CN105462315A - High-stain-resistance elastic and tip-shaped broom-finish emulsion paint and preparation method thereof - Google Patents
High-stain-resistance elastic and tip-shaped broom-finish emulsion paint and preparation method thereof Download PDFInfo
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- CN105462315A CN105462315A CN201510937066.8A CN201510937066A CN105462315A CN 105462315 A CN105462315 A CN 105462315A CN 201510937066 A CN201510937066 A CN 201510937066A CN 105462315 A CN105462315 A CN 105462315A
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- emulsion paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/022—Emulsions, e.g. oil in water
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/025—Preservatives, e.g. antimicrobial agents
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
Abstract
The invention relates to high-stain-resistance elastic and tip-shaped broom-finish emulsion paint. The emulsion paint is prepared from water, a pH regulating agent, a dispersing agent, a wetting agent, an anti-freezing agent, a defoaming agent, bentonite, titanium dioxide, precipitated barium sulfate, heavy calcium carbonate, calcined kaolin, ultraviolet crosslinking type elastic emulsion, opaque polymer, a coalescing agent, a water-based paint enhancing agent, sterilization preservatives, a mould-preventing agent and a thickening agent. The emulsion paint overcomes the defects that existing elastic broom-finish emulsion paint cannot have high stain resistance and high elasticity at the same time, defoaming is difficult, and a preparation method is complicated, and has the advantages that high stain resistance (stain resistance is smaller than 15%) and high elasticity (normal-temperature break elongation is larger than 250%) are achieved at the same time, defoaming performance is excellent, the number of paint film pin holes is small, and the preparation method is simple and convenient.
Description
Technical field
The present invention relates to a kind of high dirt resistance elasticity point moulding plucking emulsion paint and preparation method thereof, be applied in architectural decoration water-borne coatings field.
Background technology
Current skin body of wall base material is generally cement based, after it affects by factors such as environment, temperature and humidity changes, and the as easy as rolling off a log generation fine cracks of body of wall.It is attractive in appearance that this not only destroys body of wall, also easily makes inner body of wall suffer erosion.
Elastic emulsion paint can be divided into the flat painting of elasticity and elastic napping two kinds.Elasticity is flat is painted with scumble (film build is about 60um), and film is plane, smooth; And elastic napping is heavy-film coating (coating thickness is about 300um), film is three-dimensional, rough.Elasticity puts down to be coated with has the color stuffing of employing, thickening material kind and ratio different with the elastic napping key distinction, and the viscosity painted in addition also has very big-difference.Elastic napping can be divided into again round moulding and sharp moulding two kinds according to moulding difference, and the convex sense of circle moulding is smoother, submissive, the convex sense of sharp moulding relatively more sharp-pointed, prick the hand.Circle moulding has the kind of thickening material in its system different with consumption with the key distinction of sharp moulding, and both viscosity and thixotropy also have different.
Elastic emulsion paint is that main film forming substance manufacture forms with elastic emulsion, and its film has snappiness and toughness in certain temperature range, and have covering body of wall micro-cracks, prevent the features such as concrete carbonization, it is more and more subject to market favor.But the film of elastic emulsion paint is more soft, especially in hot summer (body of wall temperature can up to more than 50 DEG C), its film coated surface even can be clamminess and easily be stained with ash, film is polluted thus affects that it is ornamental.Therefore, improving contamination resistance is the problem that elastic emulsion paint must solve in development and application.
At present, the contamination resistance < 25% of elastic emulsion paint is required in standard JG/T172-2014 " elastic building paint ", normal temperature tensile strength > 2.0MPa, normal temperature elongation at break > 150%, freezing crack elongation > 35%.Current elastic napping class emulsion paint major part on the market can meet the requirement of this standard, but there is not yet elastic napping class emulsion paint product in the market and can reach high dirt resistance (contamination resistance < 15%) and snappiness (normal temperature elongation at break > 250%) simultaneously, and there is the problem of froth breaking difficulty in high-viscosity latex paint.Therefore provide that one possesses high dirt resistance and snappiness simultaneously, defoaming effect is good, paint film pin hole is few, and preparation method's simple high dirt resistance elasticity point moulding plucking emulsion paint and preparation method thereof oneself become when business urgently.
Summary of the invention
The invention provides a kind of high dirt resistance elasticity point moulding plucking emulsion paint and preparation method thereof, which overcome existing elastic napping class emulsion paint and can not have high dirt resistance and snappiness, preparation method is complicated, froth breaking is difficult shortcoming simultaneously, have and reach high dirt resistance (contamination resistance < 15%) and snappiness (normal temperature elongation at break > 250%) simultaneously, defoaming effect is good, paint film pin hole is few, the advantage that preparation method is easy.
