CN105481173B - The processing system of carbamazepine in a kind of removal waste water - Google Patents
The processing system of carbamazepine in a kind of removal waste water Download PDFInfo
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- CN105481173B CN105481173B CN201510966192.6A CN201510966192A CN105481173B CN 105481173 B CN105481173 B CN 105481173B CN 201510966192 A CN201510966192 A CN 201510966192A CN 105481173 B CN105481173 B CN 105481173B
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- China
- Prior art keywords
- electrion
- waste water
- carbamazepine
- biopolymerization
- water
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- 239000002351 wastewater Substances 0.000 title claims abstract description 31
- FFGPTBGBLSHEPO-UHFFFAOYSA-N carbamazepine Chemical compound C1=CC2=CC=CC=C2N(C(=O)N)C2=CC=CC=C21 FFGPTBGBLSHEPO-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 229960000623 carbamazepine Drugs 0.000 title claims abstract description 27
- 229920001220 nitrocellulos Polymers 0.000 claims abstract description 46
- 229910052703 rhodium Inorganic materials 0.000 claims abstract description 37
- 239000010948 rhodium Substances 0.000 claims abstract description 37
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 claims abstract description 37
- 238000006555 catalytic reaction Methods 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 27
- 230000014621 translational initiation Effects 0.000 claims abstract description 26
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 24
- 239000008187 granular material Substances 0.000 claims abstract description 19
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 claims abstract description 18
- 238000001035 drying Methods 0.000 claims abstract description 18
- 239000000020 Nitrocellulose Substances 0.000 claims abstract description 14
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 claims abstract description 14
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 12
- 230000015572 biosynthetic process Effects 0.000 claims abstract description 12
- 125000003963 dichloro group Chemical group Cl* 0.000 claims abstract description 12
- 230000000694 effects Effects 0.000 claims abstract description 12
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 10
- 230000001105 regulatory effect Effects 0.000 claims abstract description 10
- 235000013877 carbamide Nutrition 0.000 claims abstract description 9
- 150000003672 ureas Chemical class 0.000 claims abstract description 9
- 239000000126 substance Substances 0.000 claims abstract description 8
- 230000005284 excitation Effects 0.000 claims abstract description 5
- 238000004064 recycling Methods 0.000 claims abstract description 4
- 239000002699 waste material Substances 0.000 claims description 20
- 210000005056 cell body Anatomy 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 9
- 241000588621 Moraxella Species 0.000 claims description 7
- 241000221523 Rhodotorula toruloides Species 0.000 claims description 7
- 241000194017 Streptococcus Species 0.000 claims description 7
- 238000007599 discharging Methods 0.000 claims description 7
- 239000003054 catalyst Substances 0.000 claims description 4
- 125000004122 cyclic group Chemical group 0.000 claims description 4
- 230000004071 biological effect Effects 0.000 claims description 3
- 239000000919 ceramic Substances 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 239000000945 filler Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000000746 purification Methods 0.000 claims description 3
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 claims description 3
- 229910010271 silicon carbide Inorganic materials 0.000 claims description 3
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 claims description 2
- 230000018044 dehydration Effects 0.000 claims description 2
- 238000006297 dehydration reaction Methods 0.000 claims description 2
- 239000012530 fluid Substances 0.000 claims description 2
- 230000008676 import Effects 0.000 claims description 2
- -1 is white fibrous Chemical compound 0.000 claims description 2
- 229910017604 nitric acid Inorganic materials 0.000 claims description 2
- 229920000642 polymer Polymers 0.000 claims description 2
- 238000007493 shaping process Methods 0.000 claims description 2
- 125000003368 amide group Chemical group 0.000 claims 1
- 230000005611 electricity Effects 0.000 claims 1
- 238000009413 insulation Methods 0.000 claims 1
- 229920000620 organic polymer Polymers 0.000 claims 1
- 150000001412 amines Chemical class 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 238000005516 engineering process Methods 0.000 abstract description 3
- 230000002906 microbiologic effect Effects 0.000 abstract description 2
- 229920000742 Cotton Polymers 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000011241 protective layer Substances 0.000 description 3
- 238000010586 diagram Methods 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 239000002685 polymerization catalyst Substances 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 229920002160 Celluloid Polymers 0.000 description 1
