CN105506610A - Mechanical zinc plating waterborne sealing agent - Google Patents
Mechanical zinc plating waterborne sealing agent Download PDFInfo
- Publication number
- CN105506610A CN105506610A CN201511033581.XA CN201511033581A CN105506610A CN 105506610 A CN105506610 A CN 105506610A CN 201511033581 A CN201511033581 A CN 201511033581A CN 105506610 A CN105506610 A CN 105506610A
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- China
- Prior art keywords
- parts
- silicate
- zinc
- agent
- rust
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D5/00—Electroplating characterised by the process; Pretreatment or after-treatment of workpieces
- C25D5/48—After-treatment of electroplated surfaces
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Preventing Corrosion Or Incrustation Of Metals (AREA)
Abstract
The invention provides a mechanical zinc plating waterborne sealing agent and relates to the technical field of zinc plating surface treatment. The waterborne sealing agent is prepared from polyquaternium, silicate, acrylic polymers, ground phosphate rock, zinc oxide, nickel acetate, ethylene glycol, a coupling agent, a rust-inhibiting additive, a rust-inhibiting film-forming agent, an epoxy performance additive and deionized water. The waterborne sealing agent has very high anti-corrosion performance and extremely strong adhesive force, does not contain harmful substances such as formaldehyde, benzene and heavy metal, and is beneficial to environmental protection and physical and mental health of operators.
Description
Technical field
The present invention relates to galvanizing surface processing technology field, refer more particularly to watersoluble closed dose of a kind of mechanical zinc-plating.
Background technology
The zinc-plated main corrosion protection coating as steel part, plating amount of finish in rank first, except because of process unit relatively low except, the zinc coating in steel part is anodic coating, and when there is galvanic corrosion when making moist, zinc first corrodes and makes steel substrate protected.But zinc this as amphoteric metal, neither acidproof not alkaline-resisting yet, be easy in an atmosphere generate the even white hair of zinc subcarbonate erosion and long hickie, lime.Carry out Passivation Treatment again after zinc-plated, slushing oil can be improved to some extent, extend the time of zinc corrosion itself.Therefore to Passivation Treatment be done unlimitedly after electro-galvanizing, but drying aging, remake sealing treatment after passivation again than not closing after passivation, aging far better.The ornamental multilayer coating of zinc-plated encapsulant suitable metal and single plating layer, through the coating of zinc-plated encapsulant process, its salt-fog test time and the test of other resistance to corrosion will improve more than twice, play and strengthen rot-resistant effect.Substituting the technique of chromic acid passivation for adopting, being therefore widely used in five metals, decorative coating that the communication apparatus, instrument, vapour rub on the product such as accessory, household electrical appliance.
Zinc-plated encapsulant is water-based system; there are very high antiseptic property and extremely strong sticking power; not containing objectionable impuritiess such as formaldehyde, benzene, heavy metals; be conducive to the physical and mental health of environment protection and operator; transparent bright rete is become after drying; final corrosion protection coating can be used as, also can be used as rust-proofing primer and use.Closed rete has the features such as excellent bright property, planarization, Anti-tarnishing, erosion resistance and high tack.And existing encapsulant effect not obvious, the appearance of coat unfairness of encapsulant, corrosion-resistant, abrasion resistant coatings and basal body binding force poor.Time of drying is long, needs at high temperature to dry, and alkaline resistance properties is poor.
Summary of the invention
(1) technical problem solved
Not enough for prior art; the invention provides watersoluble closed dose of a kind of mechanical zinc-plating; there are very high antiseptic property and extremely strong sticking power; not containing objectionable impuritiess such as formaldehyde, benzene, heavy metals; be conducive to the physical and mental health of environment protection and operator; encapsulant appearance of coat is smooth, and time of drying is short, and acid-proof alkaline is strong.
(2) technical scheme
For realizing above object, the present invention is achieved by the following technical programs:
A kind of watersoluble closed dose of mechanical zinc-plating, comprises the raw material of following weight part: polyquaternium 12-22 part, silicate 12-19 part, acrylate copolymer 5-15 part, ground phosphate rock 3-9 part, zinc oxide 8-17 part, nickel acetate 2-6 part, ethylene glycol 1-5 part, coupling agent 0.6-1.8 part, rust-inhibiting additive 1.5-3 part, antirust membrane-forming agent 0.8-2 part, epoxide modified auxiliary agent 0.2-0.7 part, deionized water 5-10 part.
Preferably, watersoluble closed dose of described mechanical zinc-plating comprises the raw material of following weight part: polyquaternium 15-21 part, silicate 13-17 part, acrylate copolymer 6-12 part, ground phosphate rock 4-8 part, zinc oxide 9-16 part, nickel acetate 3-6 part, ethylene glycol 2-5 part, coupling agent 0.6-1.5 part, rust-inhibiting additive 1.8-2.5 part, antirust membrane-forming agent 0.9-1.8 part, epoxide modified auxiliary agent 0.3-0.6 part, deionized water 6-9 part.
