CN105462416A - Anti-doodling healthy indoor coating water-based latex paint and preparation method thereof - Google Patents
Anti-doodling healthy indoor coating water-based latex paint and preparation method thereof Download PDFInfo
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- CN105462416A CN105462416A CN201510960983.8A CN201510960983A CN105462416A CN 105462416 A CN105462416 A CN 105462416A CN 201510960983 A CN201510960983 A CN 201510960983A CN 105462416 A CN105462416 A CN 105462416A
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- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/08—Homopolymers or copolymers of acrylic acid esters
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
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- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1656—Antifouling paints; Underwater paints characterised by the film-forming substance
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
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- C08F220/10—Esters
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- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
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- C08F220/1808—C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate
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Abstract
The invention relates to anti-doodling healthy indoor coating water-based latex paint, prepared from the following components: water, cellulose, a pH modifier, a wetting agent, a dispersant, coarse whiting, talcum powder, kaolin, titanium dioxide, a perfluorinated olefin polymer dispersoid, an antifreezing agent and a thickener. The anti-doodling healthy indoor coating water-based latex paint overcomes the defect of existing latex paint that environmental protection property and doodling prevention as well as contamination resistance cannot be all considered, and has the advantages of being capable of effectively preventing children from doodling a paint film, resisting contamination, being enviromentally friendly and healthy, and not causing adverse effects on the health of the children.
Description
Technical field
The present invention relates to the preparation method of the indoor application aqueous latex paint of a kind of anti-graffiti health and preparation method thereof, be applied in architectural decoration water-borne coatings field.
Background technology
In " the 13 " planning outline of just having closed, suggestion is decontroled general " two tires ", the enforcement of general two children, a large amount of population can be increased, many families can increase area of the house purchased, buy and overlap house more, general " two tires " has allowed Chinese real estate market welcome again new spring, and the appearance with this policy is also welcome new opportunity by the use of house decoration simultaneously emulsion paint.Along with the raising day by day of people's living standard, the concern of the Functional Requirement of the finishing material of relatives especially children's health and Environmental Health is also obviously strengthened, this is that opportunity is challenged again to the development of coating, how under the development of this new normality, crack house ornamentation emulsion paint innovatively and have health and functional if effectively prevent a difficult problem for scribble aspect the current primary problem faced of person that becomes coating concurrently.Therefore provide a kind of and can effectively prevent from scribbling, stain resistant again health environment-friendly the indoor application aqueous latex paint of anti-graffiti health and preparation method thereof oneself become when business urgently.
Summary of the invention
The invention provides indoor application aqueous latex paint of a kind of anti-graffiti health and preparation method thereof, which overcome existing emulsion paint and cannot take into account the feature of environmental protection and shortcoming that is anti-graffiti, stain resistant, have and can effectively prevent children to the scribble of paint film, stain resistant, environment protection health again, does not cause dysgenic advantage to the health of children.
Technical scheme of the present invention is as follows:
The indoor application aqueous latex paint of a kind of anti-graffiti health, it comprises the component of following weight ratio:
The indoor application aqueous latex paint of anti-graffiti health of the application is while decoration, protection existing building base material; consider that children play in indoor to live and can scrawl crow to emulsion paint coating; spy have employed perfluoroalkene polymers dispersion and makes, and this material has excellent chemical stability, erosion resistance and low surface energy.This anti-graffiti health indoor application aqueous latex paint is one side effective fine and close film forming on base material when brushing drying and forming-film, on the other hand because the low surface energy of full-fluorine group makes coating possess fabulous hydrophobicity (maximum water-intake rate < 5%), and there is the characteristic and minimum frictional coefficient (0.15-0.17) of scolding oil, not non-dust absorption and non-fouling, thus enhance the anti-graffiti property of coating significantly, even if accidentally scribble on this paint film, only can need wipe out easily with the towel being moistened with washing powder water, base material is made to obtain permanent protection and decoration.