Technical scheme of the present invention is as follows:
A kind of high dirt resistance elasticity point moulding plucking emulsion paint, it is formulated by the component of following weight ratio:
This high dirt resistance elasticity point moulding plucking emulsion paint have employed ultraviolet light cross-linking type elastic emulsion, to arrange in pairs or groups preferred color stuffing (i.e. titanium dioxide, process white, water-ground limestone and calcined kaolin), and coordinate its usage ratio, arranged in pairs or groups by the thickness of color stuffing, make that film is smooth, capillary-size pore is the least possible; Add and employ ultraviolet light cross-linking type elastic emulsion, the monomer under ultraviolet lighting in emulsion can carry out polyreaction further, improves hardness and the density of film coated surface, makes film coated surface not easily sticky ash.In addition, in system, add water-miscible paint toughener, under the prerequisite affecting paint film elongation at break hardly, improve tensile strength, density and the envelope alkalescence of film can also be improved simultaneously.The application's high dirt resistance elasticity point moulding plucking paint viscosity is 10-15 ten thousand mPas, it had both possessed snappiness (normal temperature elongation at break > 250%), there is again high dirt resistance (contamination resistance < 15%), and defoaming effect is good, paint film pin hole is few.
Described pH adjusting agent is 2-amino-2-methyl-1-propanol.
Described dispersion agent is one in ammonium polyacrylate dipersant or polycarboxylate sodium's dispersion agent or its combination.Described wetting agent is poly-hydroxyalkyl ether nonionic wetting agent.The consistency of the popular mill base (as Clariant, generation name etc.) on the high dirt resistance elasticity point moulding plucking emulsion paint that this preferred wetting and dispersing system (wetting and dispersing system comprises wetting agent and dispersion agent) makes to prepare and existing market is good, color developing is good, not loose colour can be ensured, make the toning of paint vehicle accurately, favorable reproducibility.
Described defoamer is one in mineral oil defoaming agent, water-based organic silicon defoamer or silicone-based defoamers or its arbitrary combination.Froth breaking difficulty is the common fault of high-viscosity latex paint (such as plucking paint), and the preferred antifoaming system of the application (antifoaming system comprises the reasonably combined of defoamer) makes, and the defoaming of the high dirt resistance elasticity point moulding plucking emulsion paint prepared is good, paint film pin hole is few.
Described frostproofer is ethylene glycol or propylene glycol.
Described film coalescence aid is alcohol ester-12.
Described thickening material is one in Mierocrystalline cellulose, alkali swelling type thickening material or polyurethanes thickening material or its arbitrary combination.
The preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 600-800rpm, Xiang Shuizhong adds wilkinite and mixes, and disperses 5-10min;
2. under the rotating speed of 600-800rpm, pH adjusting agent, dispersion agent, wetting agent, frostproofer, defoamer, titanium dioxide, process white, water-ground limestone and calcined kaolin is added in the mixture that 1. step is prepared, and disperse 15-20min, wherein, the consumption of defoamer is≤70% himself gross weight;
3. under the rotating speed of 600-800rpm, in the mixture that 2. step is prepared, add ultraviolet light cross-linking type elastic emulsion, Opacifying polymers, remaining defoamer, film coalescence aid, water-miscible paint toughener, fungicidal preservative, mould inhibitor successively, and disperse 3-5min;
4. under the rotating speed of 1000-1200rpm, in the mixture that 3. step is prepared, slowly add thickening material, and disperse 10-15min to mixing.
The preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint is efficient and convenient, is beneficial to and produces in batches.
Described step 2. in the consumption of defoamer be 1/2 of himself gross weight, use this preferred ratio to mix at twice, make defoamer defoaming effect in preparation process better.
Compared with prior art, the present patent application has the following advantages:
1) this high dirt resistance elasticity point moulding plucking emulsion paint can reach high dirt resistance (contamination resistance < 15%) and snappiness (normal temperature elongation at break > 250%) simultaneously;
2) preparation method's simple and fast, batch production is easy to management and control;
3) this high dirt resistance elasticity point moulding plucking emulsion paint color-adjustable and color developing is excellent;
4) the construction defoaming of this high dirt resistance elasticity point moulding plucking emulsion paint is good, and the pin hole of paint film is few.
Embodiment
Below in conjunction with each embodiment, technical scheme of the present invention is described in detail.
