CN105504407A - Electric rubber with excellent grapping property and method for treating wastewater of electric rubber - Google Patents
Electric rubber with excellent grapping property and method for treating wastewater of electric rubber Download PDFInfo
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- CN105504407A CN105504407A CN201511030998.0A CN201511030998A CN105504407A CN 105504407 A CN105504407 A CN 105504407A CN 201511030998 A CN201511030998 A CN 201511030998A CN 105504407 A CN105504407 A CN 105504407A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/02—Aerobic processes
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/341—Consortia of bacteria
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F236/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F236/02—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F236/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F236/10—Copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated with vinyl-aromatic monomers
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/38—Polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2312/00—Crosslinking
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
Abstract
The invention provides electric rubber with excellent grapping property, and relates to the field of rubber. The electric rubber is prepared from the following components in parts by weight: 10-20 parts of styrene, 10-20 parts of isoprene, 10-20 parts of butadiene, 15-25 parts of butadiene styrene rubber, 8-15 parts of neodymium naphthenate, 10-15 parts of carbon black, 3-7 parts of silicon dioxide, 3-6 parts of zinc borate, 5-13 parts of accelerant, 1-5 parts of an antiaging agent 264 and 2-6 parts of an anti-aging agent MB. The electric rubber has good abrasion resistance and strong grapping property. The invention further provides a method for treating wastewater of the electric rubber with excellent grapping property.
Description
Technical field
The present invention relates to rubber materials, possess good grasp property electric power rubber and the treatment process of waste water thereof in particular to a kind of.
Background technology
The temperature of electric power tire rubber is in motion through being everlasting more than 100 DEG C, and this is caused by strong impulse, but, also just because of this, the wearing and tearing of tire increase, and it also declines to the gripping power on ground thereupon, when the gripping power of racing car is lower, just easily there is accident.Thus, how to improve the wear resistance and grasp property that possess good grasp property electric power rubber, just become problem demanding prompt solution.
Summary of the invention
In view of this, the invention provides and a kind ofly possess good grasp property electric power rubber and the treatment process of waste water thereof, existingly possess good grasp property electric power rubber abrasive-resistance and the poor problem of gripping power to improve.
For achieving the above object, the invention provides following technical scheme:
A kind of possess good grasp property electric power rubber, count by weight, component is composed as follows: vinylbenzene 10-20 part, isoprene 10-20 part, divinyl 10-20 part, styrene-butadiene rubber(SBR) 15-25 part, organic acid neodymium 8-15 part, carbon black 10-15 part, silicon-dioxide 3-7 part, zinc borate 3-6 part, promotor 5-13 part, antioxidant 264 1-5 part, antioxidant MB 2-6 part.
Preferably, above-mentioned possesses in good grasp property electric power rubber, count by weight, component is composed as follows: vinylbenzene 14-17 part, isoprene 14-17 part, divinyl 15-18 part, styrene-butadiene rubber(SBR) 16-20 part, organic acid neodymium 10-12 part, carbon black 11.5-13 part, silicon-dioxide 3-5 part, zinc borate 4.5-5 part, promotor 6-10 part, antioxidant 264 3-4 part, antioxidant MB 4.5-6 part.
Preferably, above-mentioned possesses in good grasp property electric power rubber, and described organic acid neodymium is neodymium naphthenate.
Preferably, above-mentioned possesses in good grasp property electric power rubber, and described promotor is Vulcanization accelerator TMTD.Vulcanization accelerator TMTD is the promotor comparatively commonly used, and is easy to obtain, and facilitation effect is good.
Present invention also offers and a kind ofly process the above-mentioned method possessing the waste water of good grasp property electric power rubber, comprise the steps:
A. get engineering composite flora ADB350M bacterial classification and be placed in reaction tank, add deionized water, activate bacterial classification by oxygen increasing pump bubbling aeration, make its ramp breeding at short notice;
B. adding activating strain liquid in MABR system, being circulated to the microbial film that tubular fibre film outer surface apposition growth one deck is complete;
C. waste water is added in reaction tank, pump into MABR system, circulate, circulate pollutent in process in waste water by the microbiological deterioration in microbial film.
Relative to prior art, the present invention includes following beneficial effect: the present invention utilizes vinylbenzene, isoprene and divinyl as feed composition, vinylbenzene, isoprene and butadiene terpolymer are made up of the segment of different glass temperature, obtained rubber has good grasp property, and the vulcanization rate of sizing material is also very fast.And the organic acid neodymium, styrene-butadiene rubber(SBR) and the vinylbenzene that add, isoprene, divinyl have good synergy, modification can be carried out to it, make three give full play to respective performance, and can carry out good crosslinked.Promotor, antioxidant 264, antioxidant MB have good wear resistance and longer work-ing life, excellent combination property to making the rubber obtained, and practicality is high, suitable for large-scale promotion.
Embodiment
Below by specific embodiment, the present invention is described in further detail.
