CN1055109A - Cleaning product - Google Patents
Cleaning product Download PDFInfo
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- CN1055109A CN1055109A CN 91101871 CN91101871A CN1055109A CN 1055109 A CN1055109 A CN 1055109A CN 91101871 CN91101871 CN 91101871 CN 91101871 A CN91101871 A CN 91101871A CN 1055109 A CN1055109 A CN 1055109A
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Abstract
The foamy cleaning product of a kind of generation, comprise the compressible non-aerosol type disperser that has reservoir, dispensing head and liquid-air mixing device, wherein wrap aqueous Cleasing compositions in the reservoir, compositions includes: (a) about 0.1-16% imidazoles or ammonium type amphoteric surfactant, (b) 0.1-16% amino-alkane hydrochlorate or iminodiacetic alkanoate type amphoteric surfactant (c) are not more than 10% anion surfactant and (d) water as required; Wherein the surfactant total concentration is about and contains 20% (a) and mixture (b) in 0.2-20% and this surfactant at least.
Description
The present invention relates to cleaning product; Specifically, relate to personal blistered cleaning product, this product is suitable for cleaning skin and/or hair, and can cleansing product and forms such as facial cleaning agent, foam bath preparation, shower articles for use and shampoo use it.This cleaning product also is applicable on other purposes that need produce stable foam.The invention still further relates to and contain such as function composition such as antibacterial and demonstrate the cleaning product that effect is improved.
The make-up composition of foaming must satisfy many requirements, comprising cleaning power, foam performance with for gentleness-low irritant of skin, hair and eye mucosa (The occular mucosae).
Skin is formed the keratin and proteic which floor cellularity of collagen fiber of skin texture skeleton by topped and protection.The outermost layer of cellular layer is called horny layer, and is known to by 80
250 of thick several layers of encirclement
The albumen bundle form.Anion surfactant can penetrate said cutin tunic, and destroys its integrity by degreasing (promptly removing lipid from horny layer).The partial this destruction of skin surface causes pachylosis, and may make the final and keratin reaction of said surfactant, produces stimulation.
Skin or hair should be mildly cleaned in ideal cosmetic cleaning agent, and be non-stimulated or almost have no stimulation, and skin is not had defat and/or desiccation, and often use the no skin-tightening effect in back.But the soap blank of great majority foaming or soap rod or soap lye do not meet above-mentioned requirements.
People know that some synthetic surfactant is a mildness.But, quite the major defect of mildness synthetic surfactant system is: foam performance is not as five-star soap rod (they are to be rich in Oleum Cocois soap and adipic) when being made into the skin clean product, on the other hand, use contains the known high foam anion surfactant of foamed promoter, can produce the foam of satisfactory amount and matter.Unfortunately, in fact its clinical skin mildness is poor the highest foamy anion surfactant.In the gentleest surfactant, for example lauryl glyceryl ether sulfonic acid sodium (AGS) etc. is viable reluctantly on foaming properties.These two facts make the selection of surfactant help foaming and the compound method of skin sense becomes and very is difficult to equilibrated problem.
Very harsh requirement to the cosmetic cleaning agent is limiting the selection of surfactant, and final prescription has reflected trading off in a way.Mildness usually is to obtain sacrificing under the situation of clenaing effect, perhaps may sacrifice foaminess for mildness or product stability (or the two).
Therefore, need at present to produce abundant, stable and the high foam of quality (compactness), and be the cleaning product of effective cleaning agent of skin and hair, this product should be very gentle to skin, hair and eye mucosa.
Disclosed among the US-A-3962150 and used the moisture skin cleansing compositions that belongs to so-called " non-pressurised property " aerated foam cleaning product.But, still need at present the foam stability and the Emulsion that can provide good, have good mildness, product stability and easy-to-use frothing cleaning product under various uses and temperature conditions simultaneously.In addition, also need at present the personal cleansing product that improves antibiotic property can be provided.
