CN105548170B - A kind of lead ion Test paper and preparation method thereof and application method - Google Patents
A kind of lead ion Test paper and preparation method thereof and application method Download PDFInfo
- Publication number
- CN105548170B CN105548170B CN201610009615.XA CN201610009615A CN105548170B CN 105548170 B CN105548170 B CN 105548170B CN 201610009615 A CN201610009615 A CN 201610009615A CN 105548170 B CN105548170 B CN 105548170B
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- China
- Prior art keywords
- paper
- test paper
- test
- maceration extract
- lead ion
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Classifications
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- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N21/78—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator producing a change of colour
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/75—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated
- G01N21/77—Systems in which material is subjected to a chemical reaction, the progress or the result of the reaction being investigated by observing the effect on a chemical indicator
- G01N2021/7756—Sensor type
- G01N2021/7759—Dipstick; Test strip
Abstract
The invention belongs to heavy metal ion rapid detection technical field, it is related to a kind of lead ion Test paper and its manufacturing method and application method, feature is the Test paper by bar shaped substrate and is fixed on the test-paper of bar shaped substrate and constitutes；The bar shaped substrate includes test paper paste-side and grip end, and the test paper paste-side and grip end are located at bar shaped substrate left and right ends；The test-paper is infiltrated by filter paper in test paper maceration extract, dry cut is made after taking-up, the test paper maceration extract component is made of 0.05 0.2g Phens, 0.1 0.3g polyethylene glycol, 0.05 0.2g xylenol orange, 1.0 3.0mLOP emulsifiers, and acid, which is added dropwise, makes system in acidity.This Test paper is easy to operate, and accuracy is high, cheap, has not only facilitated family's self-test, but also enterprise, government department's high-volume is suitble to inspect by random samples.
Description
Technical field
The invention belongs to heavy metal ion rapid detection technical fields, are specifically related to a kind of lead ion Test paper and its system
Preparation Method and application method.
Background technology
Lead is a kind of heavy metal element seriously endangering human health and the larger one kind of heavy metal pollution Poisoning,
Lead can enter human body by air, food, water, once it is difficult to exclude into human body.It can influence nerve, hematopoiesis, digest, secretes
Each organoid such as urine, reproduction and development, angiocarpy, endocrine, immune, bone, lead harm is the most serious is nervous system and makes
Blood system, Mental retardation caused by lead are irreversible, and after driving lead treatment, blood lead declines, but Mental retardation is without apparent
Restore.
Lead has different people different degrees of harm, the lead poisoning of pregnant woman's period of gestation can influence the development of fetal nerve plate, sternly
The meeting of weight causes fetus to return shallow, feeblemindedness at congenital cerebral sulci；It is unmarried youth men and women's lead poisoning can cause it is infertile, even if
Fertility offspring also results in offspring's physique and oligrophrenia；Children's lead poisoning is damaged most serious with nervous system, can cause
Children have the fidgets, and personality change is slow in reacting, and intelligence, decrease of memory etc., severe patient may occur in which lead encephalopathy, even
It is dead；The elderly's lead poisoning can cause dull-witted, brain death is busy etc..
Currently, in the exploitation of lead ore and leaded metallic ore；It smelts, lead pig, stereotype, lead pipe and other leadworks is melted；Print
Typefounding, casting version in brush industry；The melting of the Storage Battery Industry in China, casting grid；Welding and fusion cutting containing lead metal and are coated with leaded paint
Metal product；Ceramics, enamel, cloisonne enamel match glaze using lead compound；Using containing lead pigments etc. in plastic processing, paint production
It is all easy to touch lead, lead is not that for the moment, can also endanger the next generation to the harm of human body.
Therefore, lead content detection is of great significance to human health and social development, so just with greater need for one kind
Fast detecting tool easy to operate, accuracy is high, cheap can both meet family's self-test, can also meet enterprise's production
Detection demand can be widely used in the inspection detection of soil, water quality, environment, cosmetics, food, all types of industries product.
