CN105459240B - The equipment that a kind of microwave vacuum method reduces artificial board formaldehyde burst size - Google Patents

The equipment that a kind of microwave vacuum method reduces artificial board formaldehyde burst size Download PDF

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Publication number
CN105459240B
CN105459240B CN201510787578.0A CN201510787578A CN105459240B CN 105459240 B CN105459240 B CN 105459240B CN 201510787578 A CN201510787578 A CN 201510787578A CN 105459240 B CN105459240 B CN 105459240B
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CN
China
Prior art keywords
microwave
formaldehyde
equipment
hatch door
row
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Expired - Fee Related
Application number
CN201510787578.0A
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Chinese (zh)
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CN105459240A (en
Inventor
朱新华
杨培
郭文川
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Northwest A&F University
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Northwest A&F University
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Priority to CN201510787578.0A priority Critical patent/CN105459240B/en
Publication of CN105459240A publication Critical patent/CN105459240A/en
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Publication of CN105459240B publication Critical patent/CN105459240B/en
Expired - Fee Related legal-status Critical Current
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/003Treating of wood not provided for in groups B27K1/00, B27K3/00 by using electromagnetic radiation or mechanical waves
    • B27K5/0065Ultrasonic treatment
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K2200/00Wooden materials to be treated
    • B27K2200/10Articles made of particles or fibres consisting of wood or other lignocellulosic material

Abstract

The present invention discloses the equipment that a kind of microwave vacuum method reduces artificial board formaldehyde burst size, belongs to the formaldehyde reduced apparatus field of woodwork microwave.The microwave action chamber of the equipment is cylindrical shape, is horizontally mounted, charging hatch door and discharging hatch door of the two ends provided with spherical crown shape, and form is respectively equipped with charging hatch door and discharging hatch door;On the cylinder inner wall of the left and right sides mouth is presented along cylinder generatrix direction at least provided with the equally distributed microwave of a row;Multiple temperature sensors and a vacuum meter are housed in microwave action intracavitary portion;Temperature sensor, vacuum meter are connected with controller respectively;The bottom of microwave action chamber is provided with guide rail, parks and passes through for material conveying trolley, and material conveying trolley is provided with the row's roller for placing wood-based plate;Microwave action chamber is sequentially connected vavuum pump and formaldehyde retracting device by pipeline.The equipment can efficiently solve the problem of artificial board formaldehyde burst size is exceeded, and meet the demand of industrial production of serialization and mass.

