CN105461003A - Bagasse containing cyanobacteria treating agent and preparation method thereof - Google Patents

Bagasse containing cyanobacteria treating agent and preparation method thereof Download PDF

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Publication number
CN105461003A
CN105461003A CN201510912663.5A CN201510912663A CN105461003A CN 105461003 A CN105461003 A CN 105461003A CN 201510912663 A CN201510912663 A CN 201510912663A CN 105461003 A CN105461003 A CN 105461003A
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CN
China
Prior art keywords
parts
leaf powder
bagasse
cyanobacteria
treating agent
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510912663.5A
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Chinese (zh)
Inventor
章云
张贝尼
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Anhui Zhongri Agriculture Environmental Protection Technology Co Ltd
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Anhui Zhongri Agriculture Environmental Protection Technology Co Ltd
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Priority to CN201510912663.5A priority Critical patent/CN105461003A/en
Publication of CN105461003A publication Critical patent/CN105461003A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/286Treatment of water, waste water, or sewage by sorption using natural organic sorbents or derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/24Naturally occurring macromolecular compounds, e.g. humic acids or their derivatives
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3021Milling, crushing or grinding
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/30Processes for preparing, regenerating, or reactivating
    • B01J20/3078Thermal treatment, e.g. calcining or pyrolizing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/20Prevention of biofouling

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Micro-Organisms Or Cultivation Processes Thereof (AREA)

Abstract

The invention discloses a bagasse containing cyanobacteria treating agent. The bagasse containing cyanobacteria treating agent is characterized by being prepared from raw materials in parts by weight as follows: 15-20 parts of bagasse, 10-15 parts of palm shells, 5-10 parts of bamboo leaf powder, 3-5 parts of ginkgo leaf powder, 3-5 parts of eucommia leaf powder, 3-5 parts of diatomite, 2-4 parts of polyvinyl alcohol, 2-4 parts of aluminum chloride, 1-2 parts of magnesium chloride, 0.5-1 part of sodium silicate, 0.5-1 part of alums and 10-15 parts of a modification aid. The cyanobacteria treating agent is prepared through effective recycling of agriculture wastes, cyanobacteria in water can be effectively adsorbed and removed, the cyanobacteria removal speed is high, the effect is good, and the treating agent has certain sterilization, heavy metal removal and organic matter removal functions, is energy-saving, environment-friendly, good in economy, pollution-free, harmless and high in practicability and has excellent biological degradability and environment compatibility.

