A kind of Waterproof Breathable coating
Technical field
The present invention relates to a kind of waterproof paint, be specifically related to a kind of Waterproof Breathable coating, belong to building coating field.
Technical background
The harm of infiltration to building of outside moisture is apparent, airproof for one deck waterproof layer covers outside thermal insulation layer by our conventional waterproof theory exactly, but Discussion on architecture temperature, humidity difference is larger, so just cause indoor moisture " accumulation " inside waterproof layer, chance cold junction reveals, accumulate over a long period certainly will cause thermal insulation layer degradation, waterproof layer sticking power goes down and then affects building life.
Along with the fast development of construction industry, the contradiction between the water-repellancy of material and water vapour permeability is more sharp-pointed.Research for Waterproof Breathable coating is a current important directions.
Also have some to have the coating of Waterproof Breathable function on the market now, but these coating contain the objectionable impuritiess such as a large amount of benzene compounds, have harm to environment and human body; And existing Waterproof Breathable coating has a lot of defect; Steam or can not be through, otherwise transmitance is very low, and effect is undesirable; And water vapour permeability causes its adhesive property degradation.
Prior art has following defect: (1) steam can not through coating, or transmitance is very low; (2) not strong with cement basal plane adhesive property; (3) water tolerance is strong not; (4) ageing-resistant performance is poor; (5) stain resistant performance and wear resisting property poor; (6) containing volatile harmful material, not environmentally.
Summary of the invention
For above-mentioned technical problem, the invention provides a kind of Waterproof Breathable coating, there is the advantages such as better waterproof, moisture-inhibiting, weather-proof, environmental protection, cohesive force be strong, to realize following goal of the invention:
1, make waterproof paint can by steam, but can liquid barrier water; Water vapor transmission rate (WVTR) is made to reach 5.0 ~ 5.5g/ (m
2d);
2, waterproof paint both Waterproof Breathables are made, meanwhile, good with cement basal plane adhesive property;
3, while making waterproof paint moisture-inhibiting, keep water resistance good;
4, the ageing-resistant performance of waterproof paint is improved;
5, contaminated resistance and the wear resisting property of waterproof paint is improved;
6, make waterproof paint of the present invention not containing any harmful volatile component, realize safety and environmental protection.
For achieving the above object, the invention provides following technical scheme:
A kind of Waterproof Breathable coating, described coating comprises priming paint and investment precoat.
Below the further improvement to technique scheme:
Described priming paint comprises component A and B component.
The mass ratio of described component A and B component is: component A: B component=10:1 ~ 15:1.
The component A of described priming paint comprises following feed composition: ethylene-vinyl acetate copolymer emulsion, property polysiloxane, aqueous polyurethane, sodium polyacrylate, hydroxyethylmethyl-cellulose, silicon sol, defoamer, sterilant.
Each feed composition of the component A of described priming paint, with parts by weight, content is: ethylene-vinyl acetate copolymer emulsion 8 ~ 10 parts, property polysiloxane 0.3 ~ 0.8 part, aqueous polyurethane 30 ~ 40 parts, sodium polyacrylate 2 ~ 3 parts, hydroxyethylmethyl-cellulose 5 ~ 10 parts, silicon sol 15 ~ 20 parts, defoamer 0.5 ~ 1 part, 0.5 ~ 1 part, sterilant.
Each feed composition of the component A of described priming paint, with parts by weight, content is: ethylene-vinyl acetate copolymer emulsion 10 parts, modified polyorganosiloxane 0.5 part, aqueous polyurethane 30 parts, sodium polyacrylate 2 parts, hydroxyethylmethyl-cellulose 10 parts, silicon sol 20 parts, defoamer 1 part, sterilant 0.8.
The B component of described priming paint is polyisocyanate curing agent.
Described investment precoat comprises following component: water-base fluorocarbon emulsion, filler, aqueous polyurethane, defoamer, dispersion agent.