The indoor application aqueous latex paint of this anti-graffiti health, also comprises the functional sterilizing mildew-resistant emulsion of 8-15 weight part, and this functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio:
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio,
Polyhexamethylene Guanidinium hydrochloride 65-75g
Ethanol 15-25mL
Glytidyl methacrylate 5-15mL
In addition, the indoor application aqueous latex paint of this anti-graffiti health have employed functional sterilizing mildew-resistant emulsion, the effective group of its fungus and mildew resistance grafts on high molecular emulsion polymer segment, permanent existence can not be volatilized loss, effectively can change osmotic pressure inside and outside bacterium fungal cell wall and energy of position causes its metabolic disorder and inactivation.And this functional sterilizing mildew-resistant emulsion possesses lower film-forming temperature (because its Glass Transition Temperature of Latex Tg is lower, minimum film-forming temperature MFFT0 DEG C), this just makes this anti-graffiti health indoor application aqueous latex paint without the need to again adding volatile sterilant, mould inhibitor and film coalescence aid, to effectively reduce in paint vehicle every objectionable impurities as organic volatile VOC and formaldehyde etc., for human consumer provides the child bedroom application emulsion paint of a health environment-friendly.
This anti-graffiti health indoor application aqueous latex paint is formulated by the component of following weight ratio:
Described functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio:
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio:
Polyhexamethylene Guanidinium hydrochloride 70g
Ethanol 20mL
Glytidyl methacrylate 10mL
The bactericidal property of the functional sterilizing mildew-resistant emulsion of this proportioning is best.
Described Mierocrystalline cellulose is Natvosol; Described kaolin is water-washed kaoline; Described titanium dioxide is rutile titanium dioxide.
Described thickening material is one in polyurethane thickener or alkali swelling thickening material or its arbitrary combination.
Described thickening material is the mixture of polyurethane thickener and alkali swelling thickening material, and wherein polyurethane thickener is 0.001-0.4 weight part, and alkali swelling thickening material is 0.001-0.3 weight part.
The preparation method of the indoor application aqueous latex paint of this anti-graffiti health, it comprises following step of carrying out successively at ambient temperature and pressure:
1) pulping process:
After water and Mierocrystalline cellulose mixing, 3-5min is disperseed under 300-600rpm rotating speed, dispersion limit, limit adds pH adjusting agent, wetting agent, dispersion agent, and continue to disperse 2-4min under 800-1200rpm rotating speed, then disperse limit to add titanium dioxide, coarse whiting, kaolin, talcum powder below at this rotating speed, adjust rotating speed afterwards and disperse 18-22min to 1500-1800rpm;
2) paint technique:
To step 1) sequentially add perfluoroalkene polymers dispersion, frostproofer and thickening material in obtained mixture, and under 800-1000rpm rotating speed, continue dispersion 4-6min even to mixture.
Described step 2) in add perfluoroalkene polymers dispersion before, also need slowly to add functional sterilizing mildew-resistant emulsion, and disperse 2-4min under 400-600rpm rotating speed; Wherein the preparation method of functional sterilizing mildew-resistant emulsion is as follows:
1) preparation (as shown in Figure 1) of functional sterilizing Acrylic Acid Monomer:
In polyhexamethylene Guanidinium hydrochloride, add ethanol stir, make it dissolve completely, then add glytidyl methacrylate, constant temperature 55-65 DEG C back flow reaction 45-55h; Be down to room temperature backward in add excessive acetone or methyl alcohol, stir abundant hypsokinesis and remove supernatant liquid, re-treatment 3-5 time; Taking precipitate, at 22-28 DEG C of vacuum-drying 10-15h, obtains functional sterilizing Acrylic Acid Monomer;
2) preparation of functional sterilizing mildew-resistant emulsion:
1. pre-emulsification step:
Xiang Shuizhong adds pH buffer reagent, emulsifying agent, initiator, methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer and functional sterilizing class Acrylic Acid Monomer successively, and with 450-550rpm rotating speed dispersion dispersion 25-35min, be prepared into pre-emulsification mixed solution;
2. polymerization procedure:
Get the little pre-emulsification mixed solution equaling himself gross weight 1/4 and be slowly warming up to 70-80 DEG C while stirring with 250-350rpm rotating speed, there is blue phase time in its reaction by the time, start inwardly slowly to drip remaining pre-emulsification mixed solution, time for adding is 2-3h, isothermal reaction 0.5-1.5h afterwards, be warming up to 75-85 DEG C again, reaction 0.35-0.75H; Afterwards this reactant is down to room temperature, then adds tri-isopropanolamine amine adjustment pH to 7-8, filter and obtain functional sterilizing mildew-resistant emulsion.
The preparation technology of the indoor application aqueous latex paint of this anti-graffiti health is simple, low-carbon environment-friendly, has very strong industrialization ability and wide market outlook.