Preferably, watersoluble closed dose of described mechanical zinc-plating comprises the raw material of following weight part: polyquaternium 16-19 part, silicate 14-16 part, acrylate copolymer 7-11 part, ground phosphate rock 5-8 part, zinc oxide 10-15 part, nickel acetate 4-6 part, ethylene glycol 2-4 part, coupling agent 0.7-1.0 part, rust-inhibiting additive 1.8-2 part, antirust membrane-forming agent 1-1.6 part, epoxide modified auxiliary agent 0.3-0.5 part, deionized water 7-8 part.
Preferably, watersoluble closed dose of described mechanical zinc-plating comprises the raw material of following weight part: polyquaternium 17 parts, silicate 16 parts, acrylate copolymer 10 parts, 6 parts, ground phosphate rock, 12 parts, zinc oxide, nickel acetate 4 parts, ethylene glycol 3 parts, coupling agent 1.2 parts, rust-inhibiting additive 2.3 parts, antirust membrane-forming agent 1.4 parts, epoxide modified auxiliary agent 0.4 part, deionized water 7 parts.
Preferably, described silicate is the wherein a kind of or two or more arbitrarily mixture of water glass, potassium silicate or lithium silicate.
Preferably, described coupling agent is one or several in silane coupling agent, titanate coupling agent, Coupling aniline.
Preferably, described rust-inhibiting additive is N-oleoyl (replacing) sarkosine stearylamine salt or sulfonated petro-leum; Antirust membrane-forming agent is alkylphenol aminoresin or tert-butyl phenol first vinegar resin.
(3) beneficial effect
The invention provides watersoluble closed dose of a kind of mechanical zinc-plating, there are very high antiseptic property and extremely strong sticking power, not containing objectionable impuritiess such as formaldehyde, benzene, heavy metals, be conducive to the physical and mental health of environment protection and operator, encapsulant appearance of coat is smooth, and time of drying is short, and acid-proof alkaline is strong, Surface of profile quality after simultaneously closing is good, does not play pollen;
The invention provides watersoluble closed dose of a kind of mechanical zinc-plating anti-neutral salt spray test time and resistance to corrosion test will improve more than three times, play and strengthen rot-resistant effect, with low cost, simple to operate, easy to use.
Embodiment
For making the object of the embodiment of the present invention, technical scheme and advantage clearly, below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is the present invention's part embodiment, instead of whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art, not making the every other embodiment obtained under creative work prerequisite, belong to the scope of protection of the invention.
Embodiment 1:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 12 parts, silicate 12 parts, acrylate copolymer 5 parts, 3 parts, ground phosphate rock, 8 parts, zinc oxide, nickel acetate 2 parts, ethylene glycol 1 part, coupling agent 0.6 part, rust-inhibiting additive 1.5 parts, antirust membrane-forming agent 0.8 part, epoxide modified auxiliary agent 0.2 part, deionized water 5 parts.
Embodiment 2:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 22 parts, silicate 19 parts, acrylate copolymer 15 parts, 9 parts, ground phosphate rock, 17 parts, zinc oxide, nickel acetate 6 parts, ethylene glycol 5 parts, coupling agent 1.8 parts, rust-inhibiting additive 3 parts, antirust membrane-forming agent 2 parts, epoxide modified auxiliary agent 0.7 part, deionized water 10 parts.
Embodiment 3:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 15 parts, silicate 13 parts, acrylate copolymer 6 parts, 4 parts, ground phosphate rock, 9 parts, zinc oxide, nickel acetate 3 parts, ethylene glycol 2 parts, coupling agent 0.6 part, rust-inhibiting additive 1.8 parts, antirust membrane-forming agent 0.9 part, epoxide modified auxiliary agent 0.3 part, deionized water 6 parts.
Embodiment 4:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 21 parts, silicate 17 parts, acrylate copolymer 12 parts, 8 parts, ground phosphate rock, 16 parts, zinc oxide, nickel acetate 6 parts, ethylene glycol 5 parts, coupling agent 1.5 parts, rust-inhibiting additive 2.5 parts, antirust membrane-forming agent 1.8 parts, epoxide modified auxiliary agent 0.6 part, deionized water 9 parts.
Embodiment 5:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 16 parts, silicate 14 parts, acrylate copolymer 7 parts, 5 parts, ground phosphate rock, 10 parts, zinc oxide, nickel acetate 4 parts, ethylene glycol 2 parts, coupling agent 0.7 part, rust-inhibiting additive 1.8 parts, antirust membrane-forming agent 1 part, epoxide modified auxiliary agent 0.3 part, deionized water 7 parts.
