CN105400336A - Film forming agent for leather garment - Google Patents

Film forming agent for leather garment Download PDF

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Publication number
CN105400336A
CN105400336A CN201610001293.4A CN201610001293A CN105400336A CN 105400336 A CN105400336 A CN 105400336A CN 201610001293 A CN201610001293 A CN 201610001293A CN 105400336 A CN105400336 A CN 105400336A
Authority
CN
China
Prior art keywords
parts
forming agent
leather
film forming
polyurethane resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201610001293.4A
Other languages
Chinese (zh)
Inventor
董强
熊雯
张丽
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Difukale Import & Export Trade Co Ltd
Original Assignee
Guangzhou Difukale Import & Export Trade Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Difukale Import & Export Trade Co Ltd filed Critical Guangzhou Difukale Import & Export Trade Co Ltd
Priority to CN201610001293.4A priority Critical patent/CN105400336A/en
Publication of CN105400336A publication Critical patent/CN105400336A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C14SKINS; HIDES; PELTS; LEATHER
    • C14CCHEMICAL TREATMENT OF HIDES, SKINS OR LEATHER, e.g. TANNING, IMPREGNATING, FINISHING; APPARATUS THEREFOR; COMPOSITIONS FOR TANNING
    • C14C11/00Surface finishing of leather
    • C14C11/003Surface finishing of leather using macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Treatment And Processing Of Natural Fur Or Leather (AREA)

Abstract

The invention relates to a film forming agent for a leather garment. The film forming agent is applicable to real clothing leather and belongs to the field of leather finishing agents. The film forming agent comprises, by weight, 90 to 120 parts of coloring cream, 115 to 160 parts of acrylic resin, 30 to 50 parts of aliphatic bonding polyurethane, 80 to 125 parts of waterborne polyurethane resin, 50 to 75 parts of modified casein, 50 to 75 parts of waterborne wax emulsion, 5 to 10 parts of a feeling agent and 440 to 520 parts of distilled water. After treatment with the film forming agent for the leather garment, real clothing leather is not viscous at a high temperature, does not crack at a low temperature, has excellent resistance to freezing and flex, can withstand a low temperature of -20 DEG C, shows good elasticity, feels smooth on the surface and presents the sensation of real leather; the film forming agent is nontoxic, pollution-free, labor-saving, material-saving, cost-saving and easily-operable; and the raw materials of the film forming agent cooperate with each other, various performances of the raw materials are comprehensively combined, and optimal compounding effect is obtained.

