CN105463943A - Anti-counterfeiting paper and manufacturing method thereof - Google Patents
Anti-counterfeiting paper and manufacturing method thereof Download PDFInfo
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- CN105463943A CN105463943A CN201610011312.1A CN201610011312A CN105463943A CN 105463943 A CN105463943 A CN 105463943A CN 201610011312 A CN201610011312 A CN 201610011312A CN 105463943 A CN105463943 A CN 105463943A
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- lithocyte
- paper
- component
- slurry
- dyeing
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Classifications
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- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
- D21H23/02—Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added
- D21H23/04—Addition to the pulp; After-treatment of added substances in the pulp
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Abstract
The invention discloses a piece of anti-counterfeiting paper and a manufacturing method thereof. The method includes the steps of dyeing stone cell components, adding the dyed stone cell components to a papermaking pulp system, and conducting papermaking to obtain the anti-counterfeiting paper. By means of the mode, the manufacturing method which is simple and easy to implement can be provided.
Description
Technical field
Field of papermaking of the present invention, is specifically related to a kind of cheque paper and manufacture method thereof.
Background technology
Cheque paper belongs to the category of speciality paper, early stage cheque paper is mainly used in printing of bank note, along with the continuous progress of science and technology and consumption market are to the increase of anti-fake paper demand, research and development, the production of cheque paper are paid much attention to gradually, have been widely used in label, ticket, package paper at present.Existing cheque paper and anti-counterfeiting technology mainly contain following several in the market:
(1) water marked paper is that wet web forms certain identification pattern in forming process, under general backlight irradiates, can see Clear & Transparent watermark recovery.As before web part of paper machine enters suction flat box, install a set of watermark ornamenting roller additional, or adopt figuratum rotary screen cage at quarter, when page finalizes the design almost, the fixed pattern be just carved on ornamenting roller impresses out the same watermark pattern of the indent slightly of regular array;
(2) fluorescent fiber paper and coloured fibre paper, be added in paper by the fluorescent fiber prepared, and under visible light, the various marks in paper are hidden state, but under UV-irradiation, specific pictograph will display; Also have coloured fibre paper in addition, part is added in the middle of paper in certain proportion through the fiber of dyeing in advance, shaping paper surface can see thread colored fiber;
(3) chemistry encryption paper, adds special compound, can develop the color or manifest fluorescence after specific chemical reagent coated again by this paper in paper pulp or when paper for surface sizing;
(4) laser holographic anti-counterfeit paper, is divided into film-sticking paper and pure paper, and film-sticking paper is composited after holographic laser film is fitted in paper surface, and pure paper directly laser holograph is imprinted on paper surface by the stamping technique of advanced person;
(5) nanometer watermark paper, is assembled in atomic nucleus track by the nano particle with electrical or magnetic, and form the track stereoscopic column with random distribution, wherein the particle diameter of nano particle is at 10-30nm;
(6) Reversible temperature is to color-changing anti-counterfeit paper, and by microcapsules technology, after temperature reaches a certain particular range, the color of material can change in time, and when temperature return, color also changes thereupon.
Above cheque paper production technology had both protected the good reputation of high-quality enterprise; also protect the interests of consumer simultaneously; for ensureing that the productive life of the mankind serves very important effect; the upper very important anti-counterfeiting technology means of existing market application; but technical sophistication; implement difficulty comparatively large, and need to carry out auxiliary enforcement by part auxiliary equipment or price material costly and complete
Summary of the invention
The technical problem that the present invention mainly solves how to provide a kind of manufacture method being simple and easy to the cheque paper implemented.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: the manufacture method providing a kind of cheque paper, and described manufacture method comprises: dye to lithocyte component; Lithocyte component after dyeing is added in paper making pulp system, carries out paper making and obtain described cheque paper.
Wherein, described the step that lithocyte component dyes to be comprised: the lithocyte solution described lithocyte component being configured to 1-10%, by the dye liquid mixing and stirring that described lithocyte solution and concentration are 0.1-1%, filter and obtain the lithocyte component after dyeing.
