CN105435383A - Breathing mask suitable for being used in high pollution weather - Google Patents

Breathing mask suitable for being used in high pollution weather Download PDF

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Publication number
CN105435383A
CN105435383A CN201510777506.8A CN201510777506A CN105435383A CN 105435383 A CN105435383 A CN 105435383A CN 201510777506 A CN201510777506 A CN 201510777506A CN 105435383 A CN105435383 A CN 105435383A
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CN
China
Prior art keywords
mask
air
breathing mask
adsorption
lens
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Pending
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CN201510777506.8A
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Chinese (zh)
Inventor
朱忠良
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Individual
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Individual
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Priority to CN201510777506.8A priority Critical patent/CN105435383A/en
Publication of CN105435383A publication Critical patent/CN105435383A/en
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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B7/00Respiratory apparatus
    • A62B7/10Respiratory apparatus with filter elements
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62BDEVICES, APPARATUS OR METHODS FOR LIFE-SAVING
    • A62B9/00Component parts for respiratory or breathing apparatus
    • A62B9/06Mouthpieces; Nose-clips
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00Catalysts comprising molecular sieves
    • B01J29/04Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10After treatment, characterised by the effect to be obtained
    • B01J2229/18After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself

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  • Health & Medical Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Pulmonology (AREA)
  • General Health & Medical Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Respiratory Apparatuses And Protective Means (AREA)
  • Catalysts (AREA)

Abstract

The invention discloses a breathing mask suitable for being used in high pollution weather. The breathing mask comprises a mask body covered with a knitted fabric. The mask body comprises a filter element connecting hole, a lens hole, an exhausting hole and a hanging hook, wherein a filter element is connected with the filter element connecting hole; a lens is mounted in the lens hole; an exhausting unit used for exhausting inner air is mounted on the exhausting hole; the hanging hook is designed to backwards protrude. A wearer wears the mask on the face so as to protect the face from harm of toxic substances. The filter element is sequentially provided with a first adsorption part, a catalysis part and a second adsorption part in the air flowing direction. By means of the breathing mask, when PM2.5 of haze reaches above 1000, air can be purified till the PM2.5 is zero, benzene, methylbenzene, dimethylbenzene, ethylbenzene, vinyl benzene, formaldehyde, acetaldehyde and acrolein in the air are removed to reach below 0.01mg per cubic meter, and meanwhile skin and eyes of the wearer can be protected.

