A kind of capsule cylindrical microwave flash distillation plant for heavy metal containing wastewater treatment
Technical field
The present invention relates to a kind of capsule cylindrical microwave flash distillation plants for heavy metal containing wastewater treatment, belong to evaporation process
Heavy metal wastewater thereby technical field.
Background technology
With the rapid development of China's modern industry, the heavy metal pollution problem getting worse in industrial wastewater.How to have
Effect administers heavy metal pollution, these heavy metal wastewater therebies of efficient process, and be allowed to recycling, and have become that people pay close attention to jointly asks
Topic.Evaporation is one of effective way for handling heavy metal ion-containing waste water.As one of important chemical engineering unit operation, evaporation is
With the method for heating, make solution under fluidized state by moisture therein or with the vaporization of volatile solvent content.Therefore, steam
Hair process is the process of a heat transfer, for metallurgical, chemical field, evaporates required heat and is mainly derived from heat
It exchanges, is one of operating unit of energy consumption maximum.
Current vaporising device can be divided into single-action, multiple-effect, indirect steam compression and Multi-stage flash hairdo, multiple-effect multiple stage flash evaporation
Formula etc..Single effect evaporation efficiency is low, and in order to improve evaporation efficiency, vaporising device gradually develops to multiple-effect evaporation.Multi-effect evaporation system
More complicated, triple effect evaporation needs three pumps, three evaporators, three sets of heat-exchange systems, and these equipment are required for high temperature resistant, resistance to
It presses and corrosion-resistant, manufacturing cost is higher.Therefore, in existing vaporising device and technique, generally existing heat exchange efficiency is low,
The technical barriers such as easy fouling, cost of investment height, equipment flowsheet length and high energy consumption.
Microwave be it is a kind of can quickly, the in situ electromagnetic wave for transferring energy, be a kind of green, it is quick, efficiently, be easy to automatic control
Novel energy.Microwave flash distillation based on microwave heating, as a kind of evaporation new technology of green high-efficient, has selectivity, wink
Shi Xing, globality, security, it is environmentally friendly and energy-efficient the features such as, have become a kind of emerging technology in heavy metal
The fields such as wastewater treatment receive more and more extensive concern.As microwave flash distillation carrier --- the design of microwave resonance cavity is just
As the key that microwave energy is thermal energy.The shape of microwave cavity has a great impact to the distribution of its interior electromagnetic field:No
Not only heating effect is bad or even can not generate resonance in the cavity for the resonator of suitable shape, so as to reach
The effect flashed to drop.
At present, common microwave flash distillation cavity mainly has rectangular cavity, cylindrical cavity and spherical cavity resonator.Rectangle
Resonator is small, and uniform temperature zone is small, and can only carry out batch processing to the smaller material of size, it is difficult to applied to large scale object
The processing of material and continuous and stable production, the scope of application are extremely limited.In order to reduce energy loss, it is necessary to improve as far as possible humorous
Shake the quality factor Q of chamber.To obtain the resonator of high q-factor, the cavity that volume is big and surface area is small should be selected, it is clear that spherical resonance
Chamber is ideal, but spherical cavity is not easy to make.Cylindrical cavity has low manufacture cost, pressure-resistant compared with rectangle and spherical cavity resonator
Ability is strong, physical dimension is larger and it is easy to control, have the advantages that very high Q values, manufacture craft are ripe.Be develop instantly it is most ripe,
A kind of most widely used microwave flash distillation cavity.Yet with the restriction of its cavity body structure, in cavity existing pattern count it is less,
Field distribution is uneven, and microwave flash distillation rate is slow, efficiency is low, high energy consumption.
The content of the invention
The technical problem to be solved by the present invention is to:It is cylindrical that the present invention provides a kind of capsule for heavy metal containing wastewater treatment
Microwave flash distillation plant, for solving in existing vaporising device and technique, generally existing heat exchange efficiency is low, easy fouling, cost of investment
High, equipment flowsheet is long and the technical barriers such as high energy consumption, while solves in the prior art due to the restriction of its cavity body structure, in cavity
The problems such as existing pattern count is less, field distribution is uneven, and microwave flash distillation rate is slow, efficiency is low, high energy consumption.