The step 2 of described functional sterilizing mildew-resistant emulsion preparation method) the pre-emulsification mixed solution that takes out in polymerization procedure accounts for 1/4 of himself gross weight.This ratio makes polyreaction more thorough, and it is better that prepared sterilization water-based builds painting emulsion property.
Compared with prior art, the present patent application has the following advantages:
1) contaminated resistance is remarkable, can effectively prevent children to the scribble of paint film;
2) reduce the use of organic volatile, environmental protection, health, be suitable for children room and use;
3) preparation technology is simple, low-carbon environment-friendly.
Accompanying drawing explanation
Fig. 1 is reaction formula prepared by functional sterilizing class Acrylic Acid Monomer.
Embodiment
Below in conjunction with each embodiment, technical scheme of the present invention is described in detail.
Raw material sources:
PH adjusting agent: Dow Chemical company limited AMP-95 multifunctional assistant;
Titanium dioxide: Du Pont R706;
Coarse whiting: Jiangling company 800 order;
Talcum powder: millimicro company talcum powder;
Kaolin: Meng Xi kaolin company water-washed kaoline;
Perfluoroalkene polymers: Jiangsu Changxin Airproof Material Co., Ltd.;
Wetting agent, dispersion agent: Nuo Puke company;
Thickening material: ROHM AND HAAS alkali swollen thickener, polyurethane thickener;
Polyhexamethylene Guanidinium hydrochloride: Taizhou chemical company;
Glytidyl methacrylate: East China, Shanghai reagent industrial;
Sodium bicarbonate: Chemical Reagent Co., Ltd., Sinopharm Group;
Acetone, methyl alcohol, ethanol, alkylphenol polyoxyethylene, Potassium Persulphate: Aladdin chemical reagent;
Methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer, sodium lauryl sulphate, tri-isopropanolamine: pacify resistance to Jilin Chemical.
Embodiment 1
The indoor application aqueous latex paint of a kind of anti-graffiti health, it is formulated by the component of following weight ratio:
Wherein, functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio:
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio:
Polyhexamethylene Guanidinium hydrochloride 65g
Ethanol 25mL
Glytidyl methacrylate 5mL
The indoor application aqueous latex paint of this anti-graffiti health, it comprises following step of carrying out successively at ambient temperature and pressure:
1) preparation of functional sterilizing Acrylic Acid Monomer:
In polyhexamethylene Guanidinium hydrochloride, add ethanol stir, make it dissolve completely, then add glytidyl methacrylate, constant temperature 55 DEG C of back flow reaction 55h; Be down to room temperature backward in add excessive acetone or methyl alcohol, stir abundant hypsokinesis and remove supernatant liquid, re-treatment 4 times; Taking precipitate, at 28 DEG C of vacuum-drying 10h, obtains functional sterilizing Acrylic Acid Monomer;
2) preparation of functional sterilizing mildew-resistant emulsion:
1. pre-emulsification step:
Sodium bicarbonate, sodium lauryl sulphate, alkylphenol polyoxyethylene, Potassium Persulphate, methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer and functional sterilizing class Acrylic Acid Monomer is added successively in deionized water, and with 500rpm rotating speed dispersion dispersion 30min, be prepared into pre-emulsification mixed solution;
2. polymerization procedure:
The pre-emulsification mixed solution getting himself gross weight 1/4 is slowly warming up to 75 DEG C while stirring with 250rpm rotating speed, and blue phase time appears in its reaction by the time, starts inwardly slowly to drip remaining pre-emulsification mixed solution, time for adding is 2h, isothermal reaction 1h afterwards, then be warming up to 80 DEG C, reaction 0.5H; Afterwards this reactant is down to room temperature, then adds tri-isopropanolamine amine adjustment pH to 7, filter and obtain functional sterilizing mildew-resistant emulsion.
3) pulping process:
After water and Natvosol mixing, 4min is disperseed under 550rpm rotating speed, dispersion limit, limit adds pH adjusting agent, wetting agent, dispersion agent, and continue to disperse 3min under 1000rpm rotating speed, then disperse limit to add rutile titanium dioxide, coarse whiting, water-washed kaoline, talcum powder below at this rotating speed, adjust rotating speed afterwards and disperse 20min to 1600rpm;
4) paint technique:
To step 3) slowly add functional sterilizing mildew-resistant emulsion in obtained mixture, and 3min is disperseed under 500rpm rotating speed; Sequentially add perfluoroalkene polymers dispersion, frostproofer, polyurethane thickener and alkali swelling thickening material again, and under 900rpm rotating speed, continue dispersion 5min even to mixture.
