CN105560076A - Hair conditioning composition capable of removing dandruff - Google Patents
Hair conditioning composition capable of removing dandruff Download PDFInfo
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- CN105560076A CN105560076A CN201610013830.7A CN201610013830A CN105560076A CN 105560076 A CN105560076 A CN 105560076A CN 201610013830 A CN201610013830 A CN 201610013830A CN 105560076 A CN105560076 A CN 105560076A
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/65—Collagen; Gelatin; Keratin; Derivatives or degradation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
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- A—HUMAN NECESSITIES
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- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/002—Preparations for repairing the hair, e.g. hair cure
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/59—Mixtures
- A61K2800/592—Mixtures of compounds complementing their respective functions
- A61K2800/5922—At least two compounds being classified in the same subclass of A61K8/18
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
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- A61K2800/596—Mixtures of surface active compounds
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Abstract
The invention discloses a hair conditioning composition capable of removing dandruff. The composition comprises the following components in percentage by weight: (a) 0.1 to 10% of fatty compound with a high melting point; (b) 0.01 to 5% of acyl amino amine, whose formula is R1CONH(CH2)mN(R2)2, wherein the R1 represents a C11-C24 residue of fatty acid, the R2 represents a C1-C4 alkyl group, and m represents an integer from 1 to 4; (c) an acid of 1-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, 1-glumatic acid hydrochloride, tartaric acid, and mixture thereof, wherein the mole ratio of aryl amino amine to the acid should be in a range of 1:0.1 to 1:0.9; (d) safe and effective amount of anti-dandruff agent; and (e) a water containing carrier. The provided hair conditioning composition can effectively remove dandruff, and is also capable of wetting, paving, and rinsing the hair. After the treatment, the hair has luster and dry hair is easy to comb.
Description
Technical field
The present invention relates to a kind of hair products, particularly relate to a kind of Wo 2008069000 containing dandruff removing agent.
Background technology
Market has developed various method and has carried out anti-dandruff conditioning hair, and these methods comprise hair conditioner on probation after hair washing, and such as leave and rinse-off products, to cleaning the shampoo with anti-dandruff conditioning hair with identical product.
Although some consumer likes using the shampoo containing anti-dandruff conditioner, but the consumer of quite a few ratio prefers to use conventional anti-dandruff conditioner composition, said composition as with the step of separating of having one's hair wash, be normally applied on hair after hair washing.Anti-dandruff care composition can be rinse-off products or leave product, can also be emulsion, cream, gel, spray and mousse.Like this kind of consumer of conventional conditioner compositions to compare and pay attention to anti-dandruff conditioning effect, the advantage of Antidaudruff hair conditioning composition is that said composition is administered on hair after shampoo stage, thus can effectively be deposited on scalp.
Based on said content above, need to provide a kind of Antidaudruff hair conditioning composition, said composition adopts and allows the preservative system used to obtain effective anti-dandruff efficacy in many countries, but anti-dandruff conditioning beneficial effect can not be reduced simultaneously, as hair wetness sensation, spreadability and rinsability, and form gloss and dry cardability.
But prior art does not all provide and can meet the plurality of advantages of consumer's use and the Antidaudruff hair conditioning composition of beneficial effect.
Summary of the invention
The object of the present invention is to provide a kind of Antidaudruff hair conditioning composition, while there is effective anti-dandruff efficacy, also there is Antidaudruff hair conditioning function.
The invention discloses a kind of Antidaudruff hair conditioning composition, by weight percentage, the following component that it comprises:
A) the hard fat compound of about 0.1%-10%;
B) about 0.01%-5% has the amidoamines of following general formula:
R
1CONH(CH
2)mN(R
2)
2，
In formula, R
1c
11-C
24the residue of fatty acid, R
2c
1-C
4alkyl, and m is the integer of 1-4;
C) acid, is selected from 1-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, 1-glutamic acid hydrochloride, tartaric acid and composition thereof, and its amount should make amidoamines be about 1: 0.1-1: 0.9 with the mol ratio of acid;
D) the dandruff removing agent compositions of safe and effective amount; The dandruff removing agent of the Zinc Pyrithione of 0.1%-3% and the undecylenoyl hydrolyzed wheat protein potassium effective dose of 0.1%-3%.
E) 84%-91% aqueous carrier.
To those skilled in the art, by reading the disclosure of the specification, these and other feature of the present invention, aspect and advantage will become apparent.
detailed Description Of The Invention
Although claims of the present invention particularly point out and know require that protection domain, should believe that following explanation will understand the present invention better.
Except as otherwise noted, herein all percent all with the weighing scale of whole compositions.Except as otherwise noted, all ratios are weight ratio.
Except as otherwise noted, the percent of all each compositions, ratio and content are all based on the actual content of composition herein, the solvent that can become be grouped together with these not included in commercially available prod, filler or other material.
Herein, " comprise or comprise " other step referring to and can add and not affect final result and other composition.This term comprises " by ... composition " and " substantially by ... form ".
All documents quoted as proof are incorporated herein by reference.The quoting and do not mean that any decision admitting that it exists as prior art relative to the present invention of any document.
hard fat compound
Wo 2008069000 of the present invention comprises hard fat compound.This hard fat compound and cationic surfactant are as amidoamines, and aqueous carrier together provides a kind of gel network, it is suitable for providing various anti-dandruff conditioning effect, as the smooth feeling on wet hair and the flexibility on dry hair, wetness sensation and control of dispersing.
