CN105504654A - PA (polyamide)/ABS (acrylonitrile-butadiene-styrene copolymer) alloy material and preparation method thereof - Google Patents
PA (polyamide)/ABS (acrylonitrile-butadiene-styrene copolymer) alloy material and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
- C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/08—Polymer mixtures characterised by other features containing additives to improve the compatibility between two polymers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/20—Recycled plastic
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Abstract
The invention discloses a PA (polyamide)/ABS (acrylonitrile-butadiene-styrene copolymer) alloy and a preparation method thereof. The PA/ABS alloy comprises the following components by mass percent: 20-60% of regenerated PA6 resin, 30-70% of ABS resin, 0-30% of glass fibers, 0-10% of compatilizer, 0.1-1% of lubricating agent, 0.1-0.5% of nucleating agent and 0.2-1% of antioxidant. The PA/ABS alloy has the beneficial effects that the prepared high-performance and low-cost PA/ABS alloy takes regenerated PA6 and ABS as binders and meanwhile the glass fibers, the compatilizer and a few other auxiliaries are added and blended with the binders, so that the PA/ABS alloy has high performances, is low in cost and has a better practical prospect and obvious social and economic benefits in the fields of automobiles, electronics, daily supplies, building materials, and the like.
Description
Technical field
The present invention relates to polymeric material field, specifically a kind of high-performance and low-cost PA/ABS alloy material and preparation method thereof.
Background technology
Along with the development of society, improving constantly of living standards of the people, carpet starts to come into huge numbers of families.Nylon carpet is as a large amount of chemical fibre class carpet used the earliest, and with its wear resistance, intensity, the excellent characteristic such as high and acid and alkali-resistance is widely used.The treatment process of current waste and old nylon carpet has energy recovery, landfill recovery, chemical recovery and salvage material etc.; along with society advocates the development of theory of environment protection, green economy, recycling economy and Sustainable development, the attention that PA6 cycling and reutilization is more and more subject to everybody will be regenerated in waste and old nylon carpet.But because regeneration PA6 is through use procedure, degraded in use procedure makes its performance compare with virgin material more decline, compares and is difficult to be directly used in engineering plastics, therefore, need the modification of carrying out again to them, recycle after obtaining high performance composite.
Summary of the invention
The object of the present invention is to provide a kind of high-performance and low-cost PA/ABS Alloy And Preparation Method.To solve the problems referred to above of prior art.
The object of the invention is to be achieved through the following technical solutions.
A kind of PA/ABS alloy material, its composition by mass percent proportioning is: regeneration PA6 resin 20% ~ 60%, ABS resin 30 ~ 70%, glass fibre 0 ~ 30%, compatilizer 0 ~ 10%, lubrication dispersing agent 0.1 ~ 1%, nucleator 0.1 ~ 0.5%, oxidation inhibitor 0.2% ~ 1%.
In described PA/ABS alloy material, described regeneration PA6 resin is the waste and old nylon carpet regeneration PA6 resin that extruding pelletization is obtained after broken, cleaning, separation, drying reclaimed, it is 2.0-2.7 according to Ubbelohde viscosimetry relative viscosity, and wherein PA6 is polycaprolactam.
Described ABS resin is the acrylonitrile-butadiene-styrene copolymer adopting suspension method, emulsion method or substance law to prepare.
Described glass fibre is alkali-free chopped glass fiber, and chopped length is 3mm ~ 4.5mm, and diameter is 9um ~ 14um, and described fiberglass surfacing is through silane coupling agent process.
Described compatilizer is styrene-maleic anhydride copolymer (SMA).
Described lubricant dispersion agent is silicone.
Described nucleator is the zinc salt of talcum powder, ethene and Sipacril 2739OF, calcium stearate and Nano-meter SiO_2
2in one.
Described oxidation inhibitor is the one in antioxidant 1010, antioxidant 1076, antioxidant 1010 and oxidation inhibitor 619F compound, antioxidant 1076 and oxidation inhibitor 619F compound.