Embodiment one
Count by weight, component is composed as follows:
Vinylbenzene 10 parts, isoprene 10 parts, divinyl 10 parts, 15 parts, styrene-butadiene rubber(SBR), organic acid neodymium 8 parts, carbon black 10 parts, silicon-dioxide 3 parts, zinc borate 3 parts, promotor 5 parts, antioxidant 264 1 part, antioxidant MB 2 parts.
Organic acid neodymium is a kind of catalyzer, and in the present embodiment, organic acid neodymium is neodymium naphthenate, and certainly, this kind is chosen not as restriction, also can select other organic acid neodymium, as neodymium caprate.
Promotor being can promote the material of sulfuration.The curing time of rubber can be shortened or reduce curing temperature, reducing the physical and mechanical properties etc. of vulcanizing agent consumption and raising rubber.In the present embodiment, promotor is captax.Certainly, also other promotor can be selected, as vulkacit D.
The present embodiment utilizes vinylbenzene, isoprene and divinyl as feed composition, and vinylbenzene, isoprene and butadiene terpolymer are made up of the segment of different glass temperature, and obtained rubber has good grasp property, and the vulcanization rate of sizing material is also very fast.And the organic acid neodymium, styrene-butadiene rubber(SBR) and the vinylbenzene that add, isoprene, divinyl have good synergy, modification can be carried out to it, make three give full play to respective performance, and can carry out good crosslinked.Promotor, antioxidant 264, antioxidant MB have good wear resistance and longer work-ing life, excellent combination property to making the rubber obtained, and practicality is high, suitable for large-scale promotion.
The present embodiment additionally provides and a kind ofly processes the above-mentioned method possessing the waste water of good grasp property electric power rubber, comprises the steps:
A. get engineering composite flora ADB350M bacterial classification and be placed in reaction tank, add deionized water, activate bacterial classification by oxygen increasing pump bubbling aeration, make its ramp breeding at short notice;
B. adding activating strain liquid in MABR system, being circulated to the microbial film that tubular fibre film outer surface apposition growth one deck is complete;
C. waste water is added in reaction tank, pump into MABR system, circulate, circulate pollutent in process in waste water by the microbiological deterioration in microbial film.
Embodiment two
Count by weight, component is composed as follows:
Vinylbenzene 20 parts, isoprene 20 parts, divinyl 20 parts, 25 parts, styrene-butadiene rubber(SBR), organic acid neodymium 15 parts, carbon black 15 parts, silicon-dioxide 7 parts, zinc borate 6 parts, promotor 13 parts, antioxidant 264 5 parts, antioxidant MB 6 parts.
In the present embodiment, organic acid neodymium is neodymium caprate.Promotor is Vulcanization accelerator TMTD.Vulcanization accelerator TMTD is the promotor comparatively commonly used, and is easy to obtain, and facilitation effect is good.
The present embodiment additionally provides and a kind ofly processes the above-mentioned method possessing the waste water of good grasp property electric power rubber, comprises the steps:
A. get engineering composite flora ADB350M bacterial classification and be placed in reaction tank, add deionized water, activate bacterial classification by oxygen increasing pump bubbling aeration, make its ramp breeding at short notice;
B. adding activating strain liquid in MABR system, being circulated to the microbial film that tubular fibre film outer surface apposition growth one deck is complete;
C. waste water is added in reaction tank, pump into MABR system, circulate, circulate pollutent in process in waste water by the microbiological deterioration in microbial film.
Embodiment three
Count by weight, component is composed as follows:
Vinylbenzene 15 parts, isoprene 16 parts, divinyl 15 parts, 18.5 parts, styrene-butadiene rubber(SBR), organic acid neodymium 10 parts, carbon black 12 parts, silicon-dioxide 3.5 parts, zinc borate 5 parts, promotor 8 parts, antioxidant 264 3.5 parts, antioxidant MB 5 parts.
In the present embodiment, organic acid neodymium is neodymium naphthenate, and promotor is Vulcanization accelerator TMTD.
The present embodiment additionally provides and a kind ofly processes the above-mentioned method possessing the waste water of good grasp property electric power rubber, comprises the steps:
A. get engineering composite flora ADB350M bacterial classification and be placed in reaction tank, add deionized water, activate bacterial classification by oxygen increasing pump bubbling aeration, make its ramp breeding at short notice;
B. adding activating strain liquid in MABR system, being circulated to the microbial film that tubular fibre film outer surface apposition growth one deck is complete;
C. waste water is added in reaction tank, pump into MABR system, circulate, circulate pollutent in process in waste water by the microbiological deterioration in microbial film.
The foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, for a person skilled in the art, the present invention can have various modifications and variations.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (5)
1. one kind possesses good grasp property electric power rubber, it is characterized in that: count by weight, component is composed as follows: vinylbenzene 10-20 part, isoprene 10-20 part, divinyl 10-20 part, styrene-butadiene rubber(SBR) 15-25 part, organic acid neodymium 8-15 part, carbon black 10-15 part, silicon-dioxide 3-7 part, zinc borate 3-6 part, promotor 5-13 part, antioxidant 264 1-5 part, antioxidant MB 2-6 part.