Description

A kind of fur clothing membrane-forming agent
Technical field
The present invention relates to a kind of membrane-forming agent, be specifically related to a kind of fur clothing membrane-forming agent, be applicable to corium clothing leather, belong to hide finishes field.
Background technology
The outward appearance of leather products has conclusive effect to the manufacture of leather goods and the selection of human consumer.Through cover with paint, lacquer, colour wash, etc. after leatherware, the defect can not only revising leather surface makes it become attractive in appearance, can improve again the wearing quality of leatherware, can also give the different style of leather and decorative pattern, make leatherware more fashion more have texture.Hide finishes, as leather top finishing material, all has vital impact to the external perception of leatherware and physical and mechanical properties.Meanwhile, skin material is various in style, different properties, with regard under the condition that China's high-quality raw material skin quantity is few, only has and improves leather finish class by ornamenting means, develops high-quality, the finishing agent of special efficacy is a very necessary behave.
Membrane-forming agent, also known as film-forming resin, be the main component of finishing agent, the performance of its structures and characteristics to finishing agent plays a decisive role.At present, conventional membrane-forming agent has acrylic resin, urethane resin and butadiene resin.
Pliable and tough and the high resilience of acrylic resin film forming, have certain opacifying property, the characteristics such as good resistance to tortuosity, fast light, ageing-resistant and wet-rub resistance, make it very welcome at hide finishes Material Field, but acrylic resin film forming is cold short hot sticky, weathering resistance is poor, and the sense of feel plastic cement is too obvious, can not give prominence to the sensation of natural leather.Urethane is used as hide finishes, its film forming properties is good, bonding firmly, coating has the advantages such as high gloss, high-wearing feature, snappiness, water-fast, weathering, cold-resistant, heat-resisting, chemical-resistant resistance, the resultant Leather good hand feeling, comfortable covered with paint, lacquer, colour wash, etc., greatly can improve the class of resultant Leather, water-soluble and product diversification are its development trends.Butadiene resin film forming particularly soft high resilience, fillibility and opacifying property spy excellent, embossing molding is splendid, and ironability is good, fabulous solvent resistance and weathering resistance, but its cost is high, also because limiting by all conditions, fails at home to put into production.
Therefore, be usually mixed two or three membrane-forming agent in practical application uses, time-consumingly takes material, increase cost, and there is plastic cement sense weight, the not resistance to defect such as to freeze, and can not give leather surface good feel.
Summary of the invention
In order to solve the problems of the technologies described above, the invention provides a kind of fur clothing membrane-forming agent.
The technical scheme adopted is: a kind of fur clothing membrane-forming agent being applicable to corium clothing leather, is made up of the component of following weight part:
Color 90 ~ 120 parts, acrylic resin 115 ~ 160 parts, aliphatics is urethane 30 ~ 50 parts then, waterborne polyurethane resin 80 ~ 125 parts, waterborne polyurethane resin 80 ~ 125 parts, modified Casein 50 ~ 75 parts, water-borne wax emulsion 50 ~ 75 parts, hand feeling agent 5 ~ 10 parts, distilled water 440 ~ 520 parts.
Preferably, described fur clothing membrane-forming agent is made up of the component of following weight part:
Color 100 ~ 120 parts, acrylic resin 140 ~ 160 parts, aliphatics is urethane 30 ~ 45 parts then, waterborne polyurethane resin 80 ~ 105 parts, waterborne polyurethane resin 80 ~ 110 parts, modified Casein 60 ~ 75 parts, water-borne wax emulsion 60 ~ 75 parts, hand feeling agent 5 ~ 8 parts, distilled water 440 ~ 490 parts.
Most preferred, described fur clothing membrane-forming agent is made up of the component of following weight part:
Color 120 parts, acrylic resin 150 parts, aliphatics is urethane 30 parts then, waterborne polyurethane resin 100 parts, waterborne polyurethane resin 100 parts, modified Casein 75 parts, water-borne wax emulsion 75 parts, hand feeling agent 5 parts, distilled water 470 parts.
Beneficial effect of the present invention is as follows: after the process of corium clothing leather fur clothing membrane-forming agent, and the sticky low temperature of high temperature does not split, and resistance to freeze resistance to tortuosity excellent, subzero 20 degree of low temperature can be born, elasticity is more excellent and epidermis feel silk sliding, with corium texture, and nontoxic pollution-free, saving of labor is material-saving again, both cost-saving, simple to operate, mutually allocate again, make the various performance of starting material obtain comprehensive combination, reach best composite effect, also extend leather work-ing life simultaneously.
Embodiment
Be described in further details the present invention below by embodiment, these embodiments are only used for the present invention is described, do not limit the present invention in any form.It should be pointed out that to those skilled in the art, without departing from the inventive concept of the premise, can also make some distortion and improvement, these all belong to protection scope of the present invention.
Embodiment 1:
Be applicable to a fur clothing membrane-forming agent for corium clothing leather, be made up of the component of following weight part:
Color 120 parts, acrylic resin 150 parts, aliphatics is urethane 30 parts then, waterborne polyurethane resin 100 parts, waterborne polyurethane resin 100 parts, modified Casein 75 parts, water-borne wax emulsion 75 parts, hand feeling agent 5 parts, distilled water 470 parts.
Embodiment 2:
Be applicable to a fur clothing membrane-forming agent for corium clothing leather, be made up of the component of following weight part:
Color 90 parts, acrylic resin 115 parts, aliphatics is urethane 50 parts then, waterborne polyurethane resin 125 parts, waterborne polyurethane resin 120 parts, modified Casein 50 parts, water-borne wax emulsion 65 parts, hand feeling agent 8 parts, distilled water 440 parts.
Embodiment 3:
Be applicable to a fur clothing membrane-forming agent for corium clothing leather, be made up of the component of following weight part:
Color 115 parts, acrylic resin 140 parts, aliphatics is urethane 33 parts then, waterborne polyurethane resin 108 parts, waterborne polyurethane resin 122 parts, modified Casein 60 parts, water-borne wax emulsion 70 parts, hand feeling agent 10 parts, distilled water 520 parts.
Embodiment 4:
Be applicable to a fur clothing membrane-forming agent for corium clothing leather, be made up of the component of following weight part:
Color 95 parts, acrylic resin 120 parts, aliphatics is urethane 40 parts then, waterborne polyurethane resin 95 parts, waterborne polyurethane resin 80 parts, modified Casein 50 parts, water-borne wax emulsion 59 parts, hand feeling agent 5 parts, distilled water 478 parts.
Embodiment 5
Be applicable to a fur clothing membrane-forming agent for corium clothing leather, be made up of the component of following weight part:
Color 100 parts, acrylic resin 155 parts, aliphatics is urethane 30 parts then, waterborne polyurethane resin 80 parts, waterborne polyurethane resin 85 parts, modified Casein 56 parts, water-borne wax emulsion 50 parts, hand feeling agent 9 parts, distilled water 500 parts.
Above specific embodiments of the invention are described.It is to be appreciated that the present invention is not limited to above-mentioned particular implementation, those skilled in the art can make various amendment within the scope of the claims, and this does not affect flesh and blood of the present invention.