Theme of the present invention is the frothing cleaning product of a kind of personal cleanliness's of being applicable to skin or hair, can be used as cleansing product and facial cleaning agent, foam bath and shower articles for use and shampoo etc.Said product comprises and has reservoir, disperses head, liquid-air mixing device and homogenizer is preferably arranged and the compressible non-aerosol disperser of non-answer valve gear, in said reservoir, accommodate the aqueous cleaning composition that belongs to a part of the present invention, wherein comprise:
(a) first kind of amphoteric surfactant from ammonium derivative about 0.1 weight %～about 16 weight %,, selecting by the imdazole derivatives of formula I and/or formula IV:
R wherein
1Be C
7-C
22Alkyl or alkenyl,
R
2Be hydrogen or CH
2Z, each Z are CO independently of one another
2M or CH
2CO
2M, and M is hydrogen, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium,
R wherein
1, R
2Define as above with Z;
(b) from about 0.1 weight %～about 16 weight %, by second kind of amphoteric surfactant selecting the iminodiacetic alkanoate of the amino-alkane hydrochlorate of formula II, formula III or its mixture:
Wherein, n and m are 1～4 numerical value, and R
1Be independently selected from the group that limits in top (a) with M;
(c) anion surfactant of as many as about 10% as required; And
(d) water;
Wherein, said Cleasing compositions contains the surfactant total concentration from about 0.2 weight %～about 20 weight %, and the total concentration of wherein said first kind and second kind amphoteric surfactant accounts at least 20 weight % of said surfactant total concentration.
Remove and to indicate in addition, otherwise whole concentration herein and ratio are all by the weight calculating of said Cleasing compositions.
The present invention relates to have good foam characteristic, and the frothing cleaning product of good mildness, stability, cleansing power and bactericidal property.According to one aspect of the present invention, said cleaning product comprises the Cleasing compositions of liquid, aqueous form, (wherein containing the amphoteric surfactant mixture that limits to some extent), said composition is contained in the compressible disperser of what is called " squash type foam maker " container (this container is equipped with and disperses head and liquia air mixing arrangement), can easily disperse said Cleasing compositions out with blister foam form from said container by extruding.The necessary characteristics and the selectivity characteristics of this respect product of the present invention are described as follows.
The said Cleasing compositions that the present invention preferably uses comprises a kind of mixture of being made up of two kinds of amphoteric surfactantes, and first kind of amphoteric surfactant is selected from the surfactant of the ammonium derivative of the imidazoles of formula I and/or formula IV:
R wherein
1Be C
7-C
22Alkyl or alkenyl,
R
2Be hydrogen or CH
2Z, each Z are CO independently of one another
2M or CH
2CO
2M,
And M is H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium,
R wherein
1, R
2Define as above with Z;
And second kind of amphoteric surfactant is selected from the amino-alkane hydrochlorate of formula II, imido grpup two alkanoates or its mixture of formula III:
Wherein n and m are 1～4 integers, and R
1Be independently selected from the group that preamble limits with M.
The Cleasing compositions that the present invention uses also can contain other (preferred gentle) surfactant, particularly anion surfactant.But, the present invention preferably wherein said first kind and second kind of amphoteric surfactant total concentration, at least accounting for about 20 weight % in total surfactant concentration, preferably account for those compositionss of about 50 weight % at least, is suitable from this ratio of viewpoint that obtains best foam characteristic.In preferred compositions, the mixture of said first and second kinds of amphoteric surfactantes accounts for the about 60% of surface activity gross weight at least, more preferably at least about 75%.
First type the amphoteric surfactant that is suitable for is sold with trade (brand) name " Miranol " on market, and it is believed that and comprise the complex mixture that is grouped into by several one-tenth.Traditionally, said " Miranols " said the structure that becomes to have formula I, but at＜CTFA cosmetic composition dictionary〉what state clearly in (the 3rd edition) is non-ring structure IV.In fact as if, the complex mixture of ring-type and non-annularity composition all exists, these two kinds definition are described so that overall understanding at this.
The example that is suitable for as first kind of amphoteric surfactant comprises wherein R
1Be C
8H
17(particularly iso-octyl), C
9H
19And C
11H
23The formula I of alkyl and/or the chemical compound of formula IV.Especially preferred R wherein
1Be C
9H
19, Z is CO
2M and R
2Be the chemical compound of H and R wherein
1Be C
11H
23, Z is CO
2M and R
2Be CH
2CO
2The chemical compound of M.
Be appreciated that such amphoteric surfactant of selling on many markets, all be with the composite form of anion surfactant, particularly with sulfonated C
8-C
18Alcohol, C
8-C
18Ethoxylated alcohol or C
8-C
18The composite form manufacturing of acyl glyceride type anion surfactant and sale.Therefore, according to one aspect of the present invention, said compositions comprises premix or the complex that said first kind of amphoteric surfactant and anion surfactant form by about 1: 1 equivalent proportion, so that proximate electric neutrality is provided.