The technical scheme is that:A kind of capsule cylindrical microwave flash distillation plant for heavy metal containing wastewater treatment, including
Resonance cavity main body, microwave feedback mouth 4, waste liquid entrance 5, waste liquid outlet 6, flash distillation nozzle 7, waste liquid conveyance conduit 9;Resonance cavity main body by
Upper wire chamber 2, cylindrical waveguide 1, lower wire chamber 3 form;Upper wire chamber 2, lower wire chamber 3 are located at the upper and lower of cylindrical waveguide 1
Both ends;Microwave feedback mouth 4 be arranged on the side of cylindrical waveguide 1 and with resonance cavity main body is closed is fastenedly connected, it is waste liquid entrance 5, useless
Liquid outlet 6 is arranged on resonator body top and bottom and is connected with its inner cavity, and flash distillation nozzle 7 is arranged in resonance cavity main body, waste liquid
Conveyance conduit 9 connects waste liquid entrance 5 and flash distillation nozzle 7.
The resonance cavity main body is cylindrical for capsule, and upper wire chamber 2, lower wire chamber 3 are dome-like, two dome-likes
Metallic conductor form symmetric confocal concave surface chamber, and with 1 equal diameter of cylindrical waveguide is closed is fastenedly connected, form a closing
The quasi-optical resonator of formula.
The flash distillation nozzle 7 is arranged at resonator main center axis.Since the wire chamber of two dome-likes is equivalent to standard
Two concave mirrors of optical resonator, due to the focus characteristics of spherical mirror, electromagnetic wave is therebetween during roundtrip,
Most of energy in resonator can be limited in the narrow regions of chamber central near axis, if by drop to be evaporated
The region is sprayed to, microwave flash distillation speed is faster, more efficient.
The microwave feedback mouth 4 is arranged at the side symmetric position of cylindrical waveguide 1, ensures the microwave warp sent from magnetron
When microwave presents 4 feed-in resonance cavity main body of mouth, energy can be symmetrically distributed in cavity, be evenly heated waste liquid.
The capsule cylinder resonator main body, the long L in inner cavity and upper wire chamber 2, the radius of curvature R 1 of lower wire chamber 3, R2
Between meet following relation:0 £ (1-L/R1) (1-L/R2) £ 1.When the geometric parameter of resonator meets above-mentioned condition,
Electromagnetic wave can establish stable resonance in the cavity, and ripple is round-trip between two minute surfaces repeatedly to be formed standing wave and do not escape out outside chamber.
The radius of curvature R 1 of two spherical mirrors of the symmetric confocal concave surface chamber being made of the metallic conductor of two dome-likes=
R2, and, i.e. R1=R2=L equal with the long L in the inner cavity of resonance cavity main body form symmetric confocal concave surface chamber.Wherein, the long L in inner cavity is glue
The length of capsule cylinder resonator main body, i.e., two spherical surfaces of the symmetric confocal concave surface chamber being made of the metallic conductor of two dome-likes
The distance between mirror;
The long L in inner cavity of the resonance cavity main body and cylindrical waveguide length of tubelBetween meet:L=l+ 2x, ensure symmetric confocal
Concave surface chamber is seamlessly connected with cylindrical waveguide.Wherein x is the cavity heights of the metal cavity of dome-like, i.e., dome-like is upper
2 inner cavity top of wire chamber is also 3 intracavity bottom of lower wire chamber of dome-like to cylinder to the distance of 1 upper end of cylindrical waveguide
The distance of 1 lower end of waveguide.
