CN105440345A - Plastic blend butadiene rubber material and preparation method thereof - Google Patents
Plastic blend butadiene rubber material and preparation method thereof Download PDFInfo
- Publication number
- CN105440345A CN105440345A CN201510941915.7A CN201510941915A CN105440345A CN 105440345 A CN105440345 A CN 105440345A CN 201510941915 A CN201510941915 A CN 201510941915A CN 105440345 A CN105440345 A CN 105440345A
- Authority
- CN
- China
- Prior art keywords
- minute
- carbon nanotube
- mentioned
- parts
- mixed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Reinforced Plastic Materials (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Carbon And Carbon Compounds (AREA)
Abstract
The invention discloses a plastic blend butadiene rubber material. The material comprises, by weight, 50-60 parts of hydroxyl-terminated polybutadiene, 0.8-1 part of alkylsuccinic acid, 17-20 parts of polypropylene, 200-300 parts of n-methylpyrrolidone, 5-7 parts of boron oxide, 160-200 parts of butadiene rubber, 2-3 parts of an antioxidant 4010, 1.3-2 parts of sulfur, 0.4-1 part of barium naphthenate, 1-2 parts of polyohtalamide, 2-3 parts of carboxymethylcellulose sodium, 1-2 parts of allyl polyethylene glycol, 10-16 parts of dibutyl maleate and 30-40 parts of carbon nanotubes. Rubber and polypropylene are blended in the invention, so the weatherability of rubber is effectively modified, and the surface strength is improved.
Description
Technical field
The present invention relates to field of rubber technology, particularly relate to one and mould mixed cis-1,4-polybutadiene rubber material and preparation method thereof.
Background technology
Carbon nanotube is widely used in polymkeric substance to the heat conduction of raising polymkeric substance, conduction and physicals etc. because of the structure of its uniqueness and the physical and chemical performance of excellence.But carbon nanotube itself has very high surface free energy, easily reunites, and not easily disperses in polymeric matrix, limit its application.The surface modification treatment of carbon nanotube is one of important channel of improving its dispersive ability in the polymer and then the excellent carbon nano-tube/polymer composite material of processability;
Hydroxy-terminated polybutadienes is liquid because of it at normal temperatures, and transparency is good, the low good processability of viscosity; And it and chainextender, linking agent react the cured article that can generate tridimensional network at ambient temperature or elevated temperature, this cured article has excellent mechanical property, good oil resistant and water resistance, particularly acid and alkali-resistance, wear-resisting, low temperature resistant and electrical insulation capability is better, become output in distant pawl series of fluids rubber maximum, purposes is a kind the most widely, is mainly used in the aspects such as solid propellant tackiness agent, polyurethane elastomer, material of construction, speciality coating, tackiness agent, Embedding Material, rubber and plastic and epoxy resin modification.Hydroxy-terminated polybutadienes gives its more characteristic by modification later, improves its performance, has widened the Application Areas of hydroxy-terminated polybutadienes.
Summary of the invention
The object of the invention is exactly the defect in order to make up prior art, provides one to mould mixed cis-1,4-polybutadiene rubber material and preparation method thereof.
The present invention is achieved by the following technical solutions:
One moulds mixed cis-1,4-polybutadiene rubber material, and it is made up of the raw material of following weight parts:
The acid of hydroxy-terminated polybutadienes 50-60, hydrocarbyl succinimide 0.8-1, polypropylene 17-20, n-methyl-2-pyrrolidone 200-300, boron oxide 5-7, cis-1,4-polybutadiene rubber 160-200, antioxidant 4010 2-3, sulphur 1.3-2, barium naphthenate 0.4-1, polyphthalamide 1-2, Xylo-Mucine 2-3, allyl polyglycol 1-2, dibutyl maleinate 10-16, carbon nanotube 30-40.
