CN105439180A - Method for preparing potassium alum from kaolin ore dressing wastewater - Google Patents
Method for preparing potassium alum from kaolin ore dressing wastewater Download PDFInfo
- Publication number
- CN105439180A CN105439180A CN201510937643.3A CN201510937643A CN105439180A CN 105439180 A CN105439180 A CN 105439180A CN 201510937643 A CN201510937643 A CN 201510937643A CN 105439180 A CN105439180 A CN 105439180A
- Authority
- CN
- China
- Prior art keywords
- potassium alum
- kaolin
- water
- waster water
- processing waster
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01F—COMPOUNDS OF THE METALS BERYLLIUM, MAGNESIUM, ALUMINIUM, CALCIUM, STRONTIUM, BARIUM, RADIUM, THORIUM, OR OF THE RARE-EARTH METALS
- C01F7/00—Compounds of aluminium
- C01F7/68—Aluminium compounds containing sulfur
- C01F7/74—Sulfates
- C01F7/76—Double salts, i.e. compounds containing, besides aluminium and sulfate ions, only other cations, e.g. alums
- C01F7/762—Ammonium or alkali metal aluminium sulfates
Abstract
The invention discloses a method for preparing potassium alum from kaolin ore dressing wastewater, and belongs to the technical field of wastewater treatment and inorganic salt preparation. The method comprises the following steps: carrying out multi-time cycle on kaolin ore dressing wastewater and kaolin to make aluminum sulfate dissolved in the wastewater is saturated, reacting the wastewater with potassium sulfate, and crystallizing twice to prepare potassium alum with the purity reaching 99.81% or above. The method can be used to effectively treat the kaolin ore dressing wastewater to make the aluminum element in the kaolin ore dressing wastewater be fully utilized, so energy saving, emission reduction, and changing of wastes into valuables are reached.
Description
Technical field
The present invention relates to wastewater treatment and inorganic salt preparing technical field, be specifically related to a kind of method utilizing kaolin processing waster water to prepare potassium alum.
Background technology
Chinese kaolin is widely distributed, spreads all over the north and southern region, but Relatively centralized, southern kaolin reserves are more, the ground such as such as Guangdong, Fujian, Jiangxi, Jiangsu.Carrying out producing beneficiation wastewater in kaolin ore dressing process, kaolin processing waster water pH value is generally about 3, and the SO containing high density
4 2-, Al
3+.The domestic process to kaolin processing waster water is mostly simply add alkali to carry out pH value neutralization, and a lot of little source mill does not even process directly discharges beneficiation wastewater, causes great destruction to environment; Some larger kaolin enterprise, beneficiation wastewater process has been carried out under the pressure of government's pressure, but do not have specialized personnel to go research and design, beneficiation wastewater processing cost is caused to remain high, water after processing can only be discharged, recycle can not be accomplished or to wherein efficient resource recycling, cause water resources and Al
3+deng active substance significant wastage, kaolin processing waster water is processed and is recycled Al
3+the document preparing potassium alum is not reported so far.
Summary of the invention
The technical problem to be solved in the present invention is to provide a kind of method utilizing kaolin processing waster water to prepare potassium alum, to solve the problem that existing kaolin processing waster water processing mode causes aluminium element significant wastage.The present invention effectively can process kaolin processing waster water, the aluminium element in kaolin processing waster water is fully used, the object reach energy-saving and emission-reduction, turning waste into wealth.
For solving above technical problem, the present invention by the following technical solutions:
Utilize kaolin processing waster water to prepare a method for potassium alum, comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, with such processing step cyclical operation, until the Tai-Ace S 150 being dissolved in kaolin processing waster water reaches capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity adds potassium sulfate reaction and generates potassium alum after control temperature and pH value;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid crystallisation by cooling, gained crystallization press filtration obtains the thick potassium alum of filter cake;
S4: thick potassium alum obtained for step S3 is dropped in water, stir after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again, gained crystallization press filtration obtains potassium alum;
S5: the potassium alum that step S4 is obtained removes moisture further, namely obtained pure potassium alum.
