemistry (AREA)
- Solid-Sorbent Or Filter-Aiding Compositions (AREA)
Abstract
The invention discloses a preparation method of composite resin having oil smoke adsorption and air filtering performance. The preparation method comprises the following steps: (1) mixing raw materials; (2) performing radiation crosslinking; (3) mixing with resin; and (4) washing and drying. According to the preparation method of composite resin having oil smoke adsorption and air filtering performance, the composite resin has high porosity and structural strength due to creative preparation process based on scientific and reasonable formulation design, can effectively improve the oil smoke and air adsorption performance, has good adsorptivity and excellent overall performance, and has remarkable effect on improvement of air environment quality.
Description
Technical field
The present invention relates to oil-absorbing resin field, particularly relate to a kind of preparation method with the compound resin of oil smoke absorption and air filtration performance.
Background technology
In recent years, haze becomes the global problem of harm air quality safety, receives the very big concern of various countries.Administer haze timely and effectively, reduce PM2.5 to improve the consistent hope that ambient air quality is the people of various countries.In formation air-polluting pollution sources, cooking fume pollutes has become the third-largest air pollution source being only second to industrial pollution and traffic pollution.Cooking fume gas pollutes and mainly contains two aspects: one is that food and edible oil generate a large amount of thermal decomposition product in high-temperature cooking; Two is the part oil vapours also contained in cooking fume.The former mainly contains the aromatic compound such as alkane, alkene, aldehyde, ketone, alcohol, ester of effumability and the heterocyclic compound of severe toxicity, and wherein polycyclic aromatic hydrocarbon compounds is strong carcinogen; The latter easily with mix dust or reaction, increased the weight of atmosphere pollution, it has very strong suction-operated in addition, is attached on trees flowers and plants, and the photosynthesis of obstruction vegetation, causes its withered death, be attached to building surface and form dirt, having a strong impact on the appearance of the city.
Existing oil smoke sorbing material exists that adsorbance is low, complicated process of preparation, do not have the shortcomings such as universality to air filtration performance, and practicality is low.
Summary of the invention
The technical problem that the present invention mainly solves is to provide a kind of preparation method with the compound resin of oil smoke absorption and air filtration performance, can solve the above-mentioned shortcoming that existing oil smoke sorbing material exists, improve its serviceability.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: provide a kind of preparation method with the compound resin of oil smoke absorption and air filtration performance, comprise the steps:
(1) raw material mixing: taking weight portion is the methyl methacrylate of 30 ~ 40 parts, the butyl methacrylate of 40 ~ 50 parts, the kaolin of 5 ~ 15 parts, the enhancing adsorbing fiber of 20 ~ 35 parts, the N of 2 ~ 5 parts, N-methylene-bisacrylamide, the isopropyl alcohol of 1 ~ 3 part, the oxidation formamide of 0.5 ~ 1 part, the antioxidant of 0.5 ~ 1 part and 1 ~ 2 part of first blowing agent are inserted in the reaction vessel of band heating agitating function, then appropriate amount of deionized water is added, be warming up to 60 ~ 80 DEG C, be uniformly mixed to evenly;
(2) crosslinking with radiation: the mixture obtained in step (1) is proceeded in quartz reactor, and then insert in microwave reaction stove and carry out crosslinking with radiation reaction, obtain fretting map crosslinked resin;
(3) mixed with resin: add the second blowing agent that weight is the epoxy resin of 30 ~ 50 parts, the silica gel of 10 ~ 20 parts, the zinc oxide of 2 ~ 5 parts and 3 ~ 5 parts in the microfarad bubble crosslinked resin obtained in step (2), magnetic agitation is to even, then proceed in quartz reactor, insert again in microwave reaction stove and carry out crosslinking with radiation reaction, obtain the compound resin that foams;
(4) washing is dry: by the foaming compound resin washing in step (3), then at vacuum tank inner drying, have the compound resin of oil smoke absorption and air filtration performance described in obtaining.
In a preferred embodiment of the present invention, in described step (1), described enhancing adsorbing fiber is that carbon fiber, bamboo fibre and polypropylene fibre are with the mixture of mass ratio 2 ~ 3:1 ~ 2:1; Described first blowing agent is POLYPROPYLENE GLYCOL formal.
