CN105537262A - Photocatalysis soil remediation device - Google Patents

Photocatalysis soil remediation device Download PDF

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Publication number
CN105537262A
CN105537262A CN201610021516.3A CN201610021516A CN105537262A CN 105537262 A CN105537262 A CN 105537262A CN 201610021516 A CN201610021516 A CN 201610021516A CN 105537262 A CN105537262 A CN 105537262A
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CN
China
Prior art keywords
soil
spiral conveying
control device
conveying blade
shell
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Granted
Application number
CN201610021516.3A
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Chinese (zh)
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CN105537262B (en
Inventor
杨俊锋
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Enbao (nanjing) Environmental Protection Technology Co Ltd
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Individual
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Priority to CN201610021516.3A priority Critical patent/CN105537262B/en
Priority to CN201711457957.9A priority patent/CN107913907B/en
Publication of CN105537262A publication Critical patent/CN105537262A/en
Application granted granted Critical
Publication of CN105537262B publication Critical patent/CN105537262B/en
Expired - Fee Related legal-status Critical Current
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B09DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
    • B09CRECLAMATION OF CONTAMINATED SOIL
    • B09C1/00Reclamation of contaminated soil
    • B09C1/08Reclamation of contaminated soil chemically

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  • Life Sciences & Earth Sciences (AREA)
  • Soil Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a photocatalysis soil remediation device which comprises a housing, a control device, a rotating shaft, a heating sleeve, a light-transmission film and ultraviolet lamps, wherein the housing is in a lower part opened frame structure; the control device is arranged on the outer side wall of the housing; a spiral conveying blade is arranged at the outer side of the heating sleeve; the ultraviolet lamps are arranged on the inner side wall of the housing; the spiral conveying blade is coated with a photocatalyst coating; a soil remediation agent storage bin is arranged on the control device; and additives in the soil remediation agent storage bin are a soil remediation agent, urea humate and nano-titanium dioxide powder. The photocatalysis soil remediation device adopts the rotating shaft to drive the spiral conveying blade to rotate, soil is stirred sufficiently, and the spiral conveying blade is coated with the photocatalyst coating, so that under the action of the ultraviolet lamps, a contact area between the contaminated soil and a photocatalyst is increased; and urea humate and titanium dioxide are added to the soil remediation agent, so that the functionality of the soil is further improved.