Description

A kind of breathing mask of applicable high pollution weather
Technical field
The present invention relates to technical field of air purification, be specifically related to a kind of breathing mask of applicable high pollution weather.
Background technology
Haze weather is a kind of atmosphere pollution state, haze is the general statement to suspended particulate substance content overproof various in air, and especially PM2.5 (equivalent aerodynamic diameter is less than or equal to the particle of 2.5 microns) is considered to " arch-criminal " that cause haze weather.Sulfur dioxide, nitrogen oxide and pellet are the main compositions of haze.
In early or mid November, 2015, the city being representative with Shenyang and other places, its haze PM2.5 index reaches surprising 1140, belongs to serious pollution.Under this kind of environment, pollutant not only injures the respiratory system of people, and the organs such as eyes also can be caused to produce burning sensation, the health of damage eyes.
Existing safeguard procedures, be generally adopt mouth mask, mouth mask divides the medical mask only possessing filtering function, and doped with the mouth mask of active carbon.This kind of mouth mask, only play filtering function, can not filter completely the fine particle in air, pernicious gas simultaneously in air, such as sulfur and nitrogen oxides, even the organic pollution such as toluene, formaldehyde, methacrylaldehyde, still enters the respiratory system of wearer, causes very big infringement to healthy by above-mentioned mouth mask.
Meanwhile, described protection, is only placed in nose and mouth, and for other organs of face, such as eyes, without any protective effect.Also have breathing mask on sale at present on the market, its design with reference to breathing mask simplifies.But this kind of breathing mask is heavier, is generally only suitable for protecting operator to use in extreme environments, wears in daily life, comfortableness is very large problem, and meanwhile, its aesthetics is also inadequate, is not suitable for wearing in daily life.
Summary of the invention
The object of the invention is to propose a kind of breathing mask being applicable to highly polluted weather; it adopts specific expiration and air suction structure; under the prerequisite realizing filtering function; catalysis can also be carried out to air; by the harmful substance in air; such as nitrogen oxide, oxycarbide, organic odor contamination such as benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, methacrylaldehyde etc.; carry out decomposing, being oxidized or/and adsorb; bactericidal purifying is carried out to air; guarantee filtered air is clean, protects the healthy of operator.
An object of the present invention is also to provide a kind of breathing mask, while the respiratory system of protection wearer, can protect eyes and the skin of face of wearer.
For reaching this object, the present invention by the following technical solutions:
Be applicable to a breathing mask for highly polluted weather, comprise the mask bodies covered by knitted fabric, described face shield comprises: filter core connecting hole, and filter core is connected with described filter core connecting hole; Lens opening, lens are arranged in described lens opening; Steam vent, the exhaust unit for discharging inner air is installed to described steam vent; And hook, be set to rearward projection, described mask is worn on the face of user to protect face not by the infringement of noxious material, and described filter core, according to the flow direction of air, is successively provided with the first adsorption element, catalytic member and the second adsorption element.
Described first adsorption element is provided with fibrous filter layer, and described fibrous filter layer is superimposed with paper fiber thing filter course and ultra-fine fibre glass thing filter course.
Described catalytic member is provided with catalyst layer, and described catalyst comprises following component,
A) molybdenum of 0.3%-10%, zirconium, vanadium and tungsten composite oxides, its mol ratio is 1:(0.5-2): (0.5-2): (0.5-2);
B) silver of 0.3%-6% and anatase titanium dioxide, the mol ratio of Ag and Ti is 2:5;
C) ZSM-5 molecular sieve of surplus.
Described second adsorption element is provided with adsorption layer, and described adsorption layer is made up of the nano titanium oxide of active carbon and Ag-bearing, and its mixing quality such as, than being 5:1-2:1,4.5:1,4:1,3.5:1,3:1 etc.
Breathing mask of the present invention is placed in the mouth and nose of wearer, the air sucked enters the first adsorption element, in the first adsorption element, successively through the filtration of paper fiber layer and ultra-fine fibre glass layer, the particle in air and macromolecular substances are filtered.
Air after filtering enters catalytic member subsequently, and in catalytic member, the organic pollution in air, such as formaldehyde etc., catalyzed oxidation, becomes harmless or be easy to other organic matters of absorbing.
Air after catalysis, enters the second adsorption element.In air, the organic pollution of catalyzed oxidation is absorbed by active carbon, and is distributed in the silver in active carbon, kills virus to the microorganism in air, thus reduces the content of bacterium.Thus the protection achieved wearer's respiratory system.
The breathing mask of applicable high pollution weather of the present invention adopts the mask of knitted fabric covering, mask bodies adopts rubber, silica gel, flexible PVC, TPU or PU polyurethane, TPE or TPR elastomeric material, the material of described main body is soft so and possess elasticity, compare with the face of wearer and agree with, can not produce and wear space thus the generation causing the situations such as gas leakage.Described mask bodies adopts knitted fabric to cover, and can promote the comfort level of wearer on the one hand, can increase aesthetics on the other hand.
Face shield of the present invention possesses lens, and described lens the eyes of available protecting wearer can can't affect sight line.
Filter core of the present invention is according to the flow direction of air, successively be provided with the first adsorption element, catalytic member and the second adsorption element, filter core is by choosing specific components A and B component, this catalyst is made to produce cooperative effect, can, when haze PM2.5 reaches more than 1000, this breathing mask be still made significantly to drop to 0 to haze PM2.5 in air.Simultaneously, catalyst activity of the present invention is high, catalytic action can be played under room temperature, the organic matter degradations such as the formaldehyde in air, benzene are called carbon dioxide, and be higher valence state by harmful oxysulfide, nitrogen oxide catalytic oxidation, and then with charcoal absorption, various pollutant is reduced to ppm level.The removal of benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, methacrylaldehyde reaches less than 0.01 milligram/cubic metre, significantly reduces the content of microorganisms in circulating air simultaneously.
Detailed description of the invention
The present invention is described breathing mask of the present invention by following embodiment.
Embodiment 1
Be applicable to a breathing mask for highly polluted weather, comprise the mask bodies covered by knitted fabric, described face shield comprises: filter core connecting hole, and filter core is connected with described filter core connecting hole; Lens opening, lens are arranged in described lens opening; Steam vent, the exhaust unit for discharging inner air is installed to described steam vent; And hook, be set to rearward projection, described mask is worn on the face of user to protect face not by the infringement of noxious material, and described filter core, according to the flow direction of air, is successively provided with the first adsorption element, catalytic member and the second adsorption element.
Described first adsorption element is provided with fibrous filter layer, and described fibrous filter layer sequencing is superimposed with paper fiber thing filter course and ultra-fine fibre glass thing filter course.
Described catalytic member is provided with catalyst layer, prepares catalyst by infusion process, comprises following component,
A) 9% molybdenum, zirconium, vanadium and tungsten composite oxides, its mol ratio is 1:1:1:1;
B) 6% silver and anatase titanium dioxide, the mol ratio of Ag and Ti is 2:5;
C) ZSM-5 molecular sieve of surplus.
Described second adsorption layer is made up of the nano titanium oxide of active carbon and Ag-bearing, and its mixing quality is than being 3:1.
For testing its purification function, passing into haze PM2.5 index is the air of 1400, and makes the benzene,toluene,xylene of gas, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein reach 10 milligrams/cubic metre, and dust content is medium.By described gas by breathing mask of the present invention, its haze PM2.5 index decreased is 0, and benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein reach less than 0.01 milligram/cubic metre.
Comparative example 1
Component A content 15%, not containing B component, all the other conditions are constant, and its PM2.5 value is 40, and benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein are more than 0.1 milligram/cubic metre.
Comparative example 2
B component content 15%, not containing component A, all the other conditions are constant, and its PM2.5 value is 39, and benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein are more than 0.1 milligram/cubic metre.
Comparative example 3
The ZSM-5 molecular sieve of component C is replaced with alundum (Al2O3), and all the other conditions are constant, and its PM2.5 value is 47, and benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein are more than 0.1 milligram/cubic metre.
Above-described embodiment and comparative example explanation, specific contact is there is between several component of canister of breathing mask of the present invention and between catalyst carrier, omit or replace wherein one or more, all can not reach the certain effects of the application, prove to which create cooperative effect.
Applicant states, the present invention illustrates the catalyst of breathing mask of the present invention and employing by above-described embodiment, but the present invention is not limited to above-mentioned catalyst, does not namely mean that the present invention must rely on above-mentioned detailed catalysts and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.