Each component of described investment precoat, with parts by weight, content is: water-base fluorocarbon emulsion 40 ~ 50 parts, filler 10 ~ 15 parts, aqueous polyurethane 20 ~ 30 parts, defoamer 0.5 ~ 1 part, dispersion agent 0.5 ~ 1 part.
Each component of described investment precoat, with parts by weight, content is: water-base fluorocarbon emulsion 45 parts, filler 10 parts, aqueous polyurethane 30 parts, defoamer 1 part, dispersion agent 0.5 part.
Compared with prior art, the present invention has following beneficial effect:
1, coating of the present invention can pass through steam, but can liquid barrier water; Water vapor transmission rate (WVTR) is 5.0 ~ 5.5g/ (m
2d);
2, coating of the present invention and cement basal plane cohesiveness strong; Paint adhesion is less than 1 grade;
3, water-resistant coating of the present invention is strong, can reach 30 ~ 40 days without exception;
4, coating ageing-resistant performance of the present invention is strong; Temper(ing) 1700 ~ 1800h is non-foaming, do not ftracture, do not come off;
5, coating contaminated resistance of the present invention is good, after testing, is less than 8 ~ 10%;
6, coating wear resistance of the present invention is good, after testing, is less than or equal to 50mg (index is 750g/500r);
7, not containing any volatile harmful material, to environment and body harmless, environmental protection.
Embodiment
In order to better set forth the present invention, further illustrate below in conjunction with embodiment.
Embodiment 1
a kind of Waterproof Breathable coating
Described coating comprises priming paint and investment precoat;
(1) mass parts of investment precoat consists of: water-base fluorocarbon emulsion 40 parts, filler 15 parts, aqueous polyurethane 30 parts, defoamer 1 part, dispersion agent 0.5 part;
Described water-based fluorocarbon resin is Guangdong pine and cypress chemical industry PTFE emulsion;
Described filler is Du Pont's Rutile type Titanium Dioxide;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described dispersion agent model is BYK180.
(2) priming paint comprises component A and B component;
The mass ratio of component A, B component is: component A: B component=14:1; Component A mixes with B component before using by priming paint in mass ratio.
The mass parts of the component A of described priming paint consists of:
Ethylene-vinyl acetate copolymer emulsion 10 parts, modified polyorganosiloxane 0.5 part, aqueous polyurethane 38 parts, sodium polyacrylate 2 parts, hydroxyethylmethyl-cellulose 7 parts, silicon sol 20 parts, defoamer 1 part, 0.8 part, sterilant;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described sterilant is large eastern chemical industry A266.
The B component of described priming paint is polyisocyanate curing agent;
Described polyisocyanate curing agent Bayer chemistry Bayhydur305.
Embodiment 2
a kind of Waterproof Breathable coating
Described coating comprises priming paint and investment precoat;
(1) mass parts of investment precoat consists of: water-base fluorocarbon emulsion 50 parts, filler 13 parts, aqueous polyurethane 20 parts, defoamer 1 part, dispersion agent 0.5 part;
Described water-based fluorocarbon resin is Guangdong pine and cypress chemical industry PTFE emulsion;
Described filler is Du Pont's Rutile type Titanium Dioxide;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described dispersion agent is BYK180.
(2) priming paint comprises component A and B component;
The mass ratio of component A, B component is: component A: B component=13:1; Component A mixes with B component before using by priming paint in mass ratio.
The mass parts of the component A of described priming paint consists of:
Ethylene-vinyl acetate copolymer emulsion 8 parts, modified polyorganosiloxane 0.5 part, aqueous polyurethane 40 parts, sodium polyacrylate 2 parts, hydroxyethylmethyl-cellulose 10 parts, silicon sol 15 parts, defoamer 1 part, 0.8 part, sterilant;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described sterilant is large eastern chemical industry A266.
The B component of described priming paint is polyisocyanate curing agent;
Described polyisocyanate curing agent Bayer chemistry Bayhydur305.
