CN105505198A - Building UV coating with high gloss and preparation method thereof - Google Patents
Building UV coating with high gloss and preparation method thereof Download PDFInfo
- Publication number
- CN105505198A CN105505198A CN201610033318.9A CN201610033318A CN105505198A CN 105505198 A CN105505198 A CN 105505198A CN 201610033318 A CN201610033318 A CN 201610033318A CN 105505198 A CN105505198 A CN 105505198A
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- Prior art keywords
- coating
- building
- acrylate
- high glossiness
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
- C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
- C09D167/06—Unsaturated polyesters having carbon-to-carbon unsaturation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses building UV coating with high gloss and a preparation method thereof. The building UV coating with high gloss comprises the following components in percentage by weight: 10-25% of aliphatic polyurethane acrylate, 10-20% of polyester acrylate, 10-20% of isobornyl acrylate, 10-15% of poly(pentaerythritol triacrylate), 3-5% of 1-hydroxy-cyclohexyl-phenyl ketone, 2-5% of diphenyl ketone, 5-10% of ground calcium carbonate, 10-20% of solvent and 2-5% of auxiliary agent. The building UV coating prepared according to the formula has high gloss, excellent adhesive force, high curing speed, abrasion resistance, water resistance, alkali resistance, scrub resistance and weather resistance and meets property requirements of building coating.
Description
Technical field
The present invention relates to paint field, particularly relate to a kind of building UV coating with high glossiness and preparation method thereof.
Background technology
UV-light (Ultra-VioletRay) is coating material solidified, be called for short UV coating, paint solidification film forming is made by UV light irradiation, industrial UV wavelength is its range of application with 200nm-450nm, UV coating is by roller coating, the method such as showering, spraying coating after, then through ultraviolet light irradiation film-forming.UV coating has not containing VOC, environmental protection, the saving energy, curing speed is fast, cured product performance is good, production efficiency is high, be suitable for the advantages such as suitability for industrialized production.Traditional coating is volatile, curing speed is slow, is unfavorable for environment protection, therefore, and the alternative traditional coating of UV coating.
UV coating originates from the seventies, is a kind of brand-new green environmental friendly coatings technology.Current UV coating is widely used in the fields such as 3C, woodenware, tin graphed sheet, makeup in European and American areas, but building trade application also study less, and current building UV coating to there is wear resistance strong, water tolerance is on the weak side, the shortcoming of abrasion resistance and weather resistance deficiency.
Therefore, prior art has yet to be improved and developed.
Summary of the invention
In view of above-mentioned the deficiencies in the prior art, the object of the present invention is to provide a kind of building UV coating with high glossiness and preparation method thereof, being intended to solve existing building UV coating, to there is wear resistance strong, and water tolerance is on the weak side, the problem of abrasion resistance and weather resistance deficiency.
Technical scheme of the present invention is as follows:
A kind of building UV coating with high glossiness, wherein, percentage, comprising: aliphatic urethane acrylate 10 ~ 25%, polyester acrylate 10 ~ 20%, iso-bornyl acrylate 10 ~ 20%, poly-penta tetrol triacrylate 10 ~ 15%, 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 3 ~ 5%, benzophenone 2 ~ 5%, water-ground limestone 5 ~ 10%, solvent 10 ~ 20%, auxiliary agent 2 ~ 5%.
The described building UV coating with high glossiness, wherein, described solvent is one or both in alcohols and ester class.
The described building UV coating with high glossiness, wherein, described alcohols is one or more in ethanol, n-propyl alcohol, Virahol, isopropylcarbinol.
The described building UV coating with high glossiness, wherein, described ester class is one or more in ethyl acetate, butylacetate, isobutyl acetate.
The described building UV coating with high glossiness, wherein, described auxiliary agent is flow agent, levelling control agent, wetting agent, dispersion agent, defoamer, anti-after-tack agent, photostabilizer one or more.
The described building UV coating with high glossiness, wherein, percentage, comprising: aliphatic urethane acrylate 15 ~ 20%, polyester acrylate 15 ~ 20%, iso-bornyl acrylate 10 ~ 15%, poly-penta tetrol triacrylate 13 ~ 15%, 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 3 ~ 5%, benzophenone 3 ~ 5%, water-ground limestone 8 ~ 10%, solvent 15 ~ 20%, auxiliary agent 3 ~ 5%.
