CN105401440A - Novel antiwrinkling color-keeping finishing agent and preparation method thereof - Google Patents
Novel antiwrinkling color-keeping finishing agent and preparation method thereof Download PDFInfo
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- CN105401440A CN105401440A CN201610011786.6A CN201610011786A CN105401440A CN 105401440 A CN105401440 A CN 105401440A CN 201610011786 A CN201610011786 A CN 201610011786A CN 105401440 A CN105401440 A CN 105401440A
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
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- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/328—Amines the amino group being bound to an acyclic or cycloaliphatic carbon atom
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/325—Amines
- D06M13/335—Amines having an amino group bound to a carbon atom of a six-membered aromatic ring
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
- D06M13/432—Urea, thiourea or derivatives thereof, e.g. biurets; Urea-inclusion compounds; Dicyanamides; Carbodiimides; Guanidines, e.g. dicyandiamides
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/20—Treatment influencing the crease behaviour, the wrinkle resistance, the crease recovery or the ironing ease
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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Abstract
The invention discloses a novel antiwrinkling color-keeping finishing agent, prepared from the following components in percentage by weight: 15-23 parts of polyoxyethylene sorbitan fatty acid ester, 5-10 parts of polyethylene glycol oil-based ether, 1-5 parts of sodium polyacrylate, 8-15 parts of polypropylene resin, 3-10 parts of dimethyl formamide, 8-16 parts of epoxy chloropropane, 20-28 parts of diethyl 2-ethyl-2-phenylmalonate, 12-17 parts of N-carbobenzoxy-6-aminocaproic acid, 2-9 parts of diclofenac potassium and 4-12 parts of thiocarbamide. The finishing agent can remarkably improve the antiwrinkling performance of a baffeta, meanwhile keeps the original color and handfeel of the baffeta, and reduction of wearing comfort due to antiwrinkling finishing is avoided.
Description
Technical field
The invention belongs to finishing agent field, particularly one wrinkle resistant guarantor's look finishing agent and preparation method thereof.
Background technology
Finishing agent is mainly applied in fabric, changes the surface property of fabric, thus gives a fabric part new function.In daily life, usually can run into fabric in wearing process, occur the phenomenons such as contraction or wrinkle, this just needs a kind of crease proofing agent to people.At present, although there are some crease proofing agents on the market, its wrinkle-proof effect is unsatisfactory, and fabric even can be made to lose original form after wherethrough reason, lose its original gloss, feel is not good enough, and people's wearing comfort declines etc. simultaneously.Therefore improvement is carried out to existing crease-resistant cotton fabric finishing agent and seem particularly important.
Summary of the invention
For the above technical problem existed in prior art, the invention provides a kind of wrinkle resistant guarantor's look finishing agent and preparation method thereof, to improve the crease resistance of COTTON FABRIC, keep its original gloss and feel simultaneously, avoid the reduction bringing wearing comfort sense because of wrinkle resistant process.
Technical scheme: a kind of novel crease-resistant protects look finishing agent, comprise each component of following percentage by weight: polyoxyethylene sorbitan fatty acid ester 15-23 part, polyethylene glycol oleyl ether 5-10 part, Sodium Polyacrylate 1-5 part, acrylic resin 8-15 part, dimethyl formamide 3-10 part, epoxychloropropane 8-16 part, ethyl benzoic acid 20-28 part, N-benzyloxycarbonyl group-6-aminocaprolc acid 12-17 part, Diclofenac potassium 2-9 part, thiocarbamide 4-12 part.
Further, described polyoxyethylene sorbitan fatty acid ester 18-20 part, polyethylene glycol oleyl ether 6-8 part, Sodium Polyacrylate 2-4 part, acrylic resin 10-13 part, dimethyl formamide 5-8 part, epoxychloropropane 10-14 part, ethyl benzoic acid 22-24 part, N-benzyloxycarbonyl group-6-aminocaprolc acid 13-16 part, Diclofenac potassium 3-7 part, thiocarbamide 6-10 part.
