CN105425716B - The intelligent preparation system and method for a kind of mesoporous material - Google Patents
The intelligent preparation system and method for a kind of mesoporous material Download PDFInfo
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- 238000002360 preparation method Methods 0.000 title claims abstract description 27
- 239000013335 mesoporous material Substances 0.000 title claims abstract description 26
- 238000000034 method Methods 0.000 title abstract description 12
- 239000000463 material Substances 0.000 claims abstract description 73
- 238000005303 weighing Methods 0.000 claims abstract description 39
- 238000003756 stirring Methods 0.000 claims abstract description 37
- 238000005406 washing Methods 0.000 claims abstract description 21
- 238000001514 detection method Methods 0.000 claims abstract description 18
- 238000003860 storage Methods 0.000 claims description 236
- 238000006243 chemical reaction Methods 0.000 claims description 66
- 230000001960 triggered effect Effects 0.000 claims description 31
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 27
- 229910052757 nitrogen Inorganic materials 0.000 claims description 25
- 239000000243 solution Substances 0.000 claims description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 230000015572 biosynthetic process Effects 0.000 claims description 13
- 229910001220 stainless steel Inorganic materials 0.000 claims description 13
- 239000010935 stainless steel Substances 0.000 claims description 13
- 238000003786 synthesis reaction Methods 0.000 claims description 13
- 239000008367 deionised water Substances 0.000 claims description 11
- 229910021641 deionized water Inorganic materials 0.000 claims description 11
- 230000011664 signaling Effects 0.000 claims description 10
- 239000007864 aqueous solution Substances 0.000 claims description 9
- 230000005540 biological transmission Effects 0.000 claims description 9
- 238000010438 heat treatment Methods 0.000 claims description 8
- LZZYPRNAOMGNLH-UHFFFAOYSA-M Cetrimonium bromide Chemical compound [Br-].CCCCCCCCCCCCCCCC[N+](C)(C)C LZZYPRNAOMGNLH-UHFFFAOYSA-M 0.000 claims description 7
- 230000006698 induction Effects 0.000 claims description 5
- 238000001914 filtration Methods 0.000 claims description 4
- 238000005119 centrifugation Methods 0.000 claims 1
- 239000007788 liquid Substances 0.000 claims 1
- 238000001139 pH measurement Methods 0.000 abstract description 3
- 238000012806 monitoring device Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 description 5
- 238000005192 partition Methods 0.000 description 4
- 239000011148 porous material Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 238000004438 BET method Methods 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000009903 catalytic hydrogenation reaction Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000000151 deposition Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000012065 filter cake Substances 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 239000002808 molecular sieve Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 235000011837 pasties Nutrition 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- URGAHOPLAPQHLN-UHFFFAOYSA-N sodium aluminosilicate Chemical compound [Na+].[Al+3].[O-][Si]([O-])=O.[O-][Si]([O-])=O URGAHOPLAPQHLN-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 239000010457 zeolite Substances 0.000 description 1
Classifications
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- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B19/00—Programme-control systems
- G05B19/02—Programme-control systems electric
- G05B19/04—Programme control other than numerical control, i.e. in sequence controllers or logic controllers
- G05B19/05—Programmable logic controllers, e.g. simulating logic interconnections of signals according to ladder diagrams or function charts
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B19/00—Programme-control systems
- G05B19/02—Programme-control systems electric
- G05B19/04—Programme control other than numerical control, i.e. in sequence controllers or logic controllers
- G05B19/05—Programmable logic controllers, e.g. simulating logic interconnections of signals according to ladder diagrams or function charts
- G05B19/058—Safety, monitoring
-
- G—PHYSICS
- G05—CONTROLLING; REGULATING
- G05B—CONTROL OR REGULATING SYSTEMS IN GENERAL; FUNCTIONAL ELEMENTS OF SUCH SYSTEMS; MONITORING OR TESTING ARRANGEMENTS FOR SUCH SYSTEMS OR ELEMENTS
- G05B2219/00—Program-control systems
- G05B2219/10—Plc systems
- G05B2219/16—Plc to applications
- G05B2219/163—Domotique, domestic, home control, automation, smart, intelligent house
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Automation & Control Theory (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Abstract
The invention discloses the intelligent preparation systems and method of a kind of mesoporous material, it includes：Valve control module, input module, PLC, Weighing module, alarm module, stirring module, PH detection modules, washing module, irradiation modules and roasting module；Input module inputs the gross mass N of material, PH detection modules detect the pH value of solution, and PLC performs relevant operation according to each Digital Signals valve control module of input value, pH value and reception, Weighing module, alarm module, stirring module, washing module, irradiation modules and roasting module.Present invention incorporates controlling and automatically controlling manually, operation is facilitated, the energy saving energy；Parameters that can also be in stringent control system, such as the sensing of pH value, material, time and proportion scale, substantially increase reliability and the safety of preparation system, also with monitoring device, have and alarm and self-protection function.
Description
Technical field
The present invention relates to automation field, the intelligent preparation system and method for especially a kind of mesoporous material.
Background technology
From the angle of the utilization of resources and environmental protection, high-efficiency coal cleaning resources technology, exploitation " green fuel " tool are utilized
There are important strategic importance and application prospect.CO catalytic hydrogenations synthesizing low-carbon mixed alcohol (C1-C6 mixed alcohols) is that coal resources are clean
One of important channel of net profit.The application prospect of low carbon mixed alcohol depends on the exploitation of catalyst haveing excellent performance.
Mesoporous material refers to a polyporous materials of the aperture between 2-50nm.Mesoporous material have high specific surface area,
The features such as regular pore passage structure, narrow pore-size distribution, pore size are continuously adjustable so that it is in many micro-pore zeolites
Molecular sieve is difficult to play a role in the absorption for the macromolecular completed, separation, especially catalysis reaction.Moreover, this material has
Sequence duct can be used as " microreactor ", become after uniform and stable " object " material of assembling with nanoscale wherein
" Subjective and Objective material ", the small-size effect that may have due to its master, host and guest's bulk effect between object and guest materials, quantum
Dimensional effect etc. will be allowed to be expected in electrode material, photoelectric device, microelectric technique, chemical sensor, nonlinear optical material
The fields of grade are widely used.Therefore mesoporous material from it be born attracted at the very start in the world physics, chemistry, biology,
The broad interest in the multidisciplinary researches such as material and information field, become at present in the world across multi-disciplinary hot spot Disciplinary Frontiers it
One.