Invention content
In consideration of it, the invention is intended to provide a kind of lead ion Test paper and preparation method thereof and application method, the test paper
Reagent type is few needed for preparing, and preparation method is simple, free from environmental pollution, applied widely, easy to operate, accuracy is high, price
Cheaply.
To achieve the above object, present invention employs following technical proposals
A kind of lead ion Test paper, including：Bar shaped substrate and the test-paper for being fixed on bar shaped substrate, wherein test-paper
It is infiltrated in maceration extract by filter paper, dry cut is made after taking-up, and the test paper maceration extract component is by 0.05-0.2g neighbour's Féraud
Quinoline, 0.1-0.3g polyethylene glycol, 0.05-0.2g xylenol orange, 1.0-3.0mLOP- emulsifiers composition, and acid, which is added dropwise, makes the system be in
It is acid.
The hydrochloric acid that the acid is 1-3 drops 1moL/L, naturally it is also possible to use sulfuric acid and nitric acid.
More specifically, the bar shaped substrate is equipped with test paper paste-side and grip end, test-paper is fixed on test paper paste-side
On.
The preparation method of lead ion Test paper of the present invention, specifically includes following steps：
Step 1：Complex reaction can occur with the lead ion in sample in acid condition according to xylenol orange, generate purple
The chemical principle of red compound, the maceration extract are made by following steps：
A. 0.1000g Phens are weighed to be dissolved in 100mL distilled water, maceration extract is made in heating stirring dissolving on electric furnace
Ⅰ；
B. 0.2000g polyethylene glycol and 0.1000g xylenol orange are weighed, is added in cooling maceration extract I and dissolves, leaching is made
Stain liquid II；
C. 2.0mLOP- emulsifiers are added in maceration extract II, and a small amount of hydrochloric acid, which is added dropwise, makes system at acidity, is sufficiently stirred
Uniformly to get test paper maceration extract；
Step 2：The filter paper cut out is slowly immersed in test paper maceration extract, filter paper takes out after being impregnated in test paper maceration extract,
Drying；
Step 3：This test-paper is pasted on item by the test-paper that the filter paper of drying is cut into required specification on instrument
Lead ion Test paper is made in shape substrate.
Further, filter paper takes out after impregnating 10-15min in test paper maceration extract, is laid on clean glass plate, sets
In baking oven, 2-3h are dried at 35-40 DEG C to dry.
Further, manufactured test paper need to be protected from light, 0-30 DEG C dry of storage under room temperature, be sure not directly sudden and violent
Dew is in air.
Further, temperature is 5-30 DEG C to filter paper immersion environment indoors, and humidity is 40%-70%, is avoided drying in the shade
It is impregnated under intense light conditions.
Further, hold one's breath bubble among filter paper immersion and filter paper during taking-up and maceration extract, ensures that filter paper is uniform
Degree, filter paper soak out to dry on a glass, cannot in an oven heat together with PVC board, be waved when PVC board being avoided to heat
Certain ingredient sent out is reacted with test paper.
A kind of application method of lead ion Test paper, it is characterised in that：Test paper is immersed 1 in leaded prepare liquid~
It is taken out after 2 seconds；Activator is added dropwise to the Test paper again；Test paper becomes red；Again by the Test paper and reference colour
Card comparison；Realize detection to lead content according to the depth of color, Test paper aobvious color with lead concentration in prepare liquid
Increase and gradually deepens to be peony from light red.
In the present invention, used test paper and bar shaped substrate are conventional material, of low cost, using xylenol orange conduct
Test paper, and combine Phen, polyethylene glycol, LOP- emulsifiers adjust test paper maceration extract so that its wellability is good, lead from
Sub- Test paper show uniformity is good, improves accuracy in detection.This Test paper is easy to operate, and accuracy is high, cheap, both
Facilitate family's self-test, and enterprise, government department's high-volume is suitble to inspect by random samples.
Description of the drawings
Fig. 1 is the structural schematic diagram of Test paper of the present invention.
End is held in 1. test-paper, 2. bar shaped substrate, 3. test paper paste-side 4. in figure.
