CN105400282A - Highlight insulation gold varnish and preparation method there - Google Patents

Highlight insulation gold varnish and preparation method there Download PDF

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Publication number
CN105400282A
CN105400282A CN201510964747.3A CN201510964747A CN105400282A CN 105400282 A CN105400282 A CN 105400282A CN 201510964747 A CN201510964747 A CN 201510964747A CN 105400282 A CN105400282 A CN 105400282A
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CN
China
Prior art keywords
resin
byk
highlighted
insulation
blending oil
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Pending
Application number
CN201510964747.3A
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Chinese (zh)
Inventor
王景泉
刘树群
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CHUZHOU JINQIAO DEKE NEW MATERIAL CO., LTD.
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王景泉
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Priority to CN201510964747.3A priority Critical patent/CN105400282A/en
Publication of CN105400282A publication Critical patent/CN105400282A/en
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D11/00Inks
    • C09D11/02Printing inks
    • C09D11/10Printing inks based on artificial resins
    • C09D11/102Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
    • C09D11/104Polyesters

Abstract

A highlight insulation gold varnish comprises the following components by weight: 10-30% of resin A, 10-40% of resin B, 5-10% of resin C, 5-40% of a solvent and 2-6% of an additive. The method is as below: adding the resin A, resin B and the resin C into the solvent, dissolving, starring a stirrer, stirring at a constant speed until completely dissolution of all solids, and then slowly adding to the additive, and stirring and dispersing uniformly to obtain a liquid 1; and filtering the liquid 1 by a polyester filter screen to obtain a finished product of the highlight insulation gold varnish. The gold varnish has high gloss and high leveling property, can be matched with coloring matters such as color paste and gold and silver powder, and has excellent matching performance; the gold varnish can greatly enhance the transparency and vividness of a pigment paste, promote the arrangement of gold and silver powder in the curing and film formation, thereby enhancing the gloss of the coating and achieve excellent decorative effect; and the gold varnish also has high insulation resistance, and can be used in the field of packaging and printing of electronic components products.

