CN105440823A - Water-soluble anticorrosive coating prepared by means of polished tile white mud waste and styrene-acrylic emulsion and preparation method thereof - Google Patents
Water-soluble anticorrosive coating prepared by means of polished tile white mud waste and styrene-acrylic emulsion and preparation method thereof Download PDFInfo
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- CN105440823A CN105440823A CN201610046977.6A CN201610046977A CN105440823A CN 105440823 A CN105440823 A CN 105440823A CN 201610046977 A CN201610046977 A CN 201610046977A CN 105440823 A CN105440823 A CN 105440823A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
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- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
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Abstract
The invention provides a water-soluble anticorrosive coating prepared by means of polished tile white mud waste and styrene-acrylic emulsion. The water-soluble anticorrosive coating is prepared from a coalescing agent, the styrene-acrylic emulsion, polished tile white mud waste micro powder, graphite, a defoaming agent and a corrosion remover. The obtained anticorrosive coating is good in acid resistance, will not disengage or deform or blister after being soaked with 10% hydrochloric acid for 1000 h, will not disengage or deform or blister after being soaked with 10% sulfuric acid for 1000 h and will not disengage or deform or blister after being soaked with 10% nitric acid for 1000 h; a paint film does not change and has no crack after the coating is soaked with 40% hydrofluoric acid for 90 d, and the surface is whitened and softened; the alkali resistance is good, and no change is formed after the coating is soaked with 10% NaOH for 1000 h; the coating is resistant to high temperature, baking is performed at the temperature of 150 DEG C for 200 h, and the film becomes softened and is recovered after being cooled; the salt fog resistance is good, and no blister or rust exists after salt fog is resisted for 1000 h; the watertightness is good and is achieved at 0.3 MPa for 30 min.
Description
Technical field
The present invention relates to and a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion and preparation method thereof, belong to protective system technical field.
Background technology
Along with the propelling of expanding economy and urbanization process, building trade obtains the development of advancing by leaps and bounds, according to statistics, within 2014, China's ceramic tile output reaches 14,000,000,000 square metres, wherein polished tile accounts for 20-30%, in the grinding and polishing operation of ceramic polished brick, usually will from adobe surface removal 0.5-0.7 millimeter upper layer, sometimes even up to 1-2 millimeter, so produce 1 square metre of polished tile and will form the brick bits of about 1.5-2.0 kilogram, calculate by this, the quantum of output of the annual polished tile polished waste material of China can reach 6,000,000; Someone utilizes these useless powder to prepare light ceramic material at present, but major part still adopts landfill method process, causes serious environmental pollution and the wasting of resources.
Protective system, is generally divided into conventional protective system and heavy-duty coating, is requisite a kind of coating in paint.Conventional protective system is under general condition; etch-proof effect is played to metal etc.; the life-span that protection non-ferrous metal uses; heavy-duty coating refers to relatively conventional protective system; can apply in relatively harsh corrosive environment, and there is a class protective system that can reach the protection period longer than conventional protective system.Protective system is generally made up of five large class raw materials, i.e. grease, resin, pigment, other subsidiary material of solvent, grease is main film forming substance, and it is the most basal component of material, if do not have them just can not form attachment about firm paint film on a surface of an, it is generally also claimed to be sticking agent.Solvent and other subsidiary material are the auxiliary film forming matters in coating composition, and be also indispensable, it is conducive to the construction of coating, and can improve the performance of paint film, as improved the levelling property of coating in construction, prevent painting from growing dim, sagging, pin hole etc.In recent years, China had progressively eliminated the rust-inhibiting paint containing heavy metal compounds such as Hg, Cr, Pb, promoted the rust-stabilising pigments such as nontoxic zinc phosphate, aluminum phosphate.
There is following technical problem in existing protective system:
(1) the acidproof time is short, and acidproof kind is single, not hydrofluoric acid resistant;
(2) the alkaline-resisting time is short, and resistance to paper mill wastewater is low;
(3) resistance to elevated temperatures is poor;
(4) salt-fog resistant time is short;
(5) water resistance is poor;
(6) cost is higher.
