CN105503912A - Novel Zn (II) metal organic framework and synthetic method and application thereof - Google Patents
Novel Zn (II) metal organic framework and synthetic method and application thereof Download PDFInfo
- Publication number
- CN105503912A CN105503912A CN201610004058.2A CN201610004058A CN105503912A CN 105503912 A CN105503912 A CN 105503912A CN 201610004058 A CN201610004058 A CN 201610004058A CN 105503912 A CN105503912 A CN 105503912A
- Authority
- CN
- China
- Prior art keywords
- organic framework
- tetrazole
- biphenyl
- novel
- metallic organic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 title claims abstract description 26
- 238000010189 synthetic method Methods 0.000 title claims abstract description 8
- 239000012621 metal-organic framework Substances 0.000 title abstract description 29
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 239000013078 crystal Substances 0.000 claims abstract description 15
- 150000003751 zinc Chemical class 0.000 claims abstract description 5
- 238000001035 drying Methods 0.000 claims abstract description 4
- 238000000034 method Methods 0.000 claims abstract description 4
- 239000013384 organic framework Substances 0.000 claims description 32
- 239000011701 zinc Substances 0.000 claims description 27
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 8
- 230000015572 biosynthetic process Effects 0.000 claims description 6
- 238000003786 synthesis reaction Methods 0.000 claims description 6
- 239000007788 liquid Substances 0.000 claims description 4
- RKTYLMNFRDHKIL-UHFFFAOYSA-N copper;5,10,15,20-tetraphenylporphyrin-22,24-diide Chemical compound [Cu+2].C1=CC(C(=C2C=CC([N-]2)=C(C=2C=CC=CC=2)C=2C=CC(N=2)=C(C=2C=CC=CC=2)C2=CC=C3[N-]2)C=2C=CC=CC=2)=NC1=C3C1=CC=CC=C1 RKTYLMNFRDHKIL-UHFFFAOYSA-N 0.000 claims description 3
- 125000004433 nitrogen atom Chemical group N* 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 2
- 239000007850 fluorescent dye Substances 0.000 claims description 2
- 238000007789 sealing Methods 0.000 claims description 2
- 238000003756 stirring Methods 0.000 claims description 2
- 239000000725 suspension Substances 0.000 claims description 2
- 229910021645 metal ion Inorganic materials 0.000 claims 2
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 abstract description 5
- 238000001914 filtration Methods 0.000 abstract description 2
- 238000005406 washing Methods 0.000 abstract description 2
- 238000010586 diagram Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 229920000642 polymer Polymers 0.000 description 3
- 239000012453 solvate Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 2
- 238000004020 luminiscence type Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000013110 organic ligand Substances 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000000975 bioactive effect Effects 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000005284 excitation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 229910001428 transition metal ion Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
- C07F3/06—Zinc compounds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/06—Luminescent, e.g. electroluminescent, chemiluminescent materials containing organic luminescent materials
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/62—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light
- G01N21/63—Systems in which the material investigated is excited whereby it emits light or causes a change in wavelength of the incident light optically excited
- G01N21/64—Fluorescence; Phosphorescence
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
- C07B2200/00—Indexing scheme relating to specific properties of organic compounds
- C07B2200/13—Crystalline forms, e.g. polymorphs
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2211/00—Chemical nature of organic luminescent or tenebrescent compounds
- C09K2211/10—Non-macromolecular compounds
- C09K2211/1018—Heterocyclic compounds
- C09K2211/1025—Heterocyclic compounds characterised by ligands
- C09K2211/1074—Heterocyclic compounds characterised by ligands containing more than three nitrogen atoms as heteroatoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Materials Engineering (AREA)
- Nuclear Medicine, Radiotherapy & Molecular Imaging (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
Abstract
The invention relates to a novel Zn (II) metal organic framework and a synthetic method and application thereof. According to the technical scheme, the method comprises the steps that metal zinc salt, 4'-(1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid and N,N-dimethyl formamide are added into a container and stirred at normal temperature; the container is sealed and put into a drying oven for one day at the temperature of 348 K; the container is slowly cooled to the room temperature, and a colorless bulk crystal is obtained; washing, filtering and drying are conducted, and the target product is obtained. The metal organic framework (MOFs) constructed through Zn (II) and 4'-(1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid shows a strong fluorescence property and has a specific recognition function on Mg<2+>.
