CN105505034A - Single-component air-dried plastic paint - Google Patents
Single-component air-dried plastic paint Download PDFInfo
- Publication number
- CN105505034A CN105505034A CN201610103675.8A CN201610103675A CN105505034A CN 105505034 A CN105505034 A CN 105505034A CN 201610103675 A CN201610103675 A CN 201610103675A CN 105505034 A CN105505034 A CN 105505034A
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- CN
- China
- Prior art keywords
- weight part
- single component
- plastic paint
- coupling agent
- titanate coupling
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/22—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment
- C09D127/24—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers modified by chemical after-treatment halogenated
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses single-component air-dried plastic paint which is composed of perchloroethylene sheet liquid, polyester resin, polyethylene wax liquid, chlorinated polypropylene resin, cellulose acetate, oxide/modified nano porous carbon/titanate coupling agent, cellulose and solvent. The invention further discloses a preparation method of the single-component air-dried plastic paint.
Description
Technical field
The present invention relates to technical field of coatings, be specifically related to a kind of single component from dry plastic paint.
Background technology
The active weak plastic cement of current prior art effects on surface is (as PP; PA66, PE+EPDM etc.) carry out protecting with when decorating, in order to improve the performances such as the sticking power of paint and wear-resisting, ethanol-tolerant; mainly adopt and first spray PP priming paint, then spray the method for two-pack colored paint (colored paint+solidifying agent).Such paint in use not only needs 2-3 procedure, and the colored paint of two-pack open packaging latter 2 hours in must be finished, otherwise understand oneself solidification, can not re-use.In addition, the colored paint of two-pack easily solidifies, and cannot make filling blowing retouching paint and carry out sectional repair on plastic parts.Moreover the PP water of first spraying on market again can not to comprising PP by the method for double compositions paint, PA66, PE, PE+EPDM are at interior all plastic parts solution sticking power, rub resistance, ethanol-tolerant, all properties such as ageing-resistant.
Therefore, a kind of high adhesive force, rub resistance, ethanol-tolerant, ageing-resistant and construction technology simple, plastic paint that can be filling is necessary very much to prepare.
Summary of the invention
In order to solve the problem, this application provides a kind of single component from dry plastic paint, its raw material comprises:
The chlorinated polyvinyl chloride sheet liquid of 100 weight parts;
The vibrin of 20-30 weight part;
The polyethylene wax liquid of 5-10 weight part;
The chlorinated polypropylene of 5-10 weight part;
The cellulose acetate of 2-8 weight part;
The defoamer of 2-6 weight part;
The solvent of 15-30 weight part.
In one embodiment, the oxide compound/modified Nano porous carbon/titanate coupling agent of 5-15 weight part is comprised further.
In one embodiment, the urethane resin of 3-10 weight part is comprised further.
The invention provides the preparation method of described single component from dry plastic paint, comprise: chlorinated polyvinyl chloride sheet liquid is dissolved in solvent, after abundant stirring, add vibrin, polyethylene wax liquid, chlorinated polypropylene, cellulose acetate, urethane resin and defoamer to stir, finally add oxide compound/nanoporous carbon/titanate coupling agent fully to stir, to obtain final product.
Embodiment
The detailed description of the following preferred implementation method of the present invention of participation in the election and the embodiment comprised more easily can understand present disclosure.Can mention a large amount of term in following specification sheets and claims, these terms are defined as following implication.
Singulative comprises plural number and object is discussed, unless clearly indicated in addition in context.
" optional " or " optionally " refers to that the item that describes thereafter or event can occur or not occur, and this description comprises situation that event occurs and the situation that event does not occur.
Approximate term in specification sheets and claims is used for modifying quantity, represents that the present invention is not limited to this concrete quantity, also comprises close to this quantity acceptable and can not cause the part of the correction of the change of relevant basic function.In some example, approximate term may correspond to the precision of the instrument measuring numerical value.In present specification and claims, scope limits and can combine and/or exchange, if do not illustrate that these scopes comprise contained all subranges therebetween in addition.
Aforesaid example is only illustrative, for explaining some features of feature of the present disclosure.Appended claim is intended to the scope wide as far as possible that requirement it is contemplated that, and the embodiment presented herein is only the explanation of the embodiment of the selection of combination according to all possible embodiment.Therefore, the purpose of applicant is the selectional restriction that appended claim is not illustrated the example of feature of the present invention.And progress in science and technology is not replaced to be formed due to the inaccurate reason of language performance by the possible equivalent considered at present or son, and these changes also should be interpreted as being covered by appended claim in the conceived case.