The fusing point being applicable to hard fat compound of the present invention is 25 DEG C or higher, and is selected from fatty alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid and composition thereof.Those skilled in the art should be appreciated that, disclosed in this joint of description, compound may belong in more than one classification in some cases, and such as some fatty alcohol derivative can also classify as derivative of fatty acid.In any case the classification of specifying not means and limits this particular compound, but for the ease of clssification and designation.In addition, it will be understood by those skilled in the art that the number according to double bond and position, and the length and location of side chain, some compounds may have the fusing point lower than 25 DEG C with having certain required carbon atom.This low-melting compound is not included in this joint.
Being applicable to fatty alcohol of the present invention is the fatty alcohol with about 14 to about 30 carbon atoms, preferably about 16 to about 22 carbon atoms.These fatty alcohol are saturated, and can be straight or branched alcohol.The limiting examples of fatty alcohol comprises spermol, stearyl alcohol, docosanol and their mixture.
Being applicable to fatty acid of the present invention is the fatty acid with about 10 to about 30 carbon atoms, preferred about 12 to about 22 carbon atoms, more preferably from about 16 to about 22 carbon atoms.These fatty acids are saturated, and can be straight or branched acid.
The preferably hard fat compound of highly purified single compound.The single compound being selected from the pure fat alcohol of pure spermol, stearyl alcohol and tadenan is highly preferred.In this article, so-called " pure " refers to that the purity of compound is at least about 90%, is preferably at least about 95%.These high-purity single compounds provide good flushability when consumer rinses out said composition.
This fatty alcohol can be about 0.1%-10% by weight, is more preferably about 0.1%-5%, and the amount most preferably being about 0.5-3% comprises in the composition.Be applicable to can comprise by hard fat compound commercially in the present invention: spermol, stearyl alcohol and docosanol, its commodity are called LANETTE series, are provided by BASF AG.
amidoamines
Wo 2008069000 of the present invention comprises the amidoamines with following general formula:
R
1CONH(CH
2)
mN(R
2)
2；
R
1c
11-C
24the residue of fatty acid, R
2c
1-C
4alkyl, and m is the integer of 1-4.
This amidoamines can be about 0.01%-5% by weight, is more preferably about 0.15%-4%, and the amount most preferably being about 0.35-3% comprises in the composition.
Be applicable to preferred amidoamines of the present invention and comprise stearamidopropyldimethylamine, stearamidopropyl diethylamine, the amino alcohol of stearoyl, the amino dimethylamine of stearoyl, palmitoylamino diemethylamine, palmitoylamino propyl group diethylamine, palmitoylamino alcohol, palmitoylamino dimethylamine, docosane cocamidopropyl dimethylamine, docosane amidopropyl diethylamine, docosane acylamino-alcohol, docosane acylamino-dimethylamine, Semen arachidis hypogaeae cocamidopropyl dimethylamine, Semen arachidis hypogaeae amidopropyl diethylamine, Semen arachidis hypogaeae acylamino-alcohol, Semen arachidis hypogaeae acylamino-dimethylamine and composition thereof, be more preferably stearamidopropyldimethylamine, the amino alcohol of stearoyl and composition thereof.
Can commercially be applicable to amidoamines of the present invention comprise: (commodity are called TEGOAMIDS18 to stearamidopropyl dimethylamine, are called AmidoamineMPS, from NikkoL from EVONIK and commodity.
acid
Wo 2008069000 of the present invention comprises the acid being selected from following acid: Pidolidone, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, Pidolidone hydrochlorate, tartaric acid and composition thereof; Preferably Pidolidone, lactic acid, hydrochloric acid and composition thereof.The content of this acid makes amidoamines be about 1: 0.1-1: 0.9 with the mol ratio of acid, is preferably about 1: 0.5-1: 0.8.
Can commercially be applicable to acid of the present invention comprise: Pidolidone: the Pidolidone (cosmetics-stage) obtained by Ajinomoto.
dandruff removing agent
Compositions of the present invention comprises the dandruff removing agent of safe and effective amount.When there is dandruff removing agent, typically its amount is the about 0.1%-5% of composition weight, is preferably about 0.3%-2.5%, is more preferably about 0.5%-2%.
Pyrithione salt is applicable to the present invention.Suitable pyrithione salt is the heavy metallic salt of pyrithione, and this heavy metallic salt is zinc, stannum, cadmium, magnesium, aluminum and zirconium.Preferably ZPT, it in this area as Zinc Pyrithione (zincpyrithione) for people are known, more preferably its particle size is up to about 20 microns, is more preferably about 1-10 micron.Can commercially be applicable to pyrithione of the present invention and comprise the ZincPyrithione obtained by Zhejiang Regen Chemical Co., Ltd.