Raw material sources:
PH adjusting agent: Tao Shi AMP-95;
Dispersion agent: Sheng Nuopuke SN-5040, ROHM AND HAAS CA-2500;
Wetting agent: Sheng Nuopuke SN-WET996;
Frostproofer: Depew chemical industry propylene glycol, ethylene glycol;
Defoamer: extra large river NXZ, Sheng Nuopuke SN-345;
Wilkinite: ITCMIN-U-GEL400;
Titanium dioxide: Du Pont R-706;
Water-ground limestone: Jinpeng 800 order coarse whiting;
Calcined kaolin: cover the white calcined kaolin of western ultra-fine height;
Process white: two profit chemical industry CB-1250A;
Ultraviolet light cross-linking type elastic emulsion: BASF 7026G;
Opacifying polymers: Tao Shi Unihub E;
Film coalescence aid: Yi Shiman CS-12;
Water-miscible paint toughener: Kang Yu chemical industry RA-11;
Fungicidal preservative: Sol HF;
Mould inhibitor: Sol EPW;
Thickening material: ROHM AND HAAS ASE-60, ROHM AND HAAS TT-935, ROHM AND HAAS RM-8W.
Embodiment 1
A kind of high dirt resistance elasticity point moulding plucking emulsion paint, it is formulated by the component of following weight ratio:
The preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 700rpm, Xiang Shuizhong adds wilkinite and mixes, and disperses 8min;
2. under the rotating speed of 750rpm, 2-amino-2-methyl-1-propanol, ammonium polyacrylate dipersant, poly-hydroxyalkyl ether nonionic wetting agent, ethylene glycol, water-based organic silicon defoamer, titanium dioxide, process white, water-ground limestone and calcined kaolin is added in the mixture that 1. step is prepared, and disperse 18min, wherein, the consumption of water-based organic silicon defoamer is 1/2 of himself gross weight;
3. under the rotating speed of 700rpm, in the mixture that 2. step is prepared, add ultraviolet light cross-linking type elastic emulsion, Opacifying polymers, remaining water-based organic silicon defoamer, alcohol ester-12, water-miscible paint toughener, fungicidal preservative, mould inhibitor successively, and disperse 4min;
4. under the rotating speed of 1100rpm, in the mixture that 3. step is prepared, slowly add alkali swelling type thickening material, and disperse 12min to mixing.
Embodiment 2
A kind of high dirt resistance elasticity point moulding plucking emulsion paint, it is formulated by the component of following weight ratio:
The preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 600rpm, Xiang Shuizhong adds wilkinite and mixes, and disperses 10min;
2. under the rotating speed of 600rpm, 2-amino-2-methyl-1-propanol, ammonium polyacrylate dipersant, poly-hydroxyalkyl ether nonionic wetting agent, propylene glycol, mineral oil defoaming agent, titanium dioxide, process white, water-ground limestone and calcined kaolin is added in the mixture that 1. step is prepared, and disperse 20min, wherein, the consumption of mineral oil defoaming agent is 40% of himself gross weight;
3., under the rotating speed of 600rpm, in the mixture that 2. step is prepared, add ultraviolet light cross-linking type elastic emulsion, Opacifying polymers, remaining mineral oil defoaming agent, water-miscible paint toughener, fungicidal preservative, mould inhibitor successively, and disperse 5min;
3. under the rotating speed of 1000rpm, in the mixture that 3. step is prepared, slowly add alkali swelling type thickening material, and disperse 15min to mixing.
Embodiment 3
A kind of high dirt resistance elasticity point moulding plucking emulsion paint, it is formulated by the component of following weight ratio:
The preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 800rpm, Xiang Shuizhong adds wilkinite and mixes, and disperses 5min;
2. under the rotating speed of 800rpm, 2-amino-2-methyl-1-propanol, ammonium polyacrylate dipersant, poly-hydroxyalkyl ether nonionic wetting agent, ethylene glycol, mineral oil defoaming agent, titanium dioxide, process white, water-ground limestone and calcined kaolin is added in the mixture that 1. step is prepared, and disperse 15min, wherein, the consumption of mineral oil defoaming agent is 50% of himself gross weight;
3. under the rotating speed of 800rpm, in the mixture that 2. step is prepared, add ultraviolet light cross-linking type elastic emulsion, Opacifying polymers, remaining mineral oil defoaming agent, alcohol ester-12, water-miscible paint toughener, fungicidal preservative, mould inhibitor successively, and disperse 3min;
4. under the rotating speed of 1200rpm, in the mixture that 3. step is prepared, slowly add alkali swelling type thickening material, and disperse 10min to mixing.