Description

A kind of bagasse blue algae treatment agent and preparation method thereof
Technical field
The present invention relates to water treatment field, be specifically related to a kind of bagasse blue algae treatment agent and preparation method thereof.
Background technology
Blue-green alga bloom is a kind of phenomenon that the blue-green algae rapid, high volume propagation in water body forms macroscopic blue-green algae colony or causes water body color to change, can at the floating algae mat gathering formation one deck green of water surface time serious, even algae slurry.In recent years, being on the rise of environmental pollution, especially the increasing the weight of of body eutrophication, cause blue-green alga bloom frequently to break out in water body, bring great inconvenience to the life of local resident, very serious to the threat of economic production and people ' s health.
At present, physical method, chemical process and biological process etc. are mainly contained to the prevention and control measure of blue-green algae.Physical method is common changes note Xin Shui, dig bed mud etc., but this method needs at substantial manpower and materials, and effectiveness comparison short-term, can not fundamentally solve blue-green alga bloom problem.Use the chemicals such as copper sulfate to play certain for algae effect, but the frequent chemicals etc. that uses easily destroys ecosystem population structure in aquaculture water, and to environment, there is toxicity.Biological method mainly contains microbial control and food chain control etc., and this method still takes effect comparatively slow, not easily in water body, sets up dynamic ecological balanced system.
Summary of the invention
The object of this invention is to provide a kind of bagasse blue algae treatment agent, consumption be few, except algae speed fast, can algal control sterilization, economy is high, and Environmental compatibility is good.
The present invention is achieved by the following technical solutions:
A kind of bagasse blue algae treatment agent, it is characterized in that, it is obtained by the raw material of following weight parts:
Bagasse 15-20, palm hull 10-15, bamboo leaf powder 5-10, ginkgo leaf powder 3-5, Eucommia Leaf Powder 3-5, diatomite 3-5, polyvinyl alcohol 2-4, aluminum chloride 2-4, magnesium chloride 1-2, water glass 0.5-1, alum 0.5-1, modified additive 10-15;
Wherein modified additive is made up of the raw material of following weight part:
Chitosan 2-4, gelatin 1-2, citric acid 1-2, hydroxypropyl-beta-cyclodextrin 1-2, maltodextrin 3-5, lauryl glucosyl 0.5-1, water 40-50;
The preparation method of modified additive is:
Citric acid and lauryl glucosyl are added to the water, 60-80 DEG C, 400-600r/min stirs after 0.5-1h and adds chitosan and gelatin, stir 4-8h under similarity condition, finally add hydroxypropyl-beta-cyclodextrin and maltodextrin 40-60 DEG C, 400-600r/min stirs 1-2h, to obtain final product.
A preparation method for bagasse blue algae treatment agent, is characterized in that, comprises the following steps:
(1) take raw material by weight, add the acetum 60-80 DEG C of stirring 4-8h of 6-8% after bagasse, palm hull, bamboo leaf powder, ginkgo leaf powder and Eucommia Leaf Powder being mixed by solid-liquid weight ratio 1:5-1:4, after filtration, obtain filter residue and filtrate respectively; To be mixed with diatomite by described filter residue and dry after stirring, 300-400 DEG C of process 6-8h, after cooling, grinding evenly, obtains component A;
(2) mix with polyvinyl alcohol and modified additive after the filtrate obtained in (1) being concentrated into the 1/30-1/25 of original volume, 80-90 DEG C, 600-800r/min stirs 0.5-1h, obtains B component;
(3) component A is mixed with B component, first 50-60 DEG C, 800-1000r/min stirs 1-2h, then grind 0.5-1h, add all the other raw materials after 80-90 DEG C of drying and again grind evenly, after packing and get final product.
Advantage of the present invention is:
1. the present invention adopts bagasse, palm hull, polyvinyl alcohol, chitosan etc. to prepare blue algae treatment agent as raw material, by the synergy between each component, charge neutrality is utilized to combine with adsorption bridging effect, active adsorption and the blue-green algae of removing in water body, except algae speed is fast, effective, and there is certain sterilization, removing heavy metals, organic matter removal effect, practical;
2. effective recycling agricultural waste, energy-conserving and environment-protective, good economy performance, and there is good biological degradability and Environmental compatibility, pollution-free nuisanceless.
Embodiment
Non-limiting examples of the present invention is as follows:
A kind of bagasse blue algae treatment agent, is prepared from by the component raw material of following weight (kg):
Bagasse 18, palm hull 12, bamboo leaf powder 8, ginkgo leaf powder 4, Eucommia Leaf Powder 4, diatomite 4, polyvinyl alcohol 3, aluminum chloride 3, magnesium chloride 1.5, water glass 0.8, alum 0.8, modified additive 12;
Wherein, modified additive is made up of the raw material of following weight part:
Chitosan 3, gelatin 1.5, citric acid 1.5, hydroxypropyl-beta-cyclodextrin 1.5, maltodextrin 4, lauryl glucosyl 0.8, water 45;
The preparation method of modified additive is:
Citric acid and lauryl glucosyl are added to the water, 80 DEG C, 400r/min stirs after 0.5h and add chitosan and gelatin, stirs 6h under similarity condition, finally add hydroxypropyl-beta-cyclodextrin and maltodextrin 40 DEG C, 600r/min stir 1h, to obtain final product.
The preparation method of bagasse blue algae treatment agent comprises the following steps:
(1) take raw material by weight, add the acetum 80 DEG C stirring 6h of 8% after bagasse, palm hull, bamboo leaf powder, ginkgo leaf powder and Eucommia Leaf Powder being mixed by solid-liquid weight ratio 1:5, after filtration, obtain filter residue and filtrate respectively; To be mixed with diatomite by described filter residue and dry after stirring, 400 DEG C of process 8h, after cooling, grinding evenly, obtains component A;
(2) mix with polyvinyl alcohol and modified additive after the filtrate obtained in (1) being concentrated into 1/30 of original volume, 90 DEG C, 800r/min stirs 0.5h, obtains B component;
(3) component A is mixed with B component, first 60 DEG C, 1000r/min stirs 1h, then grind 0.5h, add all the other raw materials after 90 DEG C of dryings and again grind evenly, after packing and get final product.
The blue algae treatment agent that obtains of inspection the present embodiment except algae effect, result is as follows:
Before process, stoste Cells of Blue-green Algae concentration is about 1 × 10 7cells/mL, after adding treatment agent by 10mg/L, 10min removes algae efficiency is 94.1%.