The described preparation method moulding mixed cis-1,4-polybutadiene rubber material, comprises the following steps:
(1) above-mentioned Xylo-Mucine is joined in 20-30 times of deionized water, add barium naphthenate, carbon nanotube, at 80-90 DEG C, insulated and stirred is done to water, be placed in water do after weight of material 40-50 doubly, massfraction is the aqueous hydrogen peroxide solution ultrasonic disperse 30-40 minute of 0.3-0.5%, 100-120 minute is incubated at 75-80 DEG C, filtration, vacuum-drying, obtain pre-treatment carbon nanotube;
(2) get sulfuric acid that volume ratio is 3-4:1, salpeter solution mixing, stir, described sulfuric acid concentration is 70-75%, concentration of nitric acid is 80-85%;
(3) pre-treatment carbon nanotube obtained above is joined in above-mentioned mixed acid solution, ultrasonic 100-110 minute at 50-60 DEG C, filtration under diminished pressure, be neutral by carbon nanotube deionized water repetitive scrubbing to the filtrate obtained, the vacuum drying oven putting into 76-80 DEG C is dried, and obtains acidifying carbon nanotube;
(4) above-mentioned acidifying carbon nanotube is mixed with hydroxy-terminated polybutadienes, magnetic agitation 2-3 minute, join in said n-methyl-2-pyrrolidone, ultrasonic 10-16 minute, suction filtration, by filter cake dry 20-30 minute at 100-105 DEG C, obtains hydroxyl modification acidifying carbon nanotube;
(5) mixed with boron oxide by above-mentioned hydroxyl modification acidifying carbon nanotube, ball milling is even; Being sent to concentration is in the phosphoric acid solution of 10-15%, constant temperature dipping 120-130 minute at 150-160 DEG C, discharging, and dry, send in reactor, under nitrogen protection, thermal treatment 100-120 minute at 400-450 DEG C, obtains phosphate impregnation compounded mix;
(6) joined by above-mentioned polyphthalamide in its weight 10-12 dehydrated alcohol doubly, stirring, is alcohol liquid;
(7) above-mentioned hydrocarbyl succinimide acid is joined in allyl polyglycol, stir, add the 3-4% of above-mentioned cis-1,4-polybutadiene rubber weight, insulated and stirred 10-20 minute at 50-60 DEG C, add above-mentioned polypropylene, send in the oil bath of 110-120 DEG C, insulated and stirred 10-17 minute, discharging, mixes with above-mentioned alcohol liquid, be stirred to normal temperature, obtain composite modified plastic rubber material;
(8) by above-mentioned phosphate impregnation compounded mix, composite modified plastic rubber material, the mixing of remaining cis-1,4-polybutadiene rubber, plasticate 2-3 minute at 46-50 DEG C, add each raw material of residue, mixing 4-6 minute, is placed in two roller mills by the rubber unvulcanizate obtained, mixing 6-10 minute is supplemented at 30-40 DEG C, discharging, at room temperature parks 20-25 hour by sizing material, sends in vulcanizing press, at 150-155 DEG C, carry out sulfuration, to obtain final product;
Described a kind of preparation method moulding mixed cis-1,4-polybutadiene rubber material, the weight of described mixed acid solution is 18-20 times of pre-treatment carbon nanotubes.
Advantage of the present invention is:
First the present invention carries out Carboxylation process to carbon nanotube, then react with hydroxy-terminated polybutadienes, the intensity of sizing material can be strengthened, this is due to the hydroxyl reaction in the carboxyl of carbon nano tube surface and hydroxy-terminated polybutadienes, carbon nano tube surface is connected by covalent linkage with hydroxy-terminated polybutadienes molecular chain, thus improve its dispersiveness in the base, and enhance the bounding force of itself and rubber matrix, make it in rubber matrix, show better reinforcing effect;
Then the carboxylic acid carbon nanotube after hydroxy-terminated polybutadienes process is mixed with boron oxide, use phosphate impregnation compounded mix, the pyrogenous origin product P 4O10 of phosphoric acid is phosphorus oxygen glass structure, introduce B2O3 in the melt, [BPO4] structural unit can be formed, glass structure is made to change rack-like into by chain, these rack-like structures are cross-linked with each other, strengthen network structure, strengthen the bonding strength with matrix, one deck coating can be covered at matrix surface, covering surfaces hole more effectively, confining surface active site, effective prevention oxidizing gas enters intrinsic silicon by micropore or crackle, effectively raise physical strength and the antioxidant property of finished product.