The preparation method of above-mentioned this PA/ABS alloy, comprises the following steps:
(1) PA6, ABS will be regenerated at 100 DEG C ~ 120 DEG C dry more than 8 hours, glass fibre, compatilizer, lubricant dispersion agent, nucleator and oxidation inhibitor at 70 DEG C ~ 100 DEG C dry 4 hours;
(2) by regeneration PA6, ABS, the compatilizer after drying treatment, after lubrication dispersing agent, nucleator and oxidation inhibitor take in proportion, put into high-speed mixer, stir 5 ~ 20 minutes under normal temperature.
(3) step (2) mixed material is joined the main spout of twin screw extruder, the glass fibre taken by weight ratio is joined the side spout of twin screw extruder, extrude after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, obtain a kind of high-performance and low-cost PA/ABS alloy of the present invention.
The invention has the beneficial effects as follows, a kind of high-performance and low-cost PA/ABS alloy that the present invention obtains regenerates PA6 and ABS for base-material, add simultaneously glass fibre, compatilizer and on a small quantity other complementary auxiliary agent carry out blended, there is performance high and with low cost, there are in fields such as automobile, electronic apparatus, articles for daily use and building materials good practical prospect and obvious economic results in society.
Embodiment
Further illustrate technical scheme of the present invention below by preferred embodiment and comparative example, do not violating under aim of the present invention, the present invention should be not limited to the content that following experimental example is specifically expressed.
Comparative example raw materials is as follows:
Polycaprolactam (PA6): relative viscosity scope is 2.0-2.7;
Acrylonitrile-butadiene-styrene copolymer (ABS): substance law ABS;
Glass fibre: surface is through the alkali-free short glass fiber of silane coupling agent process;
Compatilizer: styrene-maleic anhydride copolymer (SMA);
Lubrication dispersing agent: silicone;
Nucleator: talcum powder;
Oxidation inhibitor: antioxidant 1010;
Product performance testing method:
Density: by ISO1183-1 method.
Tensile property: by ISO527 method, draw speed 50 mm/min.
Bending property: by ISO178 method, trial speed 2 mm/min.
Notched Izod impact strength: by ISO179 method, 4 mm thick samples.
Embodiment 1
A kind of high-performance and low-cost PA/ABS alloy, its composition by mass percent proportioning is: regeneration PA6 resin 30%, ABS resin 64%, styrene-maleic anhydride copolymer (SMA) 5%, silicone 0.5%, talcum powder 0.2%, antioxidant 1010 0.3%.Wherein, described regeneration PA6 resin is the waste and old nylon carpet regeneration PA6 resin that extruding pelletization is obtained after broken, cleaning, separation, drying reclaimed, and it is 2.0-2.7 according to Ubbelohde viscosimetry relative viscosity, and wherein PA6 is polycaprolactam.Described ABS resin is substance law acrylonitrile-butadiene-styrene copolymer.
Preparation method: (1) will regenerate PA6, ABS at 100 DEG C ~ 120 DEG C dry more than 8 hours, styrene-maleic anhydride copolymer (SMA), silicone, talcum powder, antioxidant 1010 at 70 DEG C ~ 100 DEG C dry 4 hours; (2) regeneration PA6, the ABS after drying treatment, styrene-maleic anhydride copolymer (SMA), silicone, talcum powder, antioxidant 1010 are put into high-speed mixer after taking in proportion, stir 5 ~ 20 minutes under normal temperature.(3) step (2) mixed material is joined the main spout of twin screw extruder, extrude after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, obtain a kind of high-performance and low-cost PA/ABS alloy of the present invention, adopt injection moulding machine preparation standard mechanical test sample, test result is in table 1.
Embodiment 2
A kind of high-performance and low-cost PA/ABS alloy, its composition by mass percent proportioning is: regeneration PA6 resin 50%, ABS resin 44%, styrene-maleic anhydride copolymer (SMA) 5%, silicone 0.5%, calcium stearate 0.2%, antioxidant 1010 and oxidation inhibitor 619F compound 0.3%.Wherein, described regeneration PA6 resin is the waste and old nylon carpet regeneration PA6 resin that extruding pelletization is obtained after broken, cleaning, separation, drying reclaimed, and it is 2.0-2.7 according to Ubbelohde viscosimetry relative viscosity, and wherein PA6 is polycaprolactam.Described ABS resin is substance law acrylonitrile-butadiene-styrene copolymer.