Description

A kind of photocatalysis soil restoring device
Technical field
The invention belongs to environmental protection technical field, be specifically related to a kind of photocatalysis soil restoring device.
Background technology
Soil pollution can be caused by many things, comprises the existence of the material that non-natural produces in such as natural soils environment.Pollution can because of the leakage of such as buried tank, utilization of pesticides, polluted surface water infiltrate into subsurface formations, oil and fuel draining, the refuse of refuse landfill leaches or industrial waste is directly disposed to soil and causes.Some Common materials seen in contaminated soil comprise petroleum hydrocarbon, solvent, pesticide, lead and other heavy metals.Wherein, soil organic contamination mainly refers to the pollution of chemical pesticide, it can make composition of the soil and physicochemical property change, then the normal composition of spoiled soil, last by processes such as the absorption of plant and the accumulation of food chain, and then harm is formed to health, such as " three cause " effect: cause a disease, carcinogenic, mutagenesis.
In the prior art, the minimizing technology of pin organic polluted soil is the discarded or heating etc. utilizing the absorption of active carbon, contaminated soil, but mostly just pollutant is departed from soil, does not realize in essence thoroughly eliminating organic pollution.Even if utilize photochemical catalytic oxidation principle, also often contact abundant not with photochemical catalyst because be repaired soil, still residual a lot of pollutant, the effect of soil remediation is undesirable.
And soil remediation means of the prior art cause the degeneration of soil function more, so the pollutant in soil should be removed, ensure that soil function becomes in prior art the problem needing to solve again.
Summary of the invention
The object of the present invention is to provide a kind of photocatalysis soil restoring device, to solve the problem proposed in above-mentioned background technology.
For achieving the above object, the invention provides following technical scheme: a kind of photocatalysis soil restoring device, comprise shell 1, control device 2, turning cylinder 3, heating muff 4, light transmission film 5 and ultraviolet lamp 6, described shell 1 is the frame structure of lower open, control device 2 is arranged on the lateral wall of shell 1, the two ends of described turning cylinder 3 are longitudinally connected with the drive disk assembly be arranged on shell 1 madial wall, this drive disk assembly is electrically connected with the drive motors be arranged in control device 2, this drive disk assembly is controlled by drive motors switch 7, it is outside that heating muff 4 is fixedly installed on turning cylinder 3, be electrically connected with control device 2 and controlled by heater switch 8, the outside of this heating muff 4 is also provided with spiral conveying blade 9, the transverse direction perpendicular to turning cylinder 3 that the maximum rotating diameter of this spiral conveying blade 9 is less than shell 1 is wide, described light transmission film 5 covers the top being arranged at shell 1, ultraviolet lamp 6 is arranged on the madial wall of shell 1, and be electrically connected with control device 2, and controlled by ultraviolet lamp switch 10, spiral conveying blade 9 is also coated with photocatalytic coating, the top of described control device 2 is also provided with soil-repairing agent storage warehouse 14, the top of this soil-repairing agent storage warehouse 14 is uncovered, shell 1 madial wall of soil-repairing agent storage warehouse 14 side is provided with discharging opening 13, and discharging opening 13 is positioned at above spiral conveying blade 9, discharging opening 13 is provided with electrically operated valve 15, this electrically operated valve 15 is electrically connected with control device 2 and is controlled by electrically operated valve switch 16, additive in described soil-repairing agent storage warehouse 14 is soil-repairing agent, UHA and nano titanium dioxide powder, described spiral conveying blade 9 is provided with equally distributed circular protrusions 11, these protruding 11 surfaces scribble photocatalysis coating, this photocatalyst layer 12 is specially aluminum network structure, inner additive is nano titania silk, wherein soil-repairing agent comprises following component by weight:
Di-n-octyl sebacate 10-18
Isosorbide-5-Nitrae-lupetazin 6-12
Salicin 7-13
4-(2,6,6-trimethyl-2-cyclo-octene-1-base)-3-butene-2-one 2-8
4-aminoisoquinoline 0.8-2
Deionized water 20-40.
Preferably, described spiral conveying blade is provided with equally distributed circular protrusions, and this convex surfaces scribbles photocatalysis coating.
Preferably, the inner surface of described light transmission film is provided with photocatalyst layer, this photocatalyst layer is specially aluminum network structure, and inner additive is nano titania silk.
Compared with prior art, the invention has the beneficial effects as follows:
(1) this invention adopts rotating shaft to drive spiral conveying blade to rotate, thus stir contaminated soil fully, this spiral conveying blade is coated with photocatalytic coating, under the effect of ultraviolet lamp, considerably increase the contact area of contaminated soil and photochemical catalyst, improve the efficiency to soil remediation; In soil-repairing agent, add UHA and titanium dioxide, under the stirring action of spiral conveying blade, not only increase the functional of soil, and titania powder fully contacts with soil, strengthen photocatalysis effect further.
(2) heavy metal contained in soil and di-n-octyl sebacate, 4-(2,6,6-trimethyl-2-cyclo-octene-1-base)-3-butene-2-one, 1,4-lupetazin, salicin, 4-aminoisoquinoline five kinds of materials produce synergy, heavy metal ion generation chelatropic reaction is made by the inducing action of Analyses of High Affinity Binding Peptides, chelation can be produced with contents of many kinds of heavy metal ion such as copper, zinc, lead, chromium, cadmium, platinum, silver, gold, generate metal complex, this complex compound is water insoluble, removed by centrifugation operation, its removal efficiency of heavy metals can reach 99.3%.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention;