Wherein, described kind of dyes is at least one in ACID DYES, basic-dyeable fibre, direct dyes and pigment, described dyestuff colour system be redness, yellow, bluish violet, purple and orange in the formed induced color of one or more combinations.
Wherein, the lithocyte component after dyeing is to join in paper making pulp system relative to the ratio of slurry oven-dry weight 0.01-1%.
Wherein, the lithocyte component after dyeing is to join in paper making pulp system relative to the ratio of slurry oven-dry weight 0.01-01%.
Wherein, before lithocyte component is dyeed, also comprise: after fiber is screened out at least one slurry in leaf wood slurry and grass tree section slurry, obtain the gleanings after screening out fiber; Lithocyte component is wherein filtered out from described gleanings.
Wherein, described leaf wood slurry is at least one in poplar, birch, Eucalyptus, beech, principal columns of a hall wood and Acacia; Described grass family slurry is at least one in bamboo, reed, reed, giantreed, bagasse, kaoliang stalk, straw, wheat straw, mulberry skin, wingceltis skin and structure skin.
Wherein, in described paper making pulp system, the concentration of paper making pulp controls as 0.1-10%, and slurry temperature controls as 20-60 DEG C.
For solving the problems of the technologies described above, another technical solution used in the present invention is: provide the cheque paper that a kind of above-mentioned preparation method prepares.
The invention has the beneficial effects as follows: the situation being different from prior art, the present invention, by dyeing to lithocyte component, then says that the lithocyte component after dyeing is added in paper making pulp system, carries out paper making and obtain cheque paper.Make use of the transparent lenticular of lithocyte, be colored transparent lenticular after dyed, its structure and optical property are different from general fibre, define difference to a certain degree, thus realize manufacturing paper with pulp of cheque paper with paper fibre optical characteristics.By such mode, only need the lithocyte component of adding dyeing in the paper making pulp system of routine, manufacturing paper with pulp of cheque paper can be realized, be simple and easy to implement.
Accompanying drawing explanation
Fig. 1 is the flow chart of the manufacture method of a kind of cheque paper that the embodiment of the present invention provides.
Detailed description of the invention
Refer to Fig. 1, Fig. 1 is the flow chart of the manufacture method of a kind of cheque paper that the embodiment of the present invention provides, and as shown in the figure, the manufacture method of the cheque paper of the present embodiment comprises the following steps:
S101: lithocyte component is dyeed.
The lithocyte of the embodiment of the present invention is a kind of prothenchyma (of wood) with supporting function, and they have thick, usually lignified secondary wall, have common simple pit.Generally all protoplast is lost after ripe.In many plants, lithocyte shows as idioblas in the distribution of lithocyte, i.e. the aspect such as thickness of its shape, size and wall, comparatively easily and peripheral cell distinguish and come.
Wherein, the lithocyte component in the embodiment of the present invention can be the lithocyte component obtained by any way.As a kind of concrete implementation, the lithocyte component of the embodiment of the present invention by filtering out from slurry wherein.Specifically can select containing in the many leaf wood slurry of lithocyte Component comparison, grass tree section slurry wherein or both combined slurries, after fiber is screened out to leaf wood slurry and/or grass tree section slurry, then pass through >=325 object net collection screens except the gleanings after fiber, from gleanings, then filter out lithocyte component wherein.
Wherein, leaf wood slurry can be selected from wherein one or more the combination in poplar, birch, Eucalyptus, beech, principal columns of a hall wood and Acacia, and grass tree section slurry can be selected from wherein one or more the combination in bamboo, reed, reed, giantreed, bagasse, kaoliang stalk, straw, wheat straw, mulberry skin, wingceltis skin and structure skin.