An aspect of the application provides a kind of single component from dry plastic paint, and its raw material comprises:
The chlorinated polyvinyl chloride sheet liquid of 100 weight parts;
The vibrin of 20-30 weight part;
The polyethylene wax liquid of 5-10 weight part;
The chlorinated polypropylene of 5-10 weight part;
The cellulose acetate of 2-8 weight part;
The defoamer of 2-6 weight part;
The solvent of 15-30 weight part.
A kind of single component that the application provides is from dry plastic paint, and its raw material comprises the oxide compound/modified Nano porous carbon/titanate coupling agent of 5-15 weight part further.
A kind of single component that the application provides is from dry plastic paint, and its raw material comprises the urethane resin of 3-10 weight part further.
The term " oxide compound/modified Nano porous carbon/titanate coupling agent mixture " used in the application refers to by oxide carried on modified Nano porous carbon materials, then the mixture be obtained by reacting with titanate coupling agent.
In one embodiment, oxide compound for the application is one or more in zirconium white, aluminum oxide, silicon oxide, titanium oxide, manganese oxide, chromic oxide, cupric oxide, silver suboxide, magnesium oxide, calcium oxide, zinc oxide, Tungsten oxide 99.999, vanadium oxide, ferric oxide, one or more of concrete is Manganse Dioxide, chromic oxide, titanium oxide, silicon oxide.
In one embodiment, for the specific surface area of the application's modified Nano porous carbon at 1000-3500m
2/ g, is in particular 1500-3000m
2/ g.
In one embodiment, titanate coupling agent for the application is tetra-sodium type titanate coupling agent, alkyl carbon chain on tetra-sodium acyloxy is long is 6C-10C, and particularly, the alkyl carbon chain in described tetra-sodium titanate coupling agent on tetra-sodium acyloxy is long is 6C-8C.
In one embodiment, in described oxide compound/modified Nano porous carbon/titanate coupling agent mixture, the weight percentage of modified Nano porous carbon and titanate coupling agent is respectively 30%-50% and 0.1%-0.3%, preferably, in described oxide compound/nanoporous carbon/titanate coupling agent mixture, the weight percentage of modified Nano porous carbon and titanate coupling agent is respectively 37% and 0.9%.
For the preparation method of the oxide compound/nanoporous carbon/titanate coupling agent mixture of the application, comprising:
Step one: be react 1-5h under 70-80 degree in the nitration mixture of 3:1 in the vitriol oil/concentrated nitric acid volume ratio by nanoporous carbon, is washed till neutral acidified modified nanoporous carbon with deionized water.
Step 2: by step one gained nanoporous carbon ultrasonic disperse 0.5-3h, adds potassium permanganate and stirs 0.5-2h, and put into microwave reactor reaction 1-60min, obtained load has the nanoporous carbon of Manganse Dioxide.
Step 3: have the nanoporous carbon of Manganse Dioxide to add in high speed ball mill in step one gained nanoporous carbon or the load of step 2 gained, add nano-oxide and carry out high speed ball milling, namely obtained load has the modified Nano porous carbon of oxide compound.
Step 4: added by titanate coupling agent in Virahol, the mass ratio of titanate coupling agent and Virahol controls between 1:1-1:5.The modified Nano porous carbon of oxide compound is had to put into homogenizer load described in step 2 or step 3, the titanate coupling agent after isopropanol is sprayed into vaporific, the add-on percentage of titanate coupling agent is 0.1%-3%, stir 5-30min, namely synthesize described oxide compound/modified Nano porous carbon/titanate coupling agent matrix material.Preferably, described modified Nano porous carbon is the modified Nano porous carbon that the load obtained through step 2 has Manganse Dioxide.
Applicant finds, single component described in preparation adds described oxide compound/modified Nano porous carbon/titanate coupling agent mixture when dry plastic paint, paint film wear resistance significantly increases, sticking power also corresponding enhancing, solid-filling amount is corresponding improve also, simultaneously, paint film has more excellent oilness, shock-resistance and resistance toheat, therefore constitutes beneficial effect of the present invention.
Chlorinity for the chlorinated polyvinyl chloride sheet liquid of the application counts 61%-65% with massfraction.