Fig. 2 is A-A directional profile figure in Fig. 1 of the present invention.
In figure: 1 shell, 2 control device, 3 turning cylinders, 4 heating muffs, 5 light transmission films, 6 ultraviolet lamps, 7 drive motors switches, 8 heater switch, 9 spiral conveying blades, 10 ultraviolet lamp switches, 11 projections, 12 photocatalyst layers, 13 discharging openings, 14 soil-repairing agent storage warehouses, 15 electrically operated valves, 16 electrically operated valve switches.
Detailed description of the invention
Below in conjunction with the accompanying drawing in the embodiment of the present invention, be clearly and completely described the technical scheme in the embodiment of the present invention, obviously, described embodiment is only the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1
Refer to Fig. 1 and Fig. 2, the present embodiment is by shell 1, control device 2, turning cylinder 3, heating muff 4, light transmission film 5 and ultraviolet lamp 6 form, described shell 1 is the frame structure of lower open, control device 2 is arranged on the lateral wall of shell 1, the two ends of described turning cylinder 3 are longitudinally connected with the drive disk assembly be arranged on shell 1 madial wall, this drive disk assembly is electrically connected with the drive motors be arranged in control device 2, and this drive disk assembly is controlled by drive motors switch 7, it is outside that heating muff 4 is fixedly installed on turning cylinder 3, and be electrically connected with control device 2 and controlled by heater switch 8, the outside of this heating muff 4 is also provided with spiral conveying blade 9, ultraviolet lamp 6 is arranged on the madial wall of shell 1, and be electrically connected with control device 2, and controlled by ultraviolet lamp switch 10, the maximum rotating diameter of spiral conveying blade 9 is limited within the transverse width perpendicular to turning cylinder 3 of shell 1, described light transmission film 5 covers the top being arranged at shell 1, described spiral conveying blade 9 is also coated with photocatalytic coating, when the device is in operation, this device is placed on contaminated soil, open drive motors switch 6 respectively, heater switch 7 and ultraviolet lamp switch 10, spiral conveying blade 9 rotates along with the rotation of turning cylinder 3, the caking of contaminated soil is stirred by spiral conveying blade 9 to be opened, heating muff 4 heats and conducts heat to spiral conveying blade 8, heat reaches by the soil stirred thereupon, make some organic pollutants under high temperature action, depart from soil, under the effect of ultraviolet lamp 6, react with the photocatalytic coating that spiral conveying blade 9 covers, thus elimination organic pollution, described spiral conveying blade 9 is made up of the carbide alloy of wolfram steel or chromium steel material, the steel alloy selecting intensity high makes spiral conveying blade 9 when stirring contaminated soil, more abundant, and soil should not lump, and organic contaminants in soil and photocatalytic coating contact area are increased, the top of described control device 2 is also provided with soil-repairing agent storage warehouse 14, the top of this soil-repairing agent storage warehouse 14 is uncovered, bottom is provided with discharging opening 13, this discharging opening 13 is arranged on shell 1 madial wall of soil-repairing agent storage warehouse 14 side, and be positioned at above spiral conveying blade 9, discharging opening 13 is provided with electrically operated valve 15, this electrically operated valve 15 is electrically connected with control device 2 and is controlled by electrically operated valve switch 16, discharging opening 13 is to the direction discharge soil-repairing agent of spiral conveying blade 9, when spiral conveying blade 9 rotates, be stirred in uniformly in soil, make the additive in soil-repairing agent storage warehouse 14 and mix more fully, additive in described soil-repairing agent storage warehouse 14 is soil-repairing agent, the mixture of UHA and nano titanium dioxide powder, humic acid can flocculate, become a kind of cementing agent, the soil particle cementation of dispersion can be got up, form the crumb structure that water stability is good, improve soil enzyme activity, nano titanium dioxide powder can fully be repaired soil and contact, the nano titanium dioxide powder stayed in soil effectively can catch remaining organic pollution and virus in soil, further increase the adequacy of light-catalyzed reaction, and strengthen soil be repaired after functional,
Wherein soil-repairing agent comprises following component by weight:
Di-n-octyl sebacate 10-18
Isosorbide-5-Nitrae-lupetazin 6-12
Salicin 7-13
4-(2,6,6-trimethyl-2-cyclo-octene-1-base)-3-butene-2-one 2-8
4-aminoisoquinoline 0.8-2
Deionized water 20-40.
Described spiral conveying blade 9 is provided with equally distributed circular protrusions 11, these protruding 11 surfaces scribble photocatalysis coating, projection adds the surface area of photocatalytic coating on spiral conveying blade 9, organic contaminants in soil and photocatalytic coating contact area are increased, improves the efficiency removing pollutant in soil further.
Embodiment 2
Refer to Fig. 1 and Fig. 2, the inner surface of described light transmission film 5 is in the present embodiment provided with photocatalyst layer 12, this photocatalyst layer 12 is specially aluminum network structure, and inner additive is nano titania silk, other parts and connecting relation all identical with embodiment 1; This photocatalyst layer 12 increases the contact area of organic pollution and photochemical catalyst, can catch through the aerial organic pollution of heating volatilization, under the effect of ultraviolet lamp 6, eliminate the organic pollution be attached on photocatalyst layer 12, improve the efficiency removing pollutant in soil.
Although illustrate and describe embodiments of the invention, for the ordinary skill in the art, be appreciated that and can carry out multiple change, amendment, replacement and modification to these embodiments without departing from the principles and spirit of the present invention, scope of the present invention is by claims and equivalents thereof.