Summary of the invention
For solving in prior art the technical problem existed, the invention provides and a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion and preparation method thereof, to realize following goal of the invention:
(1) protective system prepared of the present invention, acid resistance is good, and 10% salt acid soak 1000h does not come off, indeformable, non-foaming; 10% sulfuric acid soaks 1000h, does not come off, indeformable, non-foaming; 10% nitric acid dousing 1000h, does not come off, indeformable, non-foaming; The hydrofluoric acid dips of 40% 90 days, paint film does not change, crack-free, some whiting of surface, deliquescing;
(2) protective system prepared of the present invention, alkali resistance is good, and the NaOH of 10% soaks 1000h, unchanged;
(3) protective system prepared of the present invention, high temperature resistant, 150 DEG C of baking 200h, and paint film deliquescing, restores to the original state after cooling;
(4) protective system prepared of the present invention, salt fog resistance is good, salt spray resistance 1000h, without bubble and rust staining;
(5) protective system prepared of the present invention, watertightness is good, and 0.3MPa, 30min are waterproof;
(6) refuse reclamation, cost-saving.
For solving the problems of the technologies described above, the technical scheme that the present invention takes is as follows:
Utilize polished tile white clay waste, a water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: raw material comprises film coalescence aid, benzene emulsion, polished tile white clay waste, graphite, defoamer, sanitas.
Below the further improvement to technique scheme:
Raw material also comprises deionized water, dispersion agent, AMP-95, the agent of anti-sudden strain of a muscle rust, quartz sand, thickening material.
Described protective system, with parts by weight, comprise following feed composition: deionized water 0-20 part, dispersion agent 0-6 part, AMP-950-3 part, anti-sudden strain of a muscle rust agent 0-6 part, film coalescence aid 25-36 part, benzene emulsion 300-650 part, polished tile white clay waste micro mist 300-400 part, quartz sand 0-600 part, graphite 20-100 part, defoamer 1-3 part, sanitas 1-3 part, thickening material 0-10 part;
Described protective system, with parts by weight, comprise following feed composition: deionized water 0-20 part, dispersion agent 3-6 part, AMP-951.5-3 part, anti-sudden strain of a muscle rust agent 3-6 part, film coalescence aid 25-33 part, benzene emulsion 300-650 part, polished tile white clay waste micro mist 300-400 part, quartz sand 500-600 part, graphite 20-100 part, defoamer 1-3 part, sanitas 1-3 part, thickening material 3-10 part.
Described polished tile white clay waste micro mist, with parts by weight, comprise silicon-dioxide 64-69 part, aluminum oxide 18-22 part, ferric oxide 0.5-0.9 part, calcium oxide 1.1-1.5 part, magnesium oxide 1.1-1.4 part, sulphur trioxide 0.23-0.27 part, sodium oxide 0.8-1.2 part, potassium oxide 0.6-0.9 part, chlorion 0.008-0.011 part; Loss on ignition is 5.45-5.88%.
Described film coalescence aid is alcohol ester 12 or ethylene glycol monobutyl ether; Described graphite, particle diameter is 2000-3000 order.
Described defoamer, model is UC-9557; Described sanitas, model is UC-C23; Described benzene emulsion is styrene-acrylate emulsion.
Described dispersion agent, model is UC-6088; The agent of described anti-sudden strain of a muscle rust, model is 102; Described thickening material, model is HS-60.
Described graphite is the one in nano-graphite or Graphene fragment; Described nano-graphite, particle diameter is 8000-10000 order.
Utilize polished tile white clay waste, a method that benzene emulsion prepares water-based anticorrosive paint, comprise the preparation of polished tile white clay waste micro mist, add auxiliary agent, add benzene emulsion, add graphite, polished tile white clay waste micro mist; The preparation of described polished tile white clay waste micro mist, polished tile white clay waste is through airing, and moisture content reaches less than 5%, pulverizes, and obtains the above micro mist of 1000 order; Describedly add auxiliary agent, stir 5 minutes, rotating speed is 200-260 rev/min; Describedly add benzene emulsion, stir 5 minutes, rotating speed is 200-260 rev/min; Describedly add graphite, polished tile white clay waste micro mist, speedup, to 400-500 rev/min, adds graphite, polished tile white clay waste micro mist successively after stirring, and continues stirring 30 minutes.