As second kind of employed suitable amphoteric surfactant example of amphoteric surfactant, comprise salt, especially tri ethanol ammonium salt and N-lauryl-Beta-alanine salt and N-lauryl-imido grpup dipropionate.
The content of first kind and second kind amphoteric surfactant preferably respectively is about 0.5～10 weight % in the said Cleasing compositions, more preferably 0.5～4 weight %.The ratio of first kind of amphoteric surfactant and second kind of amphoteric surfactant, preferred about 10: 1～about 1: 10, more preferably from about 5: 1～about 1: 5, preferred about 3: 1～about 1: 3 especially.
Compositions of the present invention can comprise or mend with the surfactant outside the amphoteric surfactant of top defined.But the total concentration of surfactant in the said compositions generally is in about 0.2～about 20 weight % scopes, preferred about 1～about 16 weight %, and 1～about 8 weight % more preferably from about are in preferred especially about 2～about 6 weight % scopes.Even product characteristics of the present invention is the foam stability and the Emulsion that can provide good under the low concentration cleansing surfactants.
Preferred surfactants is an anion surfactant in the present composition.Preferably about 0.1～10 weight % of its amount, more preferably from about 0.5～5 weight %, especially preferably about 1～about 3 weight %.The preferred anionic surfactant that comprises in the compositions of the present invention; except the alkyl sulfate and acyl glyceride sulfate of alkyl sulfate above-mentioned, ethoxylation, also has the mixture of protein, protein degradation or amino acid whose fatty acid condensation product or these condensation products.In highly preferred embodiment, said fatty acid condensation product is selected from:
(ⅰ) C
8-C
22(preferred C
10-C
18) condensation product of fatty acid and aminosal,
(ⅱ) by C
8-C
22(preferred C
10-C
18) fatty acid derived the fatty acid sarcosinate and
(ⅲ) their mixture.
Other the mildness synthesis of detergent surfactant that is suitable for that can be used in the said Cleasing compositions comprises methyl-acyl taurine salt; the fatty acyl glycinate; the N-acyl glutamate; alkyl androstanediol; alkyl glycerol ester and ethoxylated glycerol ester; the acyl group isethionic acid ester, alkyl sulfosuccinate, α-alpha-sulfonated fatty acid and salt thereof and/or ester; alkyl phosphate salt; the alkyl phosphate salt of ethoxylation, alkyl ether sulfate, glucose ester and alkylation (as methyl) glucose ester; the mixture of alkyl ether sulfate and alkyl amine oxide; betaine, Sultaines, and their mixture.In said surfactant, comprise vitriolic ammonium salt of the alkyl ether sulfate that contains no more than 12 ethyoxyls, especially lauryl ether and sodium salt.The alkyl in these surfactants and/or the chain of acyl group aim at C
8-C
22, preferred C
10-C
18
The detergent surfactant of the synthetic gentleness that these types are suitable for comprises: C
8-C
18Alkylphosphonate preferably is its polyhydric alcohol shape to small part, N for example, N, N ', N '-tetraethoxide-(ethylenediamine (tetrahydroxylic alcohol) salt, N-(C
8-C
18Fatty acyl group) glutamate, Glu, C
8-C
18The mixture of fatty acyl glycinate and/or they and other synthetic anionic detergent surfactant, with and/or their mixture.
That compositions of the present invention preferably also comprises is about 0.01～about 5%, preferred about 0.04～about 2%, preferred especially about polymeric viscosifier of 0.05～about 1%.It is found that said polymeric viscosifier helps to promote Emulsion and foamy quality and the dispersing characteristic of product do not produced negatively influencing.
In general, but useful the said polymer should be in water solvable or degree of scatter should make the composition viscosity of corresponding no polymer, under 70 °F (21.2 ℃), improve about 1 centipoise at least, preferably improve about 2～about 10 centipoises, more preferably improve about 2～about 5 centipoises.The polymer that is suitable for be high molecular weight material (for example the matter average molecular weight value with light scattering determining generally is about 2,000～3,000,000, preferably about 5,000～about 1,000,000, and more preferably from about 7,000～about 1,000,000).Because the said polymer obviously is to work by improving composition viscosity,, make under the said polymer 70 (21.2 ℃) in water the viscosity of 1% dispersion liquid greater than about 1 centipoise, preferred about 2 centipoises so the said polymer preferably has thickening property.
Operable polymer is be suitable for using in the cosmetic field cationic, nonionic, both sexes and anionic polymer.Preferred cation and non-ionic polyalcohol that those are used as hair or skin conditioner in cosmetic field.