A kind of as above arbitrary described preparation method with the building UV coating of high glossiness, wherein, comprise step: add in container according to above-mentioned formula by aliphatic urethane acrylate, polyester acrylate, iso-bornyl acrylate, poly-penta tetrol triacrylate, solvent and water-ground limestone, abundant stirring, add 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches, benzophenone and auxiliary agent again, abundant stirring, obtains building UV coating.
Beneficial effect: the building UV coating prepared by above-mentioned formula has high glossiness, excellent sticking power, and solidification rate is fast, and wear resistance, water tolerance, alkali resistance, abrasion resistance and weather resistance, meet building coating performance.
Embodiment
The invention provides a kind of building UV coating with high glossiness and preparation method thereof, for making object of the present invention, technical scheme and effect clearly, clearly, the present invention is described in more detail below.Should be appreciated that specific embodiment described herein only in order to explain the present invention, be not intended to limit the present invention.
The invention provides a kind of building UV coating with high glossiness, its percentage, comprising: aliphatic urethane acrylate 10 ~ 25%, polyester acrylate 10 ~ 20%, iso-bornyl acrylate 10 ~ 20%, poly-penta tetrol triacrylate 10 ~ 15%, 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 3 ~ 5%, benzophenone 2 ~ 5%, water-ground limestone 5 ~ 10%, solvent 10 ~ 20%, auxiliary agent 2 ~ 5%.
Preferably, a kind of building UV coating with high glossiness of the present invention, its percentage, comprising: aliphatic urethane acrylate 15 ~ 20%, polyester acrylate 15 ~ 20%, iso-bornyl acrylate 10 ~ 15%, poly-penta tetrol triacrylate 13 ~ 15%, 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 3 ~ 5%, benzophenone 3 ~ 5%, water-ground limestone 8 ~ 10%, solvent 15 ~ 20%, auxiliary agent 3 ~ 5%.Under stating screening formulation on the invention, can further improve the performance of building UV coating.
Of the present invention have in the building UV formulation for coating material of high glossiness, described aliphatic urethane acrylate and polyester acrylate are used as filmogen, it is the basic framework in building UV coating, the film with three-dimensional arrangement is formed under the effect of UV photons, and give the good sticking power of film, snappiness, gloss, ageing-resistant, fast light, weathering resistance, the performance such as inhibited from yellowing.This is because described aliphatic urethane acrylate contains the groups such as-OH ,-COOH, so good to the wetting and spreading of base material, can significantly improve glossiness, sticking power and inhibited from yellowing, fast light and weathering resistance is excellent.And described polyester acrylate has that glossiness is high, solidification rate is fast, hardness is high and the excellent properties such as wear-resisting scratch resistance.
Of the present invention have in the building UV formulation for coating material of high glossiness, and described iso-bornyl acrylate and poly-penta tetrol triacrylate are used as reactive thinner, and its Main Function participates in reaction, regulation system viscosity.Compared with using volatile organic solvent with existing general coating, the present invention above-mentioned preferably 2-phenoxyethyl acrylate and poly-penta tetrol triacrylate can participate in film-forming process directly, are the small-molecule substances with response capacity.
Of the present invention have in the building UV formulation for coating material of high glossiness, described 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches and benzophenone are used as light trigger, its role is to the energy transmitting UV photons, the crosslinking polymerization of rapid trigger monomer and resin, the liquid-solid switching process of Promotion system.The above-mentioned light trigger of the present invention has the high characteristic of efficiency of initiation, can the crosslinking polymerization of rapidly trigger monomer and resin fast, provides curing speed.
Of the present invention have in the building UV formulation for coating material of high glossiness, and described water-ground limestone is used as filler, is integral part important in building UV coating, has material impact, can reduce costs and improve workability appearance of film.
Preferably, solvent of the present invention is one or both in alcohols and ester class.
Wherein, described alcohols is one or more in ethanol, n-propyl alcohol, Virahol, isopropylcarbinol.Described ester class is one or more in ethyl acetate, butylacetate, isobutyl acetate.
Preferably, described auxiliary agent be flow agent, levelling control agent, wetting agent, dispersion agent, defoamer, anti-after-tack agent, photostabilizer one or more.Auxiliary agent is for meeting concrete service requirements, improving film performance and some accessory ingredients added.