undecylenoyl hydrolyzed wheat protein potassium
Native protein anti-dandruff and itching-relieving agent it be for primary raw material with hydrolyzed wheat protein and 9-undecylenic acid, a kind of endecatylene enoyl-hydrolyzed wheat protein potassium obtained through a series of biochemical reaction, 9-undecylenic acid in this albumen removing scurf and relieving itching raw material is a kind of well Fungicidal substance, Shiyixisuan Undecylenic Acid (10-undecylenicacid, UA) be one of important castor oil derivative, Oleum Ricini is unique raw material sources of undecylenic acid, containing carboxyl and double bond 2 functional groups in the castor oil molecule structure that China abounds with, a lot of chemical reaction can be there is, and can antibacterium, the activity of fungus, it is reported, UA has the activity suppressing candida albicans bacterium and Cycloxygenase in vivo.Because the water solublity of UA is less, its application is restricted.UA not only water solublity is little, and has stink, is difficult to be applied in the industries such as daily use chemicals.Utilize enzyme hydrolysis, by 9-undecylenic acid, hydrolyzed wheat protein etc. by obtaining water solublity undecylenoyl hydrolyzed wheat protein potassium after a series of biochemical reaction.This product substantially increases its water solublity on the basis of 9-undecylenic acid, can play its antibacterial action better.Meanwhile, by this reaction, improve 9-undecylenic acid niff, and then product can be made to be widely used in daily use chemicals industry, there is well sterilization and antibacterial action.Particularly protect in product washing, the anti-microbial property that it is superior can be played, there is good anti-dandruff and itching-relieving efficacies.The mechanism of this product removing scurf and relieving itching is just that it is by methods such as sterilization, antioxidation Sum decomposition peroxide, fundamentally block the outside channel that dandruff produces, thus effectively effect a radical cure dandruff, stopping head itching, instead of presentation, temporarily eliminate dandruff by defat etc. mode.Not only there is good anti-dandruff and itching-relieving efficacies, simultaneously because it contains hydrolyzed wheat protein, thus there is the significant moisture-keeping nutrient effect of wheat protein.Be used in correct leatherware in hair washing product and have good affinity; therefore; scalp horny layer convergence scalp skin effectively can be softened while removing scurf and relieving itching; enhance the effect of removing scurf and relieving itching; to scalp, also there is extraordinary protective effect simultaneously, really can reach anti-dandruff and not hinder the effect of scalp.This native protein anti-dandruff and itching-relieving agent has good dissolubility, excellent removing scurf and relieving itching effect, extremely low zest, and the application therefore in daily chemical products is unrestricted, is used in masses and washes in removing scurf and relieving itching products such as protecting product,
Compositions of the present invention comprises the dandruff removing agent undecylenoyl hydrolyzed wheat protein potassium of safe and effective amount.
When there is dandruff removing agent, typically its amount is the about 0.1%-5% of composition weight, is preferably about 0.3%-2.5%, is more preferably about 0.5%-2%.Undecylenoyl hydrolyzed wheat protein potassium is applicable to the present invention, and this raw material is provided by Chongqing Haifan Biological & Chemical Co., Ltd..
Above-mentioned dandruff removing agent can be used alone, also can with mutually combinationally use.
This preservative system can contain the antiseptic of safe and effective amount.
cation opsonizing agent
Wo 2008069000 of the present invention comprises a kind of cation opsonizing agent.This cation opsonizing agent and hard fat compound together provide a kind of gel network, and it is suitable for providing various conditioning effect, as the smooth feeling on wet hair and the flexibility on dry hair, wetness sensation and control of dispersing.
This cation opsonizing agent can be about 0.1%-10% by weight, is more preferably about 0.25%-8%, and the amount most preferably being about 0.5-3% comprises in the composition.
This cation opsonizing agent is selected from cationic surfactant.
cationic surfactant
To be applicable to cationic surfactant of the present invention be known to persons of ordinary skill in the art and content is in the composition preferably about 0.1%-10% by weight, is more preferably about 0.25%-8%, most preferably is about 0.5-3%.
In this cationic surfactant, being applicable to of the present invention is correspond to those decoloriz ations following
In the middle of cationic surfactant, preferably comprise the surfactant that at least one has the alkyl chain of at least 16 carbon atoms in the molecule.The non-limitative example of these preferred cationic surfactants comprises: INCROQUAT TMC-80 ECONOL TM22, such as, obtained by Croda with trade name INCROQUATTMC-80, CTAB, such as, obtained by NikkoChemicals with trade name CA-2350, hydrogenated tallow alkyl trimethyl ammonium chloride, dialkyl group (14-18) alkyl dimethyl ammonium chloride, two tallow alkyl alkyl dimethyl ammonium chlorides, dihydrogenated tallowalkyl alkyl dimethyl ammonium chloride, VARISOFT TA100, two cetyl dimethyl ammonium chloride, two (docosyl/Semen arachidis hypogaeae acyl group) alkyl dimethyl ammonium chloride, two (docosyl) alkyl dimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, stearyl propylene glycol phosphate ester alkyl dimethyl ammonium chloride, stearyl cocoamidopropyl dimethyl benzyl ammonium chloride, stearyl cocoamidopropyl dimethyl (myristyl acetate) ammonium chloride, and N-(stearyl gallbladder carbamo, lmethyl) pyridinium chloride.
The cationic surfactant of highly preferred hydrophilic replacement comprises dialkylamido ethyl-hydroxyethyl methyl amine salt, dialkylamido ethyldimethyl amine salt, dialkyloyl hydroxyethyl methyl amine salt, dialkyloyl dimethyl amine salt and composition thereof, and the salt of primary, secondary and tertiary fatty amine is also suitable cationic surfactant.The alkyl of this kind of amine preferably has an about 12-22 carbon atom, and can be substituted or not replace.The acylamino-amine salt of particularly suitable is selected from material disclosed in title " amidoamines " above and " acid ".Preferably, acylamino-amine salt is used as cation opsonizing agent in the composition.
polysiloxane compound
The present composition is preferably containing polysiloxane compound.The content of the silicone compounds comprised in the composition is preferably about 0.1%-10% by weight, is more preferably about 0.25%-8%, most preferably is about 0.5%-3%.