The representative polymer that hair or skin are had regulating action, comprise cationic and the nonionic polysaccharide, cationic and the nonionic homopolymer and the copolymer of deriving out by acrylic acid and/or methacrylic acid, cationic and nonionic celluosic resin, dimethyl diallyl ammonium chloride and acrylic acid cation copolymer, the cationic homopolymer of dimethyl diallyl ammonium chloride, cationic polyalkylene and ethyoxyl polyalkyleneimine, the siloxanes of seasonization and their mixture.
The example of the cationic polymerization regulator that the present invention preferably uses comprises: cation guanidine glue, Hydroxyproyl Trimethyl ammonium guanidine glue (substitution value 0.11～0.22) for example, the commercially available brand name of this guanidine glue is Jaguar C-14-S(RTM) and Jaguar C-17(RTM) and Jaguar C-16(RTM), hydroxypropyl substituent group (substitution value 0.8-1.1) wherein except that containing above-mentioned cation group, also comprised; And brand name is the cellulose ethers of the seasonization of Ucare Polymer JR and Celquat when commercially available.Other cation type polymer that is suitable for is that brand name is the homopolymer of the commercially available dimethyl diallyl ammonium chloride of Merquat 100, brand name is commercially available amino-ethyl dimethylaminoethyl acrylate methyl ester and the copolymer of acrylamide and the copolymer of dimethyl diallyl ammonium chloride and acrylamide of Merquat 550 and Merquat S, with the brand name vinyl pyrrolidone acrylate or the methacrylate copolymer of the seasonization of the amino alcohol sold of Gafguat, and polyalkyleneimine class, for example polymine of polymine and ethoxylation.
Other polymer that is suitable for the present invention's use comprises: hydroxyethyl-cellulose (as Natrosol 250MXR and Natrosol 250HHR), xanthene glue (as Keltrol T), the polymer of saccharide or oligosaccharide and compatible synthon, the polycarboxylate of seasonization, Polyethylene Glycol monoesters/ether and dibasic acid esters/ethers (as Polyethylene Glycol (20-500) distearate).
Said Cleasing compositions can optionally comprise hair or skin moisturizing agent.Preferred humidizer concentration is about 3～about 40 weight %.In preferred embodiments, said humidizer be non-occlusor and also be selected from:
1, water-soluble liquid polyhydric alcohol,
2, the natural amino-acid compound that is present in the necessity in the keratodermatitis, and
3, non-how pure non-occlusor agent of water solublity and composition thereof.
Some example of preferred non-occlusor humidizer is a glycerol, Polyethylene Glycol, propylene glycol, sorbitol, the Polyethylene Glycol of the glucose of first (as methyl glucosan-20) and the ethers of propylene glycol, the Polyethylene Glycol of lanolin alcohol (as Solulan-75) and the ethers of propylene glycol, ketopyrrolidine sodium formate, lactic acid, carbamide, L-proline, guanidine, ketopyrrolidine and composition thereof.Glycerol most preferably in the above-mentioned substance.
Other example of the non-occlusor humidizer of water solublity comprises: water solublity adipic acid, lactic acid, oleic acid, stearic acid, isostearic acid, myristic acid or linoleic cetyl ester, myristyl ester, isodecyl ester or isopropyl esters, and the esters of many and their correspondent alcohols (isostearoyl lactate sodium and octyl group lactate sodium), the protein of hydrolysis and other collagenic protein class, aloe vera gel and acetamide monoethanolamine (acetamide MEA).
Another useful characteristics of the present invention are so wonderful discoveries, promptly mix the usefulness of Cleasing compositions after the functional components such as antibiotic or antibacterial, are significantly improved because of this Cleasing compositions being placed the foaming cleaner of inflation.Especially find: in water insoluble basically but in said Cleasing compositions (preferably with homogenizing micellar solution form) obtain those functional components of solubilising, show good surface deposition effect and direct characteristics, thereby the usefulness of improvement arranged.Therefore, provide a kind of personal cleaning compositions in the squash type foam maker that is contained in according to a second aspect of the present invention, in said compositions, comprised about 0.5～about 16 weight % surfactants (synthetic, soap or its mixture) and preferred about 0.01～about 5(preferably about 0.1～about 4) the water-solubility function composition of weight % (as antibacterial etc.).