Specific implementation mode
Embodiment 1
As shown in Figure 1, a kind of lead ion Test paper, including：Bar shaped substrate 2 and the test-paper for being fixed on bar shaped substrate 2
1, wherein bar shaped substrate 2 is equipped with：Test paper paste-side 3 and grip end 4, test-paper 1 are fixed on test paper paste-side 3；Wherein, it tries
The scraps of paper 1 are infiltrated by filter paper in maceration extract, and dry cut is made after taking-up, and the test paper maceration extract component is adjacent luxuriant and rich with fragrance by 0.1000g
The hydrochloric acid composition of sieve quinoline, 0.2000g polyethylene glycol, 0.1000g xylenol orange, 2.0mLOP- emulsifiers and 2 drop 1moL/L.
Embodiment 2
The preparation method of lead ion Test paper of the present invention, includes the following steps：
Step 1：It weighs 0.1000g Phens to be dissolved in 100mL distilled water, leaching is made in heating stirring dissolving on electric furnace
Stain liquid I；0.2000g polyethylene glycol and 0.1000g xylenol orange are weighed, is added in cooling maceration extract I and dissolves, maceration extract is made
Ⅱ；2.0mLOP- emulsifiers are added in maceration extract II, the plastic dropper of 3mL be used in combination that the hydrochloric acid of 2 drop 1moL/L is added dropwise, fully stirs
It mixes uniformly to get test paper maceration extract；
Step 2：The test paper maceration extract is poured into glass plate, the filter paper cut out is slowly immersed in maceration extract, filter paper
It takes out, is laid on clean glass plate after impregnating 12min in soak, be placed in 2-3h of baking in 40 DEG C of baking ovens；
Step 3：By the filter paper of drying cut on instrument width be 8.9-9.1mm strip (in the cut place of filter paper item
Must not have flash), test-paper 1 is made, this test-paper 1 is pasted on the test paper paste-side 3 of PVC or pet substrate, is placed in certainly
In dynamic cutting machine, test strips are cut by specification, that is, lead ion Test paper is made；Manufactured test paper need to be protected from light, dry
0-30 DEG C of storage under room temperature, is sure not to be directly exposed in air.
Embodiment 3
Step 1：It weighs 0.0500g Phens to be dissolved in 100mL distilled water, leaching is made in heating stirring dissolving on electric furnace
Stain liquid I；0.1000g polyethylene glycol and 0.0500g xylenol orange are weighed, is added in cooling maceration extract I and dissolves, maceration extract is made
Ⅱ；1.0mLOP- emulsifiers are added in maceration extract II, the plastic dropper of 3mL be used in combination that the hydrochloric acid of 1 drop 1moL/L is added dropwise, fully stirs
It mixes uniformly to get test paper maceration extract；
Step 2：The test paper maceration extract is poured into glass plate, the filter paper cut out is slowly immersed in maceration extract, filter paper
It is taken out after impregnating 10min in soak, is laid on clean glass plate, is placed in 35 DEG C of baking ovens and dries；
Step 3：By the filter paper of drying cut on instrument width be 8.9-9.1mm strip (in the cut place of filter paper item
Must not have flash), test-paper 1 is made, this test-paper 1 is pasted on the test paper paste-side 3 of PVC substrates, is placed in and cuts automatically
In cutting mill, test strips are cut by specification, that is, lead ion Test paper is made；Manufactured test paper need to be protected from light, and dry 0-30
DEG C storage under room temperature, be sure not to be directly exposed in air.
Embodiment 4
Step 1：It weighs 0.2000g Phens to be dissolved in 100mL distilled water, leaching is made in heating stirring dissolving on electric furnace
Stain liquid I；0.3000g polyethylene glycol and 0.2000g xylenol orange are weighed, is added in cooling maceration extract I and dissolves, maceration extract is made
Ⅱ；3.0mLOP- emulsifiers are added in maceration extract II, the plastic dropper of 3mL be used in combination that the nitric acid of 3 drop 1moL/L is added dropwise, fully stirs
It mixes uniformly to get test paper maceration extract；
Step 2：The test paper maceration extract is poured into glass plate, the filter paper cut out is slowly immersed in maceration extract, filter paper
It takes out, is laid on clean glass plate after impregnating 15min in soak, be placed in 2-3h of baking in 45 DEG C of baking ovens；
Step 3：By the filter paper of drying cut on instrument width be 8.9-9.1mm strip (in the cut place of filter paper item
Must not have flash), test-paper 1 is made, this test-paper 1 is pasted on the test paper paste-side 3 of pet substrate, is placed in and cuts automatically
In cutting mill, test strips are cut by specification, that is, lead ion Test paper is made；Manufactured test paper need to be protected from light, and dry 0-30
DEG C storage under room temperature, be sure not to be directly exposed in air.