Vibrin described in the application is not particularly limited, can be commercially available, as the trade mark be TM195,5692, F45,575, TM197, TM199,5685,7901,191,196, TM182,197,3301, the vibrin of 323, also can synthesize and obtain.
Urethane resin described in the application is obtained by polyol prepolymer and aliphatic diisocyanate synthesis.
In one embodiment, add triphenyl phosphite in described urethane resin building-up process, add-on counts 1%-3% with molecular fraction; Preferably, the add-on of described triphenyl phosphite counts 1.7% with molecular fraction.
For the concrete preparation method of the described urethane resin of the application, comprise: 150ml polyvalent alcohol performed polymer is joined in dry 500ml four-hole boiling flask, pass into drying nitrogen, be warming up to 70-80 degree, a certain amount of aliphatic diisocyanate is added by constant pressure funnel, make the mol ratio of vulcabond and hydroxyl in mixture at about 3-4, reaction 0.5-3h, instilling molecular fraction by constant pressure funnel is the dihydroxyphenyl propane of 0.1-5%, reaction 0.5-3h, add the triphenyl phosphite that molecular fraction is 1%-3%, stir, the 2-hydroxy-ethyl acrylate that molecular fraction is 0.01-0.1% is added after 30-60min, high-speed stirring, obtain polyurethane dispersions,
Described polyol prepolymer is selected from ethylene glycol prepolymer, 1, 2-propylene glycol prepolymer, 1, ammediol prepolymer, 1, 2-butyleneglycol prepolymer, 1, 3-butyleneglycol prepolymer, 1, 4-butyleneglycol prepolymer, 1, 2-pentanediol prepolymer, 1, 3-pentanediol prepolymer, 1, 4-pentanediol prepolymer, 1, 5-pentanediol prepolymer, 1, 2-hexylene glycol prepolymer, 1, 3-hexylene glycol prepolymer, 1, 4-hexylene glycol prepolymer, 1, 5-hexylene glycol prepolymer, 1, 6-hexylene glycol prepolymer, 1, 7-heptanediol prepolymer, 1, 8-ethohexadiol prepolymer, 1, 9-nonanediol prepolymer, 1, one or more of 10-decanediol prepolymer.Preferably, described polyol prepolymer is selected from the one in ethylene glycol prepolymer, 1,3-PD prepolymer, BDO prepolymer, 1,6-hexylene glycol prepolymer, and molecular weight is between 200-1000;
Described aliphatic diisocyanate is selected from one or more of hexamethylene diisocyanate, isophorone diisocyanate, dicyclohexyl methane diisocyanate, tetramethylxylylene diisocyanate and vinyl toluene isocyanic ester; preferably, described aliphatic diisocyanate is hexamethylene diisocyanate;
The sticking power that the adding of described urethane resin can increase on the one hand coating, the performance such as water-fast, wear-resisting, corrosion-resistant, also improve the ageing-resistant performance of coating on the other hand, moreover, triphenyl phosphite directly adds in urethane resin the generation that it also avoid itself and the side reaction of tetra-sodium type titanate coupling agent, because herein is provided beneficial effect of the present invention.
The molecular weight of the polyethylene wax liquid used in the application is 1000-5000; Preferably, the molecular weight of described polyethylene wax liquid is 3000-4000.
In the application, the chlorinity of chlorinated polypropylene used is calculated in mass percent as 55%-65%.
Described in the application, defoamer is not particularly limited, and can be commercially available, also can synthesize and obtain.
Solvent described in the application is vinyl acetic monomer, N-BUTYL ACETATE, one or more in propylene dichloride, pimelinketone.
Single component described in the application is from the preparation method of dry plastic paint, concrete steps are: be dissolved in solvent by described chlorinated polyvinyl chloride sheet liquid, abundant stirring, then add after vibrin, polyethylene wax liquid, chlorinated polypropylene, cellulose acetate and defoamer stir, finally add oxide compound/modified Nano porous carbon/titanate coupling agent fully to stir, obtain of the present invention from dry plastic paint.
Below by way of specific embodiment, the present invention is specifically described, should be appreciated that specific embodiment described herein only for explaining the present invention, being not intended to limit the present invention.
In addition, if do not have other to illustrate, all raw materials are all commercially available, and following material number used is weight part.