- 229910004679 ONO2 Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- NWPJLRSCSQHPJV-UHFFFAOYSA-N carpipramine Chemical compound C1CN(CCCN2C3=CC=CC=C3CCC3=CC=CC=C32)CCC1(C(=O)N)N1CCCCC1 NWPJLRSCSQHPJV-UHFFFAOYSA-N 0.000 description 1
- 229960000700 carpipramine Drugs 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 230000001037 epileptic effect Effects 0.000 description 1
- 230000032050 esterification Effects 0.000 description 1
- 238000005886 esterification reaction Methods 0.000 description 1
- 210000003608 fece Anatomy 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000002207 metabolite Substances 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000013618 particulate matter Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- DPJRMOMPQZCRJU-UHFFFAOYSA-M thiamine hydrochloride Chemical compound Cl.[Cl-].CC1=C(CCO)SC=[N+]1CC1=CN=C(C)N=C1N DPJRMOMPQZCRJU-UHFFFAOYSA-M 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
- 206010044652 trigeminal neuralgia Diseases 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D223/00—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom
- C07D223/14—Heterocyclic compounds containing seven-membered rings having one nitrogen atom as the only ring hetero atom condensed with carbocyclic rings or ring systems
- C07D223/18—Dibenzazepines; Hydrogenated dibenzazepines
- C07D223/22—Dibenz [b, f] azepines; Hydrogenated dibenz [b, f] azepines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08B—POLYSACCHARIDES; DERIVATIVES THEREOF
- C08B5/00—Preparation of cellulose esters of inorganic acids, e.g. phosphates
- C08B5/02—Cellulose nitrate, i.e. nitrocellulose
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/4608—Treatment of water, waste water, or sewage by electrochemical methods using electrical discharges
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/46—Treatment of water, waste water, or sewage by electrochemical methods
- C02F1/461—Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/66—Treatment of water, waste water, or sewage by neutralisation; pH adjustment
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/343—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the pharmaceutical industry, e.g. containing antibiotics
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2201/00—Apparatus for treatment of water, waste water or sewage
- C02F2201/002—Construction details of the apparatus
- C02F2201/007—Modular design
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2301/00—General aspects of water treatment
- C02F2301/08—Multistage treatments, e.g. repetition of the same process step under different conditions
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F3/00—Biological treatment of water, waste water, or sewage
- C02F3/34—Biological treatment of water, waste water, or sewage characterised by the microorganisms used
- C02F3/347—Use of yeasts or fungi
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- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Biochemistry (AREA)
- Hydrology & Water Resources (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Water Treatment By Electricity Or Magnetism (AREA)
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Removal Of Specific Substances (AREA)
Abstract
The invention discloses a kind of processing system for removing carbamazepine in waste water, including the organic rhodium catalysis polymerization reaction trough of pH regulating reservoirs, coarse rack, inclined-plate clarifying basin, biopolymerization reactor, electrion, water purifying tank, weak nitrocotton drying formation system etc..The system it is creative employ physical means, the technology path that chemical method is combined with microbiological treatment, pass through the direct effect of energy effect and polymerization catalyzed effect, high-energy is by N caused by high-voltage arc, N dialkyl ureas absorbs, the chemical bond of amine root and carbonyl therein is played pendulum by energy excitation, and key occurs under the surface catalysis of the rhodium of four carbonyl of dichloro two and is broken and recombinates, it is final that polymerisation generation cellulose nitrate granule thing occurs（Weak nitrocotton）, it is achieved thereby that the recycling of nitrogen resource.
Description
Technical field
The present invention relates to a kind of processing system for removing carbamazepine in waste water, the wastewater treatment neck belonged in environmental protection
Domain.
Background technology
Carbamazepine (also known as carbadipimidine) is a kind of clinical conventional spirituality medicine, and its frequent and other drugs is together
Using treating epileptics, depression and trigeminal neuralgia etc..Patient takes rear portion denominator body and its metabolite with excreta
Into in water body environment.Therefore, the parent of carbamazepine and metabolin are often detected in sewage.The change of carbamazepine
Scientific name claims to be 5H- dibenzo【b,f】Azatropylidene -5- formamides, it is nitrogenous aromatic compound, chemical constitution is complicated, simultaneously
Its concentration in waste water is very low, and existing sewage water treatment method is very difficult to the carbamazepine except low concentration.