And the preparation of mesoporous material and its design of automatic control system all the quality of mesoporous material is played it is most important
Effect, if its time, pH value and proportion scale cannot be controlled strictly, seriously affect its effect for playing in catalysis is reacted.
The preparation system efficiency of present mesoporous material is low, and the degree of automation is low, and depends on manual operation and artificial judgment mostly,
When particularly feeding, need manually to go charging dispensing.And the safety monitoring assembly of existing most of preparation system is less, function
It is incomplete, do not have warning function and self-protection function.
Invention content
The goal of the invention of the present invention is：In view of the above problems, the intelligence for providing a kind of mesoporous material prepares system
System and method, combine and control and automatically control manually, eliminate manually-operated trouble, while also automatically controlling realization ratio
Manual operation is added during compared with waste of resource, facilitates operation, the energy saving energy；Parameters in the stringent control system of energy,
Such as sensing of pH value, material, time and proportion scale, substantially increase reliability and the safety of preparation system, also have prison
It surveys device, there is alarm and self-protection function.
The technical solution adopted by the present invention is as follows：
A kind of intelligent preparation system of mesoporous material, it includes：Valve control module, input module, PLC, Weighing module,
Alarm module, stirring module, PH detection modules, washing module, irradiation modules and roasting module；
Input module includes input equipment, for inputting the gross mass N of required material, and is converted into digital signaling zero 01 and passes
It is handed to PLC；
PH detection modules include the PH detectors set on reaction unit two, for detecting the PH of solution in reaction unit two
Value, when pH value=8.5, to PLC transmitting digital signals 101；
PLC respectively with valve control module, input module, Weighing module, alarm module, stirring module, PH detection modules,
Washing module, irradiation modules are connected with roasting module, for receiving digital signaling zero 01, transmit and perform to valve control module
Signal 201 transmits to Weighing module and performs signal 301；Digital signal 401 is received, is transmitted to valve control module and performs signal
202；Digital signal 402 is received, is transmitted to valve control module and performs signal 203；Digital signal 403 is received, is controlled to valve
Module, which is transmitted, performs signal 204；Digital signal 404 is received, is transmitted to valve control module and performs signal 205；Receive number letter
Numbers 405, it is transmitted to valve control module and performs signal 206；Digital signal 406 is received, is transmitted to stirring module and performs signal
501, and transmitted to valve control module and perform signal 207；Digital signal 407 is received, letter is performed to valve control module transmission
Numbers 208；Digital signal 101 is received, is transmitted to valve control module and performs signal 209, is transmitted to stirring module and performs signal
502；Digital signal 408 is received, is transmitted to alarm module and performs signal 601；Digital signal 409 is received, is transmitted to alarm module
Perform signal 602；Digital signal 410 is received, is transmitted to valve control module and performs signal 210；Digital signal 411 is received, to
Alarm module, which transmits, performs signal 603；Digital signal 412 is received, is transmitted to alarm module and performs signal 604；
Valve control module includes solenoid valve one, solenoid valve two, solenoid valve three, solenoid valve four and solenoid valve five；For connecing
Row signal 201 is accepted, opens the solenoid valve one in storage box one, storage box two, storage box three, storage box four and storage box five；
It receives and performs signal 202, close the solenoid valve one in storage box one, open the solenoid valve two in storage box one, closed after 10min
It closes；It receives and performs signal 203, close the solenoid valve one in storage box two, the solenoid valve two in storage box two is opened, after 10min
It closes；
It receives and performs signal 204, close the solenoid valve one in storage box three, open the solenoid valve two in storage box three,
It is closed after 10min；It receives and performs signal 205, close the solenoid valve one in storage box four, open the solenoid valve two on storage tank four,
It closes after 20 min, completes backward PLC transmitting digital signals 406；It receives and performs signal 206, close the electromagnetism in storage box five
Valve one is opened the solenoid valve two on storage tank five, is closed after 10min；It receives and performs signal 207, opens solenoid valve three, after 30min
It closes；It receives and performs signal 208, open the solenoid valve two in storage box six；It receives and performs signal 209, close in storage box six
Solenoid valve two；It receives and performs signal 210, open solenoid valve five, closed after 30min；
Weighing module includes weighing device, signal 301 is performed for receiving, for weighing the weight of material T in each storage box；
Weighing module is additionally operable to：In storage box one, as T=18%N, to PLC transmitting digital signals 401；In storage box two, when
During T=18%N, to PLC transmitting digital signals 402；In storage box three, as T=64%N, to PLC transmitting digital signals
403；In storage box four, as T=66%N, to PLC transmitting digital signals 401；In storage box five, when T=predetermined weights
When 01, to PLC transmitting digital signals 405；
It stirs module and includes blender；Signal 501 is performed for receiving, starts blender, is closed after stirring 20min, it is complete
Into backward PLC transmitting digital signals 407；It receives and performs signal 502, start blender, closed after 60min, complete backward PLC and pass
Pass digital signal 408；
Alarm module includes alarm, for receiving execution signal 601, execution signal 602, execution signal 603 and performing
Signal 604 starts alarm, is closed after 2min；
Heating module includes the heater set on stainless steel synthesis reactor, and the heater is equipped with trigger button three, works as triggering
After button three is triggered, start heater, holding mode is adjusted to after being heated to 120 DEG C, heater is closed after keeping the temperature 90h, and
To PLC transmitting digital signals 409；
Washing module includes centrifuge, and the centrifuge is equipped with trigger button four, after trigger button four is triggered, starts
Centrifuge, which (washs material), closes centrifuge after 1h, and to PLC transmitting digital signals 410；
Irradiation modules include baking oven, and after trigger button one is triggered, (oven temperature is adjusted to 60 DEG C) starts baking oven
It is closed after 30min, completes backward PLC transmitting digital signals 411；
It roasts module and includes calciner, after trigger button two is triggered, start the calciner, (calciner
Keep the temperature 3h after its interior temperature is heated to 500 DEG C) roasting 3h after close calciner, complete backward PLC transmitting digital signals
412。
By adopting the above scheme, the material gross mass needed for input in the input equipment, according to material gross mass and
The ratio of each material distributes the quality of each material, and PH detection modules have accurately detected the pH value of solution in reaction unit two,
Valve control module admirably controls the open and close of each solenoid valve, and the major part for saving staff is troublesome in poeration, and
Real-time of the present invention is excellent, and stability is good, Weighing module also can each weight of material for setting of automatic weighing, present invention incorporates hands
Dynamic operation is with automatically controlling, and when needing manual operation, by alarm, staff is reminded to be operated, during which work people
Member can do other things, and intelligence degree is high.