Embodiment 6:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 19 parts, silicate 16 parts, acrylate copolymer 11 parts, 8 parts, ground phosphate rock, 15 parts, zinc oxide, nickel acetate 6 parts, ethylene glycol 4 parts, coupling agent 1.0 parts, rust-inhibiting additive 2 parts, antirust membrane-forming agent 1.6 parts, epoxide modified auxiliary agent 0.5 part, deionized water 8 parts.
Embodiment 7:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 17 parts, silicate 16 parts, acrylate copolymer 10 parts, 6 parts, ground phosphate rock, 12 parts, zinc oxide, nickel acetate 4 parts, ethylene glycol 3 parts, coupling agent 1.2 parts, rust-inhibiting additive 2.3 parts, antirust membrane-forming agent 1.4 parts, epoxide modified auxiliary agent 0.4 part, deionized water 7 parts.
Embodiment 8:
Watersoluble closed dose of the present embodiment mechanical zinc-plating, is made up of the raw material of following weight part: polyquaternium 19 parts, silicate 15 parts, acrylate copolymer 9 parts, 6 parts, ground phosphate rock, 12 parts, zinc oxide, nickel acetate 4.5 parts, ethylene glycol 3.5 parts, coupling agent 1 part, rust-inhibiting additive 2.1 parts, antirust membrane-forming agent 1.3 parts, epoxide modified auxiliary agent 0.45 part, deionized water 8 parts.
It should be noted that, in this article, the such as relational terms of first and second grades and so on is only used for an entity or operation to separate with another entity or operational zone, and not necessarily requires or imply the relation that there is any this reality between these entities or operation or sequentially.And, term " comprises ", " comprising " or its any other variant are intended to contain comprising of nonexcludability, thus make to comprise the process of a series of key element, method, article or equipment and not only comprise those key elements, but also comprise other key elements clearly do not listed, or also comprise by the intrinsic key element of this process, method, article or equipment.When not more restrictions, the key element limited by statement " comprising ... ", and be not precluded within process, method, article or the equipment comprising described key element and also there is other identical element.
Above embodiment is only in order to illustrate technical scheme of the present invention, be not intended to limit, although with reference to previous embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that: it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature; And these amendments or replacement, do not make the essence of appropriate technical solution depart from the spirit and scope of various embodiments of the present invention technical scheme.
Claims (7)
1. watersoluble closed dose an of mechanical zinc-plating, it is characterized in that, comprise the raw material of following weight part: polyquaternium 12-22 part, silicate 12-19 part, acrylate copolymer 5-15 part, ground phosphate rock 3-9 part, zinc oxide 8-17 part, nickel acetate 2-6 part, ethylene glycol 1-5 part, coupling agent 0.6-1.8 part, rust-inhibiting additive 1.5-3 part, antirust membrane-forming agent 0.8-2 part, epoxide modified auxiliary agent 0.2-0.7 part, deionized water 5-10 part.
2. watersoluble closed dose of mechanical zinc-plating according to claim 1, it is characterized in that, comprise the raw material of following weight part: polyquaternium 15-21 part, silicate 13-17 part, acrylate copolymer 6-12 part, ground phosphate rock 4-8 part, zinc oxide 9-16 part, nickel acetate 3-6 part, ethylene glycol 2-5 part, coupling agent 0.6-1.5 part, rust-inhibiting additive 1.8-2.5 part, antirust membrane-forming agent 0.9-1.8 part, epoxide modified auxiliary agent 0.3-0.6 part, deionized water 6-9 part.
3. watersoluble closed dose of mechanical zinc-plating according to claim 1, it is characterized in that, comprise the raw material of following weight part: polyquaternium 16-19 part, silicate 14-16 part, acrylate copolymer 7-11 part, ground phosphate rock 5-8 part, zinc oxide 10-15 part, nickel acetate 4-6 part, ethylene glycol 2-4 part, coupling agent 0.7-1.0 part, rust-inhibiting additive 1.8-2 part, antirust membrane-forming agent 1-1.6 part, epoxide modified auxiliary agent 0.3-0.5 part, deionized water 7-8 part.
4. watersoluble closed dose of mechanical zinc-plating according to claim 1, it is characterized in that, comprise the raw material of following weight part: polyquaternium 17 parts, silicate 16 parts, acrylate copolymer 10 parts, 6 parts, ground phosphate rock, 12 parts, zinc oxide, nickel acetate 4 parts, ethylene glycol 3 parts, coupling agent 1.2 parts, rust-inhibiting additive 2.3 parts, antirust membrane-forming agent 1.4 parts, epoxide modified auxiliary agent 0.4 part, deionized water 7 parts.