The upper wire chamber 2 of the dome-like, the cavity heights x of lower wire chamber 3,1 radius a of cylindrical waveguide and cylindrical wave
Catheter lengthlBetween meet:a2+(l+x)2=(l+2x)2., ensure that symmetric confocal concave surface chamber can be straight with cylindrical waveguide etc.
Footpath is closed to be fastenedly connected.
The present invention operation principle be:
Cylindrical waveguide is combined, design one by the present invention according to the principle of quasi-optical resonator with quasi-optical resonator
The microwave flash distillation plant of kind capsule cylinder.The 2.45GHz microwave energies sent from magnetron present mouth 4 by microwave(It can be used
The rectangular waveguide feedback mouth of BJ-26 types)It is fed into flash distillation cavity(Capsule cylinder resonator main body)In after, microwave can by two circle
Roundtrip between the symmetric confocal concave surface chamber that the metallic conductor of roof shape is formed so that most microwave energies are in space
On to middle section converge, if by effluent containing heavy metal ions drop to be evaporated spray to flash distillation cavity in field strength distribution compared with concentration
Middle section, you can achieve the purpose that the reaction rate and efficiency that improve microwave flash distillation.
Thus the microwave flash distillation plant of capsule cylinder of the present invention includes the resonance cavity main body of capsule cylinder, arranged on cavity
The rectangular waveguide of side and BJ-26 types in communication presents mouth, the flash distillation nozzle 7 being placed at central axis, containing heavy metal ion
The entrance and exit of waste liquid drop 8 and the waste liquid conveyance conduit 9 of connection waste liquid entrance 5 and flash distillation nozzle 7.
The capsule cylinder that the above-mentioned symmetric confocal concave surface chamber being made of two metallic conductors and cylindrical waveguide collectively constitute is humorous
Shake cavity main body, meets following relation between the radius of curvature R 1 of the long L in inner cavity and symmetric confocal concave surface chamber, R2:0 £ (1-L/
R1) (1-L/R2) £ 1, concave surface chamber with cylindrical waveguide equal diameter is closed is fastenedly connected.BJ-26 types arranged on cavity side
Rectangular waveguide feedback mouth with capsule cylinder resonator main body is closed is fastenedly connected.Effluent containing heavy metal ions drop to be evaporated by
The flash distillation nozzle being placed at chamber central axis sprays.Heavy metal ion waste liquid material after concentration goes out again from the waste liquid of cavity
Mouth discharges and carries out secondary recovery.
The microwave flash distillation plant of capsule cylinder of the present invention is the principle according to quasi-optical resonator, by cylindrical waveguide with
The symmetric confocal resonator being made of two metallic conductors is combined into, and the wire chamber of two dome-likes is equivalent to quasi-optical resonator
Two concave mirrors, when the microwave that magnetron is sent through rectangle microwave feedback mouth 4 be radiated in cavity when, due to the convergence of concave mirror
Effect, between two wire chambers during roundtrip, microwave can spatially to middle section be converged and formed steady microwave
Fixed field distribution, so as to effectively improve the reaction rate and efficiency of microwave flash distillation.
The beneficial effects of the invention are as follows:
1st, the configuration of the present invention is simple solves existing evaporation plant equipment long flow path, the problems such as cost of investment is high, high temperature resistant,
It is pressure-resistant and corrosion-resistant;
2nd, present invention green, quick, efficient, energy-saving and environmental protection.Microwave is a kind of electricity that can transfer energy quickly, in situ
Magnetic wave is a kind of novel energy for being easy to automatic control.Microwave flash distillation based on microwave heating is a kind of new skill of the evaporation of green high-efficient
Art has the characteristics that selectivity, instantaneity, globality, security, environmentally friendly and energy-efficient;
3rd, have between microwave of the invention feedback mouth and flash distillation cavity preferable microwave coupling efficiency, cavity volume it is larger,
The stronger region concentration degree of field strength is high, cavity quality factor, that is, Q values are high;
4th, the present invention can be on the basis of the various advantages of cylindrical microwave flash distillation plant be given full play to so that in cavity
Evenly, pattern spectral profile is more concentrated near working frequency 2.45GHz for field distribution, microwave flash distillation speed faster, efficiency
Higher, cost are lower.