Polysiloxane compound of the present invention can comprise volatile solvable or insoluble, or nonvolatile solvable or insoluble silicone conditioning agents.Solvable refers to that polysiloxane compound can be miscible with forming section phase homophase with the carrier of compositions.Insoluble refers to that polysiloxanes formation is separated with carrier, discontinuous phase, such as, emulsion in polysiloxanes droplet or form of suspension.Polysiloxane compound in the present invention can be reacted by typical polymerization or emulsion polymerization and obtaining.
Be applicable to the preferred viscosity of polysiloxane compound of the present invention and at 25 DEG C, be about 1,000-2,000,000 centistoke, be more preferably about 10,000-1,800,000 centistoke, most preferably be about 25,000-1,500,000 centistoke.This viscosity can pass through glass capillary tube viscometer, according to DowCorningCorporateTestMethodCTM0004, in 20 days July in 1970, said method measures, and the document is incorporated herein as a reference and all.The polysiloxane compound of high molecular can be prepared by emulsion polymerization.
Be applicable to polysiloxane compound of the present invention comprise poly-alkyl and gather aryl siloxanes, polyalkyleneoxide-modified siloxanes, polyorganosiloxane resin, the amino siloxanes replaced and composition thereof.This polysiloxane compound is preferably selected from poly-alkyl and gathers aryl siloxanes, polyalkyleneoxide-modified siloxanes, polyorganosiloxane resin and composition thereof, is more preferably selected from one or more poly-alkyl and gathers aryl siloxanes.
Be applicable to poly-alkyl of the present invention gather aryl siloxanes and comprise those materials with having structure (I):
In formula, R is alkyl or aryl, and x is about 7-8, the integer of 000." A " represents the group closing this polysiloxanes chain end.Any structure can be had at the alkyl or aryl (R) of siloxanes chain substitution or the alkyl or aryl (A) that replaces on siloxane chain end, as long as the polysiloxanes obtained at room temperature remains fluid, dispersible, non-stimulated, nontoxic, harmless when being applied on hair, can be compatible with other composition in said composition, be stable chemical nature under regular service conditions and storage requirement, and can be deposited on hair and conditioning hair.The A group be suitable for comprises hydroxyl, methyl, methoxyl group, ethyoxyl, propoxyl group and aryloxy group.Two R group on the silicon atoms can represent identical or different group.Preferably, two R group represent identical group.Suitable R group comprises methyl, ethyl, propyl group, phenyl, aminomethyl phenyl and phenyl methyl.Preferred polysiloxane compound is polydimethylsiloxane, polydiethylsiloxane and PSI.The polydimethylsiloxane being also called simethicone (dimethicone) is especially preferred.Spendable poly-alkylsiloxane comprises such as polydimethylsiloxane.For example, these polysiloxane compounds can be bought with itself ViscasilR and SF96 series by GeneralElectricCompany and be bought with its DowCorning200 series by DowCorning.Such as, the present invention is applicable to as SF1075 methyl phenyl fluid or from DowCorning as the PSI of 556 Cosmetic Grade Fluid from GeneralElectricCompany.
Preferred be equally refractive index is about 1.46 or higher for what improve hair gloss characteristic, is particularly about the polysiloxane compound of the height arylation of 1.52 or higher, such as the PES-4 of height phenylating.When using these high refractive index polysiloxane compounds, it should be mixed with spreading agent such as surfactant or polyorganosiloxane resin as described below, to reduce the surface tension of material and to improve its film forming ability.
It is silicone gums that the another kind of particularly suitable gathers alkylsiloxane.Term used herein " silicone gums " refers to and is more than or equal to 1,000, the polysiloxane of 000 centistoke 25 DEG C of its viscosity.Will be appreciated that, silicone gums as herein described also can have some overlapping with above-mentioned polysiloxane compound.This overlap is not the restriction to these materials any.Silicone gums is described by Petrarch, and other document comprises United States Patent (USP) 4,152,416 (people such as Spitzer, on May 1st, 1979 authorizes) and Noll, Walter, ChemistryandTechnologyofSilicones, NewYork:AcademicPress1968.What describe silicone gums also has GeneralElectricSiliconeRubberProductDataSheetsSE30, SE33, SE54 and SE76.All these documents are incorporated herein all as a reference and in full.The molecular weight being somebody's turn to do " silicone gums " is generally about 200, more than 000, usually in about 200,000-1,000,000 scopes.Example comprises polydimethylsiloxane, poly-(dimethylsiloxane methyl vinylsiloxane) copolymer, poly-(dimethyl siloxane diphenyl siloxane methyl vinyl silicone) copolymer and composition thereof.
For example, being applicable to polyalkyleneoxide-modified siloxanes of the present invention comprises polypropylene oxide modified with polyethylene oxide modified polydimethylsiloxane.The level of oxirane and expoxy propane should be enough low, not affect the dispersive property of polysiloxanes.These materials are also called simethicone polyol (dimethiconecopolyols).