Claims (2)

1. a bagasse blue algae treatment agent, is characterized in that, it is obtained by the raw material of following weight parts:
Bagasse 15-20, palm hull 10-15, bamboo leaf powder 5-10, ginkgo leaf powder 3-5, Eucommia Leaf Powder 3-5, diatomite 3-5, polyvinyl alcohol 2-4, aluminum chloride 2-4, magnesium chloride 1-2, water glass 0.5-1, alum 0.5-1, modified additive 10-15;
Described modified additive is made up of the raw material of following weight part:
Chitosan 2-4, gelatin 1-2, citric acid 1-2, hydroxypropyl-beta-cyclodextrin 1-2, maltodextrin 3-5, lauryl glucosyl 0.5-1, water 40-50;
The preparation method of described modified additive is:
Citric acid and lauryl glucosyl are added to the water, 60-80 DEG C, 400-600r/min stirs after 0.5-1h and adds chitosan and gelatin, stir 4-8h under similarity condition, finally add hydroxypropyl-beta-cyclodextrin and maltodextrin 40-60 DEG C, 400-600r/min stirs 1-2h, to obtain final product.
2. the preparation method of a kind of bagasse blue algae treatment agent according to claim 1, is characterized in that, comprise the following steps:
(1) take raw material by weight, add the acetum 60-80 DEG C of stirring 4-8h of 6-8% after bagasse, palm hull, bamboo leaf powder, ginkgo leaf powder and Eucommia Leaf Powder being mixed by solid-liquid weight ratio 1:5-1:4, after filtration, obtain filter residue and filtrate respectively; To be mixed with diatomite by described filter residue and dry after stirring, 300-400 DEG C of process 6-8h, after cooling, grinding evenly, obtains component A;
(2) mix with polyvinyl alcohol and modified additive after the filtrate obtained in (1) being concentrated into the 1/30-1/25 of original volume, 80-90 DEG C, 600-800r/min stirs 0.5-1h, obtains B component;
(3) component A is mixed with B component, first 50-60 DEG C, 800-1000r/min stirs 1-2h, then grind 0.5-1h, add all the other raw materials after 80-90 DEG C of drying and again grind evenly, after packing and get final product.
CN201510912663.5A 2015-12-11 2015-12-11 Bagasse containing cyanobacteria treating agent and preparation method thereof Pending CN105461003A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105753090A (en) * 2016-04-12 2016-07-13 芜湖凯奥尔环保科技有限公司 Blue-green alga treatment agent with deodorization effect and preparation method of blue-green alga treatment agent
CN105831173A (en) * 2016-04-12 2016-08-10 芜湖凯奥尔环保科技有限公司 A blue-green algae treating agent containing waste tobacco stems and a preparing method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234809A (en) * 2008-02-22 2008-08-06 合肥市东方美捷分子材料技术有限公司 Ecological algae flocculating material
US20110318798A1 (en) * 2010-06-24 2011-12-29 Cobalt Technologies, Inc. Removal of inhibitors of microbial fermentation from inhibitor-containing compositions
JP2012179589A (en) * 2011-02-10 2012-09-20 Sony Corp Decontaminant, carbon/polymer composite, decontamination sheet member and filter material
CN104472565A (en) * 2014-11-03 2015-04-01 芜湖市祥荣食品有限公司 Kaolin composite processing agent for blue-green algae and preparation method thereof
CN104591345A (en) * 2014-12-26 2015-05-06 安徽省中日农业环保科技有限公司 Plaster-base cyanobacteria treating agent and preparation method thereof
CN104604948A (en) * 2014-12-26 2015-05-13 安徽省中日农业环保科技有限公司 Blue algae treating agent prepared from kelp and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101234809A (en) * 2008-02-22 2008-08-06 合肥市东方美捷分子材料技术有限公司 Ecological algae flocculating material
US20110318798A1 (en) * 2010-06-24 2011-12-29 Cobalt Technologies, Inc. Removal of inhibitors of microbial fermentation from inhibitor-containing compositions
JP2012179589A (en) * 2011-02-10 2012-09-20 Sony Corp Decontaminant, carbon/polymer composite, decontamination sheet member and filter material
CN104472565A (en) * 2014-11-03 2015-04-01 芜湖市祥荣食品有限公司 Kaolin composite processing agent for blue-green algae and preparation method thereof
CN104591345A (en) * 2014-12-26 2015-05-06 安徽省中日农业环保科技有限公司 Plaster-base cyanobacteria treating agent and preparation method thereof
CN104604948A (en) * 2014-12-26 2015-05-13 安徽省中日农业环保科技有限公司 Blue algae treating agent prepared from kelp and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105753090A (en) * 2016-04-12 2016-07-13 芜湖凯奥尔环保科技有限公司 Blue-green alga treatment agent with deodorization effect and preparation method of blue-green alga treatment agent
CN105831173A (en) * 2016-04-12 2016-08-10 芜湖凯奥尔环保科技有限公司 A blue-green algae treating agent containing waste tobacco stems and a preparing method thereof

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Application publication date: 20160406

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