But if the carbamazepine remained in waste water and environment can not be efficiently removed, then to human health, there is height
The potential threat of risk.Therefore a kind of processing system and method that can effectively remove carbamazepine in waste water is continued.
The content of the invention
To solve the deficiencies in the prior art, the present invention provides a kind of processing system for removing carbamazepine in waste water
System, the system include the organic rhodium catalysis polymerization of pH regulating reservoirs, coarse rack, inclined-plate clarifying basin, biopolymerization reactor, electrion
Reactive tank, water purifying tank, weak nitrocotton drying formation system etc.；Wherein the waste water containing carbamazepine is adjusted by waste line into pH
The import in pond is saved, the outlet of pH regulating reservoirs connects coarse rack by waste line, and the outlet of coarse rack is connected by waste line
Inclined-plate clarifying basin, the outlet of inclined-plate clarifying basin connect biopolymerization reactor by waste line, biopolymerization reactor it is upper
Portion's leakage fluid dram connects the organic rhodium catalysis polymerization reaction trough of electrion by waste line, and the organic rhodium catalysis polymerization of electrion is anti-
The outlet of groove is answered to connect water purifying tank by waste line, water purifying tank is exported after the system is handled by waste line
Purify and arranged outside water outlet, meanwhile, the nitrocellulose generated in the organic rhodium catalysis polymerization reaction trough of electrion is arranged by particulate matter
Mouth discharge is put, and enters weak nitrocotton drying formation system, drying dehydration and compressing weak nitrocotton obtained and can be recovered
Utilize；Wherein, biopolymerization inside reactor secures multiple biopolymerization films, and high activity circle rhodosporidium toruloides are attached with film
Bacterium and Moraxella streptococcus etc., when waste water contacts into biopolymerization reactor with biopolymerization film, Rhodosporidium toruloides
The cyclic structure in carbamazepine molecule can be opened during biological activity with Moraxella streptococcus and make intermolecular generation
Polymerisation, it is N to form repeat unit, the larger molecular organicses of N- dialkyl ureas；Wherein, the organic rhodium catalysis polymerization of electrion
The outer surface of reactive tank is enclosed with cell body insulating protective layer, and inside is silicon carbide ceramics structure, the upper right quarter of reactive tank be provided with into
Penstock, lower left quarter are provided with flowing water Valve, and cell body middle body is provided with the rhodium porous aggregate of four carbonyl of dichloro two, anti-as polymerization
Catalyst is answered, packing layer bottom is connected with multiple granular material discharged mouths, and arranged on left and right sides wallboard center is respectively provided with a height and pressed
Electrode, one stirrer paddle is respectively housed in reaction tank bottom arranged on left and right sides, the waste water by biopolymerization reactor for treatment leads to
The inlet valve for crossing the organic rhodium catalysis polymerization reaction trough of electrion enters inside reactive tank, and high-voltage discharging electrode is at interval of 0.1s
An electrion is carried out, can produce the high-voltage arc that traverses cell body or so together in reactive tank, caused by high-voltage arc
High-energy is absorbed by N, N- dialkyl ureas, and the chemical bond of amine root and carbonyl therein is played pendulum by energy excitation,
And key occurs under the surface catalysis of the rhodium of four carbonyl of dichloro two and is broken and recombinates, it is final that polymerisation generation nitric acid fibre occurs
Crude granule thing is tieed up, the cellulose nitrate granule thing for reacting generation is directly discharged from granular material discharged mouth, meanwhile, purified by reaction
Waste water afterwards is discharged reactive tank by flowing water Valve and entered in water purifying tank；Wherein, the effect of weak nitrocotton drying formation system
It is that the cellulose nitrate granule thing for reacting generation is dehydrated and dried, then by extrusion molding, is finally made weak nitrocotton block and supplies
Recycling.