Description
Technical field
The present invention relates to synthesis and the application thereof of novel Zn (II) metallic organic framework, specifically, relate to a kind of by Zn (II) and 4' – (1H-tetrazole-5)-biphenyl-3, the metallic organic framework (MOFs) that 5-dicarboxylic acid is constructed demonstrates very strong fluorescence property, and to Mg
2+there is specific recognition function.
Background technology
Metallic organic framework (MOFs) ligand polymer is crystal three materials of a class novelty, and in catalysis, gas adsorption, molecular recognition, the fields such as optics are by extensive concern.The multi-function metal organic backbone with character such as luminescence, magnetic, highly porouies receives special concern because can be used as chemical sensor.In recent years, along with the continuous progress of science and technology, fluorescence chemical sensor enjoys people to pay close attention to because of its highly sensitive feature.Fluorescence chemical sensor all has a wide range of applications in the field such as detection and explosive detection of bio-active substance quality detection, ion, molecule.Most metal-organic framework materials is built by transition metal ion bunch, and these systems receive increasing concern at present, is not only because its charming structure, also because he can be applied in different scientific domains.The structure of ligand polymer uniqueness regulates the coordination mode of metal and part to obtain by different structure modules and reaction conditions.Therefore building the metallic organic framework with special construction and function by design, selection organic ligand and metal unit, is the problem of constantly research and development.
Summary of the invention
The object of the invention is to utilize zinc as metal node, utilize 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid as organic ligand, at a certain temperature, utilize the method for solvent thermal to synthesize a kind of 3D ligand polymer.
The technical solution used in the present invention is: novel Zn (II) metallic organic framework, this compound is by Zn (II) and 4' – (1H-tetrazole-5)-biphenyl-3, 5-dicarboxylic acid is constructed, this compound crystal structure belongs to tetragonal system, the Zn Atomic coordinate pattern that two kinds different is had in compound, wherein, the first Zn Atomic coordinate pattern is four-coordination pattern: two Sauerstoffatoms are from 4' – (1H-tetrazole-5)-biphenyl-3, 5-dicarboxylates, a N is from 4' – (1H-tetrazole-5)-biphenyl-3, 5-dicarboxylates, a Sauerstoffatom is from coordination OH
-, the second Zn Atomic coordinate pattern is hexa-coordinate pattern: three nitrogen-atoms are from 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, two Sauerstoffatoms carry out 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, and a Sauerstoffatom is from coordination OH
-.
The synthetic method of above-mentioned novel Zn (II) metallic organic framework, comprises following synthesis step:
1) by metal zinc salt, 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid, DMF adds in container, under normal temperature, stirs; Preferably, described metal zinc salt is Zn (NO
3)
2.
2) put into baking oven by after container sealing, under 343-353, keep 22-28h;
3) progressively cool to room temperature, obtain colourless bulk crystals; Preferably, the described rate of temperature fall progressively cooling to room temperature is 15-20 DEG C of h
-1.
4) wash, filter and drying, obtain target product.
The invention has the beneficial effects as follows: the metal organic frame (MOFs) that the Zn (II) prepared by the present invention and 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid are constructed demonstrates very strong fluorescence property, and to Mg
2+there is specific recognition function.Metal organic frame (MOFs) preparation method that Zn of the present invention (II) and 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid is constructed is simple, and this compound has very large using value in field of fluorescence.
Accompanying drawing explanation
Fig. 1 is the synthesis schematic diagram of novel Zn of the present invention (II) metallic organic framework (MOFs).
Fig. 2 is the XRD figure of novel Zn of the present invention (II) metallic organic framework (MOFs).
Fig. 3 is the coordination mode schematic diagram of novel Zn of the present invention (II) metallic organic framework (MOFs).
Fig. 4 is the three-dimensional structure schematic diagram figure of novel Zn of the present invention (II) metallic organic framework (MOFs).
Fig. 5 is the fluorescent liquid utilizing emitted light spectrogram of novel Zn of the present invention (II) metallic organic framework (MOFs).
Fig. 6 is methyl alcohol suspension liquid fluorescence intensity figure under different metal of novel Zn of the present invention (II) metallic organic framework (MOFs).