Description of the drawings
Fig. 1 is schematic structural view of the invention;
Fig. 2 be embodiment of the present invention when microwave source working frequency is 2.45GHz, in the electric field strength point of YOZ planes
Butut(The field intensity map generated by high-frequency electromagnetic simulation software HFSS);
Fig. 3 be embodiment of the present invention when the working frequency of microwave source is 2.45GHz, in the electric field strength of XOZ planes
Distribution map(The field intensity map generated by high-frequency electromagnetic simulation software HFSS).
Each label in Fig. 1:1- cylindrical waveguides, the upper wire chambers of 2-, wire chamber under 3-, 4- microwaves feedback mouth, 5- waste liquid entrances,
6- waste liquid outlets, 7- flash distillation nozzles, 8- waste liquid drops, 9- waste liquid conveyance conduits.
Specific embodiment
In the following with reference to the drawings and specific embodiments, the invention will be further described.
Embodiment 1:As shown in Figs. 1-3, a kind of capsule cylindrical microwave flash distillation plant for heavy metal containing wastewater treatment, bag
Include resonance cavity main body, microwave feedback mouth 4, waste liquid entrance 5, waste liquid outlet 6, flash distillation nozzle 7, waste liquid conveyance conduit 9;Resonance cavity main body
It is made of upper wire chamber 2, cylindrical waveguide 1, lower wire chamber 3;Upper wire chamber 2, lower wire chamber 3 are located at the upper of cylindrical waveguide 1
Lower both ends;Microwave feedback mouth 4 be arranged on the side of cylindrical waveguide 1 and with resonance cavity main body is closed is fastenedly connected, waste liquid entrance 5,
Waste liquid outlet 6 is arranged on resonator body top and bottom and is connected with its inner cavity, and flash distillation nozzle 7 is arranged in resonance cavity main body, is given up
Liquid conveyance conduit 9 connects waste liquid entrance 5 and flash distillation nozzle 7.
The resonance cavity main body is cylindrical for capsule, and upper wire chamber 2, lower wire chamber 3 are dome-like, and capsule cylinder is humorous
The cavity main body that shakes is closed by the symmetric confocal concave surface chamber that the metallic conductor of two dome-likes is formed and 1 equal diameter of cylindrical waveguide
Formula is fastenedly connected.
The flash distillation nozzle 7 is arranged at resonator main center axis.
The microwave feedback mouth 4 is arranged at the side symmetric position of cylindrical waveguide 1.
Embodiment 2:As shown in Figs. 1-3, a kind of capsule cylindrical microwave flash distillation plant for heavy metal containing wastewater treatment, bag
Include resonance cavity main body, microwave feedback mouth 4, waste liquid entrance 5, waste liquid outlet 6, flash distillation nozzle 7, waste liquid conveyance conduit 9;Resonance cavity main body
It is made of upper wire chamber 2, cylindrical waveguide 1, lower wire chamber 3;Upper wire chamber 2, lower wire chamber 3 are located at the upper of cylindrical waveguide 1
Lower both ends;Microwave feedback mouth 4 be arranged on the side of cylindrical waveguide 1 and with resonance cavity main body is closed is fastenedly connected, waste liquid entrance 5,
Waste liquid outlet 6 is arranged on resonator body top and bottom and is connected with its inner cavity, and flash distillation nozzle 7 is arranged in resonance cavity main body, is given up
Liquid conveyance conduit 9 connects waste liquid entrance 5 and flash distillation nozzle 7.
The resonance cavity main body is cylindrical for capsule, and upper wire chamber 2, lower wire chamber 3 are dome-like, and capsule cylinder is humorous
The cavity main body that shakes is closed by the symmetric confocal concave surface chamber that the metallic conductor of two dome-likes is formed and 1 equal diameter of cylindrical waveguide
Formula is fastenedly connected.