Further, described polyoxyethylene sorbitan fatty acid ester 19 parts, polyethylene glycol oleyl ether 7 parts, Sodium Polyacrylate 3 parts, acrylic resin 12 parts, dimethyl formamide 7 parts, epoxychloropropane 12 parts, ethyl benzoic acid 23 parts, N-benzyloxycarbonyl group-6-aminocaprolc acid 15 parts, Diclofenac potassium 5 parts, thiocarbamide 8 parts.
Novel crease-resistant protects a preparation method for look finishing agent, comprises following steps:
S1: polyoxyethylene sorbitan fatty acid ester 15-23 part, polyethylene glycol oleyl ether 5-10 part and Diclofenac potassium 2-9 part are added in reactor to mix and once stirs 5-10min; Temperature is risen to 35-65 DEG C, adds Sodium Polyacrylate 1-5 part and acrylic resin 8-15 part subsequently, for subsequent use after secondary agitation reaction 10-15min;
S2: by dimethyl formamide 3-10 part, ethyl benzoic acid 20-28 part, thiocarbamide 4-12 part and epoxychloropropane 8-16 part at temperature 60-70 DEG C, stirring reaction 15-20min;
S3: the solution mixing that step S1 and step S2 is obtained, under constantly stirring, add N-benzyloxycarbonyl group-6-aminocaprolc acid 12-17 part, be warming up to 50-65 DEG C subsequently, continue stirring reaction 20-30min after leaving standstill 5-8min, be described wrinkle resistant guarantor's look finishing agent after cooling.
Further, the speed once stirred in step S1 is 100-130r/min, the time is 8min, and temperature is 50 DEG C, and the speed of secondary agitation is 200-220r/min, the time is 13min.
Further, temperature described in step S2 is 65 DEG C, and the speed of described stirring is 260-320r/min, stirring reaction 18min.
Further, temperature 58 DEG C in step S3, leaves standstill 5min, stirs 26min.
Beneficial effect:
The preparation method of wrinkle resistant guarantor's look finishing agent of the present invention, by rationally adding ethyl benzoic acid, N-benzyloxycarbonyl group-6-aminocaprolc acid, Diclofenac potassium 2-9 part in the technique preparing finishing agent, effectively raise the crease resistance of finishing agent, maintain the original gloss of fabric and comfort level simultaneously.This preparation method is simple, has stronger industrialization prospect of production.
Detailed description of the invention
Embodiment 1
S1: polyoxyethylene sorbitan fatty acid ester 15 parts, polyethylene glycol oleyl ether 5 parts and Diclofenac potassium 2 parts are added in reactor and mixes, once stir 5min with 100r/min speed; Temperature is risen to 35 DEG C, add Sodium Polyacrylate 1 part and acrylic resin 8 parts subsequently, with for subsequent use after 200r/min speed secondary agitation reaction 10min;
S2: by dimethyl formamide 3 parts, ethyl benzoic acid 20 parts, thiocarbamide 4 parts and epoxychloropropane 8 parts under temperature 60 C, with 260r/min speed stirring reaction 15min;
S3: the solution mixing that step S1 and step S2 is obtained, under constantly stirring, add N-benzyloxycarbonyl group-6-aminocaprolc acid 12 parts, be warming up to 50 DEG C subsequently, continue with speed 350r/min stirring reaction 20min after leaving standstill 5min, be described wrinkle resistant guarantor's look finishing agent after cooling.
Comparative example 1
S1: polyoxyethylene sorbitan fatty acid ester 15 parts and polyethylene glycol oleyl ether 5 parts are added in reactor and mixes, once stir 5min with 100r/min speed; Temperature is risen to 35 DEG C, add Sodium Polyacrylate 1 part and acrylic resin 8 parts subsequently, with for subsequent use after 200r/min speed secondary agitation reaction 10min;
S2: by dimethyl formamide 3 parts, thiocarbamide 4 parts and epoxychloropropane 8 parts under temperature 60 C, with 260r/min speed stirring reaction 15min;
S3: the solution mixing obtained by step S1 and step S2, is warming up to 50 DEG C, continues, with speed 350r/min stirring reaction 20min, to be finishing agent after cooling after leaving standstill 5min.