Embodiment
Embodiment 1Zn (II) metallic organic framework (MOFs)
By the Zn (NO of 0.25mmol
3)
2, 4' – (1H-tetrazole-5)-biphenyl-3, the 5-dicarboxylic acid of 0.05mmol, 1mlN, dinethylformamide adds in the vial of 5ml.Vial good seal is put into baking oven.Heating makes the temperature of baking oven reach 348K, and is incubated 24 hours under maintaining the temperature at this condition.With 15-20 DEG C of h
-1rate of temperature fall progressively cool to room temperature, obtain colourless bulk crystals; Washing, filtration are also dry, and be target product Zn (II) metallic organic framework (MOFs), productive rate is 65%.
As shown in Figure 2, in figure, i is the crystal powder diffractogram of simulation to the XRD of Zn (II) metallic organic framework of the present invention's synthesis, and ii is the powder diagram that composite crystals is surveyed.
As shown in Figure 3 and Figure 4, this crystalline structure belongs to tetragonal system to the structure of Zn (II) metallic organic framework of the present invention's synthesis.Molecular formula is: { [Zn
2(L)
3.5(OH)
2] (DMF)
3(H
2o)
2}
n(L is 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates).The Zn Atomic coordinate pattern that two kinds different is had in this compound.Zn1 is four-coordination pattern, and two Sauerstoffatoms are from 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, and a N is from 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, and a Sauerstoffatom is from coordination OH
-; Zn2 is hexa-coordinate pattern, and three nitrogen-atoms are from 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, and two Sauerstoffatoms carry out 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, and a Sauerstoffatom is from coordination OH
-.
The luminescence of (MOFs) of embodiment 2Zn (II) metallic organic framework
Method: (MOFs) of Zn (II) metallic organic framework prepared with embodiment 1 carries out luminescent properties experiment.
1) crystal getting (MOFs) of Zn (II) metallic organic framework is dissolved in methanol solvate, and obtaining Zn (II) metallic organic framework (MOFs) concentration is 1 × 10
-4the mixing solutions of M is 305nm with excitation wavelength, and record the fluorescence emission spectrogram (as shown in Figure 5) of crystal, emission peak is 560nm.Fig. 5 is the fluorescent liquid utilizing emitted light spectrogram of the metal organic frame (MOFs) that Zn (II) and 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid is constructed.
2) crystal getting Zn (II) metallic organic framework (MOFs) is dissolved in methanol solvate, and obtaining Zn (II) metallic organic framework (MOFs) concentration is 1 × 10
-4the mixing solutions of M.
Get mixing solutions 5ml respectively, adding 25ul concentration is respectively 1 × 10
-4the Ag of M
+, Zn
2+, Al
3+, Bi
3+, Cd
2+, Ce
3+, Co
2+, Cr
3+, Cu
2+, Fe
3+, Hg
2+, In
3+, Mg
2+, Na
+, Ni
2+, Pb
2+methanol solution, do blank (blank) simultaneously.Take wavelength as 305nm light be exciting light, detect the change of the fluorescence intensity of Zn (II) metallic organic framework (MOFs) crystal in mixing solutions with fluorophotometer.
As shown in Figure 6, as seen from Figure 6, in collection of illustrative plates, there is the emmission spectrum that Zn (II) metallic organic framework (MOFs) is characteristic emission wavelength in result.Illustrate that the metal organic frame (MOFs) that Zn of the present invention (II) and 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid is constructed has very strong fluorescence property at normal temperatures.As seen from Figure 6, the crystal of metal organic frame (MOFs) constructed of Zn (II) and 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid is at Mg
2+in methanol solvate, fluorescence is the strongest.This illustrates that the crystal of the metal organic frame (MOFs) that one of the present invention is constructed by Zn (II) and 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid can be used as fluorescent probe and detects Mg
2+.
Claims (8)
1. novel Zn (II) metallic organic framework, it is characterized in that: this compound is by Zn (II) and 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid is constructed, this compound crystal structure belongs to tetragonal system, the Zn Atomic coordinate pattern that two kinds different is had in compound, wherein, the first Zn Atomic coordinate pattern is four-coordination pattern: two Sauerstoffatoms are from 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, a N is from 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, a Sauerstoffatom is from coordination OH
-; The second Zn Atomic coordinate pattern is hexa-coordinate pattern: three nitrogen-atoms are from 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, two Sauerstoffatoms carry out 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylates, and a Sauerstoffatom is from coordination OH
-.