Compared with prior art, beneficial effect of the present invention is:
(1) protective system prepared of the present invention, acid resistance is good, and 10% salt acid soak 1000h does not come off, indeformable, non-foaming; 10% sulfuric acid soaks 1000h, does not come off, indeformable, non-foaming; 10% nitric acid dousing 1000h, does not come off, indeformable, non-foaming; The hydrofluoric acid dips of 40% 90 days, paint film does not change, crack-free, some whiting of surface, deliquescing;
(2) protective system prepared of the present invention, alkali resistance is good, and the NaOH of 10% soaks 1000h, unchanged;
(3) protective system prepared of the present invention, high temperature resistant, 150 DEG C of baking 200h, and paint film deliquescing, restores to the original state after cooling;
(4) protective system prepared of the present invention, salt fog resistance is good, salt spray resistance 1000h, without bubble and rust staining;
(5) protective system prepared of the present invention, watertightness is good, and 0.3MPa, 30min are waterproof;
(6) the present invention is by polished tile white clay refuse reclamation, cost-saving 20-30%.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein is only for instruction and explanation of the present invention, is not intended to limit the present invention.
The water-based anticorrosive paint that embodiment 1 one kinds utilizes polished tile white clay waste, prepared by benzene emulsion
With parts by weight, comprise following feed composition:
Deionized water 15 parts
Dispersion agent 5 parts
AMP-952.5 part
The agent 5 parts of anti-sudden strain of a muscle rust
Film coalescence aid 30 parts
Benzene emulsion 550 parts
Polished tile white clay waste micro mist 360 parts
Quartz sand 0 part
50 parts, graphite
Defoamer 2 parts
Sanitas 1.5 parts
Thickening material 5 parts;
Described graphite, particle diameter is 2000-3000 order;
Described dispersion agent, model is UC-6088;
The agent of described anti-sudden strain of a muscle rust, model is 102;
Described film coalescence aid is alcohol ester 12;
Described benzene emulsion is styrene-acrylate emulsion;
Described defoamer, model is UC-9557;
Described sanitas, model is UC-C23;
Described thickening material, model is HS-60;
Described polished tile white clay waste micro mist, with parts by weight, comprises silicon-dioxide 64 parts, 18 parts, aluminum oxide, ferric oxide 0.5 part, 1.1 parts, calcium oxide, 1.1 parts, magnesium oxide, sulphur trioxide 0.23 part, sodium oxide 0.8 part, potassium oxide 0.6 part, chlorion 0.008 part; Loss on ignition is 5.45%.
The preparation method of described protective system:
Comprise the following steps:
(1) preparation of polished tile white clay waste micro mist
Polished tile white clay waste is through airing, and moisture content reaches less than 5%, and the polished tile white clay good to airing is pulverized, and pulverizes with roll mill, obtains the above micro mist of 1000 order; Described roll mill is the LHG roll mill that Weifang Zhengyuan Powder Engineering Equipment Co., Ltd. produces;
(2) deionized water is added
Deionized water is dropped into after in stirred pot, open and stir 200-260 rev/min;
(3) auxiliary agent is added
Add dispersion agent more successively, AMP-95, anti-sudden strain of a muscle rust agent, film coalescence aid stir 5 minutes, rotating speed is 200-260 rev/min;
(4) benzene emulsion is added
Add benzene emulsion, stir 5 minutes, rotating speed is 200-260 rev/min;
(5) graphite, polished tile white clay waste micro mist is added
Speedup, to 400-500 rev/min, adds graphite, polished tile white clay waste micro mist successively after stirring, continue stirring 30 minutes;
(6) remaining component is added
Add defoamer again, sanitas, thickening material stir and be namely processed into water-based anticorrosive paint.