Based on the above-mentioned building UV coating with high glossiness, the present invention also provides a kind of as above arbitrary described preparation method with the building UV coating of high glossiness, it comprises step: add in container according to above-mentioned formula by aliphatic urethane acrylate, polyester acrylate, iso-bornyl acrylate, poly-penta tetrol triacrylate, solvent and water-ground limestone, abundant stirring, add 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches, benzophenone and auxiliary agent again, abundant stirring, obtains building UV coating.
Below by specific embodiment, the present invention is described in detail.
Embodiment 1
Have a building UV coating for high glossiness, wherein, percentage, comprising:
Aliphatic urethane acrylate 20%
Polyester acrylate 15%
Iso-bornyl acrylate 15%
Poly-penta tetrol triacrylate 15%
1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 4%
Benzophenone 4%
Water-ground limestone 8%
Ethanol: n-propyl alcohol: butylacetate=2:1:116%
Photostabilizer 1%
Flow agent 0.5%
Defoamer 1%
Dispersion agent 0.5%
The aliphatic urethane acrylate of above-mentioned weight percentage, polyester acrylic, iso-bornyl acrylate, poly-penta tetrol triacrylate, water-ground limestone, ethanol, n-propyl alcohol, butylacetate are added in container, abundant stirring, add the photostabilizer of above-mentioned weight percentage, flow agent, defoamer, dispersion agent and 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches, benzophenone again, abundant stirring, namely obtains building UV coating.
Embodiment 2
Have a building UV coating for high glossiness, wherein, percentage, comprising:
Aliphatic urethane acrylate 25%
Polyester acrylate 10%
Iso-bornyl acrylate 20%
Poly-penta tetrol triacrylate 15%
1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 5%
Benzophenone 5%
Water-ground limestone 7%
Ethanol: isopropylcarbinol: ethyl acetate=2:1:110%
Photostabilizer 1%
Wetting agent 1%
Flow agent 0.5%
Defoamer 1%
Dispersion agent 0.5%
The aliphatic urethane acrylate of above-mentioned weight percentage, polyester acrylate, iso-bornyl acrylate, iso-bornyl acrylate, water-ground limestone, ethanol, isopropylcarbinol, ethyl acetate are added in container, abundant stirring, add the photostabilizer of above-mentioned weight percentage, wetting agent, flow agent, defoamer, dispersion agent and 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches, benzophenone again, abundant stirring, namely obtains building UV coating.
Embodiment 3
Have a building UV coating for high glossiness, wherein, percentage, comprising:
Aliphatic urethane acrylate 10%
Polyester acrylate 20%
Iso-bornyl acrylate 20%
Poly-penta tetrol triacrylate 10%
1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 4%
Benzophenone 5%
Water-ground limestone 7%
Ethanol: ethyl acetate: isobutyl acetate=2:1:120%
Photostabilizer 1%
Prevent after-tacking agent 1%
Flow agent 0.5%
Defoamer 1%
Dispersion agent 0.5%
The aliphatic urethane acrylate of above-mentioned weight percentage, polyester acrylate, iso-bornyl acrylate, poly-penta tetrol triacrylate, water-ground limestone, ethanol, ethyl acetate, isobutyl acetate are added in container, abundant stirring, add the photostabilizer of above-mentioned weight percentage again, prevent after-tacking agent, flow agent, defoamer, dispersion agent and 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches, benzophenone, abundant stirring, namely obtains building UV coating.
The building UV coating that above-described embodiment 1,2 and 3 obtains has high glossiness, excellent sticking power, and solidification rate is fast, and wear resistance, water tolerance, alkali resistance, abrasion resistance and weather resistance, meet building coating performance.
In sum, a kind of building UV coating with high glossiness provided by the invention and preparation method thereof, percentage, described building UV coating comprises: aliphatic urethane acrylate 10 ~ 25%, polyester acrylate 10 ~ 20%, iso-bornyl acrylate 10 ~ 20%, poly-penta tetrol triacrylate 10 ~ 15%, 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 3 ~ 5%, benzophenone 2 ~ 5%, water-ground limestone 5 ~ 10%, solvent 10 ~ 20%, auxiliary agent 2 ~ 5%.The building UV coating prepared by above-mentioned formula has high glossiness, excellent sticking power, and solidification rate is fast, and wear resistance, water tolerance, alkali resistance, abrasion resistance and weather resistance, meet building coating performance.