The present invention adopts rubber and polypropene blended mode, and the effective modification weathering resistance of rubber, improves surface strength.
Embodiment
One moulds mixed cis-1,4-polybutadiene rubber material, and it is made up of the raw material of following weight parts:
Hydroxy-terminated polybutadienes 50, hydrocarbyl succinimide acid 0.8, polypropylene 17, n methyl-2-pyrrolidone 200, boron oxide 5, cis-1,4-polybutadiene rubber 160, antioxidant 4010 2, sulphur 1.3, barium naphthenate 0.4, polyphthalamide 1, Xylo-Mucine 2, allyl polyglycol 1, dibutyl maleinate 10, carbon nanotube 30.
The described preparation method moulding mixed cis-1,4-polybutadiene rubber material, comprises the following steps:
(1) above-mentioned Xylo-Mucine is joined in 20 times of deionized waters, add barium naphthenate, carbon nanotube, at 80 DEG C, insulated and stirred is done to water, be placed in water do after weight of material 40 times, massfraction be 0.3% aqueous hydrogen peroxide solution ultrasonic disperse 30 minutes, 100 minutes are incubated at 75 DEG C, filtration, vacuum-drying, obtain pre-treatment carbon nanotube;
(2) get sulfuric acid that volume ratio is 3:1, salpeter solution mixing, stir, described sulfuric acid concentration is 70%, concentration of nitric acid is 80%;
(3) pre-treatment carbon nanotube obtained above is joined in above-mentioned mixed acid solution, at 50 DEG C ultrasonic 100 minutes, carbon nanotube deionized water repetitive scrubbing to the filtrate obtained was neutral by filtration under diminished pressure, the vacuum drying oven putting into 76 DEG C is dried, and obtains acidifying carbon nanotube;
(4) above-mentioned acidifying carbon nanotube is mixed with hydroxy-terminated polybutadienes, magnetic agitation 2 minutes, join in said n methyl-2-pyrrolidone, ultrasonic 10 minutes, suction filtration, by filter cake at 100 DEG C dry 20 minutes, obtain hydroxyl modification acidifying carbon nanotube;
(5) mixed with boron oxide by above-mentioned hydroxyl modification acidifying carbon nanotube, ball milling is even; Being sent to concentration is in the phosphoric acid solution of 10%, and at 150 DEG C, constant temperature floods 120 minutes, discharging, dry, and send in reactor, under nitrogen protection, at 400 DEG C, thermal treatment 100 minutes, obtains phosphate impregnation compounded mix;
(6) being joined by above-mentioned polyphthalamide in the dehydrated alcohol of its weight 10 times, stir, is alcohol liquid;
(7) above-mentioned hydrocarbyl succinimide acid is joined in allyl polyglycol, stir, add 3% of above-mentioned cis-1,4-polybutadiene rubber weight, at 50 DEG C, insulated and stirred 10 minutes, adds above-mentioned polypropylene, send in the oil bath of 110 DEG C, insulated and stirred 10 minutes, discharging, mixes with above-mentioned alcohol liquid, be stirred to normal temperature, obtain composite modified plastic rubber material;
(8) by above-mentioned phosphate impregnation compounded mix, composite modified plastic rubber material, the mixing of remaining cis-1,4-polybutadiene rubber, plasticate at 46 DEG C 2 minutes, add each raw material of residue, mixing 4 minutes, the rubber unvulcanizate obtained is placed in two roller mills, supplement mixing 6 minutes at 30 DEG C, discharging, at room temperature parks 20 hours by sizing material, sends in vulcanizing press, at 150 DEG C, carry out sulfuration, to obtain final product;
Described a kind of preparation method moulding mixed cis-1,4-polybutadiene rubber material, the weight of described mixed acid solution is 18 times of pre-treatment carbon nanotubes.
Stretch breaking strength (MPa): 18.6;
Surely modulus 100%(MPa is stretched): 2.4;
Mooney viscosity: 62;
70 DEG C × 70h air oven aging test:
Tensile strength at yield reduced rate: 4.3%, elongation at break reduced rate: 8.2%.