Further, it further includes set on storage box one, storage box two, storage box three, storage box four, storage box five and deposits
The infrared induction module of storage tank six, the infrared induction module include infrared inductor, when material is less than very in each storage box
For the moment, to PLC transmitting digital signals 10, PLC receives digital signal 10, is transmitted to alarm module and performs signal 20；Alarm mould
Block, which receives, performs signal 20, starts alarm, is closed after 2min.
By adopting the above scheme, infrared induction module accurately senses material storage condition, when in material storage tank
When each material amount of storage runs low, start alarm, remind staff that material is replenished in time, there is monitoring and warning function.
A kind of intelligent preparation method of the intelligent preparation system of mesoporous material, it includes the following steps：
Step 1：Install each equipment；Cu (NO3) 23H2O is stored in storage box one, Co (NO3) 26H2O is deposited
Storage tank two, ZrOCl28H2O deposits storage box three, deionized water deposit storage box four, the deposit of trimethyl cetyl ammonium bromide
Storage box five and NaOH aqueous solutions deposit storage box six；Open a kind of power supply of the intelligent preparation system of mesoporous material；
Step 2：In input equipment input needed for material gross mass N, then input module be translated into digital signal
001 is transferred to PLC；PLC receives digital signaling zero 01, is transmitted to valve control module and performs signal 201, is transmitted to Weighing module
Perform signal 301；Valve control module, which receives, performs signal 201, opens storage box one, storage box two, storage box three, storage box
Four and storage box five on solenoid valve one；Weighing module, which receives, performs signal 301, and Weighing module weighs the material in each storage box
Weight T；Weighing module also performs the following contents：In storage box one, as T=18%N, to PLC transmitting digital signals 401；
In storage box two, as T=18%N, to PLC transmitting digital signals 402；In storage box three, as T=64%N, to
PLC transmitting digital signals 403；In storage box four, as T=66%N, to PLC transmitting digital signals 401；In storage box five
In, when T=predetermined weights 01, to PLC transmitting digital signals 405；
Step 3：PLC receives digital signal 401, is transmitted to valve control module and performs signal 202；Valve control module connects
Row signal 202 is accepted, closes the solenoid valve one in storage box one, the solenoid valve two in storage box one is opened, is closed after 10min；
Step 4：PLC receives digital signal 402, is transmitted to valve control module and performs signal 203；Valve control module connects
Row signal 203 is accepted, closes the solenoid valve one in storage box two, the solenoid valve two in storage box two is opened, is closed after 10min；
Step 5：PLC receives digital signal 403, is transmitted to valve control module and performs signal 204；Valve control module connects
Row signal 204 is accepted, closes the solenoid valve one in storage box three, the solenoid valve two in storage box three is opened, is closed after 10min；
Step 6：PLC receives digital signal 404, is transmitted to valve control module and performs signal 205；Valve control module connects
Row signal 205 is accepted, closes the solenoid valve one in storage box four, the solenoid valve two on storage tank four is opened, closes after 20 min,
Complete backward PLC transmitting digital signals 406；
Step 7：PLC receives digital signal 405, is transmitted to valve control module and performs signal 206；Valve control module connects
Row signal 206 is accepted, closes the solenoid valve one in storage box five, the solenoid valve two on storage tank five is opened, is closed after 10min；
Step 8：PLC receives digital signal 406, is transmitted to stirring module and performs signal 501, and passed to valve control module
It passs and performs signal 207；It stirs module and receives execution signal 501, start blender, closed after stirring 20min, complete backward PLC
Transmitting digital signals 407；Valve control module, which receives, performs signal 207, opens solenoid valve three, is closed after 30min；It that is, will be anti-
The solution in device one is answered to be mixed and stirred for the solution in reaction unit two；
Step 9：PLC receives digital signal 407, is transmitted to valve control module and performs signal 208；Valve control module connects
Row signal 208 is accepted, opens the solenoid valve two in storage box six；That is, NaOH aqueous solutions are instilled into reaction unit two, to adjust
Save the pH value of solution；The pH value of solution in PH detection modules detection reaction unit two, when pH value=8.5, number is transmitted to PLC
Signal 101；PLC receives digital signal 101, is transmitted to valve control module and performs signal 209, and letter is performed to stirring module transmission
Numbers 502；Valve control module, which receives, performs signal 209, closes the solenoid valve two in storage box six；Stirring module reception performs letter
Numbers 502, start blender, closed after 60min, complete backward PLC transmitting digital signals 408；
Step 10：PLC receives digital signal 408, is transmitted to alarm module and performs signal 601；Alarm module, which receives, to be performed
Signal 601 starts alarm, is closed after 2min, staff is reminded to take out floccule obtained by the reaction, and move to stainless steel
In synthesis reactor；After floccule obtained by the reaction is moved to stainless steel synthesis reactor, trigger button three is triggered, when trigger button three is touched
After hair, heating module starts its heater, and holding mode is adjusted to after being heated to 120 DEG C, and heater is closed after keeping the temperature 90h, and
To PLC transmitting digital signals 409；
Step 11：PLC receives digital signal 409, is transmitted to alarm module and performs signal 602；Alarm module, which receives, to be performed
Signal 602 starts alarm, is closed after 2min；Prompting staff material is discharged in centrifuge, by material be discharged to from
After scheming, the trigger button four on centrifuge is triggered, after trigger button four is triggered, then washing module startup centrifuge (will
Material is washed) close centrifuge after 1h, and to PLC transmitting digital signals 410；
Step 12：PLC receives digital signal 410, is transmitted to valve control module and performs signal 210；Valve control module
It receives and performs signal 210, open solenoid valve five, closed after 30min；That is, the material in centrifuge is put by solenoid valve five
It is filtered in filter device；Material after filtering is placed in baking oven, trigger button one is triggered, when trigger button one is triggered
Afterwards, (oven temperature is adjusted to 60 DEG C) then irradiation modules closed after starting baking oven 30min, complete backward PLC and transmit number letter
Numbers 411；PLC receives digital signal 411, is transmitted to alarm module and performs signal 603；Alarm module, which receives, performs signal 603, opens
Alarm is moved, is closed after 2min, prompts staff that dried material is put into calciner；
Step 13：Dried material is put into calciner, trigger button two is triggered, when trigger button two is touched
After hair, then roast module and start calciner, (calciner keeps the temperature 3h after its interior temperature is heated to 500 DEG C) roasting 3h
After close calciner, complete backward PLC transmitting digital signals 412, PLC receives digital signal 412, is held to alarm module transmission
Row signal 604；Alarm module, which receives, performs signal 604, starts alarm, is closed after 2min.