Embodiment 2
The indoor application aqueous latex paint of a kind of anti-graffiti health, it is formulated by the component of following weight ratio:
Wherein, functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio:
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio:
Polyhexamethylene Guanidinium hydrochloride 70g
Ethanol 20mL
Glytidyl methacrylate 10mL
The indoor application aqueous latex paint of this anti-graffiti health, it comprises following step of carrying out successively at ambient temperature and pressure:
1) preparation of functional sterilizing Acrylic Acid Monomer:
In polyhexamethylene Guanidinium hydrochloride, add ethanol stir, make it dissolve completely, then add glytidyl methacrylate, constant temperature 60 DEG C of back flow reaction 50h; Be down to room temperature backward in add excessive acetone, stir fully, incline supernatant liquid, adds excessive methanol, and incline after fully stirring clear liquid again, then add acetone and stir the clear liquid that inclines, re-treatment 3 times altogether; Taking precipitate, at 25 DEG C of vacuum-drying 12h, obtains functional sterilizing Acrylic Acid Monomer;
2) preparation of functional sterilizing mildew-resistant emulsion:
1. pre-emulsification step:
Sodium bicarbonate, sodium lauryl sulphate, alkylphenol polyoxyethylene, Potassium Persulphate, methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer and functional sterilizing class Acrylic Acid Monomer is added successively in deionized water, and with 500rpm rotating speed dispersion dispersion 30min, be prepared into pre-emulsification mixed solution;
2. polymerization procedure:
The pre-emulsification mixed solution getting himself gross weight 1/4 is slowly warming up to 75 DEG C while stirring with 300rpm rotating speed, and blue phase time appears in its reaction by the time, starts inwardly slowly to drip remaining pre-emulsification mixed solution, time for adding is 2.5h, isothermal reaction 1h afterwards, then be warming up to 80 DEG C, reaction 0.5H; Afterwards this reactant is down to room temperature, then adds tri-isopropanolamine amine adjustment pH to 7.5, filter and obtain functional sterilizing mildew-resistant emulsion;
3) pulping process:
After water and Natvosol mixing, 5min is disperseed under 300rpm rotating speed, dispersion limit, limit adds pH adjusting agent, wetting agent, dispersion agent, and continue to disperse 4min under 800rpm rotating speed, then disperse limit to add titanium dioxide, coarse whiting, water-washed kaoline, talcum powder below at this rotating speed, adjust rotating speed afterwards and disperse 22min to 1500rpm;
4) paint technique:
To step 3) slowly add functional sterilizing mildew-resistant emulsion in obtained mixture, and 4min is disperseed under 400rpm rotating speed; Sequentially add perfluoroalkene polymers dispersion, frostproofer and alkali swelling thickening material again, and under 800rpm rotating speed, continue dispersion 6min even to mixture.
Embodiment 3
The indoor application aqueous latex paint of a kind of anti-graffiti health, it is formulated by the component of following weight ratio:
Wherein, functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio:
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio:
Polyhexamethylene Guanidinium hydrochloride 75g
Ethanol 15mL
Glytidyl methacrylate 15mL
The indoor application aqueous latex paint of this anti-graffiti health, it comprises following step of carrying out successively at ambient temperature and pressure:
1) preparation of functional sterilizing Acrylic Acid Monomer:
In polyhexamethylene Guanidinium hydrochloride, add ethanol stir, make it dissolve completely, then add glytidyl methacrylate, constant temperature 65 DEG C of back flow reaction 45h; Be down to room temperature backward in add excessive acetone or methyl alcohol, stir abundant hypsokinesis and remove supernatant liquid, re-treatment 5 times; Taking precipitate, at 22 DEG C of vacuum-drying 15h, obtains functional sterilizing Acrylic Acid Monomer;
2) preparation of functional sterilizing mildew-resistant emulsion:
1. pre-emulsification step:
Sodium bicarbonate, sodium lauryl sulphate, alkylphenol polyoxyethylene, Potassium Persulphate, methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer and functional sterilizing class Acrylic Acid Monomer is added successively in deionized water, and with 500rpm rotating speed dispersion dispersion 30min, be prepared into pre-emulsification mixed solution;
2. polymerization procedure:
Getting the pre-emulsification mixed solution equaling himself gross weight 1/4 and be slowly warming up to 75 DEG C while stirring with 300rpm rotating speed, there is blue phase time in its reaction by the time, starts inwardly slowly to drip remaining pre-emulsification mixed solution, time for adding is 3h, isothermal reaction 1h afterwards, then be warming up to 80 DEG C, reaction 0.5H; Afterwards this reactant is down to room temperature, then adds tri-isopropanolamine amine adjustment pH to 8, filter and obtain functional sterilizing mildew-resistant emulsion.