Description

The equipment that a kind of microwave vacuum method reduces artificial board formaldehyde burst size
Technical field
The industrial equipment of artificial board formaldehyde is reduced the present invention relates to a kind of, belongs to the formaldehyde reduced apparatus field of woodwork microwave.
Background technology
Urea-formaldehyde resin adhesive due to function admirable, it is with low cost the advantages of and as production wood-based plate main glue kind, But this kind of wood-based plate is often due to burst size of methanal is exceeded and seriously endangers health.Improve adhesive, addition formaldehyde catching Agent and the content of formaldehyde in wood-based plate can be reduced to a certain extent using the method such as rational wood-based plate heat pressing process, but by In sheet material mechanical property to be considered, production cost and presentation quality etc., the effect of above method reduction burst size of methanal is limited, So that substantial amounts of free formaldehyde still may be discharged in the artificial board finished product of production.
Therefore, wood-based plate also needs to carry out the drop aldehyde processing in later stage, veneer edge sealing is that current wood-based panel industry is generally used Drop aldehyde method, its role is on the one hand limit the Form aldehyde release of wood-based plate, on the other hand also prevent wood-based plate moisture absorption So that urea-formaldehyde resin adhesive occurs to hydrolyze and release formaldehyde, and but if breakage once occurs for finishing material, its inner accumulation Formaldehyde can discharge at double, therefore, this method can not fundamentally reduce the burst size of methanal of wood-based plate.Hot ammonia treatment energy The formaldehyde in wood-based plate is effectively eliminated, but ammonia consumption is larger, and processing procedure is slow, and complicated huge processing equipment So that cost is too high.Application of vacuum be utilize artificial intralamellar part and external environment are produced under condition of negative pressure concentration of formaldehyde difference so as to Promote the process of free formaldehyde release, however, individually application of vacuum is to the separation of wood-based plate inside formaldehyde molecule and diffusion Influence is smaller, therefore less efficient.The degraded effect for the formaldehyde gas that dielectric barrier discharge facture is discharged to wood-based plate Rate is higher, but the commercial Application of large-scale needs further to suppress the generation of harmful side product, increases reaction selectivity, reduction Energy consumption and operating cost.
The drop aldehyde methods and techniques in above-mentioned various wood-based plate later stages suffer from treatment effeciency, energy consumption, pollution and operation The limitation of the factors such as cost and be difficult to be applied in wood-based panel industry on a large scale.
The content of the invention
The problem of artificial board formaldehyde burst size is exceeded is solved in order to effective, and for being asked present in above-mentioned prior art Topic and defect, it is an object of the invention to provide the equipment that a kind of microwave vacuum method reduces artificial board formaldehyde burst size.
To achieve these goals, the present invention uses following design:
A kind of microwave vacuum method reduces the equipment of artificial board formaldehyde burst size, the microwave action chamber of the equipment(3)For cylinder Shape, is horizontally mounted, and can improve the uniformity of microwave distribution, also meet the design requirement of general pressure vessel;In microwave action Charging hatch door and discharging hatch door of the two ends of chamber provided with spherical crown shape, to prevent microwave leakage and keep the true of microwave action intracavitary portion Reciprocal of duty cycle.
Form is respectively equipped with charging hatch door and discharging hatch door, its inner case can be observed.
It is uniformly distributed on the left and right sides cylindrical wall in microwave action intracavitary portion along cylinder generatrix direction at least provided with a row Microwave feedback mouth, and often row include at least two microwaves feedback mouth, with improve microwave be distributed uniformity and microwave treatment efficiency; Microwave feedback mouth is connected with magnetron and controller successively.
Multiple temperature sensors and a vacuum meter are housed in microwave action intracavitary portion;Temperature sensor, vacuum meter difference It is connected with controller, the temperature in wood-based plate processing procedure and vacuum can be in real time measured.
The bottom of microwave action chamber is provided with guide rail, parks and passes through for material conveying trolley, and material conveying trolley is provided with and is horizontally mounted Multilayer row's roller, can correspondingly place multilayer wood-based plate, the conveying direction for arranging roller is identical with cylinder generatrix direction, is easy to artificial Plate is loaded and unloaded, and the distance between adjacent two layers row's roller is at least twice of artificial board thickness, to increase microwave action in artificial The area of plate and the rate of release for accelerating wood-based plate formaldehyde in processing procedure.
The microwave action chamber of the equipment is sequentially connected vavuum pump and formaldehyde retracting device by pipeline;Vavuum pump is made for microwave The formaldehyde gas that certain negative pressure is provided with intracavitary portion and makes wood-based plate be produced in processing procedure enters first by sealing pipeline Aldehyde retracting device, the formaldehyde of recovery can be used as the raw material for producing urea-formaldehyde resin adhesive after certain post-processing;Institute The formaldehyde retracting device stated reclaims formaldehyde using the principle of washing.
Described equipment can select the microwave that frequency is 915MHz or 2450MHz according to thickness, useful load of wood-based plate etc. Wood-based plate is handled.
Described charging hatch door and discharging hatch door is provided with screen layer and sealant.
Described controller can be to the display of temperature, vacuum and microwave input power, record and regulation and control.
The present invention operation principle be:
Formaldehyde is divided into two stages as the release of major pollutants, is the formaldehyde point in the presence of concentration gradient first Son moved about from the sandwich layer of material to material interface, then on gas-solid interface, due to external environmental factor, molecular motion and The presence of material hole, some formaldehyde molecules depart from material surface in the presence of concentration gradient again, enter the external world of surrounding It is then rapid to be well mixed in small space in environment, as the exchange of gas is pulled away and progressivelyes reach balance.Therefore, exist Increase the content of formaldehyde that separation and diffusion energy of the formaldehyde inside wood-based plate are effectively reduced in wood-based plate in processing procedure, and increase The concentration difference of formaldehyde is then conducive to accelerating the evaporation rate of formaldehyde inside and outside big sheet material.
The temperature of artificial plate surface is less than core layer temperature in microwave heating process, the low inside and high outside moisture content ladder with wood-based plate Degree is identical, and this moisture speeded up in wood-based plate is moved and from surface evaporation from inside to outside, so as to be formaldehyde point in wood-based plate The migration of son provides passage and driving force.The formaldehyde that wood-based plate inevitably has sandwich layer during the manufacturing contains Amount is higher than top layer, and formaldehyde has characteristic soluble in water, therefore, while moisture loss has also taken away the first in wood-based plate Aldehyde.In addition, formaldehyde as a kind of polar molecule by can also accelerate rate of release during microwave action.Meanwhile, in the work of vavuum pump Under, the negative pressure that microwave microwave action intracavitary is produced adds the concentration difference of formaldehyde gas inside and outside sheet material, is also beneficial to formaldehyde Volatilization.The formaldehyde gas that wood-based plate is produced in processing procedure enters formaldehyde under the swabbing action of vavuum pump by sealing pipeline Retracting device, the formaldehyde of collection can be used as the raw material for producing urea-formaldehyde resin adhesive after certain processing.
Therefore, the invention can be handled wood-based plate progress drop aldehyde efficient, in batches, continuously, and can realize pollutant Recycling.
Brief description of the drawings
Fig. 1 is system structure diagram of the invention
Fig. 2 is microwave action cavity configuration schematic diagram of the invention
Fig. 3 is row's roller schematic diagram of the invention
Wherein, 1. form, 2. charging hatch doors, 3. microwave action chambers, 4. temperature sensors, 5. wood-based plates, 6. row's rollers, 7. Material conveying trolley, 8. microwaves feedback mouth, 11. controllers, 12. guide rails, 13 vacuum meters, 14. vavuum pumps, 15 formaldehyde retracting devices, 16. Discharge hatch door.
Embodiment
Below in conjunction with the accompanying drawings and the present invention will be further described by embodiment.
The equipment using microwave vacuum technology to wood-based plate carry out drop aldehyde processing, microwave operational frequencies be 915MHz or 2450MHz, the microwave equipment cost that frequency is 915MHz is higher than the microwave equipment that frequency is 2450MHz, but the former is with bigger Penetration depth, therefore, in industrial production can according to the concrete conditions such as thickness, the useful load of handled wood-based plate select microwave Frequency.
The microwave action chamber 3 of the equipment is cylindrical shape, is horizontally mounted, and can improve the uniformity of microwave distribution, also meet The design requirement of general pressure vessel, in produce reality, the size of big I wood-based plate handled by of microwave action chamber Specification makes the appropriate adjustments.
Charging hatch door 2 and discharging hatch door 16 of the equipment provided with spherical crown shape, charging hatch door 2 and discharging hatch door 16 are provided with screen Layer and sealant are covered, to prevent microwave leakage and keep the vacuum in microwave action intracavitary portion, charging hatch door 2 and discharging hatch door 16 Form 1 is provided with, its inner case can be observed when the equipment works.
It is uniform at least provided with a row along cylinder generatrix direction on left and right sides cylindrical wall inside the equipment microwave action chamber 3 The microwave feedback mouth 8 of distribution, and often row includes at least two microwaves feedback mouth 8, to improve the uniformity and microwave treatment of microwave distribution Efficiency, microwave feedback mouth 8 microwave feedback mouth is connected with magnetron and controller 11 successively, microwave system using INDIRECT COUPLING energy regenerative Mode prevents gas breakdown and arcing electric discharge phenomena to reduce the power density of energy regenerative coupling aperture.
Temperature sensor 4, the vacuum meter 13 of the equipment are connected with controller 11 respectively, can be realized to people by controller 11 Make the temperature in plate processing procedure, the display of vacuum and microwave input power, record and regulate and control.
The bottom of the equipment microwave action chamber is provided with guide rail 12, parks and passes through for material conveying trolley 7, is set on material conveying trolley 7 There is the multilayer row's roller 6 being horizontally mounted, can correspondingly place multilayer wood-based plate 5, arrange the conveying direction and cylinder generatrix direction phase of roller 6 Together, it is easy to load and unload wood-based plate, the distance between adjacent two layers row's roller is at least twice of artificial board thickness, micro- to increase Ripple acts on the area of wood-based plate and accelerates the rate of release of wood-based plate formaldehyde in processing procedure.
The microwave action chamber 3 of the equipment is sequentially connected vavuum pump 14 and formaldehyde retracting device 15, vavuum pump 14 by pipeline The formaldehyde gas for providing certain negative pressure for the inside of microwave action chamber 3 and making wood-based plate be produced in processing procedure passes through seal pipe Road enters formaldehyde retracting device 15, and the formaldehyde of recovery can be used as production urea-formaldehyde resin adhesive after certain post-processing Raw material.

