CN105483666A - Preparing method of titanium salt surface conditioning agent - Google Patents

Preparing method of titanium salt surface conditioning agent Download PDF

Info

Publication number
CN105483666A
CN105483666A CN201510937019.3A CN201510937019A CN105483666A CN 105483666 A CN105483666 A CN 105483666A CN 201510937019 A CN201510937019 A CN 201510937019A CN 105483666 A CN105483666 A CN 105483666A
Authority
CN
China
Prior art keywords
mass parts
sodium
powder
parts
water content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510937019.3A
Other languages
Chinese (zh)
Inventor
钱文华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Changshu Yudong Phosphide Material Co Ltd
Original Assignee
Changshu Yudong Phosphide Material Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Changshu Yudong Phosphide Material Co Ltd filed Critical Changshu Yudong Phosphide Material Co Ltd
Priority to CN201510937019.3A priority Critical patent/CN105483666A/en
Publication of CN105483666A publication Critical patent/CN105483666A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/23—Condensed phosphates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20—Use of solutions containing silanes

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)

Abstract

The invention discloses a preparing method of a titanium salt surface conditioning agent. The preparing method comprises the following steps that firstly, 30 parts of anhydrous disodium hydrogen phosphate is prepared into a water solution with the concentration of 50%; secondly, 1-2 parts of sodium pyrophosphate, 0.8 part of titanyl sulfate, 3.5 parts of sodium pyrophosphate, 2.1 parts of sodium bicarbonate, 1.8 parts of sodium tetraborate, 3.6 parts of sodium hexametaphosphate, 0.3 part of polycarboxylic acid anion organic matter and 0.3 part of N-butyl naphthalene sulfonate are sequentially added in the water solution of disodium hydrogen phosphate, and a mixed solution is obtained; thirdly, the mixed solution is heated to 70 DEG C and fully stirred, and white powder with the water content below 2% is obtained; and fourthly, powder continues to be stirred at the temperature of 75 DEG C, 2.7 parts of sodium pyrophosphate, 1.2 parts of acetic acid, 0.7 part of methyltrimethoxysilane and 3.3 parts of magnesium sulfate are added into the powder at the same time, stirring continues, and drying is carried out till the water content is smaller than 1%. The prepared surface conditioning agent is good in scattering stability and can be stored for a long term.

Description

The preparation method of titanium salt surface conditioner
Technical field
The present invention relates to the preparation method of titanium salt surface conditioner.
Background technology
The dispersion stabilization of existing surface conditioner has much room for improvement, and can not preserve for a long time.
Summary of the invention
The object of the present invention is to provide a kind of preparation method of titanium salt surface conditioner, its surface conditioner dispersion stabilization prepared is excellent, can preserve for a long time.
For achieving the above object, technical scheme of the present invention designs a kind of preparation method of titanium salt surface conditioner, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 1 ~ 2 mass parts trisodium phosphate, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
Preferably, the preparation method of titanium salt surface conditioner, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 1 mass parts trisodium phosphate, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
Preferably, the preparation method of titanium salt surface conditioner, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 2 mass parts trisodium phosphates, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
Advantage of the present invention and beneficial effect are: the preparation method providing a kind of titanium salt surface conditioner, and its surface conditioner dispersion stabilization prepared is excellent, can preserve for a long time.
Embodiment
Below in conjunction with embodiment, the specific embodiment of the present invention is further described.Following examples only for technical scheme of the present invention is clearly described, and can not limit the scope of the invention with this.
The technical scheme that the present invention specifically implements is:
Embodiment 1
A preparation method for titanium salt surface conditioner, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 1 ~ 2 mass parts trisodium phosphate, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
Embodiment 2
The preparation method of titanium salt surface conditioner, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 1 mass parts trisodium phosphate, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
Embodiment 3
The preparation method of titanium salt surface conditioner, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 2 mass parts trisodium phosphates, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, under the prerequisite not departing from the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.

Claims (3)