Embodiment 4
The preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint, it comprises the step that next coming in order carry out:
The preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint, it comprises the step that next coming in order carry out:
1. under the rotating speed of 700rpm, Xiang Shuizhong adds wilkinite and mixes, and disperses 5min;
2. under the rotating speed of 750rpm, 2-amino-2-methyl-1-propanol, polycarboxylate sodium's dispersion agent, poly-hydroxyalkyl ether nonionic wetting agent, ethylene glycol, silicone-based defoamers, titanium dioxide, process white, water-ground limestone and calcined kaolin is added in the mixture that 1. step is prepared, and disperse 15min, wherein, the consumption of silicone-based defoamers is 50% of himself gross weight;
3. under the rotating speed of 800rpm, in the mixture that 2. step is prepared, add ultraviolet light cross-linking type elastic emulsion, Opacifying polymers, remaining silicone-based defoamers, alcohol ester-12, water-miscible paint toughener, fungicidal preservative, mould inhibitor successively, and disperse 3min;
4. under the rotating speed of 1200rpm, in the mixture that 3. step is prepared, slowly add alkali swelling type thickening material, and disperse 10min to mixing.
Embodiment 5
The difference of itself and embodiment 1 is:
Described dispersion agent is the mixture of ammonium polyacrylate dipersant and polycarboxylate sodium's dispersion agent.Described defoamer is the mixture of mineral oil defoaming agent and water-based organic silicon defoamer.Described thickening material is Mierocrystalline cellulose.
The step of the preparation method of this high dirt resistance elasticity point moulding plucking emulsion paint 2. in, the consumption of defoamer is 70% of himself gross weight.
Embodiment 6
The difference of itself and embodiment 2 is:
Described defoamer is the mixture of water-based organic silicon defoamer and silicone-based defoamers.Described thickening material is the mixture of Mierocrystalline cellulose and polyurethanes thickening material.Described pH adjusting agent is other kinds except 2-amino-2-methyl-1-propanol.
Embodiment 7
The difference of itself and embodiment 3 is:
Described defoamer is the mixture of mineral oil defoaming agent and silicone-based defoamers.Described thickening material is the mixture of Mierocrystalline cellulose and alkali swelling type thickening material.
Embodiment 8
The difference of itself and embodiment 4 is:
Described defoamer is the mixture of mineral oil defoaming agent, water-based organic silicon defoamer and silicone-based defoamers.Described thickening material is the mixture of alkali swelling type thickening material and polyurethanes thickening material.Described wetting agent is other kinds except poly-hydroxyalkyl ether nonionic wetting agent.Described film coalescence aid is other kinds except alcohol ester-12.
Embodiment 9
The difference of itself and embodiment 1 is: described defoamer is the mixture of water-based organic silicon defoamer and silicone-based defoamers.Described thickening material is the mixture of Mierocrystalline cellulose, alkali swelling type thickening material and polyurethanes thickening material.
Experimental data
Test the high dirt resistance elasticity point moulding plucking paint obtained by each embodiment according to standard JG/T172-2014 " elastic building paint ", every technical feature data are as shown in the table:
(referring to grind) color developing data of high dirt resistance elasticity point moulding plucking emulsion paint obtained by each embodiment are as shown in the table:
Shown by the practical application of the every experimental data in table and each embodiment, the properties of the high dirt resistance elasticity point moulding plucking emulsion paint in the present invention prepared by each embodiment all can meet and be better than the technical requirements of JG/T172-2014 " elastic building paint ", high dirt resistance (contamination resistance < 15%) and snappiness (normal temperature elongation at break > 250%) can be reached simultaneously, and this paint color-adjustable, the consistency of starching with current color on market is good, and mixed color developing is good.In addition, this preparation method's simple and fast, batch production are easy to management and control.
High dirt resistance elasticity point moulding plucking emulsion paint of the present invention and preparation method thereof has more than and is only confined to above-described embodiment, and every any improvement according to the principle of the invention or replacement, all should within protection scope of the present invention.
Claims (9)
1. a high dirt resistance elasticity point moulding plucking emulsion paint, is characterized in that: it is formulated by the component of following weight ratio,
2. high dirt resistance elasticity point moulding plucking emulsion paint according to claim 1, is characterized in that: described pH adjusting agent is 2-amino-2-methyl-1-propanol.