Claims (2)

1. the equipment that a kind of microwave vacuum method reduces artificial board formaldehyde burst size, it is characterised in that:The microwave action chamber of the equipment (3)For cylindrical shape, it is horizontally mounted;The charging hatch door of spherical crown shape is provided with the two ends of microwave action chamber(2)With discharging hatch door(16), Feed hatch door(2)With discharging hatch door(16)On be respectively equipped with form(1);In microwave action chamber(3)Internal left and right sides cylinder On wall mouth is presented along cylinder generatrix direction at least provided with the equally distributed microwave of a row(8);Microwave presents mouth(8)Successively with magnetron and Controller(11)It is connected;In microwave action chamber(3)Inside is equipped with multiple temperature sensors(4)With a vacuum meter(13);Temperature Sensor(4), vacuum meter(13)Respectively with controller(11)It is connected;Microwave action chamber(3)Bottom be provided with guide rail(12), for fortune Trolley(7)Park and pass through, material conveying trolley(7)Provided with placement wood-based plate(5)Row's roller(6);The microwave action of the equipment Chamber(3)Vavuum pump is sequentially connected by pipeline(14)With formaldehyde retracting device(15);
The microwave frequency of described equipment is 915MHz or 2450MHz;
Described charging hatch door(2)With discharging hatch door(16)It is provided with screen layer and sealant;
Described controller(11)To the display of temperature, vacuum and microwave input power, record and it can regulate and control;
Described formaldehyde retracting device(15)Formaldehyde is reclaimed using the principle of washing;
Material conveying trolley(7)On row's roller(6)It is horizontally mounted, the distance between adjacent two layers row's roller is at least the two of artificial board thickness Times, arrange roller(6)Conveying direction it is identical with cylinder generatrix direction.
2. the equipment that a kind of microwave vacuum method according to claim 1 reduces artificial board formaldehyde burst size, it is characterised in that Described equipment is suitable to the woodwork for applying urea-formaldehyde resin adhesive.
CN201510787578.0A 2015-11-17 2015-11-17 The equipment that a kind of microwave vacuum method reduces artificial board formaldehyde burst size Expired - Fee Related CN105459240B (en)

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Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106078988B (en) * 2016-08-02 2017-09-15 长沙源韵机械科技有限责任公司 Accelerate the voltage pulse electric field processing device of Form aldehyde release inside artificial wooden sheet material
CN106808543B (en) * 2017-01-09 2018-06-29 上海戊丰环保科技有限公司 A kind of method that formaldehyde in wood-based plate is removed using microwave
CN114451513B (en) * 2022-01-07 2023-05-02 西北农林科技大学 Method for degrading endogenous formaldehyde of food by immersing Glu-Cys solution and coupling pulse strong light

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1280662A (en) * 1997-10-30 2001-01-17 林业开发工业公司 Method for drying saw timber and device for implementing said method
CN101439529A (en) * 2008-12-23 2009-05-27 罗玉成 Microwave vacuum drying and carbonizing device and method for wood
CN205219348U (en) * 2015-11-17 2016-05-11 西北农林科技大学 Microwave vacuum method reduces equipment of wood -based plate formaldehyde emission volume

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101318347B (en) * 2008-07-01 2010-09-01 合肥溢新微波能科技有限公司 Microwave energy artificial board processor

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1280662A (en) * 1997-10-30 2001-01-17 林业开发工业公司 Method for drying saw timber and device for implementing said method
CN101439529A (en) * 2008-12-23 2009-05-27 罗玉成 Microwave vacuum drying and carbonizing device and method for wood
CN205219348U (en) * 2015-11-17 2016-05-11 西北农林科技大学 Microwave vacuum method reduces equipment of wood -based plate formaldehyde emission volume

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