Wherein, as a kind of concrete implementation, dyeing to lithocyte component and specifically can realize in the following manner: lithocyte solution lithocyte component being configured to 1-10%, is the dye liquid mixing and stirring of 0.1-1% by lithocyte solution and concentration, such as stirs 5-20 minute.Stir and terminate to carry out filtering to obtain the lithocyte component after dyeing.
Wherein, as a kind of citing specifically, the kind of dyes of the embodiment of the present invention is one or more the combination in ACID DYES, basic-dyeable fibre, direct dyes and pigment.Dyestuff colour system be redness, yellow, bluish violet, purple and orange in the formed induced color of one or more combinations.
S102: the lithocyte component after dyeing is added in paper making pulp system, carries out paper making and obtain cheque paper.
Wherein, as a kind of concrete implementation, by through hyperchromatic lithocyte to be added in paste system relative to the ratio of slurry oven-dry weight 0.01%-1% (such as 0.02%, 0.04%, 0.06%, 0.1%, 0.5% etc.), wherein preferred proportion is 0.01%-0.1%, such as 0.05%, 0.08%, 0.09% etc., slurry temperature is controlled at 20-60 DEG C, slurry concentration controls at 0.1-10%, subsequently after handsheet paper machine is shaping, again through squeezing, oven dry, shaping cheque paper can be obtained.
Obtained paper can uncoated or process coating.Normally meet light to watch, paper surface has the coloured color dot of slight band of random distribution; Under general backlight irradiates, transparent clearly color dot paper with random distribution can be seen.
The manufacture method of the cheque paper that the above embodiment of the present invention provides, by dyeing to lithocyte component, then saying that the lithocyte component after dyeing is added in paper making pulp system, carrying out paper making and obtain cheque paper.Make use of the transparent lenticular of lithocyte, be colored transparent lenticular after dyed, its structure and optical property are different from general fibre, define difference to a certain degree, thus realize manufacturing paper with pulp of cheque paper with paper fibre optical characteristics.By such mode, only need the lithocyte component of adding dyeing in the paper making pulp system of routine, manufacturing paper with pulp of cheque paper can be realized, be simple and easy to implement.
In order to further illustrate technical scheme of the present invention; be illustrated below by way of specific embodiment; the following stated embodiment is limited the representative embodiment cited by the present invention; the imbody of concrete material, formula rate and the reaction condition mentioned material, formula rate and reaction condition that only the present invention is above-mentioned mentioned, not in order to limit the scope of the invention.
Control group 1.0:
Adopt mixing slurry, wherein containing 20% chemical softwood pulp+70% chemical hardwood pulp+10% chemi-mechanical pulp, slurry temperature is 25 DEG C, and slurry concentration is 3.8%, shaping through handsheet paper machine, under backlighting environment, and test paper brocken spectrum.
Embodiment 1.1:
After screening removal fiber is carried out to leaf wood Eucalyptus 30%+ Acacia 70% chemical pulp, adopt 325 object net collection screens except the excess of fiber, pick out lithocyte wherein.Blue dyes is made into 0.1% concentration, inserts in dyestuff by the lithocyte filtered out, lithocyte concentration is 1%, uniform stirring 5min, filters, obtains through hyperchromatic lithocyte.By its with 0.01% ratio join in the mixed slurry of control group 1.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 1.2:
After screening removal fiber is carried out to leaf wood Eucalyptus 30%+ Acacia 70% chemical pulp, adopt 325 object net collection screens except the excess after fiber, pick out lithocyte wherein.Blue dyes is made into 0.1% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 1%, uniform stirring 5min, filters, obtains through hyperchromatic lithocyte.By its with 0.05% ratio join in the mixed slurry of control group 1.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 1.3:
After screening removal fiber is carried out to leaf wood Eucalyptus 30%+ Acacia 70% chemical pulp, adopt 325 object net collection screens except the excess after fiber, pick out lithocyte wherein.Blue dyes is made into 0.1% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 1%, uniform stirring 5min, filters, obtains through hyperchromatic lithocyte.By its with 0.5% ratio join in the mixed slurry of control group 1.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 1.4:
After screening removal fiber is carried out to leaf wood Eucalyptus 30%+ Acacia 70% chemical pulp, adopt 325 object net collection screens except the excess after fiber, pick out lithocyte wherein.Blue dyes is made into 0.1% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 1%, uniform stirring 5min, filters, obtains through hyperchromatic lithocyte.By its with 1% ratio join in the mixed slurry of control group 1.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Above test result is as follows:
Control group 2.0:
Adopt mixing slurry, wherein containing the chemical bamboo pulp of fine+70% hardwood chemical pulp+10% of 20% softwood pulp, slurry temperature is 20 DEG C, and slurry concentration is 1%, shaping through handsheet paper machine, under backlighting environment, and test paper brocken spectrum.