The water-based anticorrosive paint that embodiment 2 one kinds utilizes polished tile white clay waste, prepared by benzene emulsion
With parts by weight, comprise following feed composition:
Dispersion agent 5 parts
AMP-952.5 part
The agent 5 parts of anti-sudden strain of a muscle rust
Film coalescence aid 35 parts
Benzene emulsion 600 parts
Polished tile white clay waste micro mist 350 parts
20 parts, graphite
Defoamer 2 parts
Sanitas 1.5 parts
Thickening material 3 parts;
Described graphite is Graphene fragment;
Described dispersion agent, model is UC-6088;
The agent of described anti-sudden strain of a muscle rust, model is 102;
Described film coalescence aid is ethylene glycol monobutyl ether;
Described benzene emulsion is styrene-acrylate emulsion;
Described defoamer, model is UC-9557;
Described sanitas, model is UC-C23;
Described thickening material, model is HS-60;
Described polished tile white clay waste micro mist, with parts by weight, comprises silicon-dioxide 67.5 parts, 20.4 parts, aluminum oxide, ferric oxide 0.7 part, 1.3 parts, calcium oxide, 1.3 parts, magnesium oxide, sulphur trioxide 0.25 part, sodium oxide 1.0 parts, potassium oxide 0.75 part, chlorion 0.010 part, loss on ignition is 5.68%.
The preparation method of described protective system:
Comprise the following steps:
(1) preparation of polished tile white clay waste micro mist
Polished tile white clay waste is through airing, and moisture content reaches less than 5%, and the polished tile white clay good to airing is pulverized, and pulverizes with roll mill, obtains the above micro mist of 1000 order; Described roll mill is the LHG roll mill that Weifang Zhengyuan Powder Engineering Equipment Co., Ltd. produces;
(2) auxiliary agent is added
Add dispersion agent, AMP-95, anti-sudden strain of a muscle rust agent, film coalescence aid stir 5 minutes, rotating speed is 200-260 rev/min;
(3) benzene emulsion is added
Add benzene emulsion, stir 5 minutes, rotating speed is 200-260 rev/min;
(4) graphite, polished tile white clay waste micro mist is added
Speedup, to 400-500 rev/min, adds graphite, polished tile white clay waste micro mist successively after stirring, continue stirring 30 minutes;
(5) remaining component is added
Add defoamer again, sanitas, thickening material stir and be namely processed into water-based anticorrosive paint.
The water-based anticorrosive paint that embodiment 3 one kinds utilizes polished tile white clay waste, prepared by benzene emulsion
With parts by weight, comprise following feed composition:
Film coalescence aid 36 parts
Benzene emulsion 600 parts
Polished tile white clay waste micro mist 335 parts
31 parts, graphite
Defoamer 2 parts
Sanitas 1.5 parts;
Described graphite is nano-graphite, and particle diameter is 8000-10000 order;
Described film coalescence aid is ethylene glycol monobutyl ether;
Described benzene emulsion is styrene-acrylate emulsion;
Described defoamer, model is UC-9557;
Described sanitas, model is UC-C23;
Described polished tile white clay waste micro mist, with parts by weight, comprises silicon-dioxide 68 parts, 21 parts, aluminum oxide, ferric oxide 0.8 part, 1.4 parts, calcium oxide, 1.3 parts, magnesium oxide, sulphur trioxide 0.26 part, sodium oxide 1.1 parts, potassium oxide 0.7 part, chlorion 0.010 part; Loss on ignition is 5.7%.
The preparation method of described protective system:
Comprise the following steps:
(1) preparation of polished tile white clay waste micro mist
Polished tile white clay waste is through airing, and moisture content reaches less than 5%, and the polished tile white clay good to airing is pulverized, and pulverizes with roll mill, obtains the above micro mist of 1000 order; Described roll mill is the LHG roll mill that Weifang Zhengyuan Powder Engineering Equipment Co., Ltd. produces;
(2) auxiliary agent is added
Add film coalescence aid and stir 5 minutes, rotating speed is 200-260 rev/min;
(3) benzene emulsion is added
Add benzene emulsion, stir 5 minutes, rotating speed is 200-260 rev/min;
(4) graphite, polished tile white clay waste micro mist is added
Speedup, to 400-500 rev/min, adds graphite, polished tile white clay waste micro mist successively after stirring;
(5) remaining component is added
Add defoamer again, sanitas stirs and be namely processed into water-based anticorrosive paint.