Embodiment 3
a kind of Waterproof Breathable coating
Described coating comprises priming paint and investment precoat;
(1) mass parts of investment precoat consists of: water-base fluorocarbon emulsion 45 parts, filler 10 parts, aqueous polyurethane 30 parts, defoamer 1 part, dispersion agent 0.5 part;
Described water-based fluorocarbon resin is Guangdong pine and cypress chemical industry PTFE emulsion;
Described filler is Du Pont's Rutile type Titanium Dioxide;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described dispersion agent is BYK180.
(2) priming paint comprises component A and B component;
The mass ratio of component A, B component is: component A: B component=15:1; Component A mixes with B component before using by priming paint in mass ratio.
The mass parts of the component A of described priming paint consists of:
Ethylene-vinyl acetate copolymer emulsion 10 parts, modified polyorganosiloxane 0.5 part, aqueous polyurethane 30 parts, sodium polyacrylate 2 parts, hydroxyethylmethyl-cellulose 10 parts, silicon sol 20 parts, defoamer 1 part, 0.8 part, sterilant;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described sterilant is large eastern chemical industry A266.
The B component of described priming paint is polyisocyanate curing agent;
Described polyisocyanate curing agent Bayer chemistry Bayhydur305.
Embodiment 4
a kind of Waterproof Breathable coating
Described coating comprises priming paint and investment precoat;
(1) mass parts of investment precoat consists of: water-base fluorocarbon emulsion 48 parts, filler 12 parts, aqueous polyurethane 25 parts, defoamer 0.5 part, dispersion agent 0.8 part;
Described water-based fluorocarbon resin is Guangdong pine and cypress chemical industry PTFE emulsion;
Described filler is Du Pont's Rutile type Titanium Dioxide;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described dispersion agent model is BYK180.
(2) priming paint comprises component A and B component;
The mass ratio of component A, B component is: component A: B component=10:1; Component A mixes with B component before using by priming paint in mass ratio.
The mass parts of the component A of described priming paint consists of:
Ethylene-vinyl acetate copolymer emulsion 9 parts, modified polyorganosiloxane 0.3 part, aqueous polyurethane 33 parts, sodium polyacrylate 2.5 parts, hydroxyethylmethyl-cellulose 5 parts, silicon sol 17 parts, defoamer 0.5 part, 0.5 part, sterilant;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described sterilant is large eastern chemical industry A266.
The B component of described priming paint is polyisocyanate curing agent;
Described polyisocyanate curing agent Bayer chemistry Bayhydur305.
Embodiment 5
a kind of Waterproof Breathable coating
Described coating comprises priming paint and investment precoat;
(1) mass parts of investment precoat consists of: water-base fluorocarbon emulsion 42 parts, filler 11 parts, aqueous polyurethane 28 parts, defoamer 0.8 part, dispersion agent 1 part;
Described water-based fluorocarbon resin is Guangdong pine and cypress chemical industry PTFE emulsion;
Described filler is Du Pont's Rutile type Titanium Dioxide;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described dispersion agent model is BYK180.
(2) priming paint comprises component A and B component;
The mass ratio of component A, B component is: component A: B component=12:1; Component A mixes with B component before using by priming paint in mass ratio.
The mass parts of the component A of described priming paint consists of:
Ethylene-vinyl acetate copolymer emulsion 9 parts, modified polyorganosiloxane 0.8 part, aqueous polyurethane 35 parts, sodium polyacrylate 2.8 parts, hydroxyethylmethyl-cellulose 9 parts, silicon sol 18 parts, defoamer 0.8 part, 1 part, sterilant;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described sterilant is large eastern chemical industry A266.
The B component of described priming paint is polyisocyanate curing agent;
Described polyisocyanate curing agent Bayer chemistry Bayhydur305.