Embodiment 5
Step 1：It weighs 0.1000g Phens to be dissolved in 100mL distilled water, leaching is made in heating stirring dissolving on electric furnace
Stain liquid I；0.1000g polyethylene glycol and 0.15000g xylenol orange are weighed, is added in cooling maceration extract I and dissolves, dipping is made
Liquid II；2.0mLOP- emulsifiers are added in maceration extract II, the plastic dropper of 3mL are used in combination that the hydrochloric acid of 2 drop 1moL/L is added dropwise, fully
It stirs evenly to get test paper maceration extract；
Step 2：The test paper maceration extract is poured into glass plate, the filter paper cut out is slowly immersed in maceration extract, filter paper
It takes out, is laid on clean glass plate after impregnating 12min in soak, be placed in 2-3h of baking in 40 DEG C of baking ovens；
Step 3：By the filter paper of drying cut on instrument width be 8.9-9.1mm strip (in the cut place of filter paper item
Must not have flash), test-paper 1 is made, this test-paper 1 is pasted on the test paper paste-side 3 of PVC substrates, is placed in and cuts automatically
In cutting mill, test strips are cut by specification, that is, lead ion Test paper is made；Manufactured test paper need to be protected from light, and dry 0-30
DEG C storage under room temperature, be sure not to be directly exposed in air.
In the present invention, test-paper 1 can be first pasted, then PVC substrate cuts are in strip substrate 2, do so stickup conveniently, effect
Rate is high.Can certainly PVC substrate cuts be first in strip substrate 2, then paste test-paper 1 on bar shaped substrate 2.
Embodiment 6
The Test paper that previous embodiment is worth is immersed in leaded prepare liquid and is taken out after 1~2 second；It is tried again to the detection
1 drop is added dropwise by being diluted with water to after 50 milliliters of 0.1M tris solutions and 14.7 milliliters of 0.1N hydrochloric acid mixings in paper
100mL is uniformly mixed the activator being configured to；Test paper becomes red；The Test paper and standard color card are compared again；Root
Realize detection to lead content according to the depth of color, Test paper aobvious color as the increase of lead concentration in prepare liquid is from pale red
Color is gradually deepened to be peony, and test scope is wide, is operated without professional, and lead content is detected especially suitable for rapid field.
Claims (10)
1. a kind of lead ion Test paper, it is characterised in that：Including bar shaped substrate and the test-paper for being fixed on bar shaped substrate,
In, test-paper is infiltrated by filter paper in maceration extract, and dry cut is made after taking-up, and the test paper maceration extract component is by 0.05-
0.2g Phens, 100mL distilled water, 0.1-0.3g polyethylene glycol, 0.05-0.2g xylenol orange, 1.0-3.0mLOP- emulsifications
Agent forms, and acid, which is added dropwise, makes system in acidity.
2. lead ion Test paper according to claim 1, it is characterised in that：The bar shaped substrate is pasted equipped with test paper
End and grip end, test-paper are fixed on test paper paste-side.
3. lead ion Test paper according to claim 1, it is characterised in that：The test paper maceration extract component by
0.1000g Phens, 100mL distilled water, 0.2000g polyethylene glycol, 0.1000g xylenol orange, 2.0mLOP- emulsifiers and 2
Drip the hydrochloric acid composition of 1moL/L.
4. lead ion Test paper according to claim 1, it is characterised in that：The bar shaped substrate is by PVC or pet substrate
It cuts.
