CN105541885A - Niacin derivative ligand samarium metal complex with light-emitting function and preparation method thereof - Google Patents
Niacin derivative ligand samarium metal complex with light-emitting function and preparation method thereof Download PDFInfo
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- CN105541885A CN105541885A CN201610053421.XA CN201610053421A CN105541885A CN 105541885 A CN105541885 A CN 105541885A CN 201610053421 A CN201610053421 A CN 201610053421A CN 105541885 A CN105541885 A CN 105541885A
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- nicotinic acid
- carboxyphenoxy
- solution
- samarium metal
- metal complexes
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- 229910052772 Samarium Inorganic materials 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- -1 samarium metal complex Chemical class 0.000 title claims abstract description 10
- 150000002814 niacins Chemical class 0.000 title abstract 3
- 239000003446 ligand Substances 0.000 title abstract 2
- PVNIIMVLHYAWGP-UHFFFAOYSA-N Niacin Chemical compound OC(=O)C1=CC=CN=C1 PVNIIMVLHYAWGP-UHFFFAOYSA-N 0.000 claims abstract description 56
- 239000000243 solution Substances 0.000 claims abstract description 36
- 229910052751 metal Inorganic materials 0.000 claims abstract description 30
- 239000002184 metal Substances 0.000 claims abstract description 30
- 235000001968 nicotinic acid Nutrition 0.000 claims abstract description 29
- 239000011664 nicotinic acid Substances 0.000 claims abstract description 29
- KZUNJOHGWZRPMI-UHFFFAOYSA-N samarium atom Chemical compound [Sm] KZUNJOHGWZRPMI-UHFFFAOYSA-N 0.000 claims abstract description 23
- 229960003512 nicotinic acid Drugs 0.000 claims abstract description 21
- 238000000034 method Methods 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 101100220533 Zea mays CPN60I gene Proteins 0.000 claims abstract description 8
- 239000000126 substance Substances 0.000 claims abstract description 7
- 239000007864 aqueous solution Substances 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 20
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical group [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 18
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- RJQYMBZVURNGFW-UHFFFAOYSA-N 5-(4-carboxyphenoxy)pyridine-3-carboxylic acid Chemical compound OC(=O)C1=CC=C(OC2=CN=CC(=C2)C(O)=O)C=C1 RJQYMBZVURNGFW-UHFFFAOYSA-N 0.000 claims description 12
- 238000010438 heat treatment Methods 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 10
- 239000003637 basic solution Substances 0.000 claims description 9
- 239000013078 crystal Substances 0.000 claims description 5
- 150000001216 Samarium Chemical class 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 125000006850 spacer group Chemical group 0.000 claims description 3
- 239000000463 material Substances 0.000 abstract description 5
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000003912 environmental pollution Methods 0.000 abstract description 3
- 229910021117 Sm(NO3)3 Inorganic materials 0.000 abstract 1
- 239000012670 alkaline solution Substances 0.000 abstract 1
- 150000004696 coordination complex Chemical class 0.000 abstract 1
- 238000005401 electroluminescence Methods 0.000 abstract 1
- 239000012266 salt solution Substances 0.000 abstract 1
- 239000000523 sample Substances 0.000 abstract 1
- 238000004458 analytical method Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 238000002447 crystallographic data Methods 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 238000005424 photoluminescence Methods 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 238000003786 synthesis reaction Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 230000005260 alpha ray Effects 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 238000012937 correction Methods 0.000 description 1
- 238000005564 crystal structure determination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910052747 lanthanoid Inorganic materials 0.000 description 1
- 150000002602 lanthanoids Chemical class 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- WCZVUZYEOJQHNJ-UHFFFAOYSA-M potassium;pyridine-3-carboxylate Chemical class [K+].[O-]C(=O)C1=CC=CN=C1 WCZVUZYEOJQHNJ-UHFFFAOYSA-M 0.000 description 1
- 229910052761 rare earth metal Inorganic materials 0.000 description 1
- 150000002910 rare earth metals Chemical class 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/003—Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/18—Metal complexes
- C09K2211/182—Metal complexes of the rare earth metals, i.e. Sc, Y or lanthanide
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Pyridine Compounds (AREA)
Abstract
The invention provides a niacin derivative ligand samarium metal complex with a light-emitting function. The metal complex is a complex of 5-(4-carboxyl phenoxy)niacin and samarium metal, and the chemical formula is [Sm(CPNA)2]n, wherein CPNA is 5-(4-carboxyl phenoxy)niacin. According to a preparation method, an alkaline solution prepared at normal temperature, a 5-(4-carboxyl phenoxy)niacin salt solution and a Sm(NO3)3 water solution are mixed, heated and cooled to obtain the complex. The preparation method is small in environmental pollution and low in energy consumption, the process is simple, reproducibility is good, and the complex can generate fluorescence and can be widely applied to the fields of electroluminescence, chemical sensors, fluorescence PET sensors or fluorescence probes as a light-emitting material.