3) pulping process:
After water and hydroxypropylcellulose mixing, 3min is disperseed under 600rpm rotating speed, dispersion limit, limit adds pH adjusting agent, wetting agent, dispersion agent, and continue to disperse 2min under 1200rpm rotating speed, then disperse limit to add titanium dioxide, coarse whiting, water-washed kaoline, talcum powder below at this rotating speed, adjust rotating speed afterwards and disperse 18min to 11800rpm;
4) paint technique:
To step 3) slowly add functional sterilizing mildew-resistant emulsion in obtained mixture, and 2min is disperseed under 600rpm rotating speed; Sequentially add swelling thick dose of perfluoroalkene polymers dispersion, ethylene glycol and alkali again, and under 1000rpm rotating speed, continue dispersion 4min even to mixture.
Embodiment 4
The indoor application aqueous latex paint of a kind of anti-graffiti health, it is formulated by the component of following weight ratio:
Wherein, functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio:
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio:
Polyhexamethylene Guanidinium hydrochloride 65g
Ethanol 25mL
Glytidyl methacrylate 5mL
The indoor application aqueous latex paint of this anti-graffiti health, it comprises following step of carrying out successively at ambient temperature and pressure:
1) preparation of functional sterilizing Acrylic Acid Monomer:
In polyhexamethylene Guanidinium hydrochloride, add ethanol stir, make it dissolve completely, then add glytidyl methacrylate, constant temperature 65 DEG C of back flow reaction 45h; Be down to room temperature backward in add excessive acetone or methyl alcohol, stir abundant hypsokinesis and remove supernatant liquid, re-treatment 5 times; Taking precipitate, at 22 DEG C of vacuum-drying 15h, obtains functional sterilizing Acrylic Acid Monomer;
2) preparation of functional sterilizing mildew-resistant emulsion:
1. pre-emulsification step:
Sodium bicarbonate, sodium lauryl sulphate, alkylphenol polyoxyethylene, Potassium Persulphate, methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer and functional sterilizing class Acrylic Acid Monomer is added successively in deionized water, and with 500rpm rotating speed dispersion dispersion 30min, be prepared into pre-emulsification mixed solution;
2. polymerization procedure:
The pre-emulsification mixed solution getting himself gross weight 1/4 is slowly warming up to 75 DEG C while stirring with 250rpm rotating speed, and blue phase time appears in its reaction by the time, starts inwardly slowly to drip remaining pre-emulsification mixed solution, time for adding is 2h, isothermal reaction 1h afterwards, then be warming up to 80 DEG C, reaction 0.5H; Afterwards this reactant is down to room temperature, then adds tri-isopropanolamine amine adjustment pH to 7, filter and obtain functional sterilizing mildew-resistant emulsion;
3) pulping process:
After water and Natvosol mixing, 3.5min is disperseed under 350rpm rotating speed, dispersion limit, limit adds pH adjusting agent, wetting agent, dispersion agent, and continue to disperse 2.5min under 850rpm rotating speed, then disperse limit to add titanium dioxide, coarse whiting, water-washed kaoline, talcum powder below at this rotating speed, adjust rotating speed afterwards and disperse 21min to 1600rpm;
4) paint technique:
To step 3) slowly add functional sterilizing mildew-resistant emulsion in obtained mixture, and 3.54min is disperseed under 550rpm rotating speed, sequentially add perfluoroalkene polymers dispersion, ethylene glycol and polyurethane thickener again, and under 850rpm rotating speed, continue dispersion 5.5min even to mixture.