5. the preparation method of lead ion Test paper described in a kind of claim 1, it is characterised in that：Include the following steps：
Step 1：The maceration extract is made according to the following steps：
A. 0.05-0.2g Phens are weighed to be dissolved in 100mL distilled water, maceration extract I is made in heating stirring dissolving on electric furnace；
B. 0.1-0.3g polyethylene glycol and 0.05-0.2000g xylenol orange are weighed, is added in cooling maceration extract I and dissolves, be made
Maceration extract II；
C. 1.0-3.0mLOP- emulsifiers are added in maceration extract II, and acid, which is added dropwise, makes system at acidity, stirs, i.e.,
Obtain test paper maceration extract；
Step 2：The filter paper cut out is slowly immersed in test paper maceration extract, filter paper takes out after being impregnated in test paper maceration extract, dries
It is dry；
Step 3：This test-paper is pasted on bar shaped base by the test-paper that the filter paper of drying is cut into required specification on instrument
Lead ion Test paper is made in plate.
6. the preparation method of lead ion Test paper according to claim 5, it is characterised in that：Filter paper is in test paper maceration extract
It takes out, is laid on clean glass plate after impregnating 10-15min, in an oven 35-40 DEG C of drying.
7. the preparation method of lead ion Test paper according to claim 5, it is characterised in that：By the filter paper of drying in instrument
On cut into strip, test-paper is made, this test-paper is pasted on the test paper paste-side of PVC or pet substrate, is placed in automatic
In cutting machine, test strips are cut by specification, that is, lead ion Test paper is made.
8. the preparation method of lead ion Test paper according to claim 5, it is characterised in that：Filter paper impregnates environment indoors
Temperature is 5-30 DEG C, and humidity is 40%-70%, avoids impregnating under intense light conditions drying in the shade.
9. the preparation method of lead ion Test paper according to claim 5, it is characterised in that：Manufactured test paper need to kept away
Light, 0-30 DEG C dry of storage under room temperature, is sure not to be directly exposed in air.
10. the application method of lead ion Test paper described in a kind of claim 1, it is characterised in that：Test paper immersion is contained
It is taken out after 1~2 second in lead prepare liquid；Activator is added dropwise to the Test paper again；Test paper becomes red；Again by the detection
Test paper is compared with standard color card；The detection to lead content is realized according to the depth of color, and the aobvious color of Test paper institute is with to be measured
The increase of lead concentration is gradually deepened to be peony from light red in liquid.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610009615.XA CN105548170B (en) | 2016-01-08 | 2016-01-08 | A kind of lead ion Test paper and preparation method thereof and application method |
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| CN201610009615.XA CN105548170B (en) | 2016-01-08 | 2016-01-08 | A kind of lead ion Test paper and preparation method thereof and application method |
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| CN105548170A CN105548170A (en) | 2016-05-04 |
| CN105548170B true CN105548170B (en) | 2018-08-07 |
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Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106525828A (en) * | 2016-10-31 | 2017-03-22 | 百奥森（江苏）食品安全科技有限公司 | Lead ion detection test paper and production method thereof |
| CN107064131A (en) * | 2017-05-16 | 2017-08-18 | 广州蓝豚生物科技有限公司 | A kind of detection carrier and its detection method for detecting various heavy |
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| CN103207174A (en) * | 2013-03-11 | 2013-07-17 | 苏州聚阳环保科技有限公司 | Online total-lead testing instrument |
| TW201339576A (en) * | 2012-03-20 | 2013-10-01 | Po-Hsun Chang | Iron ion, lead ion and copper ion detection recipe reagent and test strips |
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| US9255900B2 (en) * | 2012-03-19 | 2016-02-09 | Glenn M. Fishbine | Hand held toxicity tester |
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| TW201339576A (en) * | 2012-03-20 | 2013-10-01 | Po-Hsun Chang | Iron ion, lead ion and copper ion detection recipe reagent and test strips |
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| CN103487432A (en) * | 2013-09-25 | 2014-01-01 | 昆明泊银科技有限公司 | Lead ion detection test paper, and preparation method and use method thereof |
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