Description
Technical field
The present invention relates to the title complex of rare earth metal samarium, be specifically related to a kind of nicotinic acid derivates part samarium metal complexes with lighting function, the invention still further relates to the preparation method of this title complex.
Background technology
Photoluminescence refers to that object relies on external light source and irradiates, thus obtains energy, produces to excite to be directed at luminous phenomenon.Photoluminescence can provide the information of the structure of some materials, composition and environment atomic arrangement, it is a kind of nondestructive, highly sensitive analytical procedure, if laser is applied in this kind of analytical procedure, this kind of analytical procedure just can be made more to be deep into the field of microcell, selective exitation and transient process, it is made to become important research means further again, be applied to the fields such as physics, Materials science, chemistry and molecular biology, progressively occur new frontier branch of science.
A metal-organic complex is subject to the people's attention due to its potential application in optical pickocff and organic luminescent device etc.As a kind of novel luminous organic material, in recent years lanthanide complex high-performance of novelty in optics receive people very big concern and by a large amount of synthesis and research, also one of forward position study hotspot becoming title complex luminescent chemical simultaneously, see: J.An, C.M.Shade, D.A.Chengelis-Czegan, S.Petoud .N.L.Rosi, J.Am.Chem.Soc.2011,133,1220 – 1223; M.D.Regulacio, M.H.Pablico, J.A.Vasquez, P.N.Myers, S.Gentry, M.Prushan, S.-W.Tam-Chang, S.L.Stoll, Inorg.Chem., 2008,47,1512-1523.P.Lenaerts, K.Driesen, R.V.Deun, K.Binnemans, Chem.Mater.2005,17,21482154; S.Petoud, S.M.Cohen, J.-C.G.Bunzli, K.N.Raymond, J.AM.CHEM.SOC.2003,125,13324-13325; Therefore, this type of title complex has wide space in the further research and development of stuctures and properties.
What the preparation method of the samarium metal complexes reported in current document adopted is solvent process for thermosynthesizing, and this method exists that organic solvent is big for environment pollution, temperature of reaction is high, danger is large, productive rate is low and the technological deficiency such as repeatable difference.
Summary of the invention
Technical problem to be solved by this invention is to provide that a kind of building-up process environmental pollution is little, energy consumption is low, productive rate is high, the nicotinic acid derivates part samarium metal complexes of tool lighting function and preparation method thereof.
For solving the problems of the technologies described above, the technical solution used in the present invention is: a kind of nicotinic acid derivates part samarium metal complexes with lighting function, for the title complex of 5-(4-carboxyphenoxy) nicotinic acid and samarium metal, chemical formula is [Sm (CPNA)
2]
n, wherein, CPNA is 5-(4-carboxyphenoxy) nicotinic acid, and the crystal of this samarium metal complexes belongs to triclinic(crystalline)system, and spacer is P-1, and unit cell parameters is:
α=93.156 (3) °, β=98.067 (3) °, γ=92.692 (3) °,
The preparation method of above-mentioned samarium metal complexes, step is as follows:
(1). under normal temperature, oxyhydroxide is soluble in water, obtain the basic solution of oxyhydroxide after stirring;
(2). under normal temperature, 5-(4-carboxyphenoxy) nicotinic acid is dissolved in the basic solution of oxyhydroxide, obtains 5-(4-carboxyphenoxy) nicotinate solution after stirring;
(3). under normal temperature, by Sm (NO
3)
3soluble in water, obtain Sm (NO after stirring
3)
3the aqueous solution;
(4). under normal temperature, by 5-(4-carboxyphenoxy) nicotinate solution and Sm (NO
3)
3aqueous solution, obtains 5-(4-carboxyphenoxy) nicotinate solution and Sm (NO after stirring
3)
3the mixing solutions of the aqueous solution;
(5). under normal temperature, 5-(4-carboxyphenoxy) nicotinate solution and Sm (NO
3)
3the mixing solutions of the aqueous solution is placed in autoclave, puts into baking oven for heating to 120 degrees Celsius of constant temperature 3 days, within 3 days, closes heating later and naturally cools to room temperature, obtain light yellow bulk-shaped monocrystal, the title complex of 5-(4-carboxyphenoxy) nicotinic acid samarium metal.