5. watersoluble closed dose of mechanical zinc-plating according to claim 1, is characterized in that, described silicate is the wherein a kind of or two or more arbitrarily mixture of water glass, potassium silicate or lithium silicate.
6. watersoluble closed dose of mechanical zinc-plating according to claim 1, is characterized in that, described coupling agent is one or several in silane coupling agent, titanate coupling agent, Coupling aniline.
7. watersoluble closed dose of mechanical zinc-plating according to claim 1, is characterized in that, described rust-inhibiting additive is N-oleoyl (replacing) sarkosine stearylamine salt or sulfonated petro-leum; Antirust membrane-forming agent is alkylphenol aminoresin or tert-butyl phenol first vinegar resin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511033581.XA CN105506610A (en) | 2015-12-31 | 2015-12-31 | Mechanical zinc plating waterborne sealing agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511033581.XA CN105506610A (en) | 2015-12-31 | 2015-12-31 | Mechanical zinc plating waterborne sealing agent |
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| Publication Number | Publication Date |
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| CN105506610A true CN105506610A (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511033581.XA Pending CN105506610A (en) | 2015-12-31 | 2015-12-31 | Mechanical zinc plating waterborne sealing agent |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106011888A (en) * | 2016-07-06 | 2016-10-12 | 安徽红桥金属制造有限公司 | Rust remover of spring steel and preparation method of rust remover |
| CN108221016A (en) * | 2017-12-21 | 2018-06-29 | 广州传福化学技术有限公司 | A kind of zinc-plated sealer and its application method |
| CN109136936A (en) * | 2018-08-27 | 2019-01-04 | 合肥绿洁环保科技有限公司 | A kind of metal antirusting agent |
| CN111019508A (en) * | 2019-12-31 | 2020-04-17 | 江南大学 | Water-based sealing protective agent and preparation method thereof |
| CN111040553A (en) * | 2019-12-31 | 2020-04-21 | 江南大学 | Sealing protective agent and preparation method thereof |
| CN111826069A (en) * | 2020-07-29 | 2020-10-27 | 江门市高信科技有限公司 | Composite zinc coating sealant with excellent scratch resistance and preparation method thereof |
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| CN101250699A (en) * | 2008-03-27 | 2008-08-27 | 武汉科技大学 | Chromium-free passivation liquid for galvanized sheet and manufacture method thereof |
| US20100291307A1 (en) * | 2009-05-18 | 2010-11-18 | Mcgee John D | Release on demand corrosion inhibitor composition |
| CN102061465A (en) * | 2010-12-31 | 2011-05-18 | 大连工业大学 | Chrome-free sealing agent |
| CN102797014A (en) * | 2012-06-18 | 2012-11-28 | 浙江康盛股份有限公司 | Rust-proof sealing agent |
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2015
- 2015-12-31 CN CN201511033581.XA patent/CN105506610A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101250699A (en) * | 2008-03-27 | 2008-08-27 | 武汉科技大学 | Chromium-free passivation liquid for galvanized sheet and manufacture method thereof |
| US20100291307A1 (en) * | 2009-05-18 | 2010-11-18 | Mcgee John D | Release on demand corrosion inhibitor composition |
| CN102061465A (en) * | 2010-12-31 | 2011-05-18 | 大连工业大学 | Chrome-free sealing agent |
| CN102797014A (en) * | 2012-06-18 | 2012-11-28 | 浙江康盛股份有限公司 | Rust-proof sealing agent |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106011888A (en) * | 2016-07-06 | 2016-10-12 | 安徽红桥金属制造有限公司 | Rust remover of spring steel and preparation method of rust remover |
| CN106011888B (en) * | 2016-07-06 | 2018-06-26 | 安徽红桥金属制造有限公司 | A kind of rust remover of spring steel and preparation method thereof |
| CN108221016A (en) * | 2017-12-21 | 2018-06-29 | 广州传福化学技术有限公司 | A kind of zinc-plated sealer and its application method |
| CN108221016B (en) * | 2017-12-21 | 2019-10-01 | 广州传福化学技术有限公司 | A kind of zinc-plated sealer and its application method |
| CN109136936A (en) * | 2018-08-27 | 2019-01-04 | 合肥绿洁环保科技有限公司 | A kind of metal antirusting agent |
| CN111019508A (en) * | 2019-12-31 | 2020-04-17 | 江南大学 | Water-based sealing protective agent and preparation method thereof |
| CN111040553A (en) * | 2019-12-31 | 2020-04-21 | 江南大学 | Sealing protective agent and preparation method thereof |
| CN111826069A (en) * | 2020-07-29 | 2020-10-27 | 江门市高信科技有限公司 | Composite zinc coating sealant with excellent scratch resistance and preparation method thereof |
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Application publication date: 20160420 |