Claims (3)
1. mould a mixed cis-1,4-polybutadiene rubber material, it is characterized in that, it is made up of the raw material of following weight parts:
The acid of hydroxy-terminated polybutadienes 50-60, hydrocarbyl succinimide 0.8-1, polypropylene 17-20, n-methyl-2-pyrrolidone 200-300, boron oxide 5-7, cis-1,4-polybutadiene rubber 160-200, antioxidant 4010 2-3, sulphur 1.3-2, barium naphthenate 0.4-1, polyphthalamide 1-2, Xylo-Mucine 2-3, allyl polyglycol 1-2, dibutyl maleinate 10-16, carbon nanotube 30-40.
2. mould a preparation method for mixed cis-1,4-polybutadiene rubber material as claimed in claim 1, it is characterized in that, comprise the following steps:
(1) above-mentioned Xylo-Mucine is joined in 20-30 times of deionized water, add barium naphthenate, carbon nanotube, at 80-90 DEG C, insulated and stirred is done to water, be placed in water do after weight of material 40-50 doubly, massfraction is the aqueous hydrogen peroxide solution ultrasonic disperse 30-40 minute of 0.3-0.5%, 100-120 minute is incubated at 75-80 DEG C, filtration, vacuum-drying, obtain pre-treatment carbon nanotube;
(2) get sulfuric acid that volume ratio is 3-4:1, salpeter solution mixing, stir, described sulfuric acid concentration is 70-75%, concentration of nitric acid is 80-85%;
(3) pre-treatment carbon nanotube obtained above is joined in above-mentioned mixed acid solution, ultrasonic 100-110 minute at 50-60 DEG C, filtration under diminished pressure, be neutral by carbon nanotube deionized water repetitive scrubbing to the filtrate obtained, the vacuum drying oven putting into 76-80 DEG C is dried, and obtains acidifying carbon nanotube;
(4) above-mentioned acidifying carbon nanotube is mixed with hydroxy-terminated polybutadienes, magnetic agitation 2-3 minute, join in said n-methyl-2-pyrrolidone, ultrasonic 10-16 minute, suction filtration, by filter cake dry 20-30 minute at 100-105 DEG C, obtains hydroxyl modification acidifying carbon nanotube;
(5) mixed with boron oxide by above-mentioned hydroxyl modification acidifying carbon nanotube, ball milling is even; Being sent to concentration is in the phosphoric acid solution of 10-15%, constant temperature dipping 120-130 minute at 150-160 DEG C, discharging, and dry, send in reactor, under nitrogen protection, thermal treatment 100-120 minute at 400-450 DEG C, obtains phosphate impregnation compounded mix;
(6) joined by above-mentioned polyphthalamide in its weight 10-12 dehydrated alcohol doubly, stirring, is alcohol liquid;
(7) above-mentioned hydrocarbyl succinimide acid is joined in allyl polyglycol, stir, add the 3-4% of above-mentioned cis-1,4-polybutadiene rubber weight, insulated and stirred 10-20 minute at 50-60 DEG C, add above-mentioned polypropylene, send in the oil bath of 110-120 DEG C, insulated and stirred 10-17 minute, discharging, mixes with above-mentioned alcohol liquid, be stirred to normal temperature, obtain composite modified plastic rubber material;
(8) by above-mentioned phosphate impregnation compounded mix, composite modified plastic rubber material, the mixing of remaining cis-1,4-polybutadiene rubber, plasticate 2-3 minute at 46-50 DEG C, add each raw material of residue, mixing 4-6 minute, is placed in two roller mills by the rubber unvulcanizate obtained, mixing 6-10 minute is supplemented at 30-40 DEG C, discharging, at room temperature parks 20-25 hour by sizing material, sends in vulcanizing press, at 150-155 DEG C, carry out sulfuration, to obtain final product.