3. high dirt resistance elasticity point moulding plucking emulsion paint according to claim 1, it is characterized in that: described dispersion agent is one in ammonium polyacrylate dipersant or polycarboxylate sodium's dispersion agent or its combination, and described wetting agent is poly-hydroxyalkyl ether nonionic wetting agent.
4. high dirt resistance elasticity according to claim 1 point moulding plucking emulsion paint, is characterized in that: described defoamer is one in mineral oil defoaming agent, water-based organic silicon defoamer or silicone-based defoamers or its arbitrary combination.
5. high dirt resistance elasticity point moulding plucking emulsion paint according to claim 1, is characterized in that: described frostproofer is ethylene glycol or propylene glycol.
6. high dirt resistance elasticity point moulding plucking emulsion paint according to claim 1, is characterized in that: described film coalescence aid is alcohol ester-12.
7. high dirt resistance elasticity according to claim 1 point moulding plucking emulsion paint, is characterized in that: described thickening material is one in Mierocrystalline cellulose, alkali swelling type thickening material or polyurethanes thickening material or its arbitrary combination.
8. the preparation method of the high dirt resistance elasticity point moulding plucking emulsion paint according to any one of claim 1-7, is characterized in that: it comprises the step that next coming in order carry out,
1. under the rotating speed of 600-800rpm, Xiang Shuizhong adds wilkinite and mixes, and disperses 5-10min;
2. under the rotating speed of 600-800rpm, pH adjusting agent, dispersion agent, wetting agent, frostproofer, defoamer, titanium dioxide, process white, water-ground limestone and calcined kaolin is added in the mixture that 1. step is prepared, and disperse 15-20min, wherein, the consumption of defoamer is≤70% himself gross weight;
3. under the rotating speed of 600-800rpm, in the mixture that 2. step is prepared, add ultraviolet light cross-linking type elastic emulsion, Opacifying polymers, remaining defoamer, film coalescence aid, water-miscible paint toughener, fungicidal preservative, mould inhibitor successively, and disperse 3-5min;
4. under the rotating speed of 1000-1200rpm, in the mixture that 3. step is prepared, slowly add thickening material, and disperse 10-15min to mixing.
9. the preparation method of high dirt resistance elasticity according to claim 8 point moulding plucking emulsion paint, is characterized in that: described step 2. in the consumption of defoamer be 1/2 of himself gross weight.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510937066.8A CN105462315A (en) | 2015-12-15 | 2015-12-15 | High-stain-resistance elastic and tip-shaped broom-finish emulsion paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510937066.8A CN105462315A (en) | 2015-12-15 | 2015-12-15 | High-stain-resistance elastic and tip-shaped broom-finish emulsion paint and preparation method thereof |
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Cited By (5)
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| CN106752532A (en) * | 2016-12-29 | 2017-05-31 | 三棵树涂料股份有限公司 | A kind of antifouling weather-resistant type external wall elastic plucking paint and preparation method thereof |
| CN111808493A (en) * | 2020-07-28 | 2020-10-23 | 三棵树涂料股份有限公司 | Weather-resistant waterproof elastic napping paint and preparation method thereof |
| CN113637373A (en) * | 2021-09-06 | 2021-11-12 | 河北三棵树涂料有限公司 | High-performance elastic galling coating and preparation method thereof |
| CN114196276A (en) * | 2021-12-23 | 2022-03-18 | 三棵树(上海)新材料研究有限公司 | Waterproof exterior wall coating and preparation method thereof |
| CN115851050A (en) * | 2022-11-15 | 2023-03-28 | 湖北三棵树新材料科技有限公司 | Low-carbon environment-friendly high-performance elastic coating and preparation method thereof |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106752532A (en) * | 2016-12-29 | 2017-05-31 | 三棵树涂料股份有限公司 | A kind of antifouling weather-resistant type external wall elastic plucking paint and preparation method thereof |
| CN111808493A (en) * | 2020-07-28 | 2020-10-23 | 三棵树涂料股份有限公司 | Weather-resistant waterproof elastic napping paint and preparation method thereof |
| CN113637373A (en) * | 2021-09-06 | 2021-11-12 | 河北三棵树涂料有限公司 | High-performance elastic galling coating and preparation method thereof |
| CN114196276A (en) * | 2021-12-23 | 2022-03-18 | 三棵树(上海)新材料研究有限公司 | Waterproof exterior wall coating and preparation method thereof |
| CN115851050A (en) * | 2022-11-15 | 2023-03-28 | 湖北三棵树新材料科技有限公司 | Low-carbon environment-friendly high-performance elastic coating and preparation method thereof |
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