The organic rhodium catalysis polymerization reaction trough of electrion, the discharge voltage range of its high-voltage discharging electrode is about 5500 ~
8000V, the aperture of the rhodium filler of four carbonyl of dichloro two is 4.8mm, specific surface area 6.0cm2/ g, the dischargeable capacity of reactive tank are
200m3。
The drying temperature of weak nitrocotton drying formation system is 70 ~ 85 DEG C, and compressing weak nitrocotton block specifications are
1.5cm×1.0cm×1.0cm。
Weak nitrocotton is a kind of nitrogenous organic high molecular polymer, and its molecular formula is：[C6H7O2（ONO2）a（OH）3-
A] n, wherein a be esterification degree, n is the degree of polymerization.It belongs to one kind of nitrocellulose, and its profile is white fibrous, physical
Matter is essentially identical with cotton.The nitrogen content of weak nitrocotton is 8 ~ 12%, available for production cinefilm, celluloid and zapon
Deng material.
The advantage of the invention is that：
（1）The system has explored a kind of new model for removing low concentration carbamazepine in waste water, creative use
The technology path that physical means, chemical method are combined with microbiological treatment, pass through energy effect and polymerization catalyzed effect
Directly act on, by N, N- dialkyl ureas absorbs high-energy caused by high-voltage arc, the chemical bond of amine root and carbonyl therein by
Played pendulum to energy excitation, and key occur under the surface catalysis of the rhodium of four carbonyl of dichloro two and is broken and recombinates,
It is final that polymerisation generation cellulose nitrate granule thing occurs,（Weak nitrocotton）, it is achieved thereby that the recovery profit of nitrogen resource
With.
（2）The system uses biopolymerization reactor, living in biology using Rhodosporidium toruloides and Moraxella streptococcus
During dynamic cyclic structure in carbamazepine molecule can be opened and make intermolecular generation polymerisation, forming repeat unit is
The larger molecular organicses of N, N- dialkyl ureas, so as to which carbamazepine molecule be enriched with, it is organic to improve subsequent treatment electrion
The treatment effeciency of rhodium catalysis polymerisation.
（3）The system employs the design of the rhodium porous aggregate of four carbonyl of dichloro two, waste water is fully sent out with catalyst
Raw haptoreaction, improves transformation efficiency, improves the disposal ability of whole system.
（4）The rhodium polymerization catalyst of four carbonyl of dichloro two in the system has service life long and is not susceptible in catalyst
The characteristics of malicious, it is achieved thereby that the low O＆M cost and long-play of processing system.
（5）The catalytic reaction of the system is carried out in liquid matrix, therefore reaction efficiency and speed are controlled, can only
Weak nitrocotton is generated, has prevented the generation of nitrogen content higher strong nitrocotton or collodion, is exploded so as to eliminate in operation
Risk.
（6）Waste water after being handled by the system, the clearance of its carbamazepine reach 99.9%, and weak nitrocotton
Conversion ratio is more than 90%.
Brief description of the drawings
Fig. 1 is the equipment schematic diagram of the present invention.
In figure：1-pH regulating reservoirs, 2- coarse racks, 3- inclined-plate clarifying basins, 4- biopolymerizations reactor, 5- electrions are organic
The weak nitrocotton drying formation system of rhodium catalysis polymerization reaction trough, 6- water purifying tanks, 7-
Fig. 2 is the schematic diagram of the organic rhodium catalysis polymerization reaction trough of electrion.