Claims (3)

1. be applicable to a fur clothing membrane-forming agent for corium clothing leather, it is characterized in that, be made up of the component of following weight part:
Color 90 ~ 120 parts, acrylic resin 115 ~ 160 parts, aliphatics is urethane 30 ~ 50 parts then, waterborne polyurethane resin 80 ~ 125 parts, waterborne polyurethane resin 80 ~ 125 parts, modified Casein 50 ~ 75 parts, water-borne wax emulsion 50 ~ 75 parts, hand feeling agent 5 ~ 10 parts, distilled water 440 ~ 520 parts.
2. a kind of fur clothing membrane-forming agent according to claim 1, is characterized in that, described fur clothing membrane-forming agent is made up of the component of following weight part:
Color 100 ~ 120 parts, acrylic resin 140 ~ 160 parts, aliphatics is urethane 30 ~ 45 parts then, waterborne polyurethane resin 80 ~ 105 parts, waterborne polyurethane resin 80 ~ 110 parts, modified Casein 60 ~ 75 parts, water-borne wax emulsion 60 ~ 75 parts, hand feeling agent 5 ~ 8 parts, distilled water 440 ~ 490 parts.
3. a kind of fur clothing membrane-forming agent according to claim 2, is characterized in that, described fur clothing membrane-forming agent is made up of the component of following weight part:
Color 120 parts, acrylic resin 150 parts, aliphatics is urethane 30 parts then, waterborne polyurethane resin 100 parts, waterborne polyurethane resin 100 parts, modified Casein 75 parts, water-borne wax emulsion 75 parts, hand feeling agent 5 parts, distilled water 470 parts.
CN201610001293.4A 2016-01-05 2016-01-05 Film forming agent for leather garment Pending CN105400336A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201610001293.4A CN105400336A (en) 2016-01-05 2016-01-05 Film forming agent for leather garment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201610001293.4A CN105400336A (en) 2016-01-05 2016-01-05 Film forming agent for leather garment

Publications (1)

Publication Number Publication Date
CN105400336A true CN105400336A (en) 2016-03-16

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Country Status (1)