Description

A kind of highlighted insulation blending oil and preparation method thereof
Technical field
Patent of the present invention relates to the technical field of a kind of resin gloss oil and preparation method thereof, especially a kind of highlighted insulation blending oil and preparation method thereof.
Background technology
In silk screen printing field, resin gloss oil typically refers to not containing the transparent ink of the coloring material such as pigment, metal(lic)powder, solvent type resin gloss oil, radiation curing gloss oil and water-based gloss oil etc. can be divided into by binder type difference, Main Function is the coating providing one deck light or dumb light after film-forming, plays protection and decoration function;
Described gloss oil can be used alone, but in actual print production, printing house needs to add the coloring materials such as each mill base or metal(lic)powder usually in gloss oil, to reach diversified decorative colour and effect, and in the process, usually because the matching of the coloring material such as mill base, metal(lic)powder and gloss oil is not good, after causing gloss oil film-forming, coating gloss declines, and have impact on the expression effect of decoration and color.
Summary of the invention
The object of the invention is, a kind of highlighted insulation blending oil and preparation method thereof is provided, this highlighted insulation blending oil possesses high gloss, high levelling, can mate with the coloring material such as mill base, metal(lic)powder, and matched performance is splendid, transparency and the vividness of dispersible pigment color paste can be strengthened greatly, and the arrangement of metal(lic)powder when film-forming can be promoted, thus improve the glossiness of coating, reach excellent decorative effect, the highlighted insulation blending oil of this invention has higher insulativity simultaneously, can be used for the packages printing field of electronic product component.
In order to solve the problems of the technologies described above, the invention provides a kind of highlighted insulation blending oil and preparation method thereof, wherein:
A kind of highlighted insulation blending oil, by mass percentage, its component comprises: the Resin A of 10-30%, 10-40% resin B, 5-10% resin C, 5-40% solvent, 2-6% auxiliary agent;
A preferred embodiment component for highlighted insulation blending oil, comprises: the Resin A of 20%, 35% resin B, 7% resin C, 32% solvent, 6% auxiliary agent; Through experimental verification, this preferred embodiment component can play more matching and insulativity effect;
Illustrate as one, described Resin A is epoxy resin;
As a kind of preferred embodiment, described epoxy resin is Tao Shi (DOW) epoxy resin DER671, DER331, DER669e, or shell 1001,1004,828, or national capital chemistry YD-112, YD-11, one in YD-115, YD-119,2209 or combination;
Illustrate as one, described resin B is vibrin;
As a kind of preferred embodiment, described vibrin is 7360,3911 of Jiangsu Miki Group, or Japan spin 226,245,360,237,600, or Shenzhen praise contain chemistry saturated polyester 7810, or win wound chemistry EPX201, L411-03, L203 in one or combination;
Illustrate as one, described resin C is synthetic resins;
As a kind of preferred embodiment, described synthetic resins is synthetic resins 1201, SK, CA, TC of winning wound chemistry, or speeds one in the SNZ905 of trade or combination in Lip river, Guangzhou;
Illustrate as one, described solvent is one in ethylene glycol monobutyl ether (BCS), ethylene glycol ethyl ether (ECS), pimelinketone (CYC), toluene, Virahol (IPA), isophorone, propylene glycol monomethyl ether (PM), 1-Methoxy-2-propyl acetate (PMA), ethylene glycol ether acetate (CAC), mixed dibasic acid ester (DBE), propyl carbinol or combination;
Illustrate as one, described auxiliary agent is one in defoamer, flow agent or coupling agent or combination;
As a kind of preferred embodiment, described defoamer is BYK055, BYK052, BYK057, BYK-066N, BYK-070, BYK-072, BYK-077, BYK-141, or enlightening high (Tego) FormaxN, 980,289,900,833,910, or Japanese common prosperity society HS01, AC2300, or Merck KGaA chemistry MOK-6010, or one in Bao Er get organosilicon BD3062 or combination;
As a kind of preferred embodiment, described flow agent be high (Tego) 410 of enlightening, KL245,432,450,2500,100, Flow300, or Bi Ke chemistry BYK-358N, BYK-390, BYK-306, BYK-307, BYK-310, BYK-361N, BYK-333, or one in Bao Er get organosilicon BD3340, BD3376, BD3303, BD3032 or combination;
As a kind of preferred embodiment, described coupling agent is KH550, KH560, KH570 of Nanjing chemical industry forward, or Norcent of Tianzhang City Fine Chemical Works TC-F, TC-2, TC-3, TC-114, TC-311, or one in TC-9, TC-70, TC-130, TC-TTS of prosperous safe chemical industry or combination;
Invention also provides a kind of preparation method of highlighted insulation blending oil, this preparation method is as follows:
Step one, in described solvent, add described Resin A, resin B, resin C dissolve, turn on agitator average rate is stirred to solid particulate and dissolves completely;
Illustrate as one, the operating environment of described step one requires to carry out under the condition of lucifuge;
Illustrate as one, described Resin A, resin B, resin C are solid;
Illustrate as one, under described average rate state, the stir speed (S.S.) of agitator is: 1000-2000r/min;
Step 2, in the solvent operated according to step one, slowly add described auxiliary agent, and dispersed with stirring is even, obtains liquid one;