The preparation facilities of the intelligent preparation system of this kind of mesoporous material, it includes reaction unit and water washing device, described anti-
Device is answered to be divided into reaction unit one and reaction unit two, the reaction unit is equipped with feeding mouth and discharge port, the reaction unit
One discharge port is connect by conduit with the feeding mouth of reaction unit two, and the conduit is equipped with solenoid valve three；The washing dress
It puts including feeding mouth and discharge port, the discharge port is connect by conduit two with filter device, and solenoid valve is set on the conduit two
Four, the reaction unit top is provided with material storage device, and blender is equipped in the reaction unit two；The water washing device
Top is equipped with heating unit.
Due to using the above structure, by Cu (NO3) 23H2O, Co (NO3) 26H2O and ZrOCl28H2O and go from
Sub- water is miscible in reaction unit one；By trimethyl cetyl ammonium bromide and deionized water in reaction unit two, then open
Solution in reaction unit one and reaction unit two is mixed, can be controlled with agreeing with according to the needs of reaction by solenoid valve three therebetween
System reaction.
Further, the material storage device is included for storing the storage box one of Cu (NO3) 23H2O, for depositing
Store up Co (NO3) 26H2O storage box two, for store ZrOCl28H2O storage box three, for storing deionized water
Storage box four, the storage box for the storage box five that stores trimethyl cetyl ammonium bromide and for storing NaOH aqueous solutions
Six；In the storage box one, storage box two, storage box three, storage box four and storage box five all upper strata is classified as equipped with partition board
Case and lower floor's case, for storing material, lower floor's case is equipped with weighing device, electricity is all equipped on each partition board the upper strata case
Magnet valve one；The storage box one, storage box two, storage box three, storage box four and storage box five six bottom of lower floor's case and storage box
End is equipped with solenoid valve two；Conduit is connected on the solenoid valve two；Conduit on the solenoid valve two of the storage box four is behaved
Font conduit；Two bypass ducts are respectively placed in reaction unit one and reaction unit two；It is placed in one bypass ducts diameter of reaction unit
To be placed in 1/10th of two bypass ducts of reaction unit.
By adopting the above scheme, in advance by various material storings in the correspondence storage box of material storage device, with
Then, it by controlling solenoid valve one that material is fed through to the lower floor of storage box from storage box upper strata, is weighed by weighing device predetermined
The material of dosage eliminates staff and calculates and weigh step by step the trouble that could be prepared, by controlling solenoid valve
Two, the material of predetermined close is directly put into from storage box into reaction unit, facilitates operation, while saved the time.
Four memory of storage box is placed with deionized water, has chevron shaped conduit on the solenoid valve two of its lower floor, and be placed in reaction unit one
Bypass ducts are a diameter of to be placed in 1/10th of two bypass ducts of reaction unit, when opening solenoid valve two, flows into reaction unit
One deionized water volume is 1/10th of the deionized water in injection reaction unit two.
Further, stainless steel synthesis reactor, baking oven, centrifuge and calciner are further included, the baking oven is equipped with triggering
Button one, the calciner are equipped with trigger button two；The centrifuge is connect by conduit with filter device, the conduit
It is equipped with solenoid valve five；The conduit of the storage box one, storage box two and storage box three is placed at the feeding mouth of reaction unit one,
The conduit of the storage box five and storage box six is placed at the feeding mouth of middle reaction unit two.
By adopting the above scheme, it is heated in stainless steel synthesis reactor, the dried material in baking oven, in centrifuge
Material washing is carried out, is roasted in calciner, control manually is combined and, with automatically controlling, facilitates operation, also save
Cost.
In conclusion by adopting the above-described technical solution, the beneficial effects of the invention are as follows：
1st, present invention incorporates controlling and automatically controlling manually, manually-operated trouble is eliminated, while also controlling automatically
System adds manual operation when realizing more wasteful resource, facilitates operation, the energy saving energy；
2nd, the parameters in the stringent control system of energy, such as the sensing of pH value, material, time and proportion scale, carry significantly
The reliability of high preparation system and safety；
3rd, the present invention also with monitoring device, with alarm and self-protection function.
Description of the drawings
Examples of the present invention will be described by way of reference to the accompanying drawings, wherein：
Fig. 1 is a kind of internal control figure of the intelligence control system of mesoporous material.
Specific embodiment
All features or disclosed all methods disclosed in this specification or in the process the step of, in addition to mutually exclusive
Feature and/or step other than, can combine in any way.
Any feature disclosed in this specification (including any accessory claim, abstract), unless specifically stated,
It is replaced by other equivalent or with similar purpose alternative features.That is, unless specifically stated, each feature is a series of
An example in equivalent or similar characteristics.
A kind of preparation facilities of mesoporous material, it includes reaction unit and water washing device, and the reaction unit is divided into reaction
Device one and reaction unit two, the reaction unit are equipped with feeding mouth and discharge port, and the discharge port of the reaction unit one passes through
Conduit is connect with the feeding mouth of reaction unit two, and the conduit is equipped with solenoid valve three；The water washing device include feeding mouth and
Discharge port, the discharge port are connect by conduit two with filter device, and solenoid valve four, the reaction unit are set on the conduit two
Top is provided with material storage device, and blender is equipped in the reaction unit two；Heating dress is equipped with above the water washing device
It puts.
The material storage device is included for storing the storage box one of Cu (NO3) 23H2O, for storing Co (NO3)
The storage box two of 26H2O, for store ZrOCl28H2O storage box three, for store the storage box four of deionized water,
Storage box six for the storage box five for storing trimethyl cetyl ammonium bromide and for storing NaOH aqueous solutions；The storage
Upper strata case and lower floor's case all are classified as equipped with partition board in case one, storage box two, storage box three, storage box four and storage box five,
For storing material, lower floor's case is equipped with weighing device, solenoid valve one is all equipped on each partition board the upper strata case；It is described
Storage box one, storage box two, storage box three, lower floor's case of storage box four and storage box five and six bottom end of storage box are equipped with electromagnetism
Valve two；Conduit is connected on the solenoid valve two；Conduit on the solenoid valve two of the storage box four is chevron shaped conduit；Two
Road conduit is respectively placed in reaction unit one and reaction unit two；It is placed in that one bypass ducts of reaction unit are a diameter of to be placed in reaction unit
/ 10th of two bypass ducts.