Raw material:
A1: chlorinated polyvinyl chloride sheet liquid
B1: vibrin
C1: vibrin (synthesize by described method, the add-on of triphenyl phosphite is designated as 1% with weight part)
C2: vibrin (synthesize by described method, the add-on of triphenyl phosphite is designated as 1.7% with weight part)
C3: vibrin (synthesize by described method, the add-on of triphenyl phosphite is designated as 3% with weight part)
D1: polyethylene wax liquid
E1: Chlorinated Polypropylene III
F1: cellulose acetate
G1: oxide compound/modified Nano porous carbon/titanate coupling agent matrix material (synthesize by described method, modified Nano porous carbon and titanate coupling agent add-on are respectively 30% and 0.1% by weight percentage)
G2: oxide compound/modified Nano porous carbon/titanate coupling agent matrix material (synthesize by described method, modified Nano porous carbon and titanate coupling agent add-on are respectively 37% and 0.9% by weight percentage)
G3: oxide compound/modified Nano porous carbon/titanate coupling agent matrix material (synthesize by described method, modified Nano porous carbon and titanate coupling agent add-on are respectively 50% and 3% by weight percentage)
H1: defoamer
I1: solvent
Embodiment 1-8 and comparative example 1-3:
Embodiment 1
By A1100 weight part, B13 weight part, C120 weight part, D15 weight part, E15 weight part, F12 weight part H12 weight part and I115 weight part stir, and add G15 weight part, fully stir.
Embodiment 2
By A1100 weight part, B110 weight part, C130 weight part, D110 weight part, E110 weight part, F18 weight part H16 weight part and I130 weight part stir, and add G115 weight part, fully stir.
Embodiment 3
By A1100 weight part, B16 weight part, C123 weight part, D17 weight part, E18 weight part, F12.5 weight part H14 weight part and I117 weight part stir, and add G37 weight part, fully stir.
Embodiment 4
By A1100 weight part, B16 weight part, C223 weight part, D17 weight part, E18 weight part, F12.5 weight part H14 weight part and I117 weight part stir, and add G27 weight part, fully stir.
Embodiment 5
By A1100 weight part, B16 weight part, C323 weight part, D17 weight part, E18 weight part, F12.5 weight part H14 weight part and I117 weight part stir, and add G17 weight part, fully stir.
Embodiment 6
By A1100 weight part, B16 weight part, C223 weight part, D110 weight part, E18 weight part, F12.5 weight part H14 weight part and I117 weight part stir, and add G27 weight part, fully stir.
Embodiment 7
By A1100 weight part, B16 weight part, C223 weight part, D17 weight part, E112 weight part, F12.5 weight part H14 weight part and I117 weight part stir, and add G27 weight part, fully stir.
Embodiment 8
By A1100 weight part, B16 weight part, C223 weight part, D17 weight part, E18 weight part, F15 weight part H14 weight part and I117 weight part stir, and add G27 weight part, fully stir.
Comparative example 1
By A1100 weight part, B16 weight part, D17 weight part, E18 weight part, F12.5 weight part H14 weight part and I117 weight part stir, and fully stir.
Comparative example 2
By A1100 weight part, B16 weight part, C223 weight part, D17 weight part, E18 weight part, F12.5 weight part H14 weight part and I117 weight part, fully stir.
Comparative example 3
By A1100 weight part, B16 weight part, D17 weight part, E18 weight part, F12.5 weight part H14 weight part and I117 weight part stir, and add G27 weight part, fully stir.
Single component is prepared from dry plastic paint according to the formula in table 1.
Table 1 prepares single component from the raw material of dry plastic paint and consumption (weight part)
Testing method:
The invention belongs to vinyl perchloride anti-corrosion paint category, so adopt HGT3358-1987 " the assorted vinyl perchloride anti-corrosion paint of G52-31 " to be Technical Reference standard.Viscosity measures according to GB/T1723-93, time of doing solid work measures according to GB GB/T1728-89, wear resistance measures according to GB/T1768-2006, and sticking power measures according to GB/T1720-85, and ageing-resistant performance measures according to GBT1766-1995.
Detected result is as shown in table 2.
Under table 2 different components add-on, single component is from the performance index of dry plastic paint
The data of table 2 show, single component prepared by the present invention has single component, from dry, high adhesive force, the premium properties such as wear-resisting, ageing-resistant from dry plastic paint, in addition, owing to being single component paint, the present invention can make filling blowing retouching paint and carry out sectional repair on plastic parts, therefore constitutes beneficial effect of the present invention.