Preferably, in step S1, kaolinic aluminium sesquioxide is dissolved in the temperature of kaolin processing waster water is 90-92 DEG C, and the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is 2-4 time with the kaolin mixed cycle operation steps newly increased,
Preferably, the temperature that the kaolin processing waster water that in step S2, Tai-Ace S 150 reaches capacity controls is 86-89 DEG C, and pH value is 3.3-3.6.
Preferably, in step S2, when adding potassium sulfate, the amount of described potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.01-1.05:1:2.01-2.08.
Preferably, temperature≤12 DEG C of clear liquid crystallisation by cooling in step S3 and S4.
Preferably, the pressure of press filtration in step S3 and S4 is 0.9-1.0MPa, and potassium alum is depressed into water ratio≤40%.
Preferably, in step S4, amount of water is weight 1.1-1.3 times of thick potassium alum.
Preferably, remove moisture and carry out under whizzer process in step S5, the rotating speed of whizzer is 4000-4500r/min, and potassium alum removing moisture is to water ratio≤0.9%.
The present invention has following beneficial effect:
(1) compared with the potassium alum produced by potassium alum and the prior art of industrial raw material production, production cost of the present invention is lower;
(2) not only purity is high for the potassium alum prepared of the present invention, reaches more than 99.81%, and steady quality;
(3) the present invention can aluminium element in effective recycling kaolin processing waster water, and does not increase new element in kaolin processing waster water, reaches the object of comprehensive utilization, energy-saving and emission-reduction.
Accompanying drawing explanation
Fig. 1 is that the present invention utilizes kaolin processing waster water to prepare the process flow diagram of potassium alum.
Embodiment
Embodiment 1
Utilize kaolin processing waster water to prepare a method for potassium alum, comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin at temperature is 90 DEG C, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, the Tai-Ace S 150 being dissolved in kaolin processing waster water is reached capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity is 86 DEG C through control temperature, pH value is add potassium sulfate 3.3 times, and the amount of added potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.01:1:2.02, reaction generate potassium alum;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid is crystallisation by cooling at temperature is 12 DEG C, and gained crystallization press filtration under pressure is 0.9MPa obtains the thick potassium alum of filter cake that water ratio is 40%;
S4: thick potassium alum obtained for step S3 is dropped in water, institute's amount of water is the weight 1.1 times of thick potassium alum, stir at temperature is 86 DEG C after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again at temperature is 12 DEG C, gained crystallization press filtration obtains the potassium alum that water ratio is 40%;
S5: the potassium alum obtained by step S4 removes moisture further under the rotating speed of whizzer is 4500r/min is till 0.9% until potassium alum water ratio, namely obtained pure potassium alum.
Embodiment 2
Utilize kaolin processing waster water to prepare a method for potassium alum, comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin at temperature is 92 DEG C, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, with such processing step cyclical operation 4 times, until the Tai-Ace S 150 being dissolved in kaolin processing waster water reaches capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity is 89 DEG C through control temperature, pH value is add potassium sulfate 3.4 times, and the amount of added potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.02:1:2.01, reaction generate potassium alum;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid is crystallisation by cooling at temperature is 10 DEG C, and gained crystallization press filtration under pressure is 1.0MPa obtains the thick potassium alum of filter cake that water ratio is 36%;
S4: thick potassium alum obtained for step S3 is dropped in water, institute's amount of water is the weight 1.3 times of thick potassium alum, stir at temperature is 88 DEG C after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again at temperature is 10 DEG C, gained crystallization press filtration obtains the potassium alum that water ratio is 35%;
S5: the potassium alum obtained by step S4 removes moisture further under the rotating speed of whizzer is 4000r/min is till 0.8% until potassium alum water ratio, namely obtained pure potassium alum.