The antibacterial that is suitable for using among the present invention comprises: 3,4-two and 3,4 ', 5-three bromo-salicylamides, 4,4 '-two chloro-3-(trifluoromethyls)-carbanilide, 3,4,4 '-Amolden MCM 400, phenyl phenol, phenoxypropanol, chlorhexidine salt, primidone salt, 2 ', 4,4 '-three chloro-2-hydroxyl-diphenyl ethers (Trichlosan), 2,2 '-methylene-two (4-chloro-6-bromophenols), salicylic acid, parachlorometaxylenol, 1-hydroxy-4-methyl-6-(2,4, the 4-tri-methyl-amyl)-2-(1H)-pyridonium salt (Octopirox) and composition thereof.For water-fast antibacterial, preferably also adding concentration is about 0.1～about 5 weight % solubilizing agents, as propylene glycol.
In said Cleasing compositions, can add many additional selectivity compositions.Such composition comprises: protein and polypeptide and derivant thereof; Water solublity or lyotropy antiseptic, for example Germall 115, the methyl ester of hydroxy benzoic acid, ethyl ester, propyl ester and butyl ester class, EDTA, Euxyl(RTM) K400,2-bromo-2-nitropropane-1,3-glycol (Bronopol); Other humidizer, as hylaronic acid, chitin and starch-grafted sodium polyacrylate (as Sanwet(RTM) IM1000, IM-1500 and IM2500, be stated from USA-4, among 076,663, sell) by Virginia, USA baud Smith city fiber alkane superabsorbent material company; Hexanediol and propylene glycol equal solvent; Ammonium ion source is (as NH
4Cl) and so on low temperature phase modifier; Coloring agent; Spice and spice solubilizing agent etc.Traditional non-ionic lubricant can be used as additional skin conditioner and is included in the said compositions, and its amount is not higher than about 10%, preferred about 1～about 6%.Such material comprises: for example esters and Cortex cocois radicis wet goods triglyceride classes such as mineral oil, sorbitan esters of fatty acids (seeing No. 3988255 United States Patent (USP)s authorizing Seiden on October 26th, 1976 for details), lanoline and lanolin derivative, isopropyl myristate.In compositions of the present invention, also can there be the about 60～about 99 weight % of concentration, preferably at least about the water of 75 weight %.
The pH of said compositions, preferred about 4～about 9, more preferably from about 4.5～about 8.5, pH for example utilizes the citric acid buffer system to be controlled.
Compositions of the present invention is contained among the compressible non-aerosol disperser of what is called " squash type foam maker " type, comprising container, disperse head, liquid-air mixing device and preferably have homogenizer and non-answer valve gear.
According to the content of following Patent publish, squash type foam maker packing container is well-known:
US-A-3,709,437(1973 January 9 authorized Wright),
US-A-3,937,364(1976 February 10 authorized Wright),
US-A-4,022,351(1977 May 10 authorized Wright),
US-A-4,147,306(1979 April 3 authorized Bennett),
US-A-4,184,615(1980 January 22 authorized Wright),
US-A-4,598,862(1986 July 8 authorized Rice),
US-A-4,615,467(1986 October 7 authorized Grogan) and
FR-A-2,604,622(1988 announced April 8, Verlhulst).
Top packing container does not use propellant, all is safe for consumer and environment therefore.Said Cleasing compositions is placed in the storeroom of said container, said storeroom for example can be a plastics squeeze bottle.When pushing the storeroom of said container with hand-power, said compositions is by making it and the blended liquid of air-air mixing head, preferably makes foam more even and control the conforming homogenizer of said foam by one more then.After this, said foam is emitted by the dispersion head of said disperser with the form of foam of homogeneous, non-pressurised inflation.
The minimum force that makes the work of said squash type foam maker is about 1, is preferably about 2～about 15 pounds/inch
2(gauge pressure).Said minimum force is relevant with the channel size of said disperser and the viscosity of said compositions etc.
Said foamy density generally should be about 0.002～about 0.25 gram/CC, and preferred value is about 0.01～about 0.07 gram/CC.Foamy density and foamy Emulsion negative correlation, therefore preferred lower foam density value.
The present invention obtains describing in detail by following non-limiting examples.