Polyorganosiloxane resin as highly cross-linked polysiloxanes system is also applicable to the present invention.Describedly crosslinked to introduce by polyorganosiloxane resin production period trifunctional being mixed together with simple function or difunctional silane or the two with four functional silanes.As is well known the art, in order to the crosslinking degree obtained needed for polyorganosiloxane resin changes according to mixing the concrete silane unit in polyorganosiloxane resin.Generally, there are the trifunctional of enough levels and four functional silane monomeric units and therefore there is the crosslinked of enough levels thus silicone materials that is that make them can form hard or firm film when becoming dry can be considered polyorganosiloxane resin.The ratio of oxygen atom and silicon atom is the indication of cross-linking level in concrete polysiloxane species.The ratio of oxygen atom and silicon atom at least about 1.1 polysiloxane species polyorganosiloxane resin normally of the present invention.Preferably, the ratio of oxygen atom and silicon atom is at least about 1.2: 1.0.Silane for the preparation of polyorganosiloxane resin comprise monomethyl-, dimethyl-, trimethyl-, a phenyl-, diphenyl-, aminomethyl phenyl-, a vinyl-and methylvinylchlorosilanes and tetrachloro silicane, wherein methyl substituted silane is the most frequently used.Preferred resin is provided as GESS4230 and SS4267 by GeneralElectric.Can polyorganosiloxane resin commercially normally provide with the form of dissolving in low viscosity volatility or nonvolatile polysiloxane fluid.Polyorganosiloxane resin used in the present invention should provide with such dissolved form and be incorporated in the present composition, and this it will be apparent to those skilled in the art that.Be not bound by theory, it is believed that polyorganosiloxane resin can strengthen the deposition of other polysiloxane compound on hair, and the gloss of the hair with high refractive index volume can be strengthened.
Other polyorganosiloxane resin spendable is polyorganosiloxane resin powder, and such as CTFA name is called the material of poly methyl silsesquioxane (polymethylsilsequioxane), and this material can have been bought from ToshibaSilicones with TospearlTM.
According to the shorthand nomenclature system (" MDTQ " nomenclature) that those skilled in the art are known, more easily polyorganosiloxane resin can be differentiated.Under this naming system, the various siloxane monomer unit according to the formation polysiloxanes existed describe polysiloxanes.In brief, symbol M represents monofunctional unit (CH3) 3SiO) .5; D represents difunctional unit (CH3) 2SiO; T represents trifunctional units (CH3) SiO1.5; Q represents four functional unit SiO2.With the unit symbol of apostrophe, as M ', D ', T ' and Q ' expression substituent group besides methyl, and must specifically define each situation.Typical alternative substituent group comprises the group of such as vinyl, phenyl, amino, hydroxyl etc.Under MDTQ system, with the symbol subscript of the total number or its meansigma methods that represent various unit in polysiloxanes, or as the ratio specifically indicated and the mol ratio of different units that binding molecule amount represents completes the description of silicone materials.In polyorganosiloxane resin, relative to D, D ', M and/or M ', T, Q, T ' of higher relative molecular weight and/or Q ' mean higher cross-linking level.But as mentioned above, total cross-linking level can also be represented by the ratio of oxygen and silicon.
Preferred polyorganosiloxane resin used in the present invention is MQ, MT, MTQ, MDQ and MDTQ resin.Therefore, preferred polysiloxanes substituent group is methyl.Especially preferred is MQ resin, and wherein M: Q ratio is about 0.5: 1.0-about 1.5: 1.0, and the mean molecule quantity of this resin is about 1000-about 10,000.
The siloxanes being applicable to amino replacement of the present invention comprises those compounds represented by having structure (II):
In formula, R is CH
3or OH, x and y are the integers depending on molecular weight, mean molecule quantity is approximately 5,000-10,000.This polymer is also called " amodimethicone ".
The siloxanes fluids that the amino be suitable for replaces comprises those compounds represented by general formula (III): (R
1)
ag
3-a-Si-(-OSiG
2)
n-(-OSiG
b(R
1)
2-b)
m-O-SiG
3-a(R
1)
a(III).
Wherein, G is selected from hydrogen, phenyl, OH, C1-C8 alkyl, and preferably methyl; A represents the integer of 0 or 1-3, and is preferably 0; B represents 0 or 1, and is preferably 1; N+m is 1-2, the number of 000, and preferably 50-150, n can represent 0-1, the number of 999, and is preferably 49-149, and m can be 1-2,000, and the integer being preferably 1-10; R
1for general formula is C
qh
2qthe monoradical of L, wherein q is the integer of 2-8, and L is selected from following groups:
-N(R
2)CH
2-CH
2-N(R
2)
2
-N(R
2)
2
-N(R
2)
3A-
-N(R
2)CH
2-CH
2-NR
2H
2A-
R in formula
2be selected from hydrogen, phenyl, benzyl, saturated hydrocarbyl, be preferably the alkyl group containing 1-20 carbon atom, and A-represent halide ion.
The siloxanes that the particularly preferred amino corresponding to general formula (III) replaces is the polymer having general formula (IV), be called " trimethylsilylamodimethicone ":
In this general formula, n and m selects according to the molecular weight of required compound.
Other amino siloxanes replaced operable represents with logical formula V:
R in formula
3represent the univalence hydrocarbyl with 1-18 carbon atom, be preferably alkyl or alkenyl, as methyl; R
4represent alkyl, be preferably C
1-C
18alkylidene or C
1-C
18, be more preferably C
1-C
8alkylidene oxygen; Q-is halide ion, is preferably chlorine; R represents the average statistical value of 2-20, is preferably 2-8; S represents the average statistical value of 20-200, is preferably 20-50.Preferred this polymer is bought with trade name " UCARSILCONEALE56. " by UnionCarbide.
polyethylene Glycol
Preferably, compositions of the present invention can further include the Polyethylene Glycol with following general formula:
H(OCH
2CH
2)
n-OH
In formula, the meansigma methods of n is about 2000-14000, is preferably about 5000-9000, is more preferably about 6000-8000.