Embodiment 3
Utilize kaolin processing waster water to prepare a method for potassium alum, comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin at temperature is 91 DEG C, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, with such processing step cyclical operation 3 times, until the Tai-Ace S 150 being dissolved in kaolin processing waster water reaches capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity is 87 DEG C through control temperature, pH value is add potassium sulfate 3.5 times, and the amount of added potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.04:1:2.06, reaction generate potassium alum;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid is crystallisation by cooling at temperature is 8 DEG C, and gained crystallization press filtration under pressure is 0.9MPa obtains the thick potassium alum of filter cake that water ratio is 30%;
S4: thick potassium alum obtained for step S3 is dropped in water, institute's amount of water is the weight 1.2 times of thick potassium alum, stir at temperature is 87 DEG C after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again at temperature is 10 DEG C, gained crystallization press filtration obtains the potassium alum that water ratio is 32%;
S5: the potassium alum obtained by step S4 removes moisture further under the rotating speed of whizzer is 4500r/min is till 0.7% until potassium alum water ratio, namely obtained pure potassium alum.
Embodiment 4
Utilize kaolin processing waster water to prepare a method for potassium alum, comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin at temperature is 92 DEG C, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, with such processing step cyclical operation 4 times, until the Tai-Ace S 150 being dissolved in kaolin processing waster water reaches capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity is 88 DEG C through control temperature, pH value is add potassium sulfate 3.3 times, and the amount of added potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.03:1:2.05, reaction generate potassium alum;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid is crystallisation by cooling at temperature is 12 DEG C, and gained crystallization press filtration under pressure is .0MPa obtains the thick potassium alum of filter cake that water ratio is 40%;
S4: thick potassium alum obtained for step S3 is dropped in water, institute's amount of water is the weight 1.3 times of thick potassium alum, stir at temperature is 86 DEG C after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again at temperature is 10 DEG C, gained crystallization press filtration obtains the potassium alum that water ratio is 36%;
S5: the potassium alum obtained by step S4 removes moisture further under the rotating speed of whizzer is 4200r/min is till 0.9% until potassium alum water ratio, namely obtained pure potassium alum.
Embodiment 5
Utilize kaolin processing waster water to prepare a method for potassium alum, comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin at temperature is 92 DEG C, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, with such processing step cyclical operation 3 times, until the Tai-Ace S 150 being dissolved in kaolin processing waster water reaches capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity is 88 DEG C through control temperature, pH value is add potassium sulfate 3.5 times, and the amount of added potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.04:1:2.05, reaction generate potassium alum;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid is crystallisation by cooling at temperature is 10 DEG C, and gained crystallization press filtration under pressure is 0.9MPa obtains the thick potassium alum of filter cake that water ratio is 35%;
S4: thick potassium alum obtained for step S3 is dropped in water, institute's amount of water is the weight 1.3 times of thick potassium alum, stir at temperature is 86 DEG C after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again at temperature is 12 DEG C, gained crystallization press filtration obtains the potassium alum that water ratio is 30%;
S5: the potassium alum obtained by step S4 removes moisture further under the rotating speed of whizzer is 4000r/min is till 0.8% until potassium alum water ratio, namely obtained pure potassium alum.
Embodiment 6
Utilize kaolin processing waster water to prepare a method for potassium alum, comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin at temperature is 92 DEG C, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, with such processing step cyclical operation 4 times, until the Tai-Ace S 150 being dissolved in kaolin processing waster water reaches capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity is 86 DEG C through control temperature, pH value is add potassium sulfate 3.6 times, and the amount of added potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.05:1:2.08, reaction generate potassium alum;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid is crystallisation by cooling at temperature is 12 DEG C, and gained crystallization press filtration under pressure is 1.0MPa obtains the thick potassium alum of filter cake that water ratio is 40%;
S4: thick potassium alum obtained for step S3 is dropped in water, institute's amount of water is the weight 1.2 times of thick potassium alum, stir at temperature is 88 DEG C after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again at temperature is 12 DEG C, gained crystallization press filtration obtains the potassium alum that water ratio is 40%;
S5: the potassium alum obtained by step S4 removes moisture further under the rotating speed of whizzer is 4500r/min is till 0.9% until potassium alum water ratio, namely obtained pure potassium alum.