Described oxyhydroxide is sodium hydroxide or potassium hydroxide.
The amount ratio of described oxyhydroxide and the aqueous solution is 0.4-0.8mol/L.
The amount ratio of described part 5-(4-carboxyphenoxy) nicotinic acid and basic solution is 0.2-0.4mol/L.
Described metal-salt Sm (NO
3)
3be 0.4-0.8mol/L with the amount ratio of the aqueous solution.
Part oxyhydroxide, 5-(4-carboxyphenoxy) nicotinic acid and metal-salt Sm (NO in described reaction solution
3)
3mol ratio be 2:1:2.
A kind of nicotinic acid derivates part samarium metal complexes with lighting function of the present invention and preparation method thereof, this preparation method's environmental pollution is little, energy consumption is low, technique is simple, and reproducibility is good.Title complex can produce fluorescence, can be used as luminescent material to be used widely in fields such as electroluminescent, chemical sensor, fluorescence PET sensor or fluorescent probes, along with continuous progress and the fast development of luminescent material technology, it is expected to, it can have great meaning in raising Energy efficiency, reduction manufacturing cost etc.
Accompanying drawing explanation
Fig. 1 represents the Sm coordination environment figure of title complex of the present invention;
Fig. 2 represents the structural representation of title complex of the present invention.
Embodiment
A kind of nicotinic acid derivates part samarium metal complexes with lighting function of the present invention, be the title complex of 5-(4-carboxyphenoxy) nicotinic acid and samarium metal, chemical formula is [Sm (CPNA)
2]
n, wherein, CPNA is 5-(4-carboxyphenoxy) nicotinic acid, and the crystal of this samarium metal complexes belongs to triclinic(crystalline)system, and spacer is P-1, and unit cell parameters is:
α=93.156 (3) °, β=98.067 (3) °, γ=92.692 (3) °,
Embodiment 1
A kind of preparation method with the nicotinic acid derivates part samarium metal complexes of lighting function of the present invention, step is as follows:
(1). under temperature, 2mmoL sodium hydroxide is dissolved in 5mL water, obtains the basic solution of oxyhydroxide after stirring;
(2). under normal temperature, 1mmol5-(4-carboxyphenoxy) nicotinic acid is dissolved in 5mL aqueous sodium hydroxide solution, obtains 5-(4-carboxyphenoxy) naotin salts solution after stirring;
(3). under normal temperature, by 2mmoLSm (NO
3)
3be dissolved in 5mL water, after stirring, obtain Sm (NO
3)
3the aqueous solution;
(4). under normal temperature, 5mL5-(4-carboxyphenoxy) naotin salts solution and 5mLSm (NO
3)
3aqueous solution, obtains 5-(4-carboxyphenoxy) naotin salts solution and Sm (NO after stirring
3)
3the mixing solutions of the aqueous solution;
(5). under normal temperature, 5-(4-carboxyphenoxy) naotin salts solution and Sm (NO
3)
3the mixing solutions of the aqueous solution is placed in autoclave, puts into baking oven for heating to 120 degrees Celsius of constant temperature 3 days, within 3 days, closes heating later and naturally cools to room temperature, obtain light yellow bulk-shaped monocrystal, the title complex of 5-(4-carboxyphenoxy) nicotinic acid samarium metal.
Embodiment 2
A kind of preparation method with the nicotinic acid derivates part samarium metal complexes of lighting function of the present invention, step is as follows:
(1). under normal temperature, 2mmoL potassium hydroxide is dissolved in 5mL water, obtains the basic solution of potassium hydroxide after stirring;
(2). under normal temperature, 1mmol5-(4-carboxyphenoxy) nicotinic acid is dissolved in 5mL potassium hydroxide aqueous solution, obtains 5-(4-carboxyphenoxy) nicotinic acid potassium salts solution after stirring;
(3). under normal temperature, by 2mmoLSm (NO
3)
3be dissolved in 5mL water, after stirring, obtain Sm (NO
3)
3the aqueous solution;
(4). under normal temperature, 5mL5-(4-carboxyphenoxy) nicotinic acid potassium salts solution and 5mLSm (NO
3)
3aqueous solution, obtains 5-(4-carboxyphenoxy) nicotinic acid potassium salts solution and Sm (NO after stirring
3)
3the mixing solutions of the aqueous solution;
(5). under normal temperature, 5-(4-carboxyphenoxy) nicotinic acid potassium salts solution and Sm (NO
3)
3the mixing solutions of the aqueous solution is placed in autoclave, puts into baking oven for heating to 120 degrees Celsius of constant temperature 3 days, within 3 days, closes heating later and naturally cools to room temperature, obtain light yellow bulk-shaped monocrystal, the title complex of 5-(4-carboxyphenoxy) nicotinic acid samarium metal.
Embodiment 3
A kind of preparation method with the nicotinic acid derivates part samarium metal complexes of lighting function of the present invention, step is as follows:
(1). under normal temperature, 4mmoL sodium hydroxide is dissolved in 5mL water, obtains the basic solution of oxyhydroxide after stirring;
(2). under normal temperature, 2mmol5-(4-carboxyphenoxy) nicotinic acid is dissolved in 5mL aqueous sodium hydroxide solution, obtains 5-(4-carboxyphenoxy) naotin salts solution after stirring;
(3). under normal temperature, by 4mmoLSm (NO
3)
3be dissolved in 5mL water, after stirring, obtain Sm (NO
3)
3the aqueous solution;
(4). under normal temperature, 5mL5-(4-carboxyphenoxy) naotin salts solution and 5mLSm (NO
3)
3aqueous solution, obtains 5-(4-carboxyphenoxy) naotin salts solution and Sm (NO after stirring
3)
3the mixing solutions of the aqueous solution;
(5). under normal temperature, 5-(4-carboxyphenoxy) naotin salts solution and Sm (NO
3)
3the mixing solutions of the aqueous solution is placed in autoclave, puts into baking oven for heating to 120 degrees Celsius of constant temperature 3 days, within 3 days, closes heating later and naturally cools to room temperature, obtain light yellow bulk-shaped monocrystal, the title complex of 5-(4-carboxyphenoxy) nicotinic acid samarium metal.
The relevant characterization of title complex of the present invention and crystal structure determination:
To choose in above-described embodiment obtained monocrystalline under the microscope and at room temperature carry out X – ray diffraction experiments.On RigakuRAXIS-RAPID single crystal diffractometer, with the Mo – K through graphite monochromator monochromatization
αray
yi φ – ω mode collects diffraction data; Reduction of data is carried out by BrukerSAINT program; The diffraction data SADABS program of part-structure carries out absorption correction; Crystalline structure is solved in conjunction with difference Fourier synthesis by direct method; Whole non-hydrogen atom coordinate and anisotropic parameters carry out complete matrix least-squares refinement, and hydrogen atom position is determined by theoretical mode computation.The detailed axonometry data of the present invention are in table 1.
Table 1: the predominant crystal data of silver complex
aR＝Σ(||F
0|-|F
C||)/Σ|F
0|；
bwR＝[Σw(|F
0|
2-|F
C|
2)
2/Σw(F
0 2)]
1/2。
Claims (7)
1. have a nicotinic acid derivates part samarium metal complexes for lighting function, it is characterized in that the title complex for 5-(4-carboxyphenoxy) nicotinic acid and samarium metal, chemical formula is [Sm (CPNA)
2]
n, wherein, CPNA is 5-(4-carboxyphenoxy) nicotinic acid, and the crystal of this samarium metal complexes belongs to triclinic(crystalline)system, and spacer is
p-1, unit cell parameters is: a=5.9738 (11), b=12.528 (2), c=18.021 (4), α=93.156 (3) °, β=98.067 (3) °, γ=92.692 (3) °, V=1331.3 (4)
3.
2. prepare a method with the nicotinic acid derivates part samarium metal complexes of lighting function according to claim 1, it is characterized in that step is as follows:
(1). under normal temperature, oxyhydroxide is soluble in water, obtain the basic solution of oxyhydroxide after stirring;
(2). under normal temperature, 5-(4-carboxyphenoxy) nicotinic acid is dissolved in the basic solution of oxyhydroxide, obtains 5-(4-carboxyphenoxy) nicotinate solution after stirring;
(3). under normal temperature, by Sm (NO
3)
3soluble in water, obtain Sm (NO after stirring
3)
3the aqueous solution;
(4). under normal temperature, by 5-(4-carboxyphenoxy) nicotinate solution and Sm (NO
3)
3aqueous solution, obtains 5-(4-carboxyphenoxy) nicotinate solution and Sm (NO after stirring
3)
3the mixing solutions of the aqueous solution;
(5). under normal temperature, 5-(4-carboxyphenoxy) nicotinate solution and Sm (NO
3)
3the mixing solutions of the aqueous solution is placed in autoclave, puts into baking oven for heating to 120 degrees Celsius of constant temperature 3 days, within 3 days, closes heating later and naturally cools to room temperature, obtain light yellow bulk-shaped monocrystal, the title complex of 5-(4-carboxyphenoxy) nicotinic acid samarium metal.
3. preparation according to claim 2 has the method for the nicotinic acid derivates part samarium metal complexes of lighting function, it is characterized in that described oxyhydroxide is sodium hydroxide or potassium hydroxide.
4. preparation according to claim 2 has the method for the nicotinic acid derivates part samarium metal complexes of lighting function, it is characterized in that the amount ratio of described oxyhydroxide and the aqueous solution is 0.4-0.8mol/L.
5. preparation according to claim 2 has the method for the nicotinic acid derivates part samarium metal complexes of lighting function, it is characterized in that the amount ratio of described part 5-(4-carboxyphenoxy) nicotinic acid and basic solution is 0.2-0.4mol/L.
6. preparation according to claim 2 has the method for the nicotinic acid derivates part samarium metal complexes of lighting function, it is characterized in that described metal-salt Sm (NO
3)
3be 0.4-0.8mol/L with the amount ratio of the aqueous solution.
7. preparation according to claim 2 has the method for the nicotinic acid derivates part samarium metal complexes of lighting function, it is characterized in that part oxyhydroxide in described reaction solution, 5-(4-carboxyphenoxy) nicotinic acid and metal-salt Sm (NO
3)
3mol ratio be 2:1:2.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112010879A (en) * | 2020-09-15 | 2020-12-01 | 山西大学 | Two-dimensional Zn functional complex and preparation method and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015164784A1 (en) * | 2014-04-25 | 2015-10-29 | Rutgers, The State University Of New Jersey | Metal organic framework (mof) yellow phosphors and their applications in white light emitting devices |
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2016
- 2016-01-26 CN CN201610053421.XA patent/CN105541885A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2015164784A1 (en) * | 2014-04-25 | 2015-10-29 | Rutgers, The State University Of New Jersey | Metal organic framework (mof) yellow phosphors and their applications in white light emitting devices |
Non-Patent Citations (4)
| Title |
|---|
| GAO Y F. ET AL: ""Structure control and crystal-to-crystal transformation for two series of lanthanide–organic coordination polymers"", 《CRYSTENGCOMM》 * |
| QIN J S. ET AL: ""Syntheses, structures and luminescent properties of a series of 3D lanthanide coordination polymers with tripodal semirigid ligand"", 《JOURNAL OF SOLID STATE CHEMISTRY》 * |
| ROEL D. ET AL: ""Synthesis, Crystal Structures, and Luminescence Properties of Carboxylate Based Rare-Earth Coordination Polymers"", 《INORG. CHEM》 * |
| WU W P. ET AL: ""Double-step CO2 sorption and guest-induced single-crystal-to-single-crystal transformation in a flexible porous framework"", 《DALTON TRANS》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112010879A (en) * | 2020-09-15 | 2020-12-01 | 山西大学 | Two-dimensional Zn functional complex and preparation method and application thereof |
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