Polyethylene Glycol can also about 0.1%-10%, and more preferably from about the amount of 0.25%-6% weight comprises in the composition.
Above said Polyethylene Glycol also with polyethylene glycol oxide and polyoxyethylene for people are known.Particularly preferred to be applicable to Polyethylene Glycol of the present invention be PEG-2M, and in formula, the meansigma methods of n is about 2000 (, also with the PolyoxWSRN-10 from DOW Dow Chemical company and with PEG-2,000 is known for PEG-2M); PEG-5M, in formula, the meansigma methods of n is about 5000 (PEG-5M is also known with PolyoxWSRN-35 and PolyoxWSRN-80, these two kinds of products are all from DOW Dow Chemical company, and as PEG-5,000 and PolyethyleneGlycol300,000 is known); PEG-7M, in formula, the meansigma methods of n is about 7,000 (PEG-7M is also known with PolyoxWSRN-750, and it is from DOW Dow Chemical company); PEG-9M, in formula, the meansigma methods of n is about 9,000 (PEG-9M is also known with PolyoxWSRN-3333, and it is from DOW Dow Chemical company); And PEG-14M, in formula, the meansigma methods of n is about 14,000 (PEG-14M is also known with PolyoxWSRN-3000, and it is from DOW Dow Chemical company).
compositions
In a preferred version of the present invention, compositions comprises following component by weight:
A) about 0.1%-10%, be preferably about the hard fat compound of 0.1%-5%, the amount most preferably being about 0.5-3% comprises in the composition.
Most preferred situation is, this hard fat compound is selected from spermol, stearyl alcohol, docosanol and composition thereof;
B) about 0.1%-10%, is preferably about the amidoamines that 0.5%-3% has following general formula:
R
1CONH(CH
2)
mN(R
2)
2；
In formula, R1 is the residue of C11-C24 fatty acid, and R2 is C1-C4 alkyl, and m is the integer of 1-4; Preferably, this amidoamines is selected from stearamidopropyldimethylamine, amino alcohol of stearoyl and composition thereof;
C) acid, is selected from 1-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, 1-glutamic acid hydrochloride, tartaric acid and composition thereof, its amount should make amidoamines be about 1: 0.3-1: 1 with the mol ratio of acid, preferably 1-glutamic acid, its amount should make amidoamines be about 1: 0.5-1: 0.9 with the mol ratio of acid;
D) the dandruff removing agent compositions of safe and effective amount, is preferably about 0.5%-2% Zinc Pyrithione and 0.5%-2% undecylenoyl hydrolyzed wheat protein potassium;
E) the present invention is also containing the 0.1%-10% that has an appointment, and is preferably the polysiloxane compound of about 0.5%-3% weight;
F) preservative system, with the weighing scale of whole compositions, it comprises the phenyl phenol of about 0.1%-1.0%, the methyl butex of about 0.0.2%-1.0% and about 0.01%-1.0% propyl p-hydroxybenzoate; And
G) about 0.1%-10%, is preferably the Polyethylene Glycol of about 0.25%-6%;
H) compositions of the present invention comprises a kind of aqueous carrier.Content and the kind of carrier is selected according to other characteristic needed for the compatibility and product of other component.
supplementary element
Wide variety of other additional components can be formulated in the present composition.These components comprise: other conditioner, as the collagen (its commodity are called Peptein2000, are obtained by Hormel) of hydrolysis; (commodity are called Emix-d to vitamin E, are obtained by Eisai; Pantothenylol (being obtained by Roche); Hydrolysis of keratin, protein, plant extraction liquid, and nutritional labeling; Antiseptic, such as benzyl alcohol, methyl butex, propylparaben and imidazolidinyl urea pH adjusting agent, such as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt, normally such as potassium acetate and sodium chloride; Coloring agent, as any one in FD & C or D & C dyestuff; Spice; And chelating agen, such as disodiumedetate.
Antidaudruff hair conditioning composition of the present invention not only has effective anti-dandruff efficacy, also has hair wetness sensation, spreadability and rinsability, and forms many dandruffs such as gloss and dry cardability and nurse one's health effect.
Detailed description of the invention
The following example further describes and demonstrates the specific embodiments in the scope of the invention.These embodiments are only illustrative, but not limit the scope of the invention, because can carry out multiple change under the conditions without departing from the spirit and scope of the present invention.Except as otherwise noted, each composition all provides with chemical name or CTFA title.
Compositions of the present invention is applicable to leave and rinse-off products, and be particularly useful for making in emulsion, the product of cream frost, gel, spray or mousse.
The definition of component raw material:
* 1-spermol: LANETTE series, from BASF AG.
* 2-stearyl alcohol: LANETTE series, from BASF AG.
* 3-stearamidopropyldimethylamine: SAPDMA, from Inolex.
* 4-1-glutamic acid: 1-glutamic acid (cosmetics-stage), from Ajinomoto.
* 5-INCROQUAT TMC-80 ECONOL TM22: INCROQUATTMC-80 is from Croda company.
* 6-Zinc Pyrithione: ZincPyrithione is from Zhejiang Regen Chemical Co., Ltd.