Claims (3)

1. a photocatalysis soil restoring device, comprise shell (1), control device (2), turning cylinder (3), heating muff (4), light transmission film (5) and ultraviolet lamp (6) etc., the frame structure that described shell (1) is lower open, control device (2) is arranged on the lateral wall of shell (1), the two ends of described turning cylinder (3) are longitudinally connected with the drive disk assembly be arranged on shell (1) madial wall, this drive disk assembly is electrically connected with the drive motors be arranged in control device (2), this drive disk assembly is controlled by drive motors switch (7), it is outside that heating muff (4) is fixedly installed on turning cylinder (3), be electrically connected with control device (2) and controlled by heater switch (8), the outside of this heating muff (4) is also provided with spiral conveying blade (9), the maximum rotating diameter of this spiral conveying blade (9) is less than the transverse width perpendicular to turning cylinder (3) of shell (1), described light transmission film (5) covers the top being arranged at shell (1), ultraviolet lamp (6) is arranged on the madial wall of shell (1), and be electrically connected with control device (2), and controlled by ultraviolet lamp switch (10), it is characterized in that: (9) are also coated with photocatalytic coating to spiral conveying blade, the top of described control device (2) is also provided with soil-repairing agent storage warehouse (14), the top of this soil-repairing agent storage warehouse (14) is uncovered, shell (1) madial wall of soil-repairing agent storage warehouse (14) side is provided with discharging opening (13), and discharging opening (13) is positioned at spiral conveying blade (9) top, discharging opening (13) is provided with electrically operated valve (15), this electrically operated valve (15) is electrically connected with control device (2) and is controlled by electrically operated valve switch (16), additive in described soil-repairing agent storage warehouse (14) is soil-repairing agent, UHA and nano titanium dioxide powder, described spiral conveying blade (9) is provided with equally distributed circular protrusions (11), this projection (11) surface scribbles photocatalysis coating, this photocatalyst layer (12) is specially aluminum network structure, inner additive is nano titania silk, wherein soil-repairing agent comprises following component by weight:
Di-n-octyl sebacate 10-18
Isosorbide-5-Nitrae-lupetazin 6-12
Salicin 7-13
4-(2,6,6-trimethyl-2-cyclo-octene-1-base)-3-butene-2-one 2-8
4-aminoisoquinoline 0.8-2
Deionized water is about 20-40.
2. a kind of photocatalysis soil restoring device according to claim 1, it is characterized in that: the inner surface of described light transmission film (5) is provided with photocatalyst layer (12), this photocatalyst layer (12) is specially aluminum network structure, and inner additive is nano titania silk.
3. a kind of photocatalysis soil restoring device according to claim 1, described spiral conveying blade (9) is made up of wolfram steel or chromium steel material.
CN201610021516.3A 2016-01-14 2016-01-14 A kind of photocatalysis soil restoring device Expired - Fee Related CN105537262B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201610021516.3A CN105537262B (en) 2016-01-14 2016-01-14 A kind of photocatalysis soil restoring device
CN201711457957.9A CN107913907B (en) 2016-01-14 2016-01-14 Photocatalysis soil prosthetic devices