Preparation method: (1) will regenerate PA6, ABS at 100 DEG C ~ 120 DEG C dry more than 8 hours, the drying 4 hours at 70 DEG C ~ 100 DEG C of styrene-maleic anhydride copolymer (SMA), silicone, calcium stearate, antioxidant 1010 and oxidation inhibitor 619F compound; (2) 2) by regeneration PA6, the ABS after drying treatment, styrene-maleic anhydride copolymer (SMA), put into high-speed mixer after silicone, calcium stearate, antioxidant 1010 and oxidation inhibitor 619F compound take in proportion, stir 5 ~ 20 minutes under normal temperature.(3) step (2) mixed material is joined the main spout of twin screw extruder, extrude after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, obtain a kind of high-performance and low-cost PA/ABS alloy of the present invention, adopt injection moulding machine preparation standard mechanical test sample, test result is in table 1.
Embodiment 3
A kind of high-performance and low-cost PA/ABS alloy, its composition by mass percent proportioning is: regeneration PA6 resin 30%, ABS resin 54%, surperficial alkali-free short glass fiber 10%, styrene-maleic anhydride copolymer (SMA) 5%, silicone 0.5%, Nano-meter SiO_2 through silane coupling agent process
20.2%, antioxidant 1076 and oxidation inhibitor 619F compound 0.3%.Wherein, described regeneration PA6 resin is the waste and old nylon carpet regeneration PA6 resin that extruding pelletization is obtained after broken, cleaning, separation, drying reclaimed, and it is 2.0-2.7 according to Ubbelohde viscosimetry relative viscosity, and wherein PA6 is polycaprolactam.Described ABS resin is substance law acrylonitrile-butadiene-styrene copolymer.
Preparation method: (1) will regenerate PA6, ABS drying more than 8 hours at 100 DEG C ~ 120 DEG C, and surface is through alkali-free short glass fiber, styrene-maleic anhydride copolymer (SMA), silicone, the Nano-meter SiO_2 of silane coupling agent process
2, antioxidant 1076 and oxidation inhibitor 619F compound at 70 DEG C ~ 100 DEG C dry 4 hours; (2) by regeneration PA6, the ABS after drying treatment, styrene-maleic anhydride copolymer (SMA), silicone, Nano-meter SiO_2
2, antioxidant 1076 and oxidation inhibitor 619F compound put into high-speed mixer after taking in proportion, stir 5 ~ 20 minutes under normal temperature.(3) step (2) mixed material is joined the main spout of twin screw extruder, the surface taken by weight ratio is joined the side spout of twin screw extruder through the alkali-free short glass fiber of silane coupling agent process, extrude after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, obtain a kind of high-performance and low-cost PA/ABS alloy of the present invention, adopt injection moulding machine preparation standard mechanical test sample, test result is in table 1.
Embodiment 4
A kind of high-performance and low-cost PA/ABS alloy, its composition by mass percent proportioning is: zinc salt 0.2%, the antioxidant 1010 0.3% of regeneration PA6 resin 50%, ABS resin 24%, the surperficial alkali-free short glass fiber 20% through silane coupling agent process, styrene-maleic anhydride copolymer (SMA) 5%, silicone 0.5%, ethene and Sipacril 2739OF.Wherein, described regeneration PA6 resin is the waste and old nylon carpet regeneration PA6 resin that extruding pelletization is obtained after broken, cleaning, separation, drying reclaimed, and it is 2.0-2.7 according to Ubbelohde viscosimetry relative viscosity, and wherein PA6 is polycaprolactam.Described ABS resin is substance law acrylonitrile-butadiene-styrene copolymer.