* 7-undecylenoyl hydrolyzed wheat protein potassium is from Chongqing Hai Fan company limited
* 8-polysiloxane mixture: SE76, from GeneralElectric.
* 9-hydrolytic collagen: Peptein2000, from Hormel.
* 10-pantothenylol: from Roche.
* 11-PEG-2M:Polyox, from DOW Dow Chemical company.
raw material components and the content of compositions embodiment 1-9 of the present invention is represented respectively with following table 1 and table 2.
the raw material components of the embodiment 1-5 of table 1 present composition and content (unit: percentage by weight %)
the raw material components of the embodiment 6-9 of table 2 present composition and content (unit: percentage by weight %)
The Wo 2008069000 of said embodiment 1-9 can be prepared by any one conventional method known in the art above.
They can be obtained by following appropriate ways:
1) if comprise polymeric material in said composition, then at room temperature this polymeric material such as Polyethylene Glycol is dispersed in water, forms a kind of polymer solution, and be heated more than 70 DEG C.
2) under agitation, amidoamines and sour or other cation opsonizing agent is added in this solution, under agitation, hard fat compound is added in this solution, thus obtained mixture is cooled to lower than 60 DEG C, and by remaining composition while stirring, as Zinc Pyrithione, polysiloxane compound add wherein and be further cooled to about 30 DEG C.
If required, SANYE kneader (triblender) and/or grinder can be adopted in each of the steps, to be disperseed by material.
Disclosed embodiment has many advantages in this article.For example, they provide effective antidandruff efficacy, simultaneously can not reduce conditioning effect, as wet hair sense, spreadability (spreadability) and rinsability and provide gloss and hair drying comb is managed.
Should be appreciated that, embodiment of the present invention and specific embodiments are only illustrative, and under the condition not deviating from spirit and scope of the invention, those of ordinary skill in the art can carry out various change or change to it.
verification the verifying results test example
9 groups of embodiments of the present invention survive bacteriostasis rate of bacterium (cfu/ml) Malassezia furfur of bacterium (cfu/ml) Malassezia furfur, test group of surviving with matched group is respectively tested to adopt following table 3 to verify.
The fungistatic effect checking of table 3 embodiment of the present invention 1-9
From the result of above-mentioned table 3,9 groups of embodiments of the present invention can suppress Malassezia furfur effectively, the few gentle and not scalp irritation of embodiment 3 dosage.
The above, it is only preferred embodiment of the present invention, not any pro forma restriction is done to the present invention, therefore everyly do not depart from technical solution of the present invention content, the any simple modification done above embodiment according to technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.
Claims (10)
1. an Antidaudruff hair conditioning composition, is characterized in that: by weight percentage, and said composition comprises:
A) the hard fat compound of about 0.1%-10%; Described its fusing point of hard fat compound is 25 DEG C or higher;
B) amidoamines of about 0.01%-5%, this amidoamines has following general formula:
R
1cONH (CH
2) mN (R
2)
2, in formula, R
1c
11-C
24the residue of fatty acid, R
2c
1-C
4alkyl, and m is the integer of 1-4;
C) acid, is selected from 1-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, 1-glutamic acid hydrochloride, tartaric acid and composition thereof, and its amount should make amidoamines be about 1: 0.1-1: 0.9 with the mol ratio of acid;
D) dandruff removing agent of safe and effective amount, its content range is at 0.1%-5.0%;
E) aqueous carrier, its content range is at 84%-91%.
2. Wo 2008069000 according to claim 1, is characterized in that: described hard fat compound accounts for the 0.1%-5% of total composition, is preferably 0.5-3%; It can be selected from fatty alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid and composition thereof.
3. Wo 2008069000 according to claim 1, it is characterized in that: described amidoamines accounts for the 0.15%-4% of total composition, be preferably about 0.35-3%, it comprises stearamidopropyldimethylamine, stearamidopropyl diethylamine, the amino alcohol of stearoyl, the amino dimethylamine of stearoyl, palmitoylamino diemethylamine, palmitoylamino propyl group diethylamine, palmitoylamino alcohol, palmitoylamino dimethylamine, docosane cocamidopropyl dimethylamine, docosane amidopropyl diethylamine, docosane acylamino-alcohol, docosane acylamino-dimethylamine, Semen arachidis hypogaeae cocamidopropyl dimethylamine, Semen arachidis hypogaeae amidopropyl diethylamine, Semen arachidis hypogaeae acylamino-alcohol, Semen arachidis hypogaeae acylamino-dimethylamine and composition thereof.
4. Wo 2008069000 according to claim 1, is characterized in that: described dandruff removing agent is the pyrithione salt of 0.1%-5% and/or the undecylenoyl hydrolyzed wheat protein potassium of 0.1%-5%.
5. Wo 2008069000 according to claim 1, is characterized in that: comprise following component by weight:
A) the hard fat compound of about 0.1%-5%, is selected from spermol, stearyl alcohol, docosanol and composition thereof;
B) amidoamines of about 0.01%-5%, is selected from stearamidopropyldimethylamine, amino alcohol of stearoyl and composition thereof;
C) 1-glutamic acid, its amount makes amidoamines be about 1: 0.1-1: 0.9 with the mol ratio of acid;
D) dandruff removing agent of the Zinc Pyrithione of about 0.1%-3% and the undecylenoyl hydrolyzed wheat protein potassium effective dose of 0.1%-3%;
E) a kind of aqueous carrier.