Embodiment 5
The indoor application aqueous latex paint of a kind of anti-graffiti health, it is formulated by the component of following weight ratio:
Wherein, functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio:
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio:
Polyhexamethylene Guanidinium hydrochloride 70g
Ethanol 20mL
Glytidyl methacrylate 10mL
The indoor application aqueous latex paint of this anti-graffiti health, it comprises following step of carrying out successively at ambient temperature and pressure:
1) preparation of functional sterilizing Acrylic Acid Monomer:
In polyhexamethylene Guanidinium hydrochloride, add ethanol stir, make it dissolve completely, then add glytidyl methacrylate, constant temperature 60 DEG C of back flow reaction 50h; Be down to room temperature backward in add excessive acetone, stir fully, incline supernatant liquid, adds excessive methanol, and incline after fully stirring clear liquid again, then add acetone and stir the clear liquid that inclines, re-treatment 3 times altogether; Taking precipitate, at 25 DEG C of vacuum-drying 12h, obtains functional sterilizing Acrylic Acid Monomer;
2) preparation of functional sterilizing mildew-resistant emulsion:
1. pre-emulsification step:
Sodium bicarbonate, sodium lauryl sulphate, alkylphenol polyoxyethylene, Potassium Persulphate, methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer and functional sterilizing class Acrylic Acid Monomer is added successively in deionized water, and with 500rpm rotating speed dispersion dispersion 30min, be prepared into pre-emulsification mixed solution;
2. polymerization procedure:
The pre-emulsification mixed solution getting himself gross weight 1/4 is slowly warming up to 75 DEG C while stirring with 300rpm rotating speed, and blue phase time appears in its reaction by the time, starts inwardly slowly to drip remaining pre-emulsification mixed solution, time for adding is 2.5h, isothermal reaction 1h afterwards, then be warming up to 80 DEG C, reaction 0.5H; Afterwards this reactant is down to room temperature, then adds tri-isopropanolamine amine adjustment pH to 7.5, filter and obtain functional sterilizing mildew-resistant emulsion;
3) pulping process:
After water and Natvosol mixing, 5min is disperseed under 600rpm rotating speed, dispersion limit, limit adds pH adjusting agent, wetting agent, dispersion agent, and continue to disperse 4min under 1200rpm rotating speed, then disperse limit to add titanium dioxide, coarse whiting, water-washed kaoline, talcum powder below at this rotating speed, adjust rotating speed afterwards and disperse 22min to 1800rpm;
4) paint technique:
To step 1) slowly add functional sterilizing mildew-resistant emulsion in obtained mixture, and 2min is disperseed under 400rpm rotating speed, sequentially add perfluoroalkene polymers dispersion, ethylene glycol and polyurethane thickener again, and under 800rpm rotating speed, continue dispersion 4min even to mixture.
Embodiment 6
The difference of itself and embodiment 1 is:
This anti-graffiti health indoor application aqueous latex paint is formulated by the component of following weight ratio:
Described thickening material is the mixture of polyurethane thickener and alkali swelling thickening material, and wherein polyurethane thickener is 0.4 weight part, and alkali swelling thickening material is 0.3 weight part.
Embodiment 7
The difference of itself and embodiment 2 is:
This anti-graffiti health indoor application aqueous latex paint is formulated by the component of following weight ratio:
Described thickening material is the mixture of polyurethane thickener and alkali swelling thickening material, and wherein polyurethane thickener is 0.001 weight part, and alkali swelling thickening material is 0.001 weight part.
Embodiment 8
The difference of itself and embodiment 3 is:
This anti-graffiti health indoor application aqueous latex paint is formulated by the component of following weight ratio:
Experimental data
One, anti-graffiti health indoor application aqueous latex paint property indices test
1. testing method
1) the indoor application aqueous latex paint of the anti-graffiti health of each embodiment holds at normal temperatures and pressures and whether stirs rear observation evenly without lump in container, and whether the time of drying and the observation of roller application twice is constructed under paint film normal temperature and film have cracking phenomena.
2) low-temperature stability: by the coating of each embodiment, be contained in-5 ± 3 DEG C by certain container tank and store 18H, then normal temperature places 6H, is so a circulation, and after continuous three circulations, whether can opening observation coating goes bad.
3) abrasion resistance test: get this water-miscible paint together with being respectively coated with without the line rod respectively by diameter 120 and 80 specifications on asbestos cement plate of size 430mm × 150mm × (4-6) mm, twice coating duration interval is not less than 6h, and the plate prepared is put in temperature 23 ± 2 DEG C, the environment maintenance of humidity 50 ± 5 parts 7 days, prepares 8 blocks of plates and A, B, C, D, E, F, G, H altogether.Then its abrasion resistance is tested with washability machine.