51- high-voltage discharging electrodes, the rhodium porous aggregate of four carbonyl of 52- dichloros two, 53- cell bodies insulating protective layer, 54- water intaking valves
Door, 55- flowing water Valves, 56- stirrer paddles, the granular material discharged mouths of 57-
Embodiment
The processing system of carbamazepine in a kind of removal waste water as shown in Figure 1, the system include pH regulating reservoirs 1, thick lattice
The organic rhodium catalysis polymerization reaction trough 5 of grid 2, inclined-plate clarifying basin 3, biopolymerization reactor 4, electrion, water purifying tank 6, weak nitrification
Cotton drying formation system 7 etc.；Wherein the waste water containing carbamazepine enters pH regulating reservoirs 1 by waste line, is concentrated herein
Keep in and pH is adjusted to 6.0-7.0, the outlet of pH regulating reservoirs 1 connects coarse rack 2 by waste line, is removed at this in waste water
Major diameter solid matter, the outlet of coarse rack 2 connects inclined-plate clarifying basin 3 by waste line, further removes waste water herein
In insoluble matter, the outlet of inclined-plate clarifying basin 3 passes through waste line and connects biopolymerization reactor 4, biopolymerization reactor 4
Inside secures multiple biopolymerization films, and high activity Rhodosporidium toruloides and Moraxella streptococcus etc. are attached with film, when useless
Water into biopolymerization reactor contacted with biopolymerization film when, Rhodosporidium toruloides and Moraxella streptococcus are in biological activity
During the cyclic structure in carbamazepine molecule can be opened and make intermolecular generation polymerisation, it is N to form repeat unit,
The larger molecular organicses of N- dialkyl ureas, in favor of the progress of the organic rhodium catalysis polymerisation of follow-up electrion, biopolymerization
The outlet of reactor 4 connects the organic rhodium catalysis polymerization reaction trough 5 of electrion, the organic rhodium catalysis of electrion by waste line
The outer layer covers of polymerization reaction trough 5 have a cell body insulating protective layer 53, and inside is silicon carbide ceramics structure, the dischargeable capacity of reactive tank
For 200m3, the upper right quarter of reactive tank is provided with inlet valve 54, and lower left quarter is provided with flowing water Valve 55, and cell body middle body is provided with
The rhodium porous aggregate 52 of four carbonyl of dichloro two, as polymerisation catalysts, the aperture of filler is 4.8mm, and specific surface area is
6.0cm2/ g, packing layer bottom are connected with granular material discharged mouth 57, and arranged on left and right sides wallboard center is respectively provided with an electrion
Electrode 51, one stirrer paddle 56 is respectively housed in reaction tank bottom arranged on left and right sides, by the waste water of biopolymerization reactor for treatment
Entered by the inlet valve 54 of the organic rhodium catalysis polymerization reaction trough 5 of electrion inside reactive tank, high-voltage discharging electrode 51 is every
It is spaced 0.1s and carries out an electrion, discharge voltage range is 5500 ~ 8000V, can be produced in reactive tank and traverse groove together
The high-voltage arc of body or so, high-energy caused by high-voltage arc are absorbed by the N in waste water, N- dialkyl ureas, amine root therein
Played pendulum by energy excitation with the chemical bond of carbonyl, and issued in the surface catalysis of the rhodium of four carbonyl of dichloro two
Raw key is broken and recombinated, and ultimately generates cellulose nitrate granule thing（Weak nitrocotton）, react the cellulose nitrate granule thing of generation
Directly discharged from granular material discharged mouth 57, meanwhile, the waste water after reaction purifies discharges reactive tank simultaneously by flowing water Valve 55
Into in water purifying tank 6, the outlet of water purifying tank 6 will be arranged by waste line outside the purification water outlet after the system is handled, meanwhile,
The nitrocellulose generated in the organic rhodium catalysis polymerization reaction trough 5 of electrion is discharged by granular material discharged mouth 57, and is entered
Weak nitrocotton dries formation system 7, and weak nitrocotton drying is dehydrated and can be recycled after compressing；Wherein, weak nitrification
The effect of cotton drying formation system 7 is that the cellulose nitrate granule thing for reacting generation is dehydrated and dried, then by extrusion molding,
It is finally made weak nitrocotton block and supplies recycling, the drying temperature of its weak nitrocotton drying formation system is 70 ~ 85 DEG C, compacting
The weak nitrocotton block specifications of shaping are 1.5cm × 1.0cm × 1.0cm, and the nitrogen content of weak nitrocotton is 8 ~ 12%.
Waste water after being handled by the system, the clearance of its carbamazepine reach 99.9%, and the conversion of weak nitrocotton
Rate is more than 90%.