The water-based anticorrosive paint that embodiment 4 one kinds utilizes polished tile white clay waste, prepared by benzene emulsion
With parts by weight, comprise following feed composition:
Film coalescence aid 25 parts
Benzene emulsion 375 parts
Polished tile white clay waste micro mist 300 parts
Quartz sand 550 parts
20 parts, graphite
Defoamer 1.5 parts
Sanitas 1.5 parts;
Described graphite is nano-graphite; Particle diameter is 8000-10000 order;
Described quartz sand is 50-200 order mixed sand;
Described film coalescence aid is ethylene glycol monobutyl ether;
Described benzene emulsion is styrene-acrylate emulsion;
Described defoamer, model is UC-9557;
Described sanitas, model is UC-C23;
Described polished tile white clay waste micro mist, with parts by weight, comprises silicon-dioxide 69 parts, 22 parts, aluminum oxide, ferric oxide 0.9 part, 1.5 parts, calcium oxide, 1.4 parts, magnesium oxide, sulphur trioxide 0.27 part, sodium oxide 1.2 parts, potassium oxide 0.9 part, chlorion 0.011 part; Loss on ignition is 5.88%.
The preparation method of described protective system:
Comprise the following steps:
(1) preparation of polished tile white clay waste micro mist
Polished tile white clay waste is through airing, and moisture content reaches less than 5%, and the polished tile white clay good to airing is pulverized, and pulverizes with roll mill, obtains the above micro mist of 1000 order; Described roll mill is the LHG roll mill that Weifang Zhengyuan Powder Engineering Equipment Co., Ltd. produces;
(2) auxiliary agent is added
Add film coalescence aid and stir 5 minutes, rotating speed is 200-260 rev/min;
(3) benzene emulsion is added
Add benzene emulsion, stir 5 minutes, rotating speed is 200-260 rev/min;
(4) graphite, polished tile white clay waste micro mist is added
Speedup, to 400-500 rev/min, adds graphite, polished tile white clay waste micro mist successively after stirring;
(5) quartz sand is added
Add quartz sand, continue stirring 30 minutes;
(6) remaining component is added
Add defoamer again, sanitas stirs and be namely processed into water-based anticorrosive paint.
Prove through lot of experiments, below fill a prescription and all can realize objects of the present invention:
A kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion
With parts by weight, comprise following feed composition:
Deionized water 0-20 part, dispersion agent 0-6 part, AMP-950-3 part, anti-sudden strain of a muscle rust agent 0-6 part, film coalescence aid 25-36 part, benzene emulsion 300-650 part, polished tile white clay waste micro mist 300-400 part, quartz sand 0-600 part, graphite 20-100 part, defoamer 1-3 part, sanitas 1-3 part, thickening material 0-10 part;
Screening formulation is:
Deionized water 0-20 part, dispersion agent 3-6 part, AMP-951.5-3 part, anti-sudden strain of a muscle rust agent 3-6 part, film coalescence aid 25-33 part, benzene emulsion 300-650 part, polished tile white clay waste micro mist 300-400 part, quartz sand 500-600 part, graphite 20-100 part, defoamer 1-3 part, sanitas 1-3 part, thickening material 3-10 part.
Protective system prepared by the present invention, antiseptic property is excellent, is applied on certain base material, after solidification parches film forming, measures the performance index of paint film, specifically in table 1
The antiseptic property index of table 1 protective system of the present invention
The water-based anticorrosive paint that embodiment 5 one kinds utilizes polished tile white clay waste, prepared by benzene emulsion
With parts by weight, comprise following feed composition:
Deionized water 30 parts
Dispersion agent 5 parts
AMP-952.5 part
The agent 5 parts of anti-sudden strain of a muscle rust
Film coalescence aid 30 parts
Benzene emulsion 650 parts
Polished tile white clay waste micro mist 360 parts
Zirconium white 20 parts
Mono-n-butyltin 3 parts
Decabromodiphenyl oxide 10 parts
N-isopropyl benzene-N '-diphenyl-para-phenylene diamine 7 parts
50 parts, graphite
Defoamer 2 parts
Sanitas 1.5 parts
Thickening material 5 parts;
Described graphite, particle diameter is 2500 orders;
Described dispersion agent, model is UC-6088;
The agent of described anti-sudden strain of a muscle rust, model is 102;
Described film coalescence aid is alcohol ester 12;
Described benzene emulsion is styrene-acrylate emulsion;
Described defoamer, model is UC-9557;
Described sanitas, model is UC-C23;
Described thickening material, model is HS-60;
Described polished tile white clay waste micro mist, with parts by weight, comprises silicon-dioxide 64 parts, 18 parts, aluminum oxide, ferric oxide 0.5 part, 1.1 parts, calcium oxide, 1.1 parts, magnesium oxide, sulphur trioxide 0.23 part, sodium oxide 0.8 part, potassium oxide 0.6 part, chlorion 0.008 part; Loss on ignition is 5.45%.