Stainless steel synthesis reactor, baking oven, centrifuge and calciner are further included, the baking oven is equipped with trigger button one, institute
Calciner is stated equipped with trigger button two；The centrifuge is connect by conduit with filter device, and the conduit is equipped with electricity
Magnet valve five；The conduit of the storage box one, storage box two and storage box three is placed at the feeding mouth of reaction unit one, the storage
Case five and the conduit of storage box six are placed at the feeding mouth of middle reaction unit two.
The intelligent preparation system of a kind of mesoporous material, which is characterized in that it includes：Valve control module, input module,
PLC, Weighing module, alarm module, stirring module, PH detection modules, washing module, irradiation modules and roasting module；
Input module includes input equipment, for inputting the gross mass N of required material, and is converted into digital signaling zero 01 and passes
It is handed to PLC；
PH detection modules include the PH detectors set on reaction unit two, for detecting the PH of solution in reaction unit two
Value, when pH value=8.5, to PLC transmitting digital signals 101；
PLC respectively with valve control module, input module, Weighing module, alarm module, stirring module, PH detection modules,
Washing module, irradiation modules are connected with roasting module, for receiving digital signaling zero 01, transmit and perform to valve control module
Signal 201 transmits to Weighing module and performs signal 301；Digital signal 401 is received, is transmitted to valve control module and performs signal
202；Digital signal 402 is received, is transmitted to valve control module and performs signal 203；Digital signal 403 is received, is controlled to valve
Module, which is transmitted, performs signal 204；Digital signal 404 is received, is transmitted to valve control module and performs signal 205；Receive number letter
Numbers 405, it is transmitted to valve control module and performs signal 206；Digital signal 406 is received, is transmitted to stirring module and performs signal
501, and transmitted to valve control module and perform signal 207；Digital signal 407 is received, letter is performed to valve control module transmission
Numbers 208；Digital signal 101 is received, is transmitted to valve control module and performs signal 209, is transmitted to stirring module and performs signal
502；Digital signal 408 is received, is transmitted to alarm module and performs signal 601；Digital signal 409 is received, is transmitted to alarm module
Perform signal 602；Digital signal 410 is received, is transmitted to valve control module and performs signal 210；Digital signal 411 is received, to
Alarm module, which transmits, performs signal 603；Digital signal 412 is received, is transmitted to alarm module and performs signal 604；
Valve control module includes solenoid valve one, solenoid valve two, solenoid valve three, solenoid valve four and solenoid valve five；For connecing
Row signal 201 is accepted, opens the solenoid valve one in storage box one, storage box two, storage box three, storage box four and storage box five；
It receives and performs signal 202, close the solenoid valve one in storage box one, open the solenoid valve two in storage box one, closed after 10min
It closes；It receives and performs signal 203, close the solenoid valve one in storage box two, the solenoid valve two in storage box two is opened, after 10min
It closes；
It receives and performs signal 204, close the solenoid valve one in storage box three, open the solenoid valve two in storage box three,
It is closed after 10min；It receives and performs signal 205, close the solenoid valve one in storage box four, open the solenoid valve two on storage tank four,
It closes after 20 min, completes backward PLC transmitting digital signals 406；It receives and performs signal 206, close the electromagnetism in storage box five
Valve one is opened the solenoid valve two on storage tank five, is closed after 10min；It receives and performs signal 207, opens solenoid valve three, after 30min
It closes；It receives and performs signal 208, open the solenoid valve two in storage box six；It receives and performs signal 209, close in storage box six
Solenoid valve two；It receives and performs signal 210, open solenoid valve five, closed after 30min；
Weighing module includes weighing device, signal 301 is performed for receiving, for weighing the weight of material T in each storage box；
Weighing module is additionally operable to：In storage box one, as T=18%N, to PLC transmitting digital signals 401；In storage box two, when
During T=18%N, to PLC transmitting digital signals 402；In storage box three, as T=64%N, to PLC transmitting digital signals
403；In storage box four, as T=66%N, to PLC transmitting digital signals 401；In storage box five, when T=predetermined weights
When 01, to PLC transmitting digital signals 405；
It stirs module and includes blender；Signal 501 is performed for receiving, starts blender, is closed after stirring 20min, it is complete
Into backward PLC transmitting digital signals 407；It receives and performs signal 502, start blender, closed after 60min, complete backward PLC and pass
Pass digital signal 408；
Alarm module includes alarm, for receiving execution signal 601, execution signal 602, execution signal 603 and performing
Signal 604 starts alarm, is closed after 2min
Heating module includes the heater set on stainless steel synthesis reactor, and the heater is equipped with trigger button three, works as triggering
After button three is triggered, start heater, holding mode is adjusted to after being heated to 120 DEG C, heater is closed after keeping the temperature 90h, and
To PLC transmitting digital signals 409；
Washing module includes centrifuge, and the centrifuge is equipped with trigger button four, after trigger button four is triggered, starts
Centrifuge, which (washs material), closes centrifuge after 1h, and to PLC transmitting digital signals 410；
Irradiation modules include baking oven, and after trigger button one is triggered, (oven temperature is adjusted to 60 DEG C) starts baking oven
It is closed after 30min, completes backward PLC transmitting digital signals 411；
It roasts module and includes calciner, after trigger button two is triggered, start the calciner, (calciner
Keep the temperature 3h after its interior temperature is heated to 500 DEG C) roasting 3h after close calciner, complete backward PLC transmitting digital signals
412。
It is further included set on storage box one, storage box two, storage box three, storage box four, storage box five and storage box six
Infrared induction module, when material is less than 1/10th in each storage box, to PLC transmitting digital signals 10, PLC receives number letter
Numbers 10, it is transmitted to alarm module and performs signal 20；Alarm module, which receives, performs signal 20, starts alarm, is closed after 2min.