4) VOC test: adopt vapor-phase chromatography, take each example composition 0.6g respectively and put into the tool plug vial claiming to have 0.2g Virahol, add 2mL dimethyl formamide respectively, cover bottle stopper, firmly shake ampoule 15min, places 5min, make it precipitate, draw 1uL clear liquid respectively, injecting chromatograph, record data.
5) formaldehyde test: absorbancy method of testing, takes the sample 2g after stirring and is placed in the matrass adding 50mL water in advance and shakes up gently, then add 200mL water.In fraction receiving vessel, add appropriate water logging does not in advance have fraction to export, the outside refrigerated with ice of fraction receiving vessel, and fraction 200mL collected by heating matrass, takes off fraction receiving vessel, fraction is settled to 250mL.The fraction distilled out should survey its absorbancy and record data in 6h.
2. test result
Two, anti-graffiti test
1. testing method
Get a certain amount of each embodiment emulsion paint respectively, with the blade applicator of 200um by its blade coating on black film, normal temperature maintenance 7 days, take out the area respectively getting 3 pieces of rectangle 2 × 5cm in black film emulsion paint film centre, to scribble respectively prepared Chinese ink, permanent pen, aqueous fluorescent pen, 2h dries, be placed in scrubbing resistance machine water (1% washing powder water, 10% washing powder water) to clean, observe the clean situation in scribble district, can remove with water and be designated as 1 grade, 1% washing powder water can be removed and be designated as 2 grades, 10% washing powder water can remove and be designated as 3 grades.
2. test data
Shown by the practical application of the every experimental data in table and each embodiment, the properties of the indoor application aqueous latex paint of the anti-graffiti health in the present invention prepared by each embodiment all can meet and be better than the national standard requirement of GB/T9755-2001, there is outstanding abrasion resistance, and detect without the organic volatile VOC be harmful to health and formaldehyde, it has more excellent antigraffiti properties simultaneously.Wherein, embodiment 1 is most preferred embodiment, and its antigraffiti properties is best.
Indoor application aqueous latex paint of anti-graffiti health of the present invention and preparation method thereof has more than and is only confined to above-described embodiment, and every any improvement according to the principle of the invention or replacement, all should within protection scope of the present invention.
Claims (10)
1. the indoor application aqueous latex paint of anti-graffiti health, is characterized in that: it comprises the component of following weight ratio,
2. the indoor application aqueous latex paint of anti-graffiti health according to claim 1, is characterized in that: it also comprises the functional sterilizing mildew-resistant emulsion of 8-15 weight part, and this functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio,
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio,
Polyhexamethylene Guanidinium hydrochloride 65-75g
Ethanol 15-25mL
Glytidyl methacrylate 5-15mL.
3. the indoor application aqueous latex paint of anti-graffiti health according to claim 2, is characterized in that: it is formulated by the component of following weight ratio,
4. the indoor application aqueous latex paint of anti-graffiti health according to claim 2, is characterized in that: described functional sterilizing mildew-resistant emulsion is formulated by the component of following weight ratio,
Wherein, functional sterilizing Acrylic Acid Monomer is formulated by the component of following ratio,
Polyhexamethylene Guanidinium hydrochloride 70g
Ethanol 20mL
Glytidyl methacrylate 10mL.
5. the indoor application aqueous latex paint of anti-graffiti health according to claim 1, is characterized in that: described Mierocrystalline cellulose is Natvosol; Described kaolin is water-washed kaoline; Described titanium dioxide is rutile titanium dioxide.
6. the indoor application aqueous latex paint of anti-graffiti health according to claim 1, is characterized in that: described thickening material is one in polyurethane thickener or alkali swelling thickening material or its arbitrary combination.
7. the indoor application aqueous latex paint of anti-graffiti health according to claim 6, it is characterized in that: described thickening material is the mixture of polyurethane thickener and alkali swelling thickening material, wherein polyurethane thickener is 0.001-0.4 weight part, and alkali swelling thickening material is 0.001-0.3 weight part.
8. the preparation method of the indoor application aqueous latex paint of the anti-graffiti health according to any one of claim 1-7, is characterized in that: it comprises following step of carrying out successively at ambient temperature and pressure,
1) pulping process:
After water and Mierocrystalline cellulose mixing, 3-5min is disperseed under 300-600rpm rotating speed, dispersion limit, limit adds pH adjusting agent, wetting agent, dispersion agent, and continue to disperse 2-4min under 800-1200rpm rotating speed, then disperse limit to add titanium dioxide, coarse whiting, kaolin, talcum powder below at this rotating speed, adjust rotating speed afterwards and disperse 18-22min to 1500-1800rpm;
2) paint technique:
To step 1) sequentially add perfluoroalkene polymers dispersion, frostproofer and thickening material in obtained mixture, and under 800-1000rpm rotating speed, continue dispersion 4-6min even to mixture.