Measure potassium alum purity in embodiment (butt meter), measuring method adopts foodstuff additive potassium alum GB standard to carry out, and analytical results sees the following form.
Embodiment | Potassium alum purity (%) | Potassium alum purity (%) | Potassium alum purity (%) | Potassium alum purity (%) | Potassium alum purity (%) | Potassium alum purity (%) |
1 | 99.81 | |||||
2 | 99.85 | |||||
3 | 99.91 | |||||
4 | 99.87 | |||||
5 | 99.9 | |||||
6 | 99.83 |
As seen from the above table, the potassium alum purity (butt meter) that the present invention utilizes kaolin processing waster water to prepare the method gained of potassium alum reaches more than 99.81%, and the potassium alum that visible the present invention obtains not only purity is high and stable.
Above content is in conjunction with concrete preferred implementation further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, some simple deduction or replace can also be made, all should be considered as belonging to the scope of patent protection that the present invention is determined by submitted to claims.
Claims (8)
1. utilize kaolin processing waster water to prepare a method for potassium alum, it is characterized in that: comprise the following steps:
S1: adopt kaolin processing waster water to mix with kaolin, kaolinic aluminium sesquioxide is made to be dissolved in kaolin processing waster water, again the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is mixed with the kaolin newly increased, with such processing step cyclical operation, until the Tai-Ace S 150 being dissolved in kaolin processing waster water reaches capacity;
S2: the kaolin processing waster water that the Tai-Ace S 150 obtained by step S1 reaches capacity adds potassium sulfate reaction and generates potassium alum after control temperature and pH value;
S3: the potassium alum solution removing impurity that step S2 reaction is generated, gained clear liquid crystallisation by cooling, gained crystallization press filtration obtains the thick potassium alum of filter cake;
S4: thick potassium alum obtained for step S3 is dropped in water, stir after thick potassium alum is dissolved completely and again remove impurity, gained clear liquid crystallisation by cooling again, gained crystallization press filtration obtains potassium alum;
S5: the potassium alum that step S4 is obtained removes moisture further, namely obtained pure potassium alum.
2. the method utilizing kaolin processing waster water to prepare potassium alum according to claim 1, it is characterized in that, in step S1, kaolinic aluminium sesquioxide is dissolved in the temperature of kaolin processing waster water is 90-92 DEG C, and the kaolin processing waster water circulation increasing Tai-Ace S 150 concentration is 2-4 time with the kaolin mixed cycle operation steps newly increased.
3. the method utilizing kaolin processing waster water to prepare potassium alum according to claim 1, is characterized in that, the temperature that the kaolin processing waster water that in step S2, Tai-Ace S 150 reaches capacity controls is 86-89 DEG C, and pH value is 3.3-3.6.
4. the method utilizing kaolin processing waster water to prepare potassium alum according to claim 1, is characterized in that, in step S2, when adding potassium sulfate, the amount of described potassium sulfate is for making K in potassium alum
+: Al
3+: SO
4 2-molar concentration rate be 1.01-1.05:1:2.01-2.08.
5. the method utilizing kaolin processing waster water to prepare potassium alum according to claim 1, is characterized in that, temperature≤12 DEG C of clear liquid crystallisation by cooling in step S3 and S4.
6. the method utilizing kaolin processing waster water to prepare potassium alum according to claim 1, is characterized in that, the pressure of press filtration in step S3 and S4 is 0.9-1.0MPa, and potassium alum is depressed into water ratio≤40%.
7. the method utilizing kaolin processing waster water to prepare potassium alum according to claim 1, is characterized in that, in step S4, amount of water is weight 1.1-1.3 times of thick potassium alum.