Embodiment 2
S1: polyoxyethylene sorbitan fatty acid ester 23 parts, polyethylene glycol oleyl ether 10 parts and Diclofenac potassium 9 parts are added in reactor and mixes, once stir 10min with 130r/min speed; Temperature is risen to 65 DEG C, add Sodium Polyacrylate 5 parts and acrylic resin 15 parts subsequently, with for subsequent use after 220r/min speed secondary agitation reaction 15min;
S2: by dimethyl formamide 10 parts, ethyl benzoic acid 28 parts, thiocarbamide 12 parts and epoxychloropropane 16 parts under temperature 70 C, with 320r/min speed stirring reaction 20min;
S3: the solution mixing that step S1 and step S2 is obtained, under constantly stirring, add N-benzyloxycarbonyl group-6-aminocaprolc acid 17 parts, be warming up to 65 DEG C subsequently, continue with speed 450r/min stirring reaction 30min after leaving standstill 8min, be described wrinkle resistant guarantor's look finishing agent after cooling.
Comparative example 2
S1: polyoxyethylene sorbitan fatty acid ester 23 parts and polyethylene glycol oleyl ether 10 parts are added in reactor and mixes, once stir 10min with 130r/min speed; Temperature is risen to 65 DEG C, add Sodium Polyacrylate 5 parts and acrylic resin 15 parts subsequently, with for subsequent use after 220r/min speed secondary agitation reaction 15min;
S2: by dimethyl formamide 10 parts, thiocarbamide 12 parts and epoxychloropropane 16 parts under temperature 70 C, with 320r/min speed stirring reaction 20min;
S3: the solution mixing obtained by step S1 and step S2, is warming up to 65 DEG C subsequently, continues, with speed 450r/min stirring reaction 30min, to be finishing agent after cooling after leaving standstill 8min.
Embodiment 3
S1: polyoxyethylene sorbitan fatty acid ester 18 parts, polyethylene glycol oleyl ether 6 parts and Diclofenac potassium 3 parts are added in reactor and mixes, once stir 6min with 110r/min speed; Temperature is risen to 45 DEG C, add Sodium Polyacrylate 2 parts and acrylic resin 10 parts subsequently, with for subsequent use after 220r/min speed secondary agitation reaction 15min;
S2: by dimethyl formamide 5 parts, ethyl benzoic acid 22 parts, thiocarbamide 6 parts and epoxychloropropane 16 parts at temperature 65 DEG C, with 280r/min speed stirring reaction 15min;
S3: the solution mixing that step S1 and step S2 is obtained, under constantly stirring, add N-benzyloxycarbonyl group-6-aminocaprolc acid 13 parts, be warming up to 65 DEG C subsequently, continue with speed 450r/min stirring reaction 30min after leaving standstill 8min, be described wrinkle resistant guarantor's look finishing agent after cooling.
Embodiment 4
S1: polyoxyethylene sorbitan fatty acid ester 20 parts, polyethylene glycol oleyl ether 8 parts and Diclofenac potassium 7 parts are added in reactor and mixes, once stir 8min with 120r/min speed; Temperature is risen to 55 DEG C, add Sodium Polyacrylate 4 parts and acrylic resin 13 parts subsequently, with for subsequent use after 220r/min speed secondary agitation reaction 15min;
S2: by dimethyl formamide 8 parts, ethyl benzoic acid 24 parts, thiocarbamide 10 parts and epoxychloropropane 14 parts under temperature 70 C, with 300r/min speed stirring reaction 20min;
S3: the solution mixing that step S1 and step S2 is obtained, under constantly stirring, add N-benzyloxycarbonyl group-6-aminocaprolc acid 16 parts, be warming up to 55 DEG C subsequently, continue with speed 400r/min stirring reaction 25min after leaving standstill 6min, be described wrinkle resistant guarantor's look finishing agent after cooling.