Claims (1)

1. be applicable to a breathing mask for highly polluted weather, comprise the mask bodies covered by knitted fabric, described face shield comprises: filter core connecting hole, and filter core is connected with described filter core connecting hole; Lens opening, lens are arranged in described lens opening; Steam vent, the exhaust unit for discharging inner air is installed to described steam vent; And hook, be set to rearward projection, described mask is worn on the face of user to protect face not by the infringement of noxious material, and described filter core, according to the flow direction of air, is successively provided with the first adsorption element, catalytic member and the second adsorption element;
Described first adsorption element is provided with fibrous filter layer, and described fibrous filter layer is superimposed with paper fiber thing filter course and ultra-fine fibre glass thing filter course;
Described catalytic member is provided with catalyst layer, and described catalyst comprises following component,
A) molybdenum of 0.3%-10%, zirconium, vanadium and tungsten composite oxides, its mol ratio is 1:(0.5-2): (0.5-2): (0.5-2);
B) silver of 0.3%-6% and anatase titanium dioxide, the mol ratio of Ag and Ti is 2:5;
C) ZSM-5 molecular sieve of surplus;
Described second adsorption filtration adsorption element is provided with adsorption layer, and described adsorption layer is made up of the nano titanium oxide of active carbon and Ag-bearing, and its mixing quality is than being 5:1-2:1.
CN201510777506.8A 2015-11-13 2015-11-13 Breathing mask suitable for being used in high pollution weather Pending CN105435383A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201510777506.8A CN105435383A (en) 2015-11-13 2015-11-13 Breathing mask suitable for being used in high pollution weather

Publications (1)

Publication Number Publication Date
CN105435383A true CN105435383A (en) 2016-03-30

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101209391A (en) * 2006-12-30 2008-07-02 中国石油化工股份有限公司 Method for removing oxysulfide and/or nitrogen oxide from flue gas and hydrocarbon oil cracking method
CN103191718A (en) * 2013-04-23 2013-07-10 江苏龙源催化剂有限公司 Preparation method of low-cost honeycomb denitration catalyst
CN103596678A (en) * 2011-02-07 2014-02-19 水晶美国股份公司 Ce containing, V-free mobile denox catalyst
CN104069867A (en) * 2014-07-11 2014-10-01 武汉大学 Monolithic catalyst as well as preparation method and application thereof
CN104837429A (en) * 2012-11-22 2015-08-12 株式会社山凊 Gas mask
CN204708043U (en) * 2015-05-23 2015-10-21 河南亚都实业有限公司 A kind of medical mask

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101209391A (en) * 2006-12-30 2008-07-02 中国石油化工股份有限公司 Method for removing oxysulfide and/or nitrogen oxide from flue gas and hydrocarbon oil cracking method
CN103596678A (en) * 2011-02-07 2014-02-19 水晶美国股份公司 Ce containing, V-free mobile denox catalyst
CN104837429A (en) * 2012-11-22 2015-08-12 株式会社山凊 Gas mask
CN103191718A (en) * 2013-04-23 2013-07-10 江苏龙源催化剂有限公司 Preparation method of low-cost honeycomb denitration catalyst
CN104069867A (en) * 2014-07-11 2014-10-01 武汉大学 Monolithic catalyst as well as preparation method and application thereof
CN204708043U (en) * 2015-05-23 2015-10-21 河南亚都实业有限公司 A kind of medical mask

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Application publication date: 20160330