2. the synthetic method of novel Zn according to claim 1 (II) metallic organic framework, is characterized in that comprising following synthesis step:
1) by metal zinc salt, 4' – (1H-tetrazole-5)-biphenyl-3,5-dicarboxylic acid, DMF adds in container, under normal temperature, stirs;
2) put into baking oven by after container sealing, under 343-353, keep 22-28h;
3) progressively cool to room temperature, obtain colourless bulk crystals;
4) wash, filter and drying, obtain target product.
3. the synthetic method of novel Zn according to claim 2 (II) metallic organic framework, is characterized in that, described metal zinc salt is Zn (NO
3)
2.
4. the synthetic method of novel Zn according to claim 3 (II) metallic organic framework, is characterized in that: by the Zn (NO of 0.25mmol
3)
2, 4' – (1H-tetrazole-5)-biphenyl-3, the 5-dicarboxylic acid of 0.05mmol, 1mlN, dinethylformamide adds in container.
5. the synthetic method of novel Zn (II) metallic organic framework according to claim 2,3 or 4, is characterized in that: the described rate of temperature fall progressively cooling to room temperature is 15-20 DEG C of h
-1.
6. the application of novel Zn according to claim 1 (II) metallic organic framework in fluorescent probe field.
7. application according to claim 6, it is characterized in that method is as follows: novel Zn according to claim 1 (II) metallic organic framework is mixed with methyl alcohol suspension liquid, the methanol solution of dropping metal ion take wavelength as 305nm light is exciting light, carries out fluoroscopic examination.
8. application according to claim 7, is characterized in that: described metal ion is Mg
2+.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610004058.2A CN105503912B (en) | 2016-01-04 | 2016-01-04 | A kind of new Zn (II) metal organic frameworks and its synthetic method and application |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610004058.2A CN105503912B (en) | 2016-01-04 | 2016-01-04 | A kind of new Zn (II) metal organic frameworks and its synthetic method and application |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN105503912A true CN105503912A (en) | 2016-04-20 |
| CN105503912B CN105503912B (en) | 2017-08-29 |
Family
ID=55712270
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610004058.2A Active CN105503912B (en) | 2016-01-04 | 2016-01-04 | A kind of new Zn (II) metal organic frameworks and its synthetic method and application |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105503912B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106699817A (en) * | 2016-12-29 | 2017-05-24 | 西北大学 | Preparation method and application of metal-organic framework material |
| CN106749348A (en) * | 2016-11-22 | 2017-05-31 | 南开大学 | A kind of metal-organic framework material and preparation method and application |
| CN106824100A (en) * | 2017-03-14 | 2017-06-13 | 山西师范大学 | A kind of zinc MOF poromerics of efficient capture iodine and preparation method and application |
| CN108314628A (en) * | 2018-01-11 | 2018-07-24 | 安徽理工大学 | A kind of magnesium metal organic complex and preparation method thereof |
| CN108384027A (en) * | 2018-05-07 | 2018-08-10 | 江西省科学院应用化学研究所 | A kind of zinc-organic frame and preparation method with acetylacetone,2,4-pentanedione fluorescence response |
| CN108587607A (en) * | 2018-05-18 | 2018-09-28 | 陕西科技大学 | The luminescent metal organic framework material and its preparation method and application detected for Thiocyanate ion in water |
| CN108864157A (en) * | 2018-08-14 | 2018-11-23 | 江苏科技大学 | A kind of fluorescent probe molecule and the preparation method and application thereof for metal ion detection |
| CN110776523A (en) * | 2018-07-30 | 2020-02-11 | 天津师范大学 | Ultra-stable three-dimensional luminous zinc (II) metal organic framework material and preparation method and application thereof |
| CN110818907A (en) * | 2018-11-26 | 2020-02-21 | 河北民族师范学院 | Zinc coordination polymer containing polycarboxylic acid and multi-nitrogen dual ligand and preparation method thereof |
| CN110853939A (en) * | 2019-10-24 | 2020-02-28 | 李建龙 | Based on biological charcoal cladding [ Zn ]4O(BDBC)3]8Super capacitor material and its making method |