Aforesaid example is only illustrative, for explaining some features of feature of the present disclosure.Appended claim is intended to the scope wide as far as possible that requirement it is contemplated that, and the embodiment presented herein is only the explanation of the embodiment of the selection of combination according to all possible embodiment.Therefore, the purpose of applicant is the selectional restriction that appended claim is not illustrated the example of feature of the present invention.And progress in science and technology is not replaced to be formed due to the inaccurate reason of language performance by the possible equivalent considered at present or son, and these changes also should be interpreted as being covered by appended claim in the conceived case.
Claims (10)
1. single component is from a dry plastic paint, it is characterized in that, its raw material comprises:
The chlorinated polyvinyl chloride sheet liquid of 100 weight parts;
The vibrin of 20-30 weight part;
The polyethylene wax liquid of 5-10 weight part;
The chlorinated polypropylene of 5-10 weight part;
The cellulose acetate of 2-8 weight part;
The defoamer of 2-6 weight part;
The solvent of 15-30 weight part.
2. a kind of single component according to claim 1 is from dry plastic paint, it is characterized in that, comprises the oxide compound/modified Nano porous carbon/titanate coupling agent of 5-15 weight part further.
3. a kind of single component according to claim 2 is from dry plastic paint, it is characterized in that, in described oxide compound/modified Nano porous carbon/titanate coupling agent, the weight percentage of modified Nano porous carbon is 30%-50%.
4. a kind of single component according to claim 3 is from dry plastic paint, it is characterized in that, the ratio of the oxygen element in described modified Nano porous carbon in carboxyl is 5at%-15at%.
5. a kind of single component according to claim 4 is from dry plastic paint, it is characterized in that, in described oxide compound/nanoporous carbon/titanate coupling agent, titanate coupling agent is tetra-sodium type titanate coupling agent, and its weight percentage is 0.1%-3%.
6. a kind of single component according to claim 1 is from dry plastic paint, it is characterized in that, the chlorinity of described chlorinated polyvinyl chloride sheet liquid counts 61%-65% with massfraction.
7. a kind of single component according to claim 1 is from dry plastic paint, it is characterized in that, comprises the urethane resin of 3-10 weight part further.
8. a kind of single component according to claim 7 is from dry plastic paint, it is characterized in that, described urethane resin is obtained by polyol prepolymer and aliphatic diisocyanate synthesis.
9. a kind of single component according to claim 1 is from dry plastic paint, it is characterized in that, described solvent is vinyl acetic monomer, N-BUTYL ACETATE, acetone, one or more in propylene dichloride, pimelinketone.
10. prepare the method for the single component as described in any one of claim 1 to 9 claim from dry plastic paint for one kind, comprise: chlorinated polyvinyl chloride sheet liquid is dissolved in solvent, after abundant stirring, add vibrin, polyethylene wax liquid, chlorinated polypropylene, cellulose acetate and defoamer to stir, finally add oxide compound/nanoporous carbon/titanate coupling agent fully to stir, to obtain final product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610103675.8A CN105505034B (en) | 2016-02-25 | 2016-02-25 | A kind of one pack system is from dry plastic paint |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610103675.8A CN105505034B (en) | 2016-02-25 | 2016-02-25 | A kind of one pack system is from dry plastic paint |
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| CN105505034A true CN105505034A (en) | 2016-04-20 |
| CN105505034B CN105505034B (en) | 2018-06-08 |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022258A (en) * | 2017-06-07 | 2017-08-08 | 南通加隆塑胶有限公司 | A kind of high absorption affinity plastic paint and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104134548A (en) * | 2014-07-09 | 2014-11-05 | 上海应用技术学院 | Porous composite material of manganese dioxide and carbon and preparation method thereof |
| CN105038441A (en) * | 2015-08-14 | 2015-11-11 | 上海祥水汽车零配件有限公司 | Single-component high wear resistance high adhering force plastic coating |
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2016
- 2016-02-25 CN CN201610103675.8A patent/CN105505034B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104134548A (en) * | 2014-07-09 | 2014-11-05 | 上海应用技术学院 | Porous composite material of manganese dioxide and carbon and preparation method thereof |
| CN105038441A (en) * | 2015-08-14 | 2015-11-11 | 上海祥水汽车零配件有限公司 | Single-component high wear resistance high adhering force plastic coating |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107022258A (en) * | 2017-06-07 | 2017-08-08 | 南通加隆塑胶有限公司 | A kind of high absorption affinity plastic paint and preparation method thereof |
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