The preparation method of described protective system:
Comprise the following steps:
(1) preparation of polished tile white clay waste micro mist
Polished tile white clay waste is through airing, and moisture content reaches less than 5%, and the polished tile white clay good to airing is pulverized, and pulverizes with roll mill, obtains the above micro mist of 1000 order; Described roll mill is the LHG roll mill that Weifang Zhengyuan Powder Engineering Equipment Co., Ltd. produces;
(2) deionized water is added
Deionized water is dropped into after in stirred pot, open and stir 200-260 rev/min;
(3) auxiliary agent is added
Add dispersion agent more successively, AMP-95, anti-sudden strain of a muscle rust agent, film coalescence aid stir 5 minutes, rotating speed is 200-260 rev/min;
(4) benzene emulsion is added
Add benzene emulsion, stir 5 minutes, rotating speed is 200-260 rev/min;
(5) add graphite, polished tile white clay waste micro mist, add zirconium white
Speedup, to 400-500 rev/min, adds graphite, polished tile white clay waste micro mist, zirconium white successively after stirring, continue stirring 30 minutes, rotating speed is 250 revs/min;
(6) Mono-n-butyltin, decabromodiphenyl oxide, N-isopropyl benzene-N '-diphenyl-para-phenylene diamine is added
Add Mono-n-butyltin, decabromodiphenyl oxide, N-isopropyl benzene-N '-diphenyl-para-phenylene diamine, continue stirring 20 minutes, rotating speed is 400 revs/min;
(7) remaining component is added
Add defoamer again, sanitas, thickening material stir and be namely processed into water-based anticorrosive paint.
Protective system prepared by above-described embodiment 5, is applied on certain base material, after solidification parches film forming, measures the performance index of paint film, as follows:
(1) acid resistance, 10% salt acid soak 3000h, does not come off, indeformable, non-foaming; 10% sulfuric acid soaks 4000h, does not come off, indeformable, non-foaming; 10% nitric acid dousing 3000h, does not come off, indeformable, non-foaming; The hydrofluoric acid dips of 40% 90 days, paint film does not change, crack-free;
(2) alkali resistance, the NaOH of 10% soaks 2000h, and paint film is unchanged;
(3) resistance to elevated temperatures is good, 200 DEG C of baking 400h, and paint film deliquescing, restores to the original state after cooling;
(4) salt fog resistance is good, salt spray resistance 6500h, comes off without bubble and rust staining, nothing;
(5) watertightness, 0.5MPa, 30min are waterproof;
(6) time of drying is short, and curing speed is fast, and surface drying is 0.5h, does solid work as 5h;
(7) strong adhesion, method of pulling open measures, and sticking power reaches 26MPa;
(8) resistance to bend(ing) is 0.6mm, and flexural strength is 57.4MPa.
Unless specifically indicated, ratio of the present invention is mass ratio, and described per-cent is mass percent.
Last it is noted that the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.
Claims (10)
1. utilize polished tile white clay waste, a water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: raw material comprises film coalescence aid, benzene emulsion, polished tile white clay waste micro mist, graphite, defoamer, sanitas.
2. according to claim 1ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: raw material also comprises deionized water, dispersion agent, AMP-95, the agent of anti-sudden strain of a muscle rust, quartz sand, thickening material.