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Application Number Priority Date Filing Date Title
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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105798057A (en) * 2016-05-12 2016-07-27 湖南恒凯环保科技投资有限公司 Rotating reaction generator and method for repairing organic contaminated soil based on photocatalysis of rotating reaction generator
CN107715647A (en) * 2017-06-17 2018-02-23 江苏奔拓电气科技有限公司 A kind of kitchen garbage organic waste gas treatment device and its application process
CN107913907A (en) * 2016-01-14 2018-04-17 邱博 A kind of photocatalysis soil restoring device
CN109226240A (en) * 2018-10-17 2019-01-18 广州市花林景观工程有限公司 A kind of catalytic type contaminated soil remediation device
CN109382404A (en) * 2017-08-11 2019-02-26 中国石油化工股份有限公司 Petroleum hydrocarbon contaminated soil prosthetic device and restorative procedure
CN110026427A (en) * 2019-03-30 2019-07-19 望江县同心农业专业合作社 One kind being based on light-catalysed organic pollution soil repair system
CN112222169A (en) * 2020-09-23 2021-01-15 南京九胜揽天科技有限公司 Efficient soil pollution treatment restoration equipment and method thereof

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CN111408617A (en) * 2020-04-18 2020-07-14 袁倪鸿 Soil remediation device
CN113526610B (en) * 2021-08-04 2022-09-09 九江南大环保创新中心有限公司 Dye wastewater photocatalysis degree of depth degradation processing apparatus

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DE19723607A1 (en) * 1997-06-05 1998-12-10 Wolfgang Dr Ing Schuldes Decontamination of soils, slurries, etc. with almost complete breakdown of contaminants
JP2003117540A (en) * 2001-10-18 2003-04-22 Mirai Kensetsu Kogyo Kk Soil amending device
JP2003320366A (en) * 2002-05-02 2003-11-11 Nippon Steel Corp Method for cleaning contaminated soil
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Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107913907A (en) * 2016-01-14 2018-04-17 邱博 A kind of photocatalysis soil restoring device
CN105798057A (en) * 2016-05-12 2016-07-27 湖南恒凯环保科技投资有限公司 Rotating reaction generator and method for repairing organic contaminated soil based on photocatalysis of rotating reaction generator
CN107715647A (en) * 2017-06-17 2018-02-23 江苏奔拓电气科技有限公司 A kind of kitchen garbage organic waste gas treatment device and its application process
CN109382404A (en) * 2017-08-11 2019-02-26 中国石油化工股份有限公司 Petroleum hydrocarbon contaminated soil prosthetic device and restorative procedure
CN109382404B (en) * 2017-08-11 2021-08-03 中国石油化工股份有限公司 Petroleum hydrocarbon polluted soil remediation device and remediation method
CN109226240A (en) * 2018-10-17 2019-01-18 广州市花林景观工程有限公司 A kind of catalytic type contaminated soil remediation device
CN110026427A (en) * 2019-03-30 2019-07-19 望江县同心农业专业合作社 One kind being based on light-catalysed organic pollution soil repair system
CN112222169A (en) * 2020-09-23 2021-01-15 南京九胜揽天科技有限公司 Efficient soil pollution treatment restoration equipment and method thereof
CN112222169B (en) * 2020-09-23 2021-08-10 江西中科玮玥生态科技发展有限公司 Efficient soil pollution treatment restoration equipment and method thereof

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