In a preferred embodiment of the present invention, in described step (2), the condition of described crosslinking with radiation is: temperature 100 DEG C, power 800 ~ 1200W/L, time 2 ~ 3h.
In a preferred embodiment of the present invention, in described step (3), described second blowing agent is AC blowing agent.
In a preferred embodiment of the present invention, in described step (3), the condition of described crosslinking with radiation is: temperature 150 DEG C, power 1000 ~ 1500W/L, time 2 ~ 3h.
The invention has the beneficial effects as follows: a kind of preparation method with the compound resin of oil smoke absorption and air filtration performance of the present invention, on the basis of scientific and reasonable formula Design, by creationary preparation technology, give the higher porosity of compound resin and structure strong team, effectively improve its absorption property to oil smoke and air, there is good adsorptivity, excellent combination property, to improving quality of air environment, there is significant benefit.
Detailed description of the invention
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
The embodiment of the present invention comprises:
Embodiment 1
There is a preparation method for the compound resin of oil smoke absorption and air filtration performance, comprise the steps:
(1) raw material mixing: taking weight portion is the methyl methacrylate of 30 parts, the butyl methacrylate of 40 parts, the kaolin of 5 parts, the enhancing adsorbing fiber of 20 parts, the N of 2 parts, N-methylene-bisacrylamide, the isopropyl alcohol of 1 part, the oxidation formamide of 0.5 part, the antioxidant of 0.5 part and 1 part of first blowing agent POLYPROPYLENE GLYCOL formal are inserted in the reaction vessel of band heating agitating function, then appropriate amount of deionized water is added, be warming up to 60 ~ 80 DEG C, be uniformly mixed to evenly; Described enhancing adsorbing fiber is that carbon fiber, bamboo fibre and polypropylene fibre are with the mixture of mass ratio 2:1:1;
(2) crosslinking with radiation: the mixture obtained in step (1) is proceeded in quartz reactor, and then insert in microwave reaction stove, temperature be 100 DEG C, power be 800W/L condition under crosslinking with radiation reaction 3h, obtain fretting map crosslinked resin;
(3) mixed with resin: add the second blowing agent AC that weight is the epoxy resin of 30 parts, the silica gel of 10 parts, the zinc oxide of 2 parts and 3 parts in the microfarad bubble crosslinked resin obtained in step (2), magnetic agitation 30 ~ 60min is to even, then proceed in quartz reactor, insert in microwave reaction stove again, it is 150 DEG C in temperature, power is crosslinking with radiation reaction 3h under the condition of 1000W/L, obtains the compound resin that foams;
(4) washing is dry: by the foaming compound resin washing in step (3), then at 0.1 ~ 0.3MPa, the vacuum tank inner drying of 50 ~ 60 DEG C, has the compound resin of oil smoke absorption and air filtration performance described in obtaining.
Embodiment 2
There is a preparation method for the compound resin of oil smoke absorption and air filtration performance, comprise the steps:
(1) raw material mixing: taking weight portion is the methyl methacrylate of 40 parts, the butyl methacrylate of 50 parts, the kaolin of 15 parts, the enhancing adsorbing fiber of 35 parts, the N of 5 parts, N-methylene-bisacrylamide, the isopropyl alcohol of 3 parts, the oxidation formamide of 1 part, the antioxidant of 1 part and 2 part of first blowing agent POLYPROPYLENE GLYCOL formal are inserted in the reaction vessel of band heating agitating function, then appropriate amount of deionized water is added, be warming up to 60 ~ 80 DEG C, be uniformly mixed to evenly; Described enhancing adsorbing fiber is that carbon fiber, bamboo fibre and polypropylene fibre are with the mixture of mass ratio 3:2:1;
(2) crosslinking with radiation: the mixture obtained in step (1) is proceeded in quartz reactor, and then insert in microwave reaction stove, temperature be 100 DEG C, power be 1200W/L condition under crosslinking with radiation reaction 2h, obtain fretting map crosslinked resin;
(3) mixed with resin: add the second blowing agent AC that weight is the epoxy resin of 50 parts, the silica gel of 20 parts, the zinc oxide of 5 parts and 5 parts in the microfarad bubble crosslinked resin obtained in step (2), magnetic agitation 30 ~ 60min is to even, then proceed in quartz reactor, insert in microwave reaction stove again, it is 150 DEG C in temperature, power is crosslinking with radiation reaction 2h under the condition of 1500W/L, obtains the compound resin that foams;
(4) washing is dry: by the foaming compound resin washing in step (3), then at 0.1 ~ 0.3MPa, the vacuum tank inner drying of 50 ~ 60 DEG C, has the compound resin of oil smoke absorption and air filtration performance described in obtaining.