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CN (1) CN105400336A (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105647371A (en) * 2016-03-29 2016-06-08 兴业皮革科技股份有限公司 Method for altering colors of finished leather
CN108192482A (en) * 2017-12-26 2018-06-22 天长市正牧铝业科技有限公司 A kind of special polyurethane finishing agent of leather
CN108997942A (en) * 2018-07-26 2018-12-14 苏州华龙化工有限公司 A kind of preparation method of sericin grape pip polysaccharide composite leather gloss agent
CN109054561A (en) * 2018-07-11 2018-12-21 徐冬 A kind of preparation method of polyacrylate coatings glue
CN109554094A (en) * 2018-11-27 2019-04-02 世联汽车内饰(苏州)有限公司 A kind of cold-resistant folding silane coupling agent of leather and preparation method thereof
CN109576420A (en) * 2018-10-16 2019-04-05 兴业皮革科技股份有限公司 A kind of leather repairing method
CN110227637A (en) * 2019-06-17 2019-09-13 漳州香洲皮革有限公司 Modified stretch-proof leather and preparation method thereof
CN115369192A (en) * 2022-08-05 2022-11-22 焦作隆丰皮草企业有限公司 Leather fabric and preparation method thereof
IT202100030317A1 (en) * 2021-11-30 2023-05-30 Conceria Nuvolari Srl MIXTURE AND METHOD FOR LEATHER TREATMENT

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102993799A (en) * 2012-11-23 2013-03-27 吴江福茂纺织有限公司 Leather finishing agent and preparation method thereof
CN103132324A (en) * 2011-11-22 2013-06-05 四川国和新材料有限公司 Alcohol water-soluble leather finishing agent
CN103965759A (en) * 2014-04-29 2014-08-06 四川大学 Composite leather coating agent and preparation method thereof
CN105131668A (en) * 2015-07-09 2015-12-09 上海琪知睿实业有限公司 Imitation top leather finish for leather priming coating, and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103132324A (en) * 2011-11-22 2013-06-05 四川国和新材料有限公司 Alcohol water-soluble leather finishing agent
CN102993799A (en) * 2012-11-23 2013-03-27 吴江福茂纺织有限公司 Leather finishing agent and preparation method thereof
CN103965759A (en) * 2014-04-29 2014-08-06 四川大学 Composite leather coating agent and preparation method thereof
CN105131668A (en) * 2015-07-09 2015-12-09 上海琪知睿实业有限公司 Imitation top leather finish for leather priming coating, and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王鸿儒: "《皮革生产的理论与技术》", 31 July 1999, 中国轻工业出版社 *

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105647371A (en) * 2016-03-29 2016-06-08 兴业皮革科技股份有限公司 Method for altering colors of finished leather
CN108192482A (en) * 2017-12-26 2018-06-22 天长市正牧铝业科技有限公司 A kind of special polyurethane finishing agent of leather
CN109054561A (en) * 2018-07-11 2018-12-21 徐冬 A kind of preparation method of polyacrylate coatings glue
CN108997942A (en) * 2018-07-26 2018-12-14 苏州华龙化工有限公司 A kind of preparation method of sericin grape pip polysaccharide composite leather gloss agent
CN109576420A (en) * 2018-10-16 2019-04-05 兴业皮革科技股份有限公司 A kind of leather repairing method
CN109554094A (en) * 2018-11-27 2019-04-02 世联汽车内饰(苏州)有限公司 A kind of cold-resistant folding silane coupling agent of leather and preparation method thereof
CN110227637A (en) * 2019-06-17 2019-09-13 漳州香洲皮革有限公司 Modified stretch-proof leather and preparation method thereof
IT202100030317A1 (en) * 2021-11-30 2023-05-30 Conceria Nuvolari Srl MIXTURE AND METHOD FOR LEATHER TREATMENT
WO2023100047A1 (en) * 2021-11-30 2023-06-08 Conceria Nuvolari Srl Mixture and method for leather treatment
CN115369192A (en) * 2022-08-05 2022-11-22 焦作隆丰皮草企业有限公司 Leather fabric and preparation method thereof

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Application publication date: 20160316