Preparation method: (1) will regenerate PA6, ABS at 100 DEG C ~ 120 DEG C dry more than 8 hours, surface is through the drying 4 hours at 70 DEG C ~ 100 DEG C of the zinc salt of the alkali-free short glass fiber of silane coupling agent process, styrene-maleic anhydride copolymer (SMA), silicone, ethene and Sipacril 2739OF, antioxidant 1010; (2) zinc salt of regeneration PA6, the ABS after drying treatment, styrene-maleic anhydride copolymer (SMA), silicone, ethene and Sipacril 2739OF, antioxidant 1010 are put into high-speed mixer after taking in proportion, stir 5 ~ 20 minutes under normal temperature.(3) step (2) mixed material is joined the main spout of twin screw extruder, the surface taken by weight ratio is joined the side spout of twin screw extruder through the alkali-free short glass fiber of silane coupling agent process, extrude after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, obtain a kind of high-performance and low-cost PA/ABS alloy of the present invention, adopt injection moulding machine preparation standard mechanical test sample, test result is in table 1.
Embodiment 5
A kind of high-performance and low-cost PA/ABS alloy, its composition by mass percent proportioning is: regeneration PA6 resin 30%, ABS resin 34%, styrene-maleic anhydride copolymer (SMA) 5%, silicone 0.5%, calcium stearate 0.2%, antioxidant 1010 and oxidation inhibitor 619F compound 0.3%.Wherein, described regeneration PA6 resin is the waste and old nylon carpet regeneration PA6 resin that extruding pelletization is obtained after broken, cleaning, separation, drying reclaimed, and it is 2.0-2.7 according to Ubbelohde viscosimetry relative viscosity, and wherein PA6 is polycaprolactam.Described ABS resin is substance law acrylonitrile-butadiene-styrene copolymer.
Preparation method: (1) will regenerate PA6, ABS at 100 DEG C ~ 120 DEG C dry more than 8 hours, surface is through the drying 4 hours at 70 DEG C ~ 100 DEG C of the alkali-free short glass fiber of silane coupling agent process, styrene-maleic anhydride copolymer (SMA), silicone, calcium stearate, antioxidant 1010 and oxidation inhibitor 619F compound; (2) put into high-speed mixer after regeneration PA6, the ABS after drying treatment, styrene-maleic anhydride copolymer (SMA), silicone, calcium stearate, antioxidant 1010 and oxidation inhibitor 619F compound being taken in proportion, stir 5 ~ 20 minutes under normal temperature.(3) step (2) mixed material is joined the main spout of twin screw extruder, the surface taken by weight ratio is joined the side spout of twin screw extruder through the alkali-free short glass fiber of silane coupling agent process, extrude after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, obtain a kind of high-performance and low-cost PA/ABS alloy of the present invention, adopt injection moulding machine preparation standard mechanical test sample, test result is in table 1.
Comparative example 1
Direct employing relative viscosity scope is the polycaprolactam (PA6) of 2.0-2.7, substance law acrylonitrile-butadiene-styrene copolymer (ABS) prepares PA/ABS alloy, and its composition by mass percent proportioning is: PA6 resin 50%, ABS resin 44%, styrene-maleic anhydride copolymer (SMA) 5%, silicone 0.5%, talcum powder 0.2%, antioxidant 1010 0.3%.Wherein, described PA6 resin is polycaprolactam, and relative viscosity is 2.0-2.7.Described acrylonitrile-butadiene-styrene copolymer (ABS) is substance law ABS.
Preparation method: (1) by PA6 and ABS at 100 DEG C ~ 120 DEG C dry more than 8 hours, styrene-maleic anhydride copolymer (SMA), silicone, talcum powder, antioxidant 1010 at 70 DEG C ~ 100 DEG C dry 4 hours; (2) PA6 after drying treatment, ABS, styrene-maleic anhydride copolymer (SMA), silicone, talcum powder, antioxidant 1010 are put into high-speed mixer after taking in proportion, stir 5 ~ 20 minutes under normal temperature.(3) step (2) mixed material is joined the main spout of twin screw extruder, extrudes after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, adopt injection moulding machine preparation standard mechanical test sample, test result is in table 1.
Table 1: the performance test results.