In an embodiment, all concentration is all by 100% activity, and all abbreviations are defined as follows:
Both sexes A:, be with R wherein through the Miranol of modification MSA
1Be C
9H
19, R
2Be H, Z is CO
2The formula I of Na and/or the amphoteric surfactant of formula IV and sodium lauryl sulfate with etc. mol ratio be composited;
Both sexes B:, be with R wherein through the Miranol of modification 2MCA
1Be C
11H
23, R
2Be CH
2CO
2Na, Z are CO
2The formula I of Na and/or the amphoteric surfactant of formula IV and sodium lauryl sulfate with etc. mol ratio be composited;
Both sexes C:N-lauryl-Beta-alanine sodium;
Both sexes D:N-lauryl-β-imino-diacetic sodium propionate;
Polymer 1: hydroxyethyl-cellulose (HEC) glue (Natrosol 250HR), molecular weight about 1,000,000;
Polymer 2: the cellulose ether of seasonization (polymer JR400);
The animal proteinum potassium salt of anion 1:CoCo hydrolysis;
Anion 2: palm-kernel oil fatty acid sarcosinate;
Antiseptic: Euxyl K400;
Disperser:, form by following parts by the squash type foam maker that Kunstoff Supermatic company produces:
1,150ml garden form height density polyethylene (HDPE)-low density polyethylene (LDPE) (LDPE) bottle;
2, the pushing away of standard-La or on-off disperse head;
3, " white " mixing chamber;
4,11.5mm is long, the drying tube of 2.00mm diameter.
Embodiment I-V
Ⅰ??Ⅱ??Ⅲ??Ⅳ??Ⅴ
Both sexes A--1.1-2.8
Both sexes B 2.8 0.9-0.5-
Both sexes C--1.1--
Both sexes D 2.8 1-0.4 2.8
Anion 1-2.7---
Anion 2-1---
Polymer 1 0.12-0.1 0.26-
Polymer 2----0.3
Glycerol 5-5-5
Hexanediol 0.6 0.2 0.4 0.1 0.6
EDTA??0.1??0.1??0.1??0.1??0.1
Antiseptic 0.2 0.2 0.2 0.2 0.2
Water-to 100-
Liquid mixing and filling method manufacturing that said squash type foam maker product utilization is traditional.The viscosity of Cleasing compositions (Brookfield LVT in embodiment I～V, corrected value under the peak load pipe joint, 70 and 60 rev/mins of axle rotating speeds) is in 1～10 centipoise scope (60 rev/mins rotating speed under correction coefficient=(axle reading-0.4) * 0.1).
Said product demonstrates improved foam bubbling character (Emulsion, rich and stable) and good sanitary characteristics and mildness.
Embodiment VI～VIII
Ⅵ??Ⅶ??Ⅷ
Both sexes A--1.1
Both sexes B 0.6 0.8-
Both sexes C--1.1
Both sexes D 1.7 1.5-
Anion 1-2-
Anion 2-1-
Polymer 1 0.1-0.1
Glycerol 12 85
Ammonium chloride 1.0 1.0 1.0
Hexanediol 0.6 0.2 0.4
Propylene glycol 3.0 4.0 2.5
EDTA??0.1??0.1??0.1
Trichlosan??0.3??0.4??0.2
Water-to 100-
Liquid mixing method and filling method manufacturing that said squash type foam maker product utilization is traditional.The viscosity of embodiment VI～VIII Cleasing compositions (Brookfield LVT, peak load pipe joint, corrected value under 70 and the 60 rev/mins of axle speed) is 1～10 centipoise (correction coefficient under 60 rev/mins=(axle reading-0.4) * 0.1).
This product demonstrates improved frostproof froth n characteristic (Emulsion, rich and stable) and good cleaning characteristics, anti-microbial property and mildness.
Claims (32)
1, the foamy cleaning product of a kind of generation, comprising a kind of compressible non-aerosol type disperser that has reservoir, dispersion head and liquid-air mixing device, it is characterized in that wherein said reservoir comprises a kind of aqueous Cleasing compositions, comprising:
(a) first kind of amphoteric surfactant of about 0.1～about 16 weight % of selecting in the ammonium derivative by the imdazole derivatives of formula I and/or formula IV:
R wherein
1Be C
7～C
22Alkyl or alkenyl,
R
2Be hydrogen or CH
2Z, each Z are CO independently
2M or CH
2CO
2M,
And M is H, alkali metal, alkaline-earth metal, ammonium or alkanol ammonium;
R wherein
1, R
2Define as above with Z;
(b) by second kind of amphoteric surfactant of about 0.1～about 16 weight % of selecting in the amino-alkane hydrochlorate of formula II, imino-diacetic chain hydrochlorate of formula III and composition thereof:
Wherein n and m are 1～4 numerical value, and R
1Be independently selected from the group that defines in top (a) with M;
(c) as required, be not higher than about 10% anion surfactant; And
(d) water;
And wherein said Cleasing compositions contains the about 0.2～about 20 weight % of surfactant total concentration, and wherein said first kind and second kind of amphoteric surfactant total concentration account for 20 weight % of said surfactant total concentration at least.