1. the preparation method of titanium salt surface conditioner, is characterized in that, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 1 ~ 2 mass parts trisodium phosphate, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
2. the preparation method of titanium salt surface conditioner according to claim 1, is characterized in that, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 1 mass parts trisodium phosphate, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
3. the preparation method of titanium salt surface conditioner according to claim 1, is characterized in that, comprises the steps to comprise the steps:
1) the light disodium of 30 mass parts anhydrous phosphoric acid is made the aqueous solution that concentration is 50%;
2) 2 mass parts trisodium phosphates, 0.8 mass parts titanyl sulfate, 3.5 mass parts trisodium phosphates, 2.1 mass parts sodium bicarbonates, 1.8 mass parts sodium tetraborates, 3.6 mass parts Sodium hexametaphosphate 99s, 0.3 mass parts poly carboxylic acid negatively charged ion there are is organism, 0.3 mass parts normal-butyl sodium naphthalene sulfonate joins in the aqueous solution of Sodium phosphate dibasic successively, obtain mixed solution;
3) mixed solution be heated to 70 DEG C and fully stir, obtaining the white powder of water content less than 2%;
4) continue to stir powder at 75 DEG C, simultaneously in powder, add 2.7 mass parts trisodium phosphates, 1.2 mass parts acetic acid, 0.7 mass parts methyltrimethoxy silane, 3.3 mass parts magnesium sulfate, then continue stirring and be dried to water content and be less than 1%.
CN201510937019.3A 2015-12-14 2015-12-14 Preparing method of titanium salt surface conditioning agent Pending CN105483666A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510937019.3A CN105483666A (en) 2015-12-14 2015-12-14 Preparing method of titanium salt surface conditioning agent

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510937019.3A CN105483666A (en) 2015-12-14 2015-12-14 Preparing method of titanium salt surface conditioning agent

Publications (1)

Publication Number Publication Date
CN105483666A true CN105483666A (en) 2016-04-13

Family

ID=55670924

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510937019.3A Pending CN105483666A (en) 2015-12-14 2015-12-14 Preparing method of titanium salt surface conditioning agent

Country Status (1)

Country Link
CN (1) CN105483666A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190144688A1 (en) * 2016-05-10 2019-05-16 Hoden Seimitsu Kako Kenkyusyo Co., Ltd. Aqueous anti-rust surface treatment composition and surface-coated metal member

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974743A (en) * 2010-10-27 2011-02-16 大连三达奥克化学股份有限公司 Ti-Mg-B surface conditioner for zinc-phosphating and preparation method thereof

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101974743A (en) * 2010-10-27 2011-02-16 大连三达奥克化学股份有限公司 Ti-Mg-B surface conditioner for zinc-phosphating and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20190144688A1 (en) * 2016-05-10 2019-05-16 Hoden Seimitsu Kako Kenkyusyo Co., Ltd. Aqueous anti-rust surface treatment composition and surface-coated metal member
EP3456862A4 (en) * 2016-05-10 2020-01-08 Hoden Seimitsu Kako Kenkyusho Co., Ltd. Aqueous anti-rust surface treatment composition and surface-coated metal member
US10907053B2 (en) 2016-05-10 2021-02-02 Hoden Seimitsu Kako Kenkyusyo Co., Ltd. Aqueous anti-rust surface treatment composition and surface-coated metal member
TWI732867B (en) * 2016-05-10 2021-07-11 日商放電精密加工研究所股份有限公司 Aqueous rust preventive surface treatment composition and surface coated metal member

Similar Documents

Publication Publication Date Title
CN104452292A (en) Finishing process of silk-like fabric
CN107558175B (en) A kind of preparation method of glass/zinc oxide
CN104478704A (en) Preparation method of anhydrous trisodium citrate
CN105483666A (en) Preparing method of titanium salt surface conditioning agent
CN105483687A (en) Preparing method of surface conditioning agent for manganese series phosphatizing
CN104445297A (en) Preparation method of nanometer magnesia
CN105369233A (en) Preparation method for metal surface regulator
CN105463441A (en) Preparing method for manganese series phosphatisation surface conditioning agent
CN105483665A (en) Preparing method of surface conditioning agent
CN104556179A (en) Method for producing cryolite from fluorine-containing waste gas
CN105525280A (en) Processing method of phosphorization materials
CN104292345A (en) Method for preparing starch phosphate by using sodium tripolyphosphate
CN104562031A (en) Pre-filming composition and pre-filming method
CN105296991A (en) Electric flat car
CN104027838B (en) The bone cement that the sodium citrate of fast solidification and using carboxyl chitosan strengthen and preparation method
CN100433976C (en) Hydrothermal synthesis process of nanometer selenium/bamboo charcoal preservative
CN105483679A (en) Preparing method for phosphatizing material
CN105506603A (en) Preparation method for stamping part
CN104187048A (en) A pig feed additive used for resisting mildew
JP2014137599A5 (en)
CN103183507A (en) Preparation method of biphase calcium phosphate ceramic containing beta-calcium pyrophosphate
CN105369240A (en) Production technology of stainless steel shell stamping parts
CN105369607A (en) Preparation method of ultrahigh strength polyethylene fiber
CN104304680A (en) L-ascorbic acid-2-phosphate compound and preparation method and application thereof
CN105419650A (en) Production process of brightener

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160413