Embodiment 5
S1: polyoxyethylene sorbitan fatty acid ester 19 parts, polyethylene glycol oleyl ether 7 parts and Diclofenac potassium 5 parts are added in reactor and mixes, once stir 8min with 120r/min speed; Temperature is risen to 50 DEG C, add Sodium Polyacrylate 3 parts and acrylic resin 12 parts subsequently, with for subsequent use after 210r/min speed secondary agitation reaction 13min;
S2: by dimethyl formamide 7 parts, ethyl benzoic acid 23 parts, thiocarbamide 8 parts and epoxychloropropane 12 parts at temperature 65 DEG C, with 300r/min speed stirring reaction 18min;
S3: the solution mixing that step S1 and step S2 is obtained, under constantly stirring, add N-benzyloxycarbonyl group-6-aminocaprolc acid 15 parts, be warming up to 58 DEG C subsequently, continue with speed 400r/min stirring reaction 26min after leaving standstill 5min, be described wrinkle resistant guarantor's look finishing agent after cooling.
Finishing agent in each embodiment and comparative example is applied in fabric and determines its crease-resistant grade, fabric elasticity creasy recovery angle: test according to AATCC66-2003 on elastic apparatus; Fabric tear is powerful: measure according to ASTMD1424, result is as following table:
| Experiment | Creasy recovery angle ° | Tearing brute force gf |
| Embodiment 1 | 187.5 | 890.2 |
| Comparative example 1 | 126.1 | 1135.0 |
| Embodiment 2 | 189.3 | 897.6 |
| Comparative example 2 | 124.3 | 1210.3 |
| Embodiment 3 | 192.3 | 901.6 |
| Embodiment 4 | 193.6 | 876.5 |
| Embodiment 5 | 195.1 | 886.9 |
Claims (7)
1. a novel crease-resistant protects look finishing agent, it is characterized in that, comprise each component of following percentage by weight: polyoxyethylene sorbitan fatty acid ester 15-23 part, polyethylene glycol oleyl ether 5-10 part, Sodium Polyacrylate 1-5 part, acrylic resin 8-15 part, dimethyl formamide 3-10 part, epoxychloropropane 8-16 part, ethyl benzoic acid 20-28 part, N-benzyloxycarbonyl group-6-aminocaprolc acid 12-17 part, Diclofenac potassium 2-9 part, thiocarbamide 4-12 part.
2. one according to claim 1 wrinkle resistant guarantor's look finishing agent, it is characterized in that, described polyoxyethylene sorbitan fatty acid ester 18-20 part, polyethylene glycol oleyl ether 6-8 part, Sodium Polyacrylate 2-4 part, acrylic resin 10-13 part, dimethyl formamide 5-8 part, epoxychloropropane 10-14 part, ethyl benzoic acid 22-24 part, N-benzyloxycarbonyl group-6-aminocaprolc acid 13-16 part, Diclofenac potassium 3-7 part, thiocarbamide 6-10 part.
3. one according to claim 2 wrinkle resistant guarantor's look finishing agent, it is characterized in that, described polyoxyethylene sorbitan fatty acid ester 19 parts, polyethylene glycol oleyl ether 7 parts, Sodium Polyacrylate 3 parts, acrylic resin 12 parts, dimethyl formamide 7 parts, epoxychloropropane 12 parts, ethyl benzoic acid 23 parts, N-benzyloxycarbonyl group-6-aminocaprolc acid 15 parts, Diclofenac potassium 5 parts, thiocarbamide 8 parts.