Embodiment 2.1:
After screening removal fiber is carried out to leaf wood poplar 100% chemical pulp, adopt 400 object net collection screens except the excess after fiber, pick out lithocyte wherein.Cudbear is made into 0.5% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 10%, uniform stirring 20min, filters, obtains through hyperchromatic lithocyte.By its with 0.01% ratio join in the mixed slurry of control group 2.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 2.2:
After screening removal fiber is carried out to leaf wood poplar 100% chemical pulp, adopt 400 object net collection screens except the excess after fiber, pick out lithocyte wherein.Cudbear is made into 0.5% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 10%, uniform stirring 20min, filters, obtains through hyperchromatic lithocyte.By its with 0.1% ratio join in the mixed slurry of control group 2.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 2.3:
After screening removal fiber is carried out to leaf wood poplar 100% chemical pulp, adopt 400 object net collection screens except the excess after fiber, pick out lithocyte wherein.Cudbear is made into 0.5% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 10%, uniform stirring 20min, filters, obtains through hyperchromatic lithocyte.By its with 0.5% ratio join in the mixed slurry of control group 2.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 2.4:
After screening removal fiber is carried out to leaf wood poplar 100% chemical pulp, adopt 400 object net collection screens except the excess after fiber, pick out lithocyte wherein.Cudbear is made into 0.5% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 10%, uniform stirring 20min, filters, obtains through hyperchromatic lithocyte.By its with 1% ratio join in the mixed slurry of control group 2.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Above test result is as follows:
Control group 3.0:
Adopt 100% chemical softwood pulp, slurry temperature is 60 DEG C, and slurry concentration is 0.3%, shaping through handsheet paper machine, under backlighting environment, and test paper brocken spectrum.
Embodiment 3.1:
After screening removal fiber is carried out to 100% chemical bamboo pulp, adopt 325 object net collection screens except the excess after fiber, pick out lithocyte wherein.Orange is made into 1% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 5%, uniform stirring 10min, filters, obtains through hyperchromatic lithocyte.By its with 0.03% ratio join in the mixed slurry of control group 3.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 3.2:
After screening removal fiber is carried out to 100% chemical bamboo pulp, adopt 325 object net collection screens except the excess after fiber, pick out lithocyte wherein.Orange is made into 1% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 5%, uniform stirring 10min, filters, obtains through hyperchromatic lithocyte.By its with 0.1% ratio join in the mixed slurry of control group 2.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 3.3:
After screening removal fiber is carried out to 100% chemical bamboo pulp, adopt 325 object net collection screens except the excess after fiber, pick out lithocyte wherein.Orange is made into 1% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 5%, uniform stirring 10min, filters, obtains through hyperchromatic lithocyte.By its with 0.5% ratio join in the mixed slurry of control group 2.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Embodiment 3.4:
After screening removal fiber is carried out to 100% chemical bamboo pulp, adopt 325 object net collection screens except the excess after fiber, pick out lithocyte wherein.Orange is made into 1% concentration, is inserted by the lithocyte filtered out, lithocyte concentration is 5%, uniform stirring 10min, filters, obtains through hyperchromatic lithocyte.By its with 1% ratio join in the mixed slurry of control group 2.0, shaping through handsheet paper machine, under backlighting environment, test paper brocken spectrum.