The flash distillation nozzle 7 is arranged at resonator main center axis.
The microwave feedback mouth 4 is arranged at the side symmetric position of cylindrical waveguide 1.
The capsule cylinder resonator main body, the long L in inner cavity and upper wire chamber 2, the radius of curvature R 1 of lower wire chamber 3, R2
Between meet following relation:0 £ (1-L/R1) (1-L/R2) £ 1.
The radius of curvature R 1 of two spherical mirrors of the symmetric confocal concave surface chamber being made of the metallic conductor of two dome-likes=
R2, and, i.e. R1=R2=L equal with the long L in the inner cavity of resonance cavity main body.
The long L in inner cavity of the resonance cavity main body and cylindrical waveguide length of tubelBetween meet:L=l+ 2x, wherein x are dome
2 inner cavity top of upper wire chamber of the cavity heights of the metal cavity of shape, i.e. dome-like to 1 upper end of cylindrical waveguide distance,
Also it is 3 intracavity bottom of lower wire chamber of dome-like to the distance of 1 lower end of cylindrical waveguide.
Embodiment 3:As shown in Figs. 1-3, a kind of capsule cylindrical microwave flash distillation plant for heavy metal containing wastewater treatment, bag
Include resonance cavity main body, microwave feedback mouth 4, waste liquid entrance 5, waste liquid outlet 6, flash distillation nozzle 7, waste liquid conveyance conduit 9;Resonance cavity main body
It is made of upper wire chamber 2, cylindrical waveguide 1, lower wire chamber 3;Upper wire chamber 2, lower wire chamber 3 are located at the upper of cylindrical waveguide 1
Lower both ends;Microwave feedback mouth 4 be arranged on the side of cylindrical waveguide 1 and with resonance cavity main body is closed is fastenedly connected, waste liquid entrance 5,
Waste liquid outlet 6 is arranged on resonator body top and bottom and is connected with its inner cavity, and flash distillation nozzle 7 is arranged in resonance cavity main body, is given up
Liquid conveyance conduit 9 connects waste liquid entrance 5 and flash distillation nozzle 7.
The resonance cavity main body is cylindrical for capsule, and upper wire chamber 2, lower wire chamber 3 are dome-like, and capsule cylinder is humorous
The cavity main body that shakes is closed by the symmetric confocal concave surface chamber that the metallic conductor of two dome-likes is formed and 1 equal diameter of cylindrical waveguide
Formula is fastenedly connected.
The flash distillation nozzle 7 is arranged at resonator main center axis.
The microwave feedback mouth 4 is arranged at the side symmetric position of cylindrical waveguide 1.
The capsule cylinder resonator main body, the long L in inner cavity and upper wire chamber 2, the radius of curvature R 1 of lower wire chamber 3, R2
Between meet following relation:0 £ (1-L/R1) (1-L/R2) £ 1.
The radius of curvature R 1 of two spherical mirrors of the symmetric confocal concave surface chamber being made of the metallic conductor of two dome-likes=
R2, and, i.e. R1=R2=L equal with the long L in the inner cavity of resonance cavity main body.
The long L in inner cavity of the resonance cavity main body and cylindrical waveguide length of tubelBetween meet:L=l+ 2x, wherein x are dome
2 inner cavity top of upper wire chamber of the cavity heights of the metal cavity of shape, i.e. dome-like to 1 upper end of cylindrical waveguide distance,
Also it is 3 intracavity bottom of lower wire chamber of dome-like to the distance of 1 lower end of cylindrical waveguide.