4. a preparation method for wrinkle resistant guarantor's look finishing agent, is characterized in that, comprise following steps:
S1: polyoxyethylene sorbitan fatty acid ester 15-23 part, polyethylene glycol oleyl ether 5-10 part and Diclofenac potassium 2-9 part are added in reactor to mix and once stirs 5-10min; Temperature is risen to 35-65 DEG C, adds Sodium Polyacrylate 1-5 part and acrylic resin 8-15 part subsequently, for subsequent use after secondary agitation reaction 10-15min;
S2: by dimethyl formamide 3-10 part, ethyl benzoic acid 20-28 part, thiocarbamide 4-12 part and epoxychloropropane 8-16 part at temperature 60-70 DEG C, stirring reaction 15-20min;
S3: the solution mixing that step S1 and step S2 is obtained, under constantly stirring, add N-benzyloxycarbonyl group-6-aminocaprolc acid 12-17 part, be warming up to 50-65 DEG C subsequently, continue stirring reaction 20-30min after leaving standstill 5-8min, be described wrinkle resistant guarantor's look finishing agent after cooling.
5. the preparation method of a kind of wrinkle resistant guarantor's look finishing agent according to claim 4, it is characterized in that, the speed once stirred described in described in step S1 is 100-130r/min, the time is 8min, and temperature is 50 DEG C, and the speed of secondary agitation is 200-220r/min, the time is 13min.
6. the preparation method of a kind of wrinkle resistant guarantor's look finishing agent according to claim 4, it is characterized in that, temperature described in step S2 is 65 DEG C, and the speed of described stirring is 260-320r/min, stirring reaction 18min.
7. the preparation method of a kind of wrinkle resistant guarantor's look finishing agent according to claim 4, is characterized in that, temperature 58 DEG C in step S3, leaves standstill 5min, stirs 26min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610011786.6A CN105401440A (en) | 2016-01-08 | 2016-01-08 | Novel antiwrinkling color-keeping finishing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610011786.6A CN105401440A (en) | 2016-01-08 | 2016-01-08 | Novel antiwrinkling color-keeping finishing agent and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107558191A (en) * | 2016-07-01 | 2018-01-09 | 姜维 | Water-soluble wash and wear finisher |
| CN107558165A (en) * | 2016-07-01 | 2018-01-09 | 姜维 | Silk fabric crease-resistant no-iron finishing agent |
| CN107558166A (en) * | 2016-07-01 | 2018-01-09 | 姜维 | Water-soluble crease-resistant no-iron finishing agent |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104746344A (en) * | 2013-12-25 | 2015-07-01 | 吴旭 | Clothing wrinkle prevention softener |
| CN104805698A (en) * | 2015-05-12 | 2015-07-29 | 湖州厉华妤婕联合纺织有限公司 | Novel anticrease finishing agent composition for cotton fabric |
| CN104846636A (en) * | 2015-06-15 | 2015-08-19 | 湖州厉华妤婕联合纺织有限公司 | Novel crease-resisting finishing agent for textiles |
| CN104894853A (en) * | 2015-07-08 | 2015-09-09 | 石忠 | Anti-wrinkling finishing agent of garment fabric |
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2016
- 2016-01-08 CN CN201610011786.6A patent/CN105401440A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104746344A (en) * | 2013-12-25 | 2015-07-01 | 吴旭 | Clothing wrinkle prevention softener |
| CN104805698A (en) * | 2015-05-12 | 2015-07-29 | 湖州厉华妤婕联合纺织有限公司 | Novel anticrease finishing agent composition for cotton fabric |
| CN104846636A (en) * | 2015-06-15 | 2015-08-19 | 湖州厉华妤婕联合纺织有限公司 | Novel crease-resisting finishing agent for textiles |
| CN104894853A (en) * | 2015-07-08 | 2015-09-09 | 石忠 | Anti-wrinkling finishing agent of garment fabric |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107558191A (en) * | 2016-07-01 | 2018-01-09 | 姜维 | Water-soluble wash and wear finisher |
| CN107558165A (en) * | 2016-07-01 | 2018-01-09 | 姜维 | Silk fabric crease-resistant no-iron finishing agent |
| CN107558166A (en) * | 2016-07-01 | 2018-01-09 | 姜维 | Water-soluble crease-resistant no-iron finishing agent |
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Application publication date: 20160316 |