2. according to claim 1 possess good grasp property electric power rubber, it is characterized in that: count by weight, component is composed as follows: vinylbenzene 14-17 part, isoprene 14-17 part, divinyl 15-18 part, styrene-butadiene rubber(SBR) 16-20 part, organic acid neodymium 10-12 part, carbon black 11.5-13 part, silicon-dioxide 3-5 part, zinc borate 4.5-5 part, promotor 6-10 part, antioxidant 264 3-4 part, antioxidant MB 4.5-6 part.
3. according to claim 1 possess good grasp property electric power rubber, it is characterized in that: described organic acid neodymium is neodymium naphthenate.
4. according to claim 1 possess good grasp property electric power rubber, it is characterized in that: described promotor is Vulcanization accelerator TMTD.
5. process the method possessing the waste water of good grasp property electric power rubber described in any one of claim 1-4, it is characterized in that, comprise the steps:
A. get engineering composite flora ADB350M bacterial classification and be placed in reaction tank, add deionized water, activate bacterial classification by oxygen increasing pump bubbling aeration, make its ramp breeding at short notice;
B. adding activating strain liquid in MABR system, being circulated to the microbial film that tubular fibre film outer surface apposition growth one deck is complete;
C. waste water is added in reaction tank, pump into MABR system, circulate, circulate pollutent in process in waste water by the microbiological deterioration in microbial film.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511030998.0A CN105504407A (en) | 2015-12-31 | 2015-12-31 | Electric rubber with excellent grapping property and method for treating wastewater of electric rubber |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201511030998.0A CN105504407A (en) | 2015-12-31 | 2015-12-31 | Electric rubber with excellent grapping property and method for treating wastewater of electric rubber |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105504407A true CN105504407A (en) | 2016-04-20 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201511030998.0A Pending CN105504407A (en) | 2015-12-31 | 2015-12-31 | Electric rubber with excellent grapping property and method for treating wastewater of electric rubber |
Country Status (1)
| Country | Link |
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| CN (1) | CN105504407A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914183A (en) * | 2010-09-04 | 2010-12-15 | 大连理工大学 | Styrene/isoprene/butadiene tri-component random copolymer of rare-earth catalysis system and preparation method thereof |
| CN102634086A (en) * | 2012-05-02 | 2012-08-15 | 三角轮胎股份有限公司 | Tread rubber composition for semisteel meridian snow tire used in extremely cold area |
| CN103073755A (en) * | 2012-12-31 | 2013-05-01 | 特拓(青岛)轮胎技术有限公司 | Rubber composition for producing wet-skid resistant tire tread |
| CN103073762A (en) * | 2012-12-31 | 2013-05-01 | 特拓(青岛)轮胎技术有限公司 | Rubber composition technology for tire treads of road traffic series passenger cars |
| CN103965410A (en) * | 2014-04-26 | 2014-08-06 | 大连理工大学 | Method for preparing ABS resin by using Nd-SIBR as flexibilizer and by using in-situ mass method |
-
2015
- 2015-12-31 CN CN201511030998.0A patent/CN105504407A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101914183A (en) * | 2010-09-04 | 2010-12-15 | 大连理工大学 | Styrene/isoprene/butadiene tri-component random copolymer of rare-earth catalysis system and preparation method thereof |
| CN102634086A (en) * | 2012-05-02 | 2012-08-15 | 三角轮胎股份有限公司 | Tread rubber composition for semisteel meridian snow tire used in extremely cold area |
| CN103073755A (en) * | 2012-12-31 | 2013-05-01 | 特拓(青岛)轮胎技术有限公司 | Rubber composition for producing wet-skid resistant tire tread |
| CN103073762A (en) * | 2012-12-31 | 2013-05-01 | 特拓(青岛)轮胎技术有限公司 | Rubber composition technology for tire treads of road traffic series passenger cars |
| CN103965410A (en) * | 2014-04-26 | 2014-08-06 | 大连理工大学 | Method for preparing ABS resin by using Nd-SIBR as flexibilizer and by using in-situ mass method |
Non-Patent Citations (4)
| Title |
|---|
| 张剑: "MABR处理模拟采油废水的研究", 《中国优秀硕士学位论文全文数据库》 * |
| 王妮妮等: "Si69/白炭黑/炭黑补强体系对SIBR胎面胶性能的影响", 《弹性体》 * |
| 陈宏等: "SIBR生胶门尼粘度对胶料性能的影响", 《轮胎工业》 * |
| 陈宏等: "白炭黑对SIBR胶料性能的影响", 《轮胎工业》 * |
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| PB01 | Publication | ||
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Application publication date: 20160420 |