Claims (4)
1. it is a kind of remove waste water in carbamazepine processing system, it is characterised in that the system include pH regulating reservoirs, coarse rack,
The organic rhodium catalysis polymerization reaction trough of inclined-plate clarifying basin, biopolymerization reactor, electrion, water purifying tank, weak nitrocotton are dried into
Shape system；Wherein the waste water containing carbamazepine enters the import of pH regulating reservoirs by waste line, and the outlet of pH regulating reservoirs passes through
Waste line connects coarse rack, and the outlet of coarse rack connects inclined-plate clarifying basin by waste line, and the outlet of inclined-plate clarifying basin leads to
Waste line connection biopolymerization reactor is crossed, the top leakage fluid dram of biopolymerization reactor connects height by waste line and pressed
The organic rhodium catalysis polymerization reaction trough of electricity, the outlet of the organic rhodium catalysis polymerization reaction trough of electrion connects water purification by waste line
Pond, the outlet of water purifying tank will be arranged by waste line outside the purification water outlet after the system is handled, meanwhile, electrion is organic
The nitrocellulose generated in rhodium catalysis polymerization reaction trough is discharged by granular material discharged mouth, and enters the drying shaping of weak nitrocotton
System, drying dehydration and compressing obtain weak nitrocotton and can be recycled；Wherein, biopolymerization inside reactor is fixed
Multiple biopolymerization films, high activity Rhodosporidium toruloides and Moraxella streptococcus are attached with film, when waste water enters biology
When polymer reactor contacts with biopolymerization film, Rhodosporidium toruloides and Moraxella streptococcus can incite somebody to action during biological activity
Cyclic structure in carbamazepine molecule is opened and makes intermolecular generation polymerisation, and it is N to form repeat unit, N- dialkyl ureas
Macromolecular organic polymer；Wherein, the outer surface of the organic rhodium catalysis polymerization reaction trough of electrion is enclosed with cell body insulation and protected
Sheath, inside are silicon carbide ceramics structure, and the upper right quarter of reactive tank is provided with inlet valve, and lower left quarter is provided with flowing water Valve, cell body
Middle body is provided with the rhodium porous aggregate of four carbonyl of dichloro two, and as polymerisation catalysts, packing layer bottom is connected with multiple
Granular material discharged mouth, arranged on left and right sides wallboard center is respectively provided with a high-voltage discharging electrode, in reaction tank bottom arranged on left and right sides
One stirrer paddle is respectively housed, the waste water by biopolymerization reactor for treatment passes through the organic rhodium catalysis polymerisation of electrion
The inlet valve of groove enters inside reactive tank, and high-voltage discharging electrode carries out an electrion at interval of 0.1s, can be in reactive tank
Middle to produce the high-voltage arc for traversing cell body or so together, high-energy caused by high-voltage arc is absorbed by N, N- dialkyl ureas, its
In amido and the chemical bond of carbonyl played pendulum by energy excitation, and in the surface catalysis of the rhodium of four carbonyl of dichloro two
The lower key that occurs of effect is broken and recombinated, final generation polymerisation generation cellulose nitrate granule thing, and the nitric acid for reacting generation is fine
Crude granule thing is tieed up directly to discharge from granular material discharged mouth, meanwhile, the waste water after reaction purifies is discharged anti-by flowing water Valve
Answer groove and enter in water purifying tank；Wherein, the effect of weak nitrocotton drying formation system is will to react the nitrocellulose generated
Grain thing is dehydrated and dried, then by extrusion molding, is finally made weak nitrocotton block and supplies recycling.
2. the processing system according to claim 1 for removing carbamazepine in waste water, it is characterised in that electrion is organic
Rhodium catalysis polymerization reaction trough, the discharge voltage range of its high-voltage discharging electrode are 5500 ~ 8000V, the rhodium filler of four carbonyl of dichloro two
Aperture be 4.8mm, specific surface area 6.0cm2/ g, the dischargeable capacity of reactive tank is 200m3。
3. the processing system according to claim 1 for removing carbamazepine in waste water, it is characterised in that weak nitrocotton drying
The drying temperature of formation system is 70 ~ 85 DEG C, and compressing weak nitrocotton block specifications are 1.5cm × 1.0cm × 1.0cm.