The compound resin that said method is obtained, is mixed with high adsorption silica gel, has higher porosity, therefore have good essential absorption property to oil smoke and air plankton by foaming, and learnt by absorption test, it reaches more than 80% to effective purifying rate of oil smoke.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (5)
1. there is a preparation method for the compound resin of oil smoke absorption and air filtration performance, it is characterized in that, comprise the steps:
(1) raw material mixing: taking weight portion is the methyl methacrylate of 30 ~ 40 parts, the butyl methacrylate of 40 ~ 50 parts, the kaolin of 5 ~ 15 parts, the enhancing adsorbing fiber of 20 ~ 35 parts, the N of 2 ~ 5 parts, N-methylene-bisacrylamide, the isopropyl alcohol of 1 ~ 3 part, the oxidation formamide of 0.5 ~ 1 part, the antioxidant of 0.5 ~ 1 part and 1 ~ 2 part of first blowing agent are inserted in the reaction vessel of band heating agitating function, then appropriate amount of deionized water is added, be warming up to 60 ~ 80 DEG C, be uniformly mixed to evenly;
(2) crosslinking with radiation: the mixture obtained in step (1) is proceeded in quartz reactor, and then insert in microwave reaction stove and carry out crosslinking with radiation reaction, obtain fretting map crosslinked resin;
(3) mixed with resin: add the second blowing agent that weight is the epoxy resin of 30 ~ 50 parts, the silica gel of 10 ~ 20 parts, the zinc oxide of 2 ~ 5 parts and 3 ~ 5 parts in the microfarad bubble crosslinked resin obtained in step (2), magnetic agitation is to even, then proceed in quartz reactor, insert again in microwave reaction stove and carry out crosslinking with radiation reaction, obtain the compound resin that foams;
(4) washing is dry: by the foaming compound resin washing in step (3), then at vacuum tank inner drying, have the compound resin of oil smoke absorption and air filtration performance described in obtaining.
2. the preparation method with the compound resin of oil smoke absorption and air filtration performance according to claim 1, it is characterized in that, in described step (1), described enhancing adsorbing fiber is that carbon fiber, bamboo fibre and polypropylene fibre are with the mixture of mass ratio 2 ~ 3:1 ~ 2:1; Described first blowing agent is POLYPROPYLENE GLYCOL formal.
3. the preparation method with the compound resin of oil smoke absorption and air filtration performance according to claim 1, it is characterized in that, in described step (2), the condition of described crosslinking with radiation is: temperature 100 DEG C, power 800 ~ 1200W/L, time 2 ~ 3h.
4. the preparation method with the compound resin of oil smoke absorption and air filtration performance according to claim 1, it is characterized in that, in described step (3), described second blowing agent is AC blowing agent.