| CN113683781A (en) * | 2020-05-18 | 2021-11-23 | 天津师范大学 | Zinc coordination polymer, synthesis method thereof and application thereof in kanamycin detection |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090143596A1 (en) * | 2007-11-15 | 2009-06-04 | University Of South Florida | Supramolecular Assemblies and Building Blocks |
| CN101560218A (en) * | 2008-04-18 | 2009-10-21 | 中国科学院福建物质结构研究所 | Organometallic complex of nonlinear optical and ferroelectric material, synthesis and application thereof |
| CN101830918A (en) * | 2010-04-30 | 2010-09-15 | 中山大学 | Synthetic method of polynitrogen azole zinc/cadmium framework material |
-
2016
- 2016-01-04 CN CN201610004058.2A patent/CN105503912B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20090143596A1 (en) * | 2007-11-15 | 2009-06-04 | University Of South Florida | Supramolecular Assemblies and Building Blocks |
| CN101560218A (en) * | 2008-04-18 | 2009-10-21 | 中国科学院福建物质结构研究所 | Organometallic complex of nonlinear optical and ferroelectric material, synthesis and application thereof |
| CN101830918A (en) * | 2010-04-30 | 2010-09-15 | 中山大学 | Synthetic method of polynitrogen azole zinc/cadmium framework material |
Non-Patent Citations (1)
| Title |
|---|
| XIAOFANGWANG ET AL.: "Constructing two new crystalline metal–organic frameworks based on a mixed-donor ligand", 《INORGANIC CHEMISTRY COMMUNICATIONS》 * |
Cited By (17)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106749348B (en) * | 2016-11-22 | 2018-10-30 | 南开大学 | A kind of metal-organic framework material and preparation method and application |
| CN106749348A (en) * | 2016-11-22 | 2017-05-31 | 南开大学 | A kind of metal-organic framework material and preparation method and application |
| CN106699817A (en) * | 2016-12-29 | 2017-05-24 | 西北大学 | Preparation method and application of metal-organic framework material |
| CN106699817B (en) * | 2016-12-29 | 2019-03-15 | 西北大学 | A kind of preparation method and applications of metal-organic framework material |
| CN106824100A (en) * | 2017-03-14 | 2017-06-13 | 山西师范大学 | A kind of zinc MOF poromerics of efficient capture iodine and preparation method and application |
| CN108314628A (en) * | 2018-01-11 | 2018-07-24 | 安徽理工大学 | A kind of magnesium metal organic complex and preparation method thereof |
| CN108384027A (en) * | 2018-05-07 | 2018-08-10 | 江西省科学院应用化学研究所 | A kind of zinc-organic frame and preparation method with acetylacetone,2,4-pentanedione fluorescence response |
| CN108384027B (en) * | 2018-05-07 | 2021-03-26 | 江西省科学院应用化学研究所 | Zinc-organic framework with acetylacetone fluorescent response and preparation method thereof |
| CN108587607A (en) * | 2018-05-18 | 2018-09-28 | 陕西科技大学 | The luminescent metal organic framework material and its preparation method and application detected for Thiocyanate ion in water |
| CN108587607B (en) * | 2018-05-18 | 2020-10-27 | 陕西科技大学 | Luminescent metal organic framework material for detecting thiocyanate ions in water and preparation method and application thereof |
| CN110776523A (en) * | 2018-07-30 | 2020-02-11 | 天津师范大学 | Ultra-stable three-dimensional luminous zinc (II) metal organic framework material and preparation method and application thereof |
| CN110776523B (en) * | 2018-07-30 | 2022-04-29 | 天津师范大学 | Ultra-stable three-dimensional luminous zinc (II) metal organic framework material and preparation method and application thereof |
| CN108864157A (en) * | 2018-08-14 | 2018-11-23 | 江苏科技大学 | A kind of fluorescent probe molecule and the preparation method and application thereof for metal ion detection |
| CN110818907A (en) * | 2018-11-26 | 2020-02-21 | 河北民族师范学院 | Zinc coordination polymer containing polycarboxylic acid and multi-nitrogen dual ligand and preparation method thereof |
| CN110818907B (en) * | 2018-11-26 | 2021-10-01 | 河北民族师范学院 | Zinc coordination polymer containing polycarboxylic acid and multi-nitrogen dual ligand and preparation method thereof |
| CN110853939A (en) * | 2019-10-24 | 2020-02-28 | 李建龙 | Based on biological charcoal cladding [ Zn ]4O(BDBC)3]8Super capacitor material and its making method |
| CN113683781A (en) * | 2020-05-18 | 2021-11-23 | 天津师范大学 | Zinc coordination polymer, synthesis method thereof and application thereof in kanamycin detection |