6. Wo 2008069000 according to claim 1, is characterized in that: the Polyethylene Glycol with following general formula also comprising about 0.1%-5% weight:
H(OCH
2CH
2)
n-OH；
In formula, the meansigma methods of n is about 2,000-14, and 000.
7. Wo 2008069000 according to claim 1, is characterized in that: the cation opsonizing agent also comprising 0.1%-10%, described cation opsonizing agent is selected from cationic surfactant, comprise the surfactant that at least one has the alkyl chain of at least 16 carbon atoms, the non-limitative example of these preferred cationic surfactants comprises: INCROQUAT TMC-80 ECONOL TM22, CTAB, hydrogenated tallow alkyl trimethyl ammonium chloride, dialkyl group (14-18) alkyl dimethyl ammonium chloride, two tallow alkyl alkyl dimethyl ammonium chlorides, dihydrogenated tallowalkyl alkyl dimethyl ammonium chloride, VARISOFT TA100, two cetyl dimethyl ammonium chloride, two (docosyl/Semen arachidis hypogaeae acyl group) alkyl dimethyl ammonium chloride, two (docosyl) alkyl dimethyl ammonium chloride, stearyl dimethyl benzyl ammonium chloride, stearyl propylene glycol phosphate ester alkyl dimethyl ammonium chloride, stearyl cocoamidopropyl dimethyl benzyl ammonium chloride, stearyl cocoamidopropyl dimethyl (myristyl acetate) ammonium chloride, and N-(stearyl gallbladder carbamo, lmethyl) pyridinium chloride,
The cationic surfactant of preferred hydrophilic replacement comprises dialkylamido ethyl-hydroxyethyl methyl amine salt, dialkylamido ethyldimethyl amine salt, dialkyloyl hydroxyethyl methyl amine salt, dialkyloyl dimethyl amine salt and composition thereof, and the salt of primary, secondary and tertiary fatty amine is also suitable cationic surfactant.
8. Wo 2008069000 according to claim 1, is characterized in that: the polysiloxane compound also comprising 0.1%-10%; Described polysiloxane compound comprises polydimethylsiloxane, poly-(dimethylsiloxane methyl vinylsiloxane) copolymer, poly-(dimethyl siloxane diphenyl siloxane methyl vinyl silicone) copolymer and composition thereof.
9. Wo 2008069000 according to claim 1, is characterized in that: the Polyethylene Glycol with following general formula also comprising 0.1%-10%:
H(OCH
2CH
2)
n-OH
In formula, the meansigma methods of n is about 2000-14000, is preferably about 5000-9000, is more preferably about 6000-8000.
10. the Wo 2008069000 according to any one of claim 1-9, is characterized in that: also comprise wide variety of other additional components, and other annexing ingredients described comprise: other conditioner, as the collagen of hydrolysis; Vitamin E; Hydrolysis of keratin, protein, plant extraction liquid, and nutritional labeling; Antiseptic, such as benzyl alcohol, methyl butex, propylparaben and imidazolidinyl urea; PH adjusting agent, such as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt, normally potassium acetate and sodium chloride; Coloring agent, spice, chelating agen.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019127214A1 (en) * | 2017-12-28 | 2019-07-04 | L'oreal | Composition for conditioning keratin fibers |
| CN112076111A (en) * | 2020-09-07 | 2020-12-15 | 广州市科能化妆品科研有限公司 | Dandruff-removing shampoo composition |
| US20210378930A1 (en) * | 2018-11-01 | 2021-12-09 | HFC Prestige International Holding Switzerland S.a.r.l. | Silicon free hair conditioning composition |
| CN114469803A (en) * | 2022-01-26 | 2022-05-13 | 乐彩华年(广州)电子商务有限公司 | Supermolecule composition and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001035912A1 (en) * | 1999-11-11 | 2001-05-25 | The Procter & Gamble Company | Antidandruff hair conditioning composition |
-
2016
- 2016-01-06 CN CN201610013830.7A patent/CN105560076A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001035912A1 (en) * | 1999-11-11 | 2001-05-25 | The Procter & Gamble Company | Antidandruff hair conditioning composition |
| CN1423548A (en) * | 1999-11-11 | 2003-06-11 | 宝洁公司 | Antidaudruff hair conditioning composition |
| US6979439B1 (en) * | 1999-11-11 | 2005-12-27 | The Procter & Gamble Company | Antidandruff hair conditioning composition |
Non-Patent Citations (1)
| Title |
|---|
| 胡梅 等: "天然蛋白去屑止痒剂在化妆品中的应用与展望", 《日用化学品科学》 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019127214A1 (en) * | 2017-12-28 | 2019-07-04 | L'oreal | Composition for conditioning keratin fibers |
| US11975089B2 (en) | 2017-12-28 | 2024-05-07 | L'oreal | Composition for conditioning keratin fibers |
| US20210378930A1 (en) * | 2018-11-01 | 2021-12-09 | HFC Prestige International Holding Switzerland S.a.r.l. | Silicon free hair conditioning composition |
| CN112076111A (en) * | 2020-09-07 | 2020-12-15 | 广州市科能化妆品科研有限公司 | Dandruff-removing shampoo composition |
| CN114469803A (en) * | 2022-01-26 | 2022-05-13 | 乐彩华年(广州)电子商务有限公司 | Supermolecule composition and preparation method and application thereof |
| CN114469803B (en) * | 2022-01-26 | 2024-03-19 | 乐彩华年(广州)电子商务有限公司 | Supermolecule composition and preparation method and application thereof |
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