8. the method utilizing kaolin processing waster water to prepare potassium alum according to claim 1, it is characterized in that, remove moisture in step S5 to carry out under whizzer process, the rotating speed of whizzer is 4000-4500r/min, and potassium alum removing moisture is to water ratio≤0.9%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510937643.3A CN105439180A (en) | 2015-12-16 | 2015-12-16 | Method for preparing potassium alum from kaolin ore dressing wastewater |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201510937643.3A CN105439180A (en) | 2015-12-16 | 2015-12-16 | Method for preparing potassium alum from kaolin ore dressing wastewater |
Publications (1)
Publication Number | Publication Date |
---|---|
CN105439180A true CN105439180A (en) | 2016-03-30 |
Family
ID=55549901
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201510937643.3A Pending CN105439180A (en) | 2015-12-16 | 2015-12-16 | Method for preparing potassium alum from kaolin ore dressing wastewater |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN105439180A (en) |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1037363A (en) * | 1988-05-07 | 1989-11-22 | 山西师范大学 | The method of comprehensive utilization of low-grade aluminium ore |
CN101671048A (en) * | 2009-09-30 | 2010-03-17 | 合肥工业大学 | Method for recovering and preparing alum from activated clay production waste liquid |
-
2015
- 2015-12-16 CN CN201510937643.3A patent/CN105439180A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1037363A (en) * | 1988-05-07 | 1989-11-22 | 山西师范大学 | The method of comprehensive utilization of low-grade aluminium ore |
CN101671048A (en) * | 2009-09-30 | 2010-03-17 | 合肥工业大学 | Method for recovering and preparing alum from activated clay production waste liquid |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103553138B (en) | Comprehensive utilization method for separating, concentrating and purifying manganese sulfate, magnesium sulfate and calcium sulfate in high-salt waste water | |
CN105540619A (en) | Method for directly preparing battery grade lithium carbonate from salt lake brine with high magnesium-to-lithium ratio | |
CN103232065B (en) | Method for recycling before-kiln dehydration filtrate and method for producing titanium dioxide | |
CN105129830A (en) | Method for preparation of potassium alum from activated clay production mother liquor | |
CN110655258A (en) | Novel integrated treatment system and process for zero discharge of high-salinity wastewater in coal chemical industry | |
CN107445139A (en) | The circulation utilization method of mother liquor in a kind of ferric phosphate production process | |
CN102849744B (en) | Technology for producing sodium fluosilicate | |
CN105293797A (en) | Method for co-production of aluminum potassium sulfate and gypsum through activated clay production mother liquid | |
CN105753211A (en) | Method and system for recovering fluorine from waste acid produced in thinning production of solar cells or glass | |
CN105000563A (en) | Method for preparing sodium fluosilicate by using fluorine-containing silicon slag | |
CN105271342A (en) | Method for preparing alum by utilization of activated clay waste acid mother solution | |
CN105293796A (en) | Method for co-production of sodalumite and gypsum through activated clay production mother liquid | |
CN105293553A (en) | Method for preparing tschermigite by utilizing activated clay production wastewater | |
CN105502456A (en) | Method for recycling and preparing aluminum ammonium sulfate from activated clay production wastewater | |
CN103395816A (en) | Process for producing calcium sulphate dihydrate by utilizing aramid fiber II spinning acid pickle | |
CN112850747A (en) | Method and device for preparing ammonium sulfate and sodium bicarbonate by using sodium sulfate and ammonium bicarbonate | |
CN205528214U (en) | High advanced oxidation - who contains salt industrial waste water divides salt crystallization combined system | |
CN104211106B (en) | A kind of carbonated rare earth preparation method not producing ammonia nitrogen waste water | |
CN105271341A (en) | Method for preparing potassium alum by utilization of activated clay production waste water | |
CN204311142U (en) | A kind of light salt brine replaces the device of part refined brine electrolysis caustic soda | |
CN105439180A (en) | Method for preparing potassium alum from kaolin ore dressing wastewater | |
CN105399125A (en) | Method for preparing ammonium alum by using kaolin mineral processing wastewater | |
CN105540633A (en) | Method for preparing mendozite by using kaolin ore dressing acidic waste water | |
CN105399123A (en) | Method for preparing sodium alum by using kaolin mineral processing wastewater | |
CN216737932U (en) | Electrolytic waste residue and fluorine-containing wastewater treatment device for electrolytic fluorine production process |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160330 |