3. a kind of preparation method moulding mixed cis-1,4-polybutadiene rubber material according to claim 2, is characterized in that, the weight of described mixed acid solution is 18-20 times of pre-treatment carbon nanotubes.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510941915.7A CN105440345A (en) | 2015-12-16 | 2015-12-16 | Plastic blend butadiene rubber material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510941915.7A CN105440345A (en) | 2015-12-16 | 2015-12-16 | Plastic blend butadiene rubber material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105440345A true CN105440345A (en) | 2016-03-30 |
Family
ID=55551015
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510941915.7A Pending CN105440345A (en) | 2015-12-16 | 2015-12-16 | Plastic blend butadiene rubber material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105440345A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694505A (en) * | 2013-12-24 | 2014-04-02 | 苏州华东橡胶工业有限公司 | Compound carbon nanotube and rubber material and preparation method thereof |
| CN104961983A (en) * | 2015-05-21 | 2015-10-07 | 青岛科凯达橡塑有限公司 | High-electrical conductivity high-thermal conductivity oil-resistant aging-resistant rubber material, and preparation method and applications thereof |
-
2015
- 2015-12-16 CN CN201510941915.7A patent/CN105440345A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103694505A (en) * | 2013-12-24 | 2014-04-02 | 苏州华东橡胶工业有限公司 | Compound carbon nanotube and rubber material and preparation method thereof |
| CN104961983A (en) * | 2015-05-21 | 2015-10-07 | 青岛科凯达橡塑有限公司 | High-electrical conductivity high-thermal conductivity oil-resistant aging-resistant rubber material, and preparation method and applications thereof |
Non-Patent Citations (2)
| Title |
|---|
| 王中光: "碳纳米管表面包覆聚合物方法的探索及其聚合物材料的性能研究", 《青岛科技大学硕士学位论文》 * |
| 雷卓研等: "氧化硼-磷酸浸渍对中间相炭微球复合材料抗氧化及力学性能的影响", 《无机材料学报》 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103408948A (en) | Rubber composition and application thereof | |
| CN105524307A (en) | Nylon blended rubber material and preparation method thereof | |
| CN104710693A (en) | Low-temperature-resistant door/window sealing strip and preparation method thereof | |
| CN105440350A (en) | Ageing resistant butadiene rubber material and preparation method thereof | |
| CN105482180A (en) | Anti-corrosive butadiene rubber material and preparation method thereof | |
| CN105440346A (en) | Lubricating butadiene rubber material and preparation method thereof | |
| CN105482179A (en) | Cis-polybutadiene rubber material and preparation method thereof | |
| CN105462001A (en) | Hydrophobic butadiene rubber material and preparation method thereof | |
| CN105440345A (en) | Plastic blend butadiene rubber material and preparation method thereof | |
| CN105440351A (en) | High strength butadiene rubber material and preparation method thereof | |
| CN105482178A (en) | Macromolecular butadiene rubber material and preparation method thereof | |
| CN106750934A (en) | A kind of hydrophobic type metal whisker composite and preparation method thereof | |
| CN105440348A (en) | Phosphatized butadiene rubber material and preparation method thereof | |
| CN105542250A (en) | Flexible rosin-butadiene rubber material and preparation method thereof | |
| CN105440353A (en) | Zirconium-based hard butadiene rubber material and preparation method thereof | |
| CN111978611A (en) | High-strength conductive self-healing rubber composite material and preparation method thereof | |
| CN105440347A (en) | Cross-linked butadiene rubber material and preparation method thereof | |
| CN111892898A (en) | Anti-ultraviolet-aging two-component polyurethane hollow glass sealant and preparation method thereof | |
| CN105440352A (en) | Heatproof butadiene rubber material and preparation method thereof | |
| CN105440344A (en) | Titanium reinforced butadiene rubber material and preparation method thereof | |
| CN105820448A (en) | Cellulose resin rubber material | |
| CN105440343A (en) | Carbon nanotube modified butadiene rubber material and preparation method thereof | |
| CN105566695A (en) | Low-cost cis-1,4-polybutadiene rubber material and preparation method thereof | |
| CN105462000A (en) | Fiber butadiene rubber material and preparing method thereof | |
| CN105482177A (en) | Rear-earth butadiene rubber material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160330 |
|
| RJ01 | Rejection of invention patent application after publication |