5. the preparation method with the compound resin of oil smoke absorption and air filtration performance according to claim 1, it is characterized in that, in described step (3), the condition of described crosslinking with radiation is: temperature 150 DEG C, power 1000 ~ 1500W/L, time 2 ~ 3h.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510952186.5A CN105561951A (en) | 2015-12-18 | 2015-12-18 | Preparation method of composite resin having oil smoke adsorption and air filtering performance |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510952186.5A CN105561951A (en) | 2015-12-18 | 2015-12-18 | Preparation method of composite resin having oil smoke adsorption and air filtering performance |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105561951A true CN105561951A (en) | 2016-05-11 |
Family
ID=55872907
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510952186.5A Pending CN105561951A (en) | 2015-12-18 | 2015-12-18 | Preparation method of composite resin having oil smoke adsorption and air filtering performance |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105561951A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110373107A (en) * | 2019-07-31 | 2019-10-25 | 广东美的厨房电器制造有限公司 | Self-cleaning coating composition, coating and its coating and kitchen electric equipment |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050101482A1 (en) * | 2001-08-16 | 2005-05-12 | Juuro Aoyagi | Novel adsorbent |
| CN104231149A (en) * | 2014-08-15 | 2014-12-24 | 太仓康盛化工有限公司 | Porous microcapsule adsorptive resin and preparation method thereof |
| CN105107263A (en) * | 2015-07-30 | 2015-12-02 | 安徽凤凰滤清器股份有限公司 | Filtering material for sterilizing and disinfecting air with oil smoke and preparation method thereof |
-
2015
- 2015-12-18 CN CN201510952186.5A patent/CN105561951A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20050101482A1 (en) * | 2001-08-16 | 2005-05-12 | Juuro Aoyagi | Novel adsorbent |
| CN104231149A (en) * | 2014-08-15 | 2014-12-24 | 太仓康盛化工有限公司 | Porous microcapsule adsorptive resin and preparation method thereof |
| CN105107263A (en) * | 2015-07-30 | 2015-12-02 | 安徽凤凰滤清器股份有限公司 | Filtering material for sterilizing and disinfecting air with oil smoke and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 中国室内装饰协会室内环境监测工作委员会: "《室内环境污染治理技术与应用》", 31 August 2005, 机械工业出版社 * |
| 周学双等: "《石化化工企业挥发性有机物污染源排查及估算方法研究与实践》", 30 June 2015, 中国环境出版社 * |
| 杨明: "《塑料添加剂应用手册》", 28 February 2002, 江苏科学技术出版社 * |
| 陈泽森等: "《水性建筑涂料生产技术》", 31 January 2007, 中国纺织出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110373107A (en) * | 2019-07-31 | 2019-10-25 | 广东美的厨房电器制造有限公司 | Self-cleaning coating composition, coating and its coating and kitchen electric equipment |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105480974B (en) | A kind of preparation method of high yield mesoporous activated carbon | |
| CN103768753B (en) | A kind of extinguishing chemical containing modification medical stone powder | |
| CN104998620B (en) | A kind of modified peanut charcoal/aluminium polychloride sludge composite adsorbing material | |
| CN103059503A (en) | Phenolic foam plastics and preparation method thereof and preparation method of foam carbon | |
| CN109589779B (en) | Multifunctional bio-based formaldehyde capture agent and preparation method thereof | |
| CN104226267A (en) | Magnetic cellulose/graphene oxide composite adsorbent and preparation method thereof | |
| CN106115699A (en) | Zinc oxide method prepares activated carbon | |
| CN102838112B (en) | Preparation method of activated carbon | |
| CN102600715B (en) | Method for absorbing carbon dioxide by using mixed solution containing ionic liquid | |
| CN105561951A (en) | Preparation method of composite resin having oil smoke adsorption and air filtering performance | |
| CN108117526A (en) | A kind of alkynyl functionalization covalent organic frame material and its synthetic method and application | |
| CN105536732A (en) | Composite resin with oil smoke adsorption and air filtration performance | |
| CN109265732A (en) | A kind of preparation method of oil absorption material | |
| CN104449755B (en) | A kind of hydrophobicity sand and preparation method thereof | |
| CN106751469B (en) | A kind of fluorine titanium Hybrid fire retardant and the preparation method and application thereof | |
| CN106698419A (en) | Activated carbon prepared from leaf residues of cinnamomum longepaniculatum and preparation method of activated carbon | |
| CN104231149A (en) | Porous microcapsule adsorptive resin and preparation method thereof | |
| CN103467642A (en) | Preparation method of ethylene glycol dealdehyding resin | |
| CN114085427A (en) | Preparation method of phosphorus-containing flame retardant for decorative plate | |
| CN105332079A (en) | Preparing method for ablation-resistant molybdic acid phenyl ester modified high-ortho phenolic fibers | |
| CN105565316A (en) | Preparation method of ilmenite-pored walnut shell-based activated carbon | |
| CN112480467B (en) | Moisture-proof modified phenolic aldehyde heat-insulating material and preparation method thereof | |
| CN104530430A (en) | High-tenacity flame-retardant bismaleimide resin and preparation method thereof | |
| CN107876022B (en) | Preparation method of formaldehyde adsorbent | |
| CN109317105B (en) | Metal organic-framework material and preparation method and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160511 |
|
| WD01 | Invention patent application deemed withdrawn after publication |