Also Published As
| Publication number | Publication date |
|---|---|
| CN105503912B (en) | 2017-08-29 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105503912A (en) | Novel Zn (II) metal organic framework and synthetic method and application thereof | |
| CN103242352B (en) | A kind of luminescent metal organic framework materials with chemical sensitisation function and its preparation method and application | |
| Han et al. | Highly chemical and thermally stable luminescent Eu x Tb 1− x MOF materials for broad-range pH and temperature sensors | |
| Hou et al. | A novel family of 3D photoluminescent lanthanide–bta–flexible MOFs constructed from 1, 2, 4, 5-benzenetetracarboxylic acid and different spanning of dicarboxylate acid ligands | |
| Wu et al. | A series of Mg–Zn heterometallic coordination polymers: Synthesis, characterization, and fluorescence sensing for Fe 3+, CS 2, and nitroaromatic compounds | |
| Sun et al. | A highly stable 8-hydroxyquinolinate-based metal–organic framework as a selective fluorescence sensor for Fe 3+, Cr 2 O 7 2− and nitroaromatic explosives | |
| CN101787043B (en) | Novel light-emitting transition metal organic framework structured compound and preparation method thereof | |
| Calahorro et al. | Luminescence and magnetic properties of three metal–organic frameworks based on the 5-(1H-tetrazol-5-yl) isophthalic acid ligand | |
| Liu et al. | A series of lanthanide (III) coordination polymers derived via in situ hydrothermal decarboxylation of quinoline-2, 3-dicarboxylic acid | |
| CN105732679A (en) | Preparation method and application of organic trinuclear rare-earth metal skeleton material | |
| CN108409758A (en) | Crystalline material containing binuclear rare earth cluster compound and preparation method and application thereof | |
| Xiao et al. | A smart sensing triazine hexacarboxylic metal–organic skeleton material: synthesis, structure and multifunctional fluorescence detector | |
| CN108558917B (en) | Zinc-furandicarboxylic acid organic framework material and preparation method thereof | |
| You et al. | Synthesis, structure and luminescence of lanthanide coordination polymers based on the 1, 3-Bis (carboxymethyl) imidazolium salt | |
| CN113402727A (en) | Terbium (III) loaded zinc-based metal organic framework and preparation and application thereof | |
| CN114133581B (en) | Mg-MOFs, preparation method thereof and application thereof in iron ion detection | |
| Li et al. | Four isostructural lanthanide coordination polymers based on rare coordinated citric acid: Syntheses, structures, magnetisms and luminescence | |
| Arıcı et al. | Cobalt (II) and zinc (II)-coordination polymers constructed from ether-linked tetracarboxylic acid and isomeric bis (imidazole) linkers: luminescence-based Fe (III) detection in aqueous media | |
| CN101781323B (en) | Luminous transition metal organic skeleton structure compound and preparation method thereof | |
| Liu et al. | Construction of high quantum yield lanthanide luminescent MOF platform by in situ doping and its temperature sensing performance | |
| Chatenever et al. | Structural diversity of four lanthanide metal–organic frameworks based on 2, 6-naphthalenedicarboxylate: synthesis, structures and photoluminescent properties | |
| CN105713024A (en) | Zn<II>-based metal-organic framework and preparation method and application thereof | |
| Yin et al. | Synthesis, structure and luminescence properties of metal-organic frameworks based on benzo-bis (imidazole) | |
| Xie et al. | Controllable synthesis of isoreticular pillared-layer MOFs based on N-rich triangular prism building units: gas adsorption and luminescent properties | |
| CN106749355B (en) | A kind of binary rare-earth organic frame crystalline material, its synthetic method and application |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant | ||
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20201202 Address after: 241100 8 / F, building 5, Wuhu TONGHANG Innovation Park, Wanbi Town, Wuhu City, Anhui Province Patentee after: Wuhu Digital Information Industrial Park Co., Ltd Address before: 110000, Liaoning, Shenyang, Shenbei New Area moral South Avenue No. 58 Patentee before: LIAONING University |