Should be understood that, application of the present invention is not limited to above-mentioned citing, for those of ordinary skills, can be improved according to the above description or convert, and all these improve and convert the protection domain that all should belong to claims of the present invention.
Claims (7)
1. one kind has the building UV coating of high glossiness, it is characterized in that, percentage, comprising: aliphatic urethane acrylate 10 ~ 25%, polyester acrylate 10 ~ 20%, iso-bornyl acrylate 10 ~ 20%, poly-penta tetrol triacrylate 10 ~ 15%, 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 3 ~ 5%, benzophenone 2 ~ 5%, water-ground limestone 5 ~ 10%, solvent 10 ~ 20%, auxiliary agent 2 ~ 5%.
2. the building UV coating with high glossiness according to claim 1, is characterized in that, described solvent is one or both in alcohols and ester class.
3. the building UV coating with high glossiness according to claim 2, is characterized in that, described alcohols is one or more in ethanol, n-propyl alcohol, Virahol, isopropylcarbinol.
4. the building UV coating with high glossiness according to claim 2, is characterized in that, described ester class is one or more in ethyl acetate, butylacetate, isobutyl acetate.
5. the building UV coating with high glossiness according to claim 1, is characterized in that, described auxiliary agent is flow agent, levelling control agent, wetting agent, dispersion agent, defoamer, anti-after-tack agent, photostabilizer one or more.
6. the building UV coating with high glossiness according to claim 1, it is characterized in that, percentage, comprising: aliphatic urethane acrylate 15 ~ 20%, polyester acrylate 15 ~ 20%, iso-bornyl acrylate 10 ~ 15%, poly-penta tetrol triacrylate 13 ~ 15%, 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches 3 ~ 5%, benzophenone 3 ~ 5%, water-ground limestone 8 ~ 10%, solvent 15 ~ 20%, auxiliary agent 3 ~ 5%.
7. one kind as arbitrary in claim 1 ~ 6 as described in the preparation method with the building UV coating of high glossiness, it is characterized in that, comprise step: add in container according to above-mentioned formula by aliphatic urethane acrylate, polyester acrylate, iso-bornyl acrylate, poly-penta tetrol triacrylate, solvent and water-ground limestone, abundant stirring, add 1-hydroxyl-ring base-phenyl ketone in the sixth of the twelve Earthly Branches, benzophenone and auxiliary agent again, abundant stirring, obtains building UV coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610033318.9A CN105505198A (en) | 2016-01-19 | 2016-01-19 | Building UV coating with high gloss and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610033318.9A CN105505198A (en) | 2016-01-19 | 2016-01-19 | Building UV coating with high gloss and preparation method thereof |
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| Publication Number | Publication Date |
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| CN105505198A true CN105505198A (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201610033318.9A Pending CN105505198A (en) | 2016-01-19 | 2016-01-19 | Building UV coating with high gloss and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590116A (en) * | 2016-12-18 | 2017-04-26 | 钦州市科学技术开发中心 | Building UV (ultra violet) paint and preparation method thereof |
| CN115340815A (en) * | 2021-12-29 | 2022-11-15 | 广东宏昊化工有限公司 | Anti-yellowing wear-resistant UV gloss oil and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977748A (en) * | 2012-11-12 | 2013-03-20 | 广东巴德士化工有限公司 | UV furniture spray-coating gloss topcoat without volatile organic solvent |
| CN104927633A (en) * | 2015-07-01 | 2015-09-23 | 卓达新材料科技集团有限公司 | UV paint for building external wall panel and preparation method of UV paint |
-
2016
- 2016-01-19 CN CN201610033318.9A patent/CN105505198A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102977748A (en) * | 2012-11-12 | 2013-03-20 | 广东巴德士化工有限公司 | UV furniture spray-coating gloss topcoat without volatile organic solvent |
| CN104927633A (en) * | 2015-07-01 | 2015-09-23 | 卓达新材料科技集团有限公司 | UV paint for building external wall panel and preparation method of UV paint |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106590116A (en) * | 2016-12-18 | 2017-04-26 | 钦州市科学技术开发中心 | Building UV (ultra violet) paint and preparation method thereof |
| CN115340815A (en) * | 2021-12-29 | 2022-11-15 | 广东宏昊化工有限公司 | Anti-yellowing wear-resistant UV gloss oil and preparation method thereof |
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Application publication date: 20160420 |
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