2, according to the described cleaning product of claim 1, the mixture of wherein said first kind and second kind amphoteric surfactant accounts for about 50 weight % of said surfactant total amount at least.
3, according to the described cleaning product of claim 2, the said mixture of wherein said first kind and second kind amphoteric surfactant accounts for 60 weight % of said surfactant total amount at least.
4, according to the described cleaning product of claim 2, the said mixture of wherein said first kind and second kind amphoteric surfactant accounts for 75 weight % of said surfactant total amount at least.
5, according to claim 1,2,3 or 4 described cleaning products, wherein said surfactant total concentration is about 1～about 16 weight % of said Cleasing compositions.
6, according to the described cleaning product of claim 5, wherein said surfactant total concentration is about 1～about 8 weight % of said Cleasing compositions.
7, according to the described cleaning product of claim 5, wherein said surfactant total concentration is about 2～about 6 weight % of said Cleasing compositions.
8,, wherein comprise first kind and second kind of amphoteric surfactant respectively accounting for the about 0.5～about 10 weight % of said Cleasing compositions amount according to the described cleaning product of arbitrary claim in the claim 1,2,3 or 4.
9,, wherein comprise first kind and second kind of amphoteric surfactant respectively accounting for the about 0.5～about 10 weight % of said Cleasing compositions amount according to the described cleaning product of claim 8.
10, according to the described cleaning product of arbitrary claim in the claim 1,2,3 or 4, weight ratio is about 10: 1～about 1: 10 between wherein said first kind of amphoteric surfactant and second kind of amphoteric surfactant.
11, according to the described cleaning product of claim 10, weight ratio is 5: 1～1: 5 between wherein said first kind of amphoteric surfactant and second kind of amphoteric surfactant.
12, according to the described cleaning product of claim 10, weight ratio is 3: 1～1: 3 between wherein said first kind of amphoteric surfactant and second kind of amphoteric surfactant.
13,, wherein also comprise the said Cleasing compositions of about 0.1～about 10 weight % in addition according to the described cleaning product of arbitrary claim in the claim 1,2,3 or 4.
14,, wherein comprise the said Cleasing compositions of 0.5～5 weight % according to the described cleaning product of claim 13.
15,, wherein comprise the said Cleasing compositions of 1～3 weight % according to the described cleaning product of claim 13.
16,, wherein comprise first kind of about 1: 1 amphoteric surfactant of equivalent proportion and the premix or the complex of second kind of amphoteric surfactant according to claim 13,14 or 15 described cleaning products.
17, according to claim 13,14 or 15 described cleaning products, wherein said anion surfactant is protein, protein degradation or amino acid whose fatty acid condensation product, or the mixture of said fatty acid condensation product.
18, according to the described cleaning product of claim 17, wherein said fatty acid condensation product is selected from:
(ⅰ) C
8-C
22, preferred C
10-C
18The condensation product of fatty acid and hydrolyzed protein;
(ⅱ) by C
8-C
22, preferred C
10-C
18The fatty acid sarcosinate that fatty acid derived is come out and
(ⅲ) its mixture.
19, according to the described cleaning product of claim 1, wherein said Cleasing compositions viscosity (Brookfield LVT, the peak load pipe joint is through 70 and 30-60 rev/min of rotating speed correction down) is not more than 50 centipoises.
20, according to the described cleaning product of claim 19, wherein said Cleasing compositions viscosity is not more than 20 centipoises.
21, according to claim 19 or 20 described cleaning products, about 2～about 15 centipoises of wherein said Cleasing compositions viscosity.
22, according to the described cleaning product of claim 21, wherein said Cleasing compositions viscosity is the 2-12 centipoise.
23, according to the described cleaning product of claim 21, wherein said Cleasing compositions viscosity is the 4-12 centipoise.
24, according to the described cleaning product of claim 1, wherein comprise and account for said cleaning combination weight 0.01-5%, preferably about 0.04-is about 2%, more preferably 0.5～1% polymeric viscosifier.
25, according to the described cleaning product of claim 1, wherein said aqueous cleaning composition comprises hair or the skin moisturizing agent of about 3-about 40%.