A kind of intelligent preparation method of the intelligent preparation system of mesoporous material, it includes the following steps：
Step 1：Install each equipment；Cu (NO3) 23H2O is stored in storage box one, Co (NO3) 26H2O is deposited
Storage tank two, ZrOCl28H2O deposits storage box three, deionized water deposit storage box four, the deposit of trimethyl cetyl ammonium bromide
Storage box five and NaOH aqueous solutions deposit storage box six；Open a kind of power supply of the intelligent preparation system of mesoporous material；
Step 2：In input equipment input needed for material gross mass N, then input module be translated into digital signal
001 is transferred to PLC；PLC receives digital signaling zero 01, is transmitted to valve control module and performs signal 201, is transmitted to Weighing module
Perform signal 301；Valve control module, which receives, performs signal 201, opens storage box one, storage box two, storage box three, storage box
Four and storage box five on solenoid valve one；Weighing module, which receives, performs signal 301, and Weighing module weighs the material in each storage box
Weight T；Weighing module also performs the following contents：In storage box one, as T=18%N, to PLC transmitting digital signals 401；
In storage box two, as T=18%N, to PLC transmitting digital signals 402；In storage box three, as T=64%N, to
PLC transmitting digital signals 403；In storage box four, as T=66%N, to PLC transmitting digital signals 401；In storage box five
In, when T=predetermined weights 01, to PLC transmitting digital signals 405；
Step 3：PLC receives digital signal 401, is transmitted to valve control module and performs signal 202；Valve control module connects
Row signal 202 is accepted, closes the solenoid valve one in storage box one, the solenoid valve two in storage box one is opened, is closed after 10min；
Step 4：PLC receives digital signal 402, is transmitted to valve control module and performs signal 203；Valve control module connects
Row signal 203 is accepted, closes the solenoid valve one in storage box two, the solenoid valve two in storage box two is opened, is closed after 10min；
Step 5：PLC receives digital signal 403, is transmitted to valve control module and performs signal 204；Valve control module connects
Row signal 204 is accepted, closes the solenoid valve one in storage box three, the solenoid valve two in storage box three is opened, is closed after 10min；
Step 6：PLC receives digital signal 404, is transmitted to valve control module and performs signal 205；Valve control module connects
Row signal 205 is accepted, closes the solenoid valve one in storage box four, the solenoid valve two on storage tank four is opened, closes after 20 min,
Complete backward PLC transmitting digital signals 406；
Step 7：PLC receives digital signal 405, is transmitted to valve control module and performs signal 206；Valve control module connects
Row signal 206 is accepted, closes the solenoid valve one in storage box five, the solenoid valve two on storage tank five is opened, is closed after 10min；
Step 8：PLC receives digital signal 406, is transmitted to stirring module and performs signal 501, and passed to valve control module
It passs and performs signal 207；It stirs module and receives execution signal 501, start blender, closed after stirring 20min, complete backward PLC
Transmitting digital signals 407；Valve control module, which receives, performs signal 207, opens solenoid valve three, is closed after 30min；It that is, will be anti-
The solution in device one is answered to be mixed and stirred for the solution in reaction unit two；
Step 9：PLC receives digital signal 407, is transmitted to valve control module and performs signal 208；Valve control module connects
Row signal 208 is accepted, opens the solenoid valve two in storage box six；That is, NaOH aqueous solutions are instilled into reaction unit two, to adjust
Save the pH value of solution；The pH value of solution in PH detection modules detection reaction unit two, when pH value=8.5, number is transmitted to PLC
Signal 101；PLC receives digital signal 101, is transmitted to valve control module and performs signal 209, and letter is performed to stirring module transmission
Numbers 502；Valve control module, which receives, performs signal 209, closes the solenoid valve two in storage box six；Stirring module reception performs letter
Numbers 502, start blender, closed after 60min, complete backward PLC transmitting digital signals 408；
Step 10：PLC receives digital signal 408, is transmitted to alarm module and performs signal 601；Alarm module, which receives, to be performed
Signal 601 starts alarm, is closed after 2min, staff is reminded to take out floccule obtained by the reaction, and move to stainless steel
In synthesis reactor；After floccule obtained by the reaction is moved to stainless steel synthesis reactor, trigger button three is triggered, when trigger button three is touched
After hair, heating module starts its heater, and holding mode is adjusted to after being heated to 120 DEG C, and heater is closed after keeping the temperature 90h, and
To PLC transmitting digital signals 409；
Step 11：PLC receives digital signal 409, is transmitted to alarm module and performs signal 602；Alarm module, which receives, to be performed
Signal 602 starts alarm, is closed after 2min；Prompting staff material is discharged in centrifuge, by material be discharged to from
After scheming, the trigger button four on centrifuge is triggered, after trigger button four is triggered, then washing module startup centrifuge (will
Material is washed) close centrifuge after 1h, and to PLC transmitting digital signals 410；
Step 12：PLC receives digital signal 410, is transmitted to valve control module and performs signal 210；Valve control module
It receives and performs signal 210, open solenoid valve five, closed after 30min；That is, the material in centrifuge is put by solenoid valve five
It is filtered in filter device；Material after filtering is placed in baking oven, trigger button one is triggered, when trigger button one is triggered
Afterwards, (oven temperature is adjusted to 60 DEG C) then irradiation modules closed after starting baking oven 30min, complete backward PLC and transmit number letter
Numbers 411；PLC receives digital signal 411, is transmitted to alarm module and performs signal 603；Alarm module, which receives, performs signal 603, opens
Alarm is moved, is closed after 2min, prompts staff that dried material is put into calciner；
Step 13：Dried material is put into calciner, trigger button two is triggered, when trigger button two is touched
After hair, then roast module and start calciner, (calciner keeps the temperature 3h after its interior temperature is heated to 500 DEG C) roasting 3h
After close calciner, complete backward PLC transmitting digital signals 412, PLC receives digital signal 412, is held to alarm module transmission
Row signal 604；Alarm module, which receives, performs signal 604, starts alarm, is closed after 2min.
The specific preparation method of the mesoporous material is as follows：
Cu (NO3) 23H2O, Co (NO3) 26H2O, ZrOCl28H2O is weighed respectively, it is miscible in deionized water；
It weighs trimethyl cetyl ammonium bromide to be dissolved in deionized water, then two kinds of solution is mixed with vigorous stirring, use NaOH
PH value is adjusted to 8.5 by aqueous solution, continues stirring 60 minutes.The pasty material of generation is transferred in stainless steel synthesis reactor and risen
The reaction was continued 90 hours to 120 DEG C for temperature, and reaction terminates to be cooled to room temperature, and material is drawn off and is repeatedly washed with centrifuge, filter cake
It is dried at room temperature for, is then roasted 3 hours at 550 DEG C under air atmosphere in tube furnace, obtain a kind of solid matter, use nitrogen
Absorption method (BET method) measures its specific surface area as 320m2/g, and XRD methods measure it with meso-hole structure, illustrate prepared material
For mesoporous material of the present invention.
The invention is not limited in aforementioned specific embodiments.The present invention, which expands to, any in the present specification to be disclosed
The step of new feature or any new combination and any new method or process disclosed or any new combination.