Above test result is as follows:
From the above embodiment of the present invention, the cheque paper that cheque paper manufacture method of the present invention prepares, relative to the paper of routine, has brocken spectrum, thus can realize false proof.
The foregoing is only embodiments of the invention; not thereby the scope of the claims of the present invention is limited; every utilize description of the present invention and accompanying drawing content to do equivalent structure or equivalent flow process conversion; or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.
Claims (9)
1. a manufacture method for cheque paper, is characterized in that, described manufacture method comprises:
Lithocyte component is dyeed;
Lithocyte component after dyeing is added in paper making pulp system, carries out paper making and obtain described cheque paper.
2. method according to claim 1, is characterized in that, describedly comprises the step that lithocyte component dyes:
Described lithocyte component being configured to the lithocyte solution of 1-10%, is the dye liquid mixing and stirring of 0.1-1% by described lithocyte solution and concentration, filters and obtains the lithocyte component after dyeing.
3. method according to claim 2, it is characterized in that, described kind of dyes is at least one in ACID DYES, basic-dyeable fibre, direct dyes and pigment, described dyestuff colour system be redness, yellow, bluish violet, purple and orange in the formed induced color of one or more combinations.
4. method according to claim 1, is characterized in that, the lithocyte component after dyeing is to join in paper making pulp system relative to the ratio of slurry oven-dry weight 0.01-1%.
5. method according to claim 1, is characterized in that, the lithocyte component after dyeing is to join in paper making pulp system relative to the ratio of slurry oven-dry weight 0.01-01%.
6. method according to claim 1, before dyeing, also comprises lithocyte component:
After fiber is screened out at least one slurry in leaf wood slurry and grass tree section slurry, obtain the gleanings after screening out fiber;
Lithocyte component is wherein filtered out from described gleanings.
7. method according to claim 6, is characterized in that, described leaf wood slurry is at least one in poplar, birch, Eucalyptus, beech, principal columns of a hall wood and Acacia; Described grass family slurry is at least one in bamboo, reed, reed, giantreed, bagasse, kaoliang stalk, straw, wheat straw, mulberry skin, wingceltis skin and structure skin.
8. method according to claim 1, is characterized in that, in described paper making pulp system, the concentration of paper making pulp controls as 0.1-10%, and slurry temperature controls as 20-60 DEG C.
9. the cheque paper that the method manufacture described in an any one of claim 1-8 obtains.
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110693372A (en) * | 2019-10-18 | 2020-01-17 | 重庆理文卫生用纸制造有限公司 | Natural color high wet strength face tissue and production process thereof |
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CN1710197A (en) * | 2005-06-17 | 2005-12-21 | 徐州师范大学 | Colour-changeable fiber anticounterfeit paper |
CN101949111A (en) * | 2010-09-10 | 2011-01-19 | 金东纸业(江苏)股份有限公司 | Method for producing anti-counterfeiting paper |
CN103103882A (en) * | 2013-02-22 | 2013-05-15 | 保定钞票纸业有限公司 | Bacterial cellulose-containing anti-counterfeiting paper and its preparation method |
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2016
- 2016-01-06 CN CN201610011312.1A patent/CN105463943B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN1710197A (en) * | 2005-06-17 | 2005-12-21 | 徐州师范大学 | Colour-changeable fiber anticounterfeit paper |
CN101949111A (en) * | 2010-09-10 | 2011-01-19 | 金东纸业(江苏)股份有限公司 | Method for producing anti-counterfeiting paper |
CN103103882A (en) * | 2013-02-22 | 2013-05-15 | 保定钞票纸业有限公司 | Bacterial cellulose-containing anti-counterfeiting paper and its preparation method |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN110693372A (en) * | 2019-10-18 | 2020-01-17 | 重庆理文卫生用纸制造有限公司 | Natural color high wet strength face tissue and production process thereof |
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