4. the processing system according to claim 1 for removing carbamazepine in waste water, it is characterised in that weak nitrocotton is one
Kind nitrocellulose, is white fibrous, and nitrogen content is 8 ~ 12%.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710728211.0A CN107324607A (en) | 2015-12-22 | 2015-12-22 | The system of carbamazepine in a kind of removal waste water |
| CN201710728210.6A CN107285577B (en) | 2015-12-22 | 2015-12-22 | The processing system of carbamazepine in a kind of removal waste water |
| CN201710728186.6A CN107311406A (en) | 2015-12-22 | 2015-12-22 | The system of carbamazepine in a kind of processing waste water |
| CN201510966192.6A CN105481173B (en) | 2015-12-22 | 2015-12-22 | The processing system of carbamazepine in a kind of removal waste water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510966192.6A CN105481173B (en) | 2015-12-22 | 2015-12-22 | The processing system of carbamazepine in a kind of removal waste water |
Related Child Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710728211.0A Division CN107324607A (en) | 2015-12-22 | 2015-12-22 | The system of carbamazepine in a kind of removal waste water |
| CN201710728210.6A Division CN107285577B (en) | 2015-12-22 | 2015-12-22 | The processing system of carbamazepine in a kind of removal waste water |
| CN201710728186.6A Division CN107311406A (en) | 2015-12-22 | 2015-12-22 | The system of carbamazepine in a kind of processing waste water |
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| Publication Number | Publication Date |
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| CN105481173A CN105481173A (en) | 2016-04-13 |
| CN105481173B true CN105481173B (en) | 2017-11-24 |
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| CN201710728210.6A Active CN107285577B (en) | 2015-12-22 | 2015-12-22 | The processing system of carbamazepine in a kind of removal waste water |
| CN201710728211.0A Pending CN107324607A (en) | 2015-12-22 | 2015-12-22 | The system of carbamazepine in a kind of removal waste water |
| CN201510966192.6A Expired - Fee Related CN105481173B (en) | 2015-12-22 | 2015-12-22 | The processing system of carbamazepine in a kind of removal waste water |
| CN201710728186.6A Pending CN107311406A (en) | 2015-12-22 | 2015-12-22 | The system of carbamazepine in a kind of processing waste water |
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| CN201710728210.6A Active CN107285577B (en) | 2015-12-22 | 2015-12-22 | The processing system of carbamazepine in a kind of removal waste water |
| CN201710728211.0A Pending CN107324607A (en) | 2015-12-22 | 2015-12-22 | The system of carbamazepine in a kind of removal waste water |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102639451A (en) * | 2009-12-01 | 2012-08-15 | 哈凯姆斯凡恩化学公司 | Method for treating wastewater produced during the manufacture of nitro compounds |
| CN102701436A (en) * | 2012-06-13 | 2012-10-03 | 哈尔滨工业大学宜兴环保研究院 | Biological activated carbon filtering pond and method for advanced wastewater treatment by using biological activated carbon filtering pond |
| JP2014131785A (en) * | 2013-01-07 | 2014-07-17 | Mitsui Zosen Plant Engineering Inc | Alkaline cleaning method of nitrogen-containing organic compound |
| CN104229972A (en) * | 2013-10-17 | 2014-12-24 | 同济大学 | Method for removing carbamazepine in sewage by virtue of strong oxidation of Fenton technology |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103170496B (en) * | 2013-03-01 | 2014-04-16 | 同济大学 | Method for removing drugs in soil by utilizing magnetism molecular imprinting-electromagnetism grating combination |
| CN103739162B (en) * | 2013-12-30 | 2015-11-25 | 江南大学 | A kind of ozone-activated carbon adsorption removes the method for PPCPs in tap water |
-
2015
- 2015-12-22 CN CN201710728210.6A patent/CN107285577B/en active Active
- 2015-12-22 CN CN201710728211.0A patent/CN107324607A/en active Pending
- 2015-12-22 CN CN201510966192.6A patent/CN105481173B/en not_active Expired - Fee Related
- 2015-12-22 CN CN201710728186.6A patent/CN107311406A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102639451A (en) * | 2009-12-01 | 2012-08-15 | 哈凯姆斯凡恩化学公司 | Method for treating wastewater produced during the manufacture of nitro compounds |
| CN102701436A (en) * | 2012-06-13 | 2012-10-03 | 哈尔滨工业大学宜兴环保研究院 | Biological activated carbon filtering pond and method for advanced wastewater treatment by using biological activated carbon filtering pond |
| JP2014131785A (en) * | 2013-01-07 | 2014-07-17 | Mitsui Zosen Plant Engineering Inc | Alkaline cleaning method of nitrogen-containing organic compound |
| CN104229972A (en) * | 2013-10-17 | 2014-12-24 | 同济大学 | Method for removing carbamazepine in sewage by virtue of strong oxidation of Fenton technology |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107311406A (en) | 2017-11-03 |
| CN107285577B (en) | 2018-03-02 |
| CN107324607A (en) | 2017-11-07 |
| CN107285577A (en) | 2017-10-24 |
| CN105481173A (en) | 2016-04-13 |
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