Claims (3)
1. the intelligent preparation system of a kind of mesoporous material, which is characterized in that it includes：Valve control module, input module, PLC,
Weighing module, alarm module, stirring module, PH detection modules, washing module, irradiation modules and roasting module；
Input module includes input equipment, for inputting the gross mass N of required material, and is converted into digital signaling zero 01 and is transferred to
PLC；
PH detection modules include the PH detectors set on reaction unit two, for detecting the pH value of solution in reaction unit two, when
During pH value=8.5, to PLC transmitting digital signals 101；
PLC respectively with valve control module, input module, Weighing module, alarm module, stirring module, PH detection modules, washing
Module, irradiation modules are connected with roasting module, for receiving digital signaling zero 01, are transmitted to valve control module and perform signal
201, it is transmitted to Weighing module and performs signal 301；Digital signal 401 is received, is transmitted to valve control module and performs signal 202；
Digital signal 402 is received, is transmitted to valve control module and performs signal 203；Digital signal 403 is received, to valve control module
It transmits and performs signal 204；Digital signal 404 is received, is transmitted to valve control module and performs signal 205；Receive digital signal
405, it is transmitted to valve control module and performs signal 206；Digital signal 406 is received, is transmitted to stirring module and performs signal 501,
And it is transmitted to valve control module and performs signal 207；Digital signal 407 is received, is transmitted to valve control module and performs signal
208；Digital signal 101 is received, is transmitted to valve control module and performs signal 209, is transmitted to stirring module and performs signal 502；
Digital signal 408 is received, is transmitted to alarm module and performs signal 601；Digital signal 409 is received, transmits and performs to alarm module
Signal 602；Digital signal 410 is received, is transmitted to valve control module and performs signal 210；Digital signal 411 is received, to alarm
Module, which is transmitted, performs signal 603；Digital signal 412 is received, is transmitted to alarm module and performs signal 604；
Valve control module includes solenoid valve one, solenoid valve two, solenoid valve three, solenoid valve four and solenoid valve five；It is held for receiving
Row signal 201 opens the solenoid valve one in storage box one, storage box two, storage box three, storage box four and storage box five；It receives
Signal 202 is performed, closes the solenoid valve one in storage box one, the solenoid valve two in storage box one is opened, is closed after 10min；It connects
Row signal 203 is accepted, closes the solenoid valve one in storage box two, the solenoid valve two in storage box two is opened, is closed after 10min；
It receives and performs signal 204, close the solenoid valve one in storage box three, the solenoid valve two in storage box three is opened, after 10min
It closes；It receives and performs signal 205, close the solenoid valve one in storage box four, the solenoid valve two on storage tank four is opened, in 20min
After close, complete backward PLC transmitting digital signals 406；It receives and performs signal 206, close the solenoid valve one in storage box five, beat
The solenoid valve two on storage tank five is opened, is closed after 10min；It receives and performs signal 207, opens solenoid valve three is closed after 30min；It connects
Row signal 208 is accepted, opens the solenoid valve two in storage box six；It receives and performs signal 209, close the solenoid valve in storage box six
Two；It receives and performs signal 210, open solenoid valve five, closed after 30min；
Weighing module includes weighing device, signal 301 is performed for receiving, for weighing the weight of material T in each storage box；It weighs
Module is additionally operable to：In storage box one, as T=18%N, to PLC transmitting digital signals 401；In storage box two, as T=18%N
When, to PLC transmitting digital signals 402；In storage box three, as T=64%N, to PLC transmitting digital signals 403；In storage box
In four, as T=66%N, to PLC transmitting digital signals 401；In storage box five, when T=predetermined weight 01, transmitted to PLC
Digital signal 405；
It stirs module and includes blender；Signal 501 is performed for receiving, starts blender, is closed after stirring 20min, after the completion
To PLC transmitting digital signals 407；It receives and performs signal 502, start blender, closed after 60min, complete backward PLC and transmit number
Word signal 408；
Alarm module includes alarm, performs signal 601 for receiving, performs signal 602, execution signal 603 and performs signal
604, start alarm, closed after 2min；
Heating module includes the heater set on stainless steel synthesis reactor, and the heater is equipped with trigger button three, works as trigger button
After three are triggered, start heater, be adjusted to holding mode after being heated to 120 DEG C, keep the temperature and heater is closed after 90h, and to PLC
Transmitting digital signals 409;
Washing module includes centrifuge, and the centrifuge is equipped with trigger button four, after trigger button four is triggered, starts centrifugation
Close centrifuge after machine 1h, and to PLC transmitting digital signals 410；
Irradiation modules include baking oven, after trigger button one is triggered, are closed after starting baking oven 30min, complete backward PLC and transmit
Digital signal 411；
It roasts module and includes calciner, after trigger button two is triggered, start calciner, roasting dress is closed after roasting 3h
It puts, completes backward PLC transmitting digital signals 412.
2. the intelligent preparation system of a kind of mesoporous material as described in claim 1, which is characterized in that it is further included set on storage
Case one, storage box two, storage box three, storage box four, the infrared induction module of storage box five and storage box six, when in each storage box
When material is less than 1/10th, to PLC transmitting digital signals 10, PLC receives digital signal 10, and letter is performed to alarm module transmission
Numbers 20；Alarm module, which receives, performs signal 20, starts alarm, is closed after 2min.