Illustrate as one, the operating environment of described step 2 is normal temperature, normal pressure and lucifuge;
Step 3, employing polyester filter screen, carry out filter operation to described liquid one, get product a kind of highlighted insulation blending oil;
Beneficial effect of the present invention:
1, according to the highlighted insulation blending oil prepared by the component described in the present invention and making method, technique is simple, and production efficiency is high, and material energy-saving environmental protection;
2, gloss is high: aperture glossmeter is tested, glossiness >=90
3, levelling property is high: reference standard " JB/T3998-1999 paint flow levelling is coated with and scrapes assay method " measures, levelling property >=8 grade
3, transparency is high: transparency meter is tested, transmittance >=95%;
Accompanying drawing explanation
Fig. 1 is the schematic flow sheet of the preparation method of a kind of highlighted insulation blending oil of the present invention
Embodiment
Below in conjunction with accompanying drawing to a preferred embodiment of the present invention will be described in detail;
With reference to shown in Fig. 1, a kind of highlighted insulation blending oil and preparation method thereof, wherein:
A kind of highlighted insulation blending oil, by mass percentage, its component comprises: the Resin A of 10-30%, 10-40% resin B, 5-10% resin C, 5-40% solvent, 2-6% auxiliary agent;
A preferred embodiment component for highlighted insulation blending oil, comprises: the Resin A of 20%, 35% resin B, 7% resin C, 32% solvent, 6% auxiliary agent; Through experimental verification, this preferred embodiment component can play more matching and insulativity effect;
Illustrate as one, described Resin A is epoxy resin;
As a kind of preferred embodiment, described epoxy resin is Tao Shi (DOW) epoxy resin DER671, DER331, DER669e, or shell 1001,1004,828, or national capital chemistry YD-112, YD-11, one in YD-115, YD-119,2209 or combination;
Illustrate as one, described resin B is vibrin;
As a kind of preferred embodiment, described vibrin is 7360,3911 of Jiangsu Miki Group, or Japan spin 226,245,360,237,600, or Shenzhen praise contain chemistry saturated polyester 7810, or win wound chemistry EPX201, L411-03, L203 in one or combination;
Illustrate as one, described resin C is synthetic resins;
As a kind of preferred embodiment, described synthetic resins is synthetic resins 1201, SK, CA, TC of winning wound chemistry, or speeds one in the SNZ905 of trade or combination in Lip river, Guangzhou;
Illustrate as one, described solvent is one in ethylene glycol monobutyl ether (BCS), ethylene glycol ethyl ether (ECS), pimelinketone (CYC), toluene, Virahol (IPA), isophorone, propylene glycol monomethyl ether (PM), 1-Methoxy-2-propyl acetate (PMA), ethylene glycol ether acetate (CAC), mixed dibasic acid ester (DBE), propyl carbinol or combination;
Illustrate as one, described auxiliary agent is one in defoamer, flow agent or coupling agent or combination;
As a kind of preferred embodiment, described defoamer is BYK055, BYK052, BYK057, BYK-066N, BYK-070, BYK-072, BYK-077, BYK-141, or enlightening high (Tego) FormaxN, 980,289,900,833,910, or Japanese common prosperity society HS01, AC2300, or Merck KGaA chemistry MOK-6010, or one in Bao Er get organosilicon BD3062 or combination;
As a kind of preferred embodiment, described flow agent be high (Tego) 410 of enlightening, KL245,432,450,2500,100, Flow300, or Bi Ke chemistry BYK-358N, BYK-390, BYK-306, BYK-307, BYK-310, BYK-361N, BYK-333, or one in Bao Er get organosilicon BD3340, BD3376, BD3303, BD3032 or combination;
As a kind of preferred embodiment, described coupling agent is KH550, KH560, KH570 of Nanjing chemical industry forward, or Norcent of Tianzhang City Fine Chemical Works TC-F, TC-2, TC-3, TC-114, TC-311, or one in TC-9, TC-70, TC-130, TC-TTS of prosperous safe chemical industry or combination;
Invention also provides a kind of preparation method of highlighted insulation blending oil, this preparation method is as follows:
Step one, in described solvent, add described Resin A, resin B, resin C dissolve, turn on agitator average rate is stirred to solid particulate and dissolves completely;
Illustrate as one, the operating environment of described step one requires to carry out under the condition of lucifuge;
Illustrate as one, described Resin A, resin B, resin C are solid;
Illustrate as one, under described average rate state, the stir speed (S.S.) of agitator is: 1000-2000r/min;
Step 2, in the solvent operated according to step one, slowly add described auxiliary agent, and dispersed with stirring is even, obtains liquid one;
Illustrate as one, the operating environment of described step 2 is normal temperature, normal pressure and lucifuge;
Step 3, employing polyester filter screen, carry out filter operation to described liquid one, get product a kind of highlighted insulation blending oil;
In order to process for preparation of the present invention is better described, existing preparation by preferred embodiment is exemplified below: (by mass percentage)
Step one, obtain 32% ethylene glycol ethyl ether (ECS), in described ECS, add the epoxy resin of 20%, the vibrin of 35%, the synthetic resins of 7% dissolves, turn on agitator average rate is stirred to whole resin solid particles and dissolves completely;
Illustrate as one, the operating environment of described step one requires to carry out under the condition of lucifuge;
Illustrate as one, described epoxy resin, vibrin, synthetic resins are solid;
Illustrate as one, under described average rate state, the stir