3. according to claim 1ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: with parts by weight, comprise following feed composition: deionized water 0-20 part, dispersion agent 0-6 part, AMP-950-3 part, anti-sudden strain of a muscle rust agent 0-6 part, film coalescence aid 25-36 part, benzene emulsion 300-650 part, polished tile white clay waste micro mist 300-400 part, quartz sand 0-600 part, graphite 20-100 part, defoamer 1-3 part, sanitas 1-3 part, thickening material 0-10 part.
4. according to claim 3ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: with parts by weight, comprise following feed composition: deionized water 0-20 part, dispersion agent 3-6 part, AMP-951.5-3 part, anti-sudden strain of a muscle rust agent 3-6 part, film coalescence aid 25-33 part, benzene emulsion 300-650 part, polished tile white clay waste micro mist 300-400 part, quartz sand 500-600 part, graphite 20-100 part, defoamer 1-3 part, sanitas 1-3 part, thickening material 3-10 part.
5. according to claim 1ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: described polished tile white clay waste micro mist, with parts by weight, comprises silicon-dioxide 64-69 part, aluminum oxide 18-22 part, ferric oxide 0.5-0.9 part, calcium oxide 1.1-1.5 part, magnesium oxide 1.1-1.4 part, sulphur trioxide 0.23-0.27 part, sodium oxide 0.8-1.2 part, potassium oxide 0.6-0.9 part, chlorion 0.008-0.011 part; Loss on ignition is 5.45-5.88%.
6. according to claim 1ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: described film coalescence aid, is alcohol ester 12 or ethylene glycol monobutyl ether; Described graphite, particle diameter is 2000-3000 order.
7. according to claim 1ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: described defoamer, model is UC-9557; Described sanitas, model is UC-C23; Described benzene emulsion is styrene-acrylate emulsion.
8. according to claim 2ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: described dispersion agent, model is UC-6088; The agent of described anti-sudden strain of a muscle rust, model is 102; Described thickening material, model is HS-60.
9. according to claim 6ly a kind ofly utilize polished tile white clay waste, water-based anticorrosive paint prepared by benzene emulsion, it is characterized in that: described graphite is the one in nano-graphite or Graphene fragment; Described nano-graphite, particle diameter is 8000-10000 order.
10. utilize polished tile white clay waste, a method that benzene emulsion prepares water-based anticorrosive paint, it is characterized in that: comprise the preparation of polished tile white clay waste micro mist, add auxiliary agent, add benzene emulsion, add graphite, polished tile white clay waste micro mist; The preparation of described polished tile white clay waste micro mist, polished tile white clay waste is through airing, and moisture content reaches less than 5%, pulverizes, and obtains the above micro mist of 1000 order; Describedly add auxiliary agent, stir 5 minutes, rotating speed is 200-260 rev/min; Describedly add benzene emulsion, stir 5 minutes, rotating speed is 200-260 rev/min; Describedly add graphite, polished tile white clay waste micro mist, speedup, to 400-500 rev/min, adds graphite, polished tile white clay waste micro mist successively after stirring, and continues stirring 30 minutes.
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| CN201610046977.6A CN105440823A (en) | 2016-01-25 | 2016-01-25 | Water-soluble anticorrosive coating prepared by means of polished tile white mud waste and styrene-acrylic emulsion and preparation method thereof |
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| CN201610046977.6A CN105440823A (en) | 2016-01-25 | 2016-01-25 | Water-soluble anticorrosive coating prepared by means of polished tile white mud waste and styrene-acrylic emulsion and preparation method thereof |
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| CN106590347A (en) * | 2016-12-19 | 2017-04-26 | 钦州市钦南区科学技术情报研究所 | Coating material containing resin material and preparation method thereof |
| CN106675233A (en) * | 2016-12-19 | 2017-05-17 | 钦州市钦南区科学技术情报研究所 | Coating containing styrene-acrylic emulsion and preparation method |
| CN106675123A (en) * | 2016-12-19 | 2017-05-17 | 钦州市钦南区科学技术情报研究所 | Coating prepared from white clay waste and preparation method |
| CN106978017A (en) * | 2017-05-24 | 2017-07-25 | 佛山实瑞先导材料研究院（普通合伙） | A kind of environment-friendlywater-based water-based anticorrosive paint and preparation method thereof |
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Application publication date: 20160330 |