9. the preparation method of the indoor application aqueous latex paint of anti-graffiti health according to claim 8, it is characterized in that: described step 2) in add perfluoroalkene polymers dispersion before, also need slowly to add functional sterilizing mildew-resistant emulsion, and disperse 2-4min under 400-600rpm rotating speed; Wherein the preparation method of functional sterilizing mildew-resistant emulsion is as follows:
1) preparation of functional sterilizing Acrylic Acid Monomer:
In polyhexamethylene Guanidinium hydrochloride, add ethanol stir, make it dissolve completely, then add glytidyl methacrylate, constant temperature 55-65 DEG C back flow reaction 45-55h; Be down to room temperature backward in add excessive acetone or methyl alcohol, stir abundant hypsokinesis and remove supernatant liquid, re-treatment 3-5 time; Taking precipitate, at 22-28 DEG C of vacuum-drying 10-15h, obtains functional sterilizing Acrylic Acid Monomer;
2) preparation of functional sterilizing mildew-resistant emulsion:
1. pre-emulsification step:
Xiang Shuizhong adds pH buffer reagent, emulsifying agent, initiator, methyl methacrylate, n-butyl acrylate, Isooctyl acrylate monomer and functional sterilizing class Acrylic Acid Monomer successively, and with 450-550rpm rotating speed dispersion dispersion 25-35min, be prepared into pre-emulsification mixed solution;
2. polymerization procedure:
Get the little pre-emulsification mixed solution equaling himself gross weight 1/4 and be slowly warming up to 70-80 DEG C while stirring with 250-350rpm rotating speed, there is blue phase time in its reaction by the time, start inwardly slowly to drip remaining pre-emulsification mixed solution, time for adding is 2-3h, isothermal reaction 0.5-1.5h afterwards, be warming up to 75-85 DEG C again, reaction 0.35-0.75H; Afterwards this reactant is down to room temperature, then adds tri-isopropanolamine amine adjustment pH to 7-8, filter and obtain functional sterilizing mildew-resistant emulsion.
10. the preparation method of the indoor application aqueous latex paint of anti-graffiti health according to claim 8, is characterized in that: the step 2 of described functional sterilizing mildew-resistant emulsion preparation method) the pre-emulsification mixed solution that takes out in polymerization procedure accounts for 1/4 of himself gross weight.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383283A (en) * | 2017-08-23 | 2017-11-24 | 广州科迩博新材料科技有限公司 | A kind of structural type antimicrobial acrylic emulsion and its preparation method and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004072197A1 (en) * | 2003-02-13 | 2004-08-26 | Daikin Industries, Ltd. | Fluorine-containing aqueous coating composition |
| CN102876158A (en) * | 2011-07-11 | 2013-01-16 | 上海富臣化工有限公司 | Soft anti-stain elastic interior wall latex paint and preparation method thereof |
| CN104592459A (en) * | 2015-01-21 | 2015-05-06 | 广西大学 | Nuclear shell type long-acting antibacterial emulsion and preparation method thereof |
-
2015
- 2015-12-18 CN CN201510960983.8A patent/CN105462416B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004072197A1 (en) * | 2003-02-13 | 2004-08-26 | Daikin Industries, Ltd. | Fluorine-containing aqueous coating composition |
| CN102876158A (en) * | 2011-07-11 | 2013-01-16 | 上海富臣化工有限公司 | Soft anti-stain elastic interior wall latex paint and preparation method thereof |
| CN104592459A (en) * | 2015-01-21 | 2015-05-06 | 广西大学 | Nuclear shell type long-acting antibacterial emulsion and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| 周日辉等: "功能化聚六亚甲基盐酸胍的合成与表征", 《合成技术及应用》 * |
| 李阳等: "聚丙烯酸酯抗菌乳液的合成及性能研究", 《2015年中国化工学会年会论文集》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107383283A (en) * | 2017-08-23 | 2017-11-24 | 广州科迩博新材料科技有限公司 | A kind of structural type antimicrobial acrylic emulsion and its preparation method and application |
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