3. a kind of intelligent preparation method of the intelligent preparation system of mesoporous material as claimed in claim 1 or 2, feature exist
In it includes the following steps：
Step 1：Install each equipment；Cu (NO3) 23H2O is stored in storage box one, Co (NO3) 26H2O deposit storage boxes
2nd, ZrOCl28H2O is stored in storage box three, deionized water deposit storage box four, the deposit storage of trimethyl cetyl ammonium bromide
Case five and NaOH aqueous solutions deposit storage box six；Open a kind of power supply of the intelligent preparation system of mesoporous material；
Step 2：In input equipment input needed for material gross mass N, then input module be translated into digital signaling zero 01 and pass
It is handed to PLC；PLC receives digital signaling zero 01, is transmitted to valve control module and performs signal 201, and letter is performed to Weighing module transmission
Numbers 301；Valve control module, which receives, performs signal 201, opens storage box one, storage box two, storage box three, storage box four and deposits
Solenoid valve one on storage tank five；Weighing module, which receives, performs signal 301, and Weighing module weighs the weight of material T in each storage box；
Weighing module also performs the following contents：In storage box one, as T=18%N, to PLC transmitting digital signals 401；In storage box
In two, as T=18%N, to PLC transmitting digital signals 402；In storage box three, as T=64%N, number letter is transmitted to PLC
Numbers 403；In storage box four, as T=66%N, to PLC transmitting digital signals 401；In storage box five, when T=predetermined weight
When 01, to PLC transmitting digital signals 405；
Step 3：PLC receives digital signal 401, is transmitted to valve control module and performs signal 202；Valve control module reception is held
Row signal 202 closes the solenoid valve one in storage box one, opens the solenoid valve two in storage box one, is closed after 10min；
Step 4：PLC receives digital signal 402, is transmitted to valve control module and performs signal 203；Valve control module reception is held
Row signal 203 closes the solenoid valve one in storage box two, opens the solenoid valve two in storage box two, is closed after 10min；
Step 5：PLC receives digital signal 403, is transmitted to valve control module and performs signal 204；Valve control module reception is held
Row signal 204 closes the solenoid valve one in storage box three, opens the solenoid valve two in storage box three, is closed after 10min；
Step 6：PLC receives digital signal 404, is transmitted to valve control module and performs signal 205；Valve control module reception is held
Row signal 205 closes the solenoid valve one in storage box four, opens the solenoid valve two on storage tank four, closes after 20 min, completes
Backward PLC transmitting digital signals 406；
Step 7：PLC receives digital signal 405, is transmitted to valve control module and performs signal 206；Valve control module reception is held
Row signal 206 closes the solenoid valve one in storage box five, opens the solenoid valve two on storage tank five, is closed after 10min；
Step 8：PLC receives digital signal 406, is transmitted to stirring module and performs signal 501, and is held to valve control module transmission
Row signal 207；It stirs module and receives execution signal 501, start blender, closed after stirring 20min, complete backward PLC and transmit
Digital signal 407；Valve control module, which receives, performs signal 207, opens solenoid valve three, is closed after 30min；That is, reaction is filled
The solution put in one is mixed and stirred for the solution in reaction unit two；
Step 9：PLC receives digital signal 407, is transmitted to valve control module and performs signal 208；Valve control module reception is held
Row signal 208 opens the solenoid valve two in storage box six；That is, NaOH aqueous solutions are instilled into reaction unit two, it is molten to adjust
The pH value of liquid；The pH value of solution in PH detection modules detection reaction unit two, when pH value=8.5, to PLC transmitting digital signals
101；PLC receives digital signal 101, is transmitted to valve control module and performs signal 209, is transmitted to stirring module and performs signal
502；Valve control module, which receives, performs signal 209, closes the solenoid valve two in storage box six；It stirs module and receives execution signal
502, start blender, closed after 60min, complete backward PLC transmitting digital signals 408；
Step 10：PLC receives digital signal 408, is transmitted to alarm module and performs signal 601；Alarm module, which receives, performs signal
601, start alarm, closed after 2min, staff is reminded to take out floccule obtained by the reaction, and move to stainless steel synthesis
In kettle；After floccule obtained by the reaction is moved to stainless steel synthesis reactor, trigger button three is triggered, when trigger button three is triggered
Afterwards, heating module starts its heater, is adjusted to holding mode after being heated to 120 DEG C, keeps the temperature and heater is closed after 90h, and to
PLC transmitting digital signals 409;
Step 11：PLC receives digital signal 409, is transmitted to alarm module and performs signal 602；Alarm module, which receives, performs signal
602, start alarm, closed after 2min；Material is discharged in centrifuge by prompting staff, and material is discharged to centrifuge
Afterwards, the trigger button four on centrifuge is triggered, after trigger button four is triggered, then washing module is closed after starting centrifuge 1h
Centrifuge, and to PLC transmitting digital signals 410；
Step 12：PLC receives digital signal 410, is transmitted to valve control module and performs signal 210；Valve control module receives
Signal 210 is performed, solenoid valve five is opened, is closed after 30min；That is, the material in centrifuge is put into filtering by solenoid valve five
It is filtered in device；Material after filtering is placed in baking oven, triggers trigger button one, after trigger button one is triggered,
Then irradiation modules are closed after starting baking oven 30min, complete backward PLC transmitting digital signals 411；PLC receives digital signal 411,
It is transmitted to alarm module and performs signal 603；Alarm module, which receives, performs signal 603, starts alarm, is closed after 2min, is prompted
Dried material is put into calciner by staff；
Step 13：Dried material is put into calciner, trigger button two is triggered, when trigger button two is triggered
Afterwards, then it roasts module and starts calciner, close calciner after roasting 3h, complete backward PLC transmitting digital signals 412, PLC
Digital signal 412 is received, is transmitted to alarm module and performs signal 604；Alarm module, which receives, performs signal 604, starts alarm,
It is closed after 2min.
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1594072A (en) * | 2004-07-04 | 2005-03-16 | 杜陵敏 | Process for preparing nanometer metal oxide and reaction apparatus therefor |
| CN101575295A (en) * | 2009-05-20 | 2009-11-11 | 江苏工业学院 | Method for preparing diaminonaphthalene by catalytic hydrogenation of dinitronaphthalene |
| CN102464539A (en) * | 2010-11-18 | 2012-05-23 | 中国石油天然气股份有限公司 | Solid acid catalytic synthesis method of linear alkylbenzene |
| CN103274940A (en) * | 2013-05-14 | 2013-09-04 | 常州大学 | Environment-friendly preparation method of pentaerythritol acrylic ester and derivate |
| FR3006206A1 (en) * | 2013-05-30 | 2014-12-05 | China Petroleum & Chemical | APPARATUS FOR PRODUCING DICUMYL PEROXIDE AND METHOD FOR PRODUCING THE SAME |
-
2015
- 2015-12-17 CN CN201510948075.7A patent/CN105425716B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1594072A (en) * | 2004-07-04 | 2005-03-16 | 杜陵敏 | Process for preparing nanometer metal oxide and reaction apparatus therefor |
| CN101575295A (en) * | 2009-05-20 | 2009-11-11 | 江苏工业学院 | Method for preparing diaminonaphthalene by catalytic hydrogenation of dinitronaphthalene |
| CN102464539A (en) * | 2010-11-18 | 2012-05-23 | 中国石油天然气股份有限公司 | Solid acid catalytic synthesis method of linear alkylbenzene |
| CN103274940A (en) * | 2013-05-14 | 2013-09-04 | 常州大学 | Environment-friendly preparation method of pentaerythritol acrylic ester and derivate |
| FR3006206A1 (en) * | 2013-05-30 | 2014-12-05 | China Petroleum & Chemical | APPARATUS FOR PRODUCING DICUMYL PEROXIDE AND METHOD FOR PRODUCING THE SAME |
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