As can be seen from Table 1, adopt preparation method of the present invention, the PA/ABS alloy of preparation has high strength and high tenacity.Be the polycaprolactam (PA6) of 2.0-2.7 with directly adopting relative viscosity, PA/ABS alloy phase ratio prepared by substance law acrylonitrile-butadiene-styrene copolymer (ABS), PA/ABS alloy property prepared by the present invention is suitable with it, but cost reduces a lot.The moulded parts obtained by the present invention can be widely used in the fields such as automobile, electronic apparatus, articles for daily use and building materials.
Claims (9)
1. a PA/ABS alloy material, it is characterized in that: its composition by mass percent proportioning is: regeneration PA6 resin 20% ~ 60%, ABS resin 30 ~ 70%, glass fibre 0 ~ 30%, compatilizer 0 ~ 10%, lubrication dispersing agent 0.1 ~ 1%, nucleator 0.1 ~ 0.5%, oxidation inhibitor 0.2% ~ 1%.
2. a kind of PA/ABS alloy material according to claim 1, it is characterized in that: described regeneration PA6 resin is the waste and old nylon carpet regeneration PA6 resin that extruding pelletization is obtained after broken, cleaning, separation, drying reclaimed, it is 2.0-2.7 according to Ubbelohde viscosimetry relative viscosity, and wherein PA6 is polycaprolactam.
3. a kind of PA/ABS alloy material according to claim 1, is characterized in that: described ABS resin is the acrylonitrile-butadiene-styrene copolymer adopting suspension method, emulsion method or substance law to prepare.
4. a kind of PA/ABS alloy material according to claim 1, it is characterized in that: described glass fibre is alkali-free chopped glass fiber, chopped length is 3mm ~ 4.5mm, and diameter is 9um ~ 14um, and described fiberglass surfacing is through silane coupling agent process.
5. a kind of PA/ABS alloy material according to claim 1, is characterized in that: described compatilizer is styrene-maleic anhydride copolymer (SMA).
6. a kind of PA/ABS alloy material according to claim 1, is characterized in that: described lubricant dispersion agent is silicone.
7. a kind of PA/ABS alloy material according to claim 1, is characterized in that: described nucleator is the zinc salt of talcum powder, ethene and Sipacril 2739OF, calcium stearate and Nano-meter SiO_2
2in one.
8. a kind of PA/ABS alloy material according to claim 1, is characterized in that: described oxidation inhibitor is the one in antioxidant 1010, antioxidant 1076, antioxidant 1010 and oxidation inhibitor 619F compound, antioxidant 1076 and oxidation inhibitor 619F compound.
9. the preparation method of one of any described PA/ABS alloy of claim 1-8, is characterized in that: comprise the following steps:
(1) PA6, ABS will be regenerated at 100 DEG C ~ 120 DEG C dry more than 8 hours, glass fibre, compatilizer, lubricant dispersion agent, nucleator and oxidation inhibitor at 70 DEG C ~ 100 DEG C dry 4 hours;
(2) by regeneration PA6, ABS, the compatilizer after drying treatment, after lubrication dispersing agent, nucleator and oxidation inhibitor take in proportion, put into high-speed mixer, stir 5 ~ 20 minutes under normal temperature.
(3) step (2) mixed material is joined the main spout of twin screw extruder, the glass fibre taken by weight ratio is joined the side spout of twin screw extruder, extrude after 200 DEG C ~ 260 DEG C fully plasticizing mixing, cooling granulation, obtain a kind of high-performance and low-cost PA/ABS alloy of the present invention.
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| CN106280417A (en) * | 2016-08-18 | 2017-01-04 | 苏州隆芝耀新材料有限公司 | A kind of enhancement mode alloy and preparation method thereof |
| CN106700519A (en) * | 2016-11-04 | 2017-05-24 | 上海普利特复合材料股份有限公司 | PA-PP alloy and preparation method thereof |
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| CN106700519A (en) * | 2016-11-04 | 2017-05-24 | 上海普利特复合材料股份有限公司 | PA-PP alloy and preparation method thereof |
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Application publication date: 20160420 |