26, according to the described cleaning product of claim 25, wherein said humidizer is non-occlusor, and is selected from:
(ⅰ) water-soluble liquid polyhydric alcohol;
(ⅱ) be present in natural necessary amino-acid compound in the keratodermatitis; With
(ⅲ) non-occlusor agent of the non-polyhydric alcohol type of water solublity and composition thereof.
27, according to the described cleaning product of claim 26, wherein said humidizer is selected from: glycerol, Polyethylene Glycol, propylene glycol, sorbitol, the polyglycol ether of methyl glucoside and propylene glycol, the polyglycol ether of lanolin alcohol and propylene glycol, ketopyrrolidine sodium formate, lactic acid, L-proline and composition thereof.
28, according to the described cleaning product of claim 27, wherein said humidizer is a glycerol.
29, according to the said cleaning product of claim 24, wherein said polymer is hair or skin conditioner, be preferably selected from: cation and nonionic polysaccharide, cation and the nonionic homopolymer and the copolymer of deriving and obtaining by acrylic acid and/or methacrylic acid, cation and nonionic celluosic resin, dimethyl diallyl ammonium chloride and acrylic acid cation copolymer, the cationic homopolymer of dimethyl diallyl ammonium chloride, cationic polyalkyleneimine and ethyoxyl polyalkyleneimine, siloxanes of seasonization and composition thereof.
30,, wherein also comprise about 0.01～about 5 weight % antibacterial in addition according to the described cleaning product of claim 1.
31,, wherein comprise the antibacterial of 0.1-4% according to the described cleaning product of claim 30.
32, according to claim 30 or 31 described cleaning products, wherein said antibacterial is selected from: 3,4-two and 3,4 ', the 5-tribromsalan, 4,4 '-two chloro-3-(trifluoromethyls) carbonyl aniline, 3,4,4 '-Amolden MCM 400, phenyl phenol, the propoxyl group propanol, chlorhexidine salt, primidone salt, 2 ', 4,4 '-three chloro-2-dihydroxy diphenyl ethers (Trichlosan), 2,2 '-methylene-two (4-chloro-6-bromophenols), salicylic acid, parachlorometaxylenol, 1-hydroxy-4-methyl-6-(2,4, the 4-trimethylphenyl)-2-(1H)-pyridonium salt (Octopirox) and composition thereof.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB909006759A GB9006759D0 (en) | 1990-03-27 | 1990-03-27 | Cleansing products |
| GB9006759.6 | 1990-03-27 | ||
| GB9009824.5 | 1990-04-27 | ||
| GB909009824A GB9009824D0 (en) | 1990-04-27 | 1990-04-27 | Cleaning products |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1055109A true CN1055109A (en) | 1991-10-09 |
Family
ID=26296842
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 91101871 Pending CN1055109A (en) | 1990-03-27 | 1991-03-27 | Cleaning product |
Country Status (6)
| Country | Link |
|---|---|
| CN (1) | CN1055109A (en) |
| AR (1) | AR244084A1 (en) |
| IE (1) | IE911000A1 (en) |
| MX (1) | MX171703B (en) |
| NZ (1) | NZ237584A (en) |
| PT (1) | PT97187A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4225795A1 (en) * | 1992-07-31 | 1994-02-03 | Schuelke & Mayr Gmbh | Synergistic Tb-effective combination of carboxylic acids and alcohols |
| CN101234070B (en) * | 2007-01-29 | 2012-06-13 | 花王株式会社 | Cleansing composition |
-
1991
- 1991-03-25 AR AR31930991A patent/AR244084A1/en active
- 1991-03-26 IE IE100091A patent/IE911000A1/en unknown
- 1991-03-26 NZ NZ23758491A patent/NZ237584A/en unknown
- 1991-03-26 MX MX2508291A patent/MX171703B/en unknown
- 1991-03-27 PT PT9718791A patent/PT97187A/en not_active Application Discontinuation
- 1991-03-27 CN CN 91101871 patent/CN1055109A/en active Pending
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4225795A1 (en) * | 1992-07-31 | 1994-02-03 | Schuelke & Mayr Gmbh | Synergistic Tb-effective combination of carboxylic acids and alcohols |
| CN101234070B (en) * | 2007-01-29 | 2012-06-13 | 花王株式会社 | Cleansing composition |
Also Published As
| Publication number | Publication date |
|---|---|
| IE911000A1 (en) | 1991-10-09 |
| NZ237584A (en) | 1994-09-27 |
| AR244084A1 (en) | 1993-10-29 |
| MX171703B (en) | 1993-11-10 |
| PT97187A (en) | 1991-12-31 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |