A kind of photocatalysis soil restoring device
Technical field
The invention belongs to environmental protection technical field, be specifically related to a kind of photocatalysis soil restoring device.
Background technology
Soil pollution can be caused by many things, comprises the existence of the material that non-natural produces in such as natural soils environment.Pollution can because of the leakage of such as buried tank, utilization of pesticides, polluted surface water infiltrate into subsurface formations, oil and fuel draining, the refuse of refuse landfill leaches or industrial waste is directly disposed to soil and causes.Some Common materials seen in contaminated soil comprise petroleum hydrocarbon, solvent, pesticide, lead and other heavy metals.Wherein, soil organic contamination mainly refers to the pollution of chemical pesticide, it can make composition of the soil and physicochemical property change, then the normal composition of spoiled soil, last by processes such as the absorption of plant and the accumulation of food chain, and then harm is formed to health, such as " three cause " effect: cause a disease, carcinogenic, mutagenesis.
In the prior art, the minimizing technology of pin organic polluted soil is the discarded or heating etc. utilizing the absorption of active carbon, contaminated soil, but mostly just pollutant is departed from soil, does not realize in essence thoroughly eliminating organic pollution.Even if utilize photochemical catalytic oxidation principle, also often contact abundant not with photochemical catalyst because be repaired soil, still residual a lot of pollutant, the effect of soil remediation is undesirable.
And soil remediation means of the prior art cause the degeneration of soil function more, so the pollutant in soil should be removed, ensure that soil function becomes in prior art the problem needing to solve again.
Summary of the invention
The object of the present invention is to provide a kind of photocatalysis soil restoring device, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme: a kind of photocatalysis soil restoring device, comprise shell 1, control device 2, turning cylinder 3, heating muff 4, light transmission film 5 and ultraviolet lamp 6, described shell 1 is the frame structure of lower open, control device 2 is arranged on the lateral wall of shell 1, the two ends of described turning cylinder 3 are longitudinally connected with the drive disk assembly be arranged on shell 1 madial wall, this drive disk assembly is electrically connected with the drive motors be arranged in control device 2, this drive disk assembly is controlled by drive motors switch 7, it is outside that heating muff 4 is fixedly installed on turning cylinder 3, be electrically connected with control device 2 and controlled by heater switch 8, the outside of this heating muff 4 is also provided with spiral conveying blade 9, the transverse direction perpendicular to turning cylinder 3 that the maximum rotating diameter of this spiral conveying blade 9 is less than shell 1 is wide, described light transmission film 5 covers the top being arranged at shell 1, ultraviolet lamp 6 is arranged on the madial wall of shell 1, and be electrically connected with control device 2, and controlled by ultraviolet lamp switch 10, spiral conveying blade 9 is also coated with photocatalytic coating, the top of described control device 2 is also provided with soil-repairing agent storage warehouse 14, the top of this soil-repairing agent storage warehouse 14 is uncovered, shell 1 madial wall of soil-repairing agent storage warehouse 14 side is provided with discharging opening 13, and discharging opening 13 is positioned at above spiral conveying blade 9, discharging opening 13 is provided with electrically operated valve 15, this electrically operated valve 15 is electrically connected with control device 2 and is controlled by electrically operated valve switch 16, additive in described soil-repairing agent storage warehouse 14 is soil-repairing agent, UHA and nano titanium dioxide powder, described spiral conveying blade 9 is provided with equally distributed circular protrusions 11, these protruding 11 surfaces scribble photocatalysis coating, this photocatalyst layer 12 is specially aluminum network structure, inner additive is nano titania silk, wherein soil-repairing agent comprises following component by weight:
Di-n-octyl sebacate 10-18
Isosorbide-5-Nitrae-lupetazin 6-12
Salicin 7-13
4-(2,6,6-trimethyl-2-cyclo-octene-1-base)-3-butene-2-one 2-8
4-aminoisoquinoline 0.8-2
Deionized water 20-40.
Preferably, described spiral conveying blade is provided with equally distributed circular protrusions, and this convex surfaces scribbles photocatalysis coating.
Preferably, the inner surface of described light transmission film is provided with photocatalyst layer, this photocatalyst layer is specially aluminum network structure, and inner additive is nano titania silk.
Compared with prior art, the invention has the beneficial effects as follows:
(1) this invention adopts rotating shaft to drive spiral conveying blade to rotate, thus stir contaminated soil fully, this spiral conveying blade is coated with photocatalytic coating, under the effect of ultraviolet lamp, considerably increase the contact area of contaminated soil and photochemical catalyst, improve the efficiency to soil remediation; In soil-repairing agent, add UHA and titanium dioxide, under the stirring action of spiral conveying blade, not only increase the functional of soil, and titania powder fully contacts with soil, strengthen photocatalysis effect further.
(2) heavy metal contained in soil and di-n-octyl sebacate, 4-(2,6,6-trimethyl-2-cyclo-octene-1-base)-3-butene-2-one, 1,4-lupetazin, salicin, 4-aminoisoquinoline five kinds of materials produce synergy, heavy metal ion generation chelatropic reaction is made by the inducing action of Analyses of High Affinity Binding Peptides, chelation can be produced with contents of many kinds of heavy metal ion such as copper, zinc, lead, chromium, cadmium, platinum, silver, gold, generate metal complex, this complex compound is water insoluble, removed by centrifugation operation, its removal efficiency of heavy metals can reach 99.3%.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
Fig. 2 is A-A directional profile figure in Fig. 1 of the present invention.
In figure: 1 shell, 2 control device, 3 turning cylinders, 4 heating muffs, 5 light transmission films, 6 ultraviolet lamps, 7 drive motors switches, 8 heater switch, 9 spiral conveying blades, 10 ultraviolet lamp switches, 11 projections, 12 photocatalyst layers, 13 discharging openings, 14 soil-repairing agent storage warehouses, 15 electrically operated valves, 16 electrically operated valve switches.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Refer to Fig. 1 and Fig. 2, the present embodiment is by shell 1, control device 2, turning cylinder 3, heating muff 4, light transmission film 5 and ultraviolet lamp 6 form, described shell 1 is the frame structure of lower open, control device 2 is arranged on the lateral wall of shell 1, the two ends of described turning cylinder 3 are longitudinally connected with the drive disk assembly be arranged on shell 1 madial wall, this drive disk assembly is electrically connected with the drive motors be arranged in control device 2, and this drive disk assembly is controlled by drive motors switch 7, it is outside that heating muff 4 is fixedly installed on turning cylinder 3, and be electrically connected with control device 2 and controlled by heater switch 8, the outside of this heating muff 4 is also provided with spiral conveying blade 9, ultraviolet lamp 6 is arranged on the madial wall of shell 1, and be electrically connected with control device 2, and controlled by ultraviolet lamp switch 10, the maximum rotating diameter of spiral conveying blade 9 is limited within the transverse width perpendicular to turning cylinder 3 of shell 1, described light transmission film 5 covers the top being arranged at shell 1, described spiral conveying blade 9 is also coated with photocatalytic coating, when the device is in operation, this device is placed on contaminated soil, open drive motors switch 6 respectively, heater switch 7 and ultraviolet lamp switch 10, spiral conveying blade 9 rotates along with the rotation of turning cylinder 3, the caking of contaminated soil is stirred by spiral conveying blade 9 to be opened, heating muff 4 heats and conducts heat to spiral conveying blade 8, heat reaches by the soil stirred thereupon, make some organic pollutants under high temperature action, depart from soil, under the effect of ultraviolet lamp 6, react with the photocatalytic coating that spiral conveying blade 9 covers, thus elimination organic pollution, described spiral conveying blade 9 is made up of the carbide alloy of wolfram steel or chromium steel material, the steel alloy selecting intensity high makes spiral conveying blade 9 when stirring contaminated soil, more abundant, and soil should not lump, and organic contaminants in soil and photocatalytic coating contact area are increased, the top of described control device 2 is also provided with soil-repairing agent storage warehouse 14, the top of this soil-repairing agent storage warehouse 14 is uncovered, bottom is provided with discharging opening 13, this discharging opening 13 is arranged on shell 1 madial wall of soil-repairing agent storage warehouse 14 side, and be positioned at above spiral conveying blade 9, discharging opening 13 is provided with electrically operated valve 15, this electrically operated valve 15 is electrically connected with control device 2 and is controlled by electrically operated valve switch 16, discharging opening 13 is to the direction discharge soil-repairing agent of spiral conveying blade 9, when spiral conveying blade 9 rotates, be stirred in uniformly in soil, make the additive in soil-repairing agent storage warehouse 14 and mix more fully, additive in described soil-repairing agent storage warehouse 14 is soil-repairing agent, the mixture of UHA and nano titanium dioxide powder, humic acid can flocculate, become a kind of cementing agent, the soil particle cementation of dispersion can be got up, form the crumb structure that water stability is good, improve soil enzyme activity, nano titanium dioxide powder can fully be repaired soil and contact, the nano titanium dioxide powder stayed in soil effectively can catch remaining organic pollution and virus in soil, further increase the adequacy of light-catalyzed reaction, and strengthen soil be repaired after functional,
Wherein soil-repairing agent comprises following component by weight:
Di-n-octyl sebacate 10-18
Isosorbide-5-Nitrae-lupetazin 6-12
Salicin 7-13
4-(2,6,6-trimethyl-2-cyclo-octene-1-base)-3-butene-2-one 2-8
4-aminoisoquinoline 0.8-2
Deionized water 20-40.
Described spiral conveying blade 9 is provided with equally distributed circular protrusions 11, these protruding 11 surfaces scribble photocatalysis coating, projection adds the surface area of photocatalytic coating on spiral conveying blade 9, organic contaminants in soil and photocatalytic coating contact area are increased, improves the efficiency removing pollutant in soil further.
Embodiment 2
Refer to Fig. 1 and Fig. 2, the inner surface of described light transmission film 5 is in the present embodiment provided with photocatalyst layer 12, this photocatalyst layer 12 is specially aluminum network structure, and inner additive is nano titania silk, other parts and connecting relation all identical with embodiment 1; This photocatalyst layer 12 increases the contact area of organic pollution and photochemical catalyst, can catch through the aerial organic pollution of heating volatilization, under the effect of ultraviolet lamp 6, eliminate the organic pollution be attached on photocatalyst layer 12, improve the efficiency removing pollutant in soil.
Although illustrate and describe embodiments of the invention, for the ordinary skill in the art, be appreciated that and can carry out multiple change, amendment, replacement and modification to these embodiments without departing from the principles and spirit of the present invention, scope of the present invention is by claims and equivalents thereof.