The upper wire chamber 2 of the dome-like, the cavity heights x of lower wire chamber 3,1 radius a of cylindrical waveguide and cylindrical wave
Catheter lengthlBetween meet:a2+(l+x)2=(l+2x)2。
Embodiment 4:As shown in Figs. 1-3, a kind of capsule cylindrical microwave flash distillation plant for heavy metal containing wastewater treatment, bag
Include resonance cavity main body, microwave feedback mouth 4, waste liquid entrance 5, waste liquid outlet 6, flash distillation nozzle 7, the waste liquid conveyance conduit of capsule cylinder
9;Resonance cavity main body is made of upper wire chamber 2, cylindrical waveguide 1, lower wire chamber 3;Upper wire chamber 2, lower wire chamber 3 are located at cylinder
The upper and lower ends of waveguide 1;Waste liquid entrance 5, waste liquid outlet 6 are arranged on resonator body top and bottom and are connected with its inner cavity,
Waste liquid conveyance conduit 9 connects waste liquid entrance 5 and flash distillation nozzle 7.
The radius a of the cylindrical waveguide 1 is 283.5mm, guide lengthlIt is metallic conductor for 377mm, material;Circle
The radius of curvature R 1 of the upper wire chamber 2 of roof shape is 539mm, cavity heights x (2 tops of upper wire chamber of dome-like to cylinder
The distance at the top of waveguide 1) be 81mm, material is metallic conductor;The radius of curvature R 2 of the lower wire chamber 3 of dome-like is still
539mm, cavity heights x (distance of 3 bottom of lower wire chamber of 1 bottom of cylindrical waveguide to dome-like) are 81mm, material is
Metallic conductor, the wire chamber of two dome-likes form symmetric confocal concave surface chamber, and the long L in inner cavity is (by the wire chamber structure of two dome-likes
The distance between two minute surfaces into symmetric confocal concave surface chamber) for 539mm, equal diameter envelope between the concave surface chamber and cylindrical waveguide 1
Enclosed is fastenedly connected;Microwave feedback mouth 4 be BJ-26 models rectangular waveguide, a length of 86.4mm, width 43.2mm, its be in circle
At the side symmetric position of column waveguide with capsule cylinder resonator main body is closed is fastenedly connected;Waste liquid entrance 5 is arranged on thole
The top of the wire chamber inner cavity 2 of dome-shaped;Waste liquid outlet 6 is arranged on the bottom of the wire chamber inner cavity 3 of dome-like;Flash distillation nozzle 7 is set
At the central axis of cavity;Waste liquid conveyance conduit 9 connects waste liquid entrance 5 and flash distillation nozzle 7;Waste liquid drop 8 is through flashing nozzle 7
It sprays;The volume of entire capsule cylinder resonator main body can reach 100 liters or so.
Present embodiment using working frequency as 2.45GHz, operation wavelength for 122.4mm microwave source through microwave transmission system
I.e. microwave energy is fed into the microwave flash distillation cavity of capsule cylinder by microwave feedback mouth 4, since the convergence of concave mirror acts on, microwave
Between two wire chambers during roundtrip, microwave can be converged spatially to middle section and form stable field point
Cloth effectively increases the reaction rate and efficiency of microwave flash distillation.
Attached drawing 1 is the structure diagram of the microwave flash distillation plant of capsule of the present invention cylinder;Attached drawing 2, attached drawing 3 are using high
After frequency electromagnetic simulation software HFSS operations, the field pattern that is formed in YOZ planes and in XOZ planes.
Light in Fig. 2,3 is strong electric field region, and black portions are weak electric field region, in resonance cavity main body almost
It is symmetric and most of Energy distribution is at chamber central axis.Due to the convergence characteristic of concave mirror, microwave is in two metals
Between chamber during roundtrip, it can spatially be converged to middle section and form stable field distribution, microwave flash distillation speed
Rate faster, it is more efficient, simulation result matches with theoretical analysis result.
Specific embodiments of the present invention are explained in detail above in conjunction with attached drawing, but the present invention is not limited to above-mentioned realities
Example is applied, it within the knowledge of a person skilled in the art, can also be on the premise of present inventive concept not be departed from
Various changes can be made.