Result detects:
The detection method of coating of the present invention: watertightness detection method is with reference to GB/T328.10A; The detection method of water vapor transmission rate (WVTR) is with reference to JC/T309-2011; The detection method of water tolerance is with reference to GB/T1733-1993; The detection method of sticking power is with reference to GB/T9286-1998; The detection method of artificial ageing resistance is with reference to ISO11507:2007; The detection method of stain resistant is with reference to GB/T9780; The detection method of wear resistance is with reference to GB/T1768-2006;
The coating property Indexs measure of embodiment 1-5 the results are shown in Table 1;
Table 1 coating property Indexs measure result
From table 1, coating watertightness detected result of the present invention is filter paper nondiscoloration, and coating impenetrable liquid water of the present invention is described;
The water vapor transmission rate (WVTR) of coating of the present invention is 5.0 ~ 5.5g/ (m
2d);
Water-resistant coating of the present invention can reach 30 ~ 40 days without exception;
Paint adhesion of the present invention is less than 1 grade;
Coating artificial ageing resistance of the present invention, 1700 ~ 1800h is non-foaming, do not ftracture, do not come off;
Coating contaminated resistance of the present invention: be less than 8 ~ 10%;
Coating wear resistance of the present invention is≤50mg (condition is 750g/500r).
Embodiment 6
a kind of Waterproof Breathable coating
Described coating comprises priming paint and investment precoat;
(1) mass parts of investment precoat consists of: water-base fluorocarbon emulsion 38 parts, filler 11 parts, aqueous polyurethane 28 parts, polypropylene glycerol aether 1.1 parts, Magnesium Stearate 2.3 parts, carnauba wax 2 parts, Manganse Dioxide 0.8 part;
Described water-based fluorocarbon resin is Guangdong pine and cypress chemical industry PTFE emulsion;
Described filler is Du Pont's Rutile type Titanium Dioxide;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718.
(2) priming paint comprises component A and B component;
The mass ratio of component A, B component is: component A: B component=12:1; Component A mixes with B component before using by priming paint in mass ratio.
The mass parts of the component A of described priming paint consists of:
Ethylene-vinyl acetate copolymer emulsion 12 parts, modified polyorganosiloxane 0.6 part, aqueous polyurethane 38 parts, sodium polyacrylate 2.1 parts, hydroxyethylmethyl-cellulose 5 parts, silicon sol 11 parts, polypropylene glycerol aether 0.8 part, dithiocarbamic acid 0.2 part, 2.1 parts, wood vinegar, myrcene 1.5 parts, alpha-linolenic acid 0.9 part;
Described aqueous polyurethane is Jining Hua Kai resin company limited HK718;
Described defoamer is BASF A10;
Described sterilant is large eastern chemical industry A266.
The mass parts of the B component of described priming paint consists of:
Polyisocyanate curing agent 5 parts, epoxy resin 0.8 part, Oenothera oil 0.2 part;
Described polyisocyanate curing agent Bayer chemistry Bayhydur305.
Through test, the coating impenetrable liquid water of the present embodiment; Water vapor transmission rate (WVTR) is 5.8g/ (m
2d); Water-resistant coating can reach 50 days without exception; Paint adhesion is less than 1 grade; Coating artificial ageing resistance, 1900h is non-foaming, do not ftracture, do not come off; Coating contaminated resistance: be less than 7%; Coating wear resistance is≤50mg (condition is 750g/500r).
Last it is noted that the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although with reference to previous embodiment to invention has been detailed description, for a person skilled in the art, it still can be modified to the technical scheme described in foregoing embodiments, or carries out equivalent replacement to wherein portion of techniques feature.Within the spirit and principles in the present invention all, any amendment done, equivalent replacement, improvement etc., all should be included within protection scope of the present invention.The above is the citing of best mode for carrying out the invention, and the part wherein do not addressed in detail is the common practise of those of ordinary skill in the art; Protection scope of the present invention is as the criterion with the content of claim, and any equivalent transformation carried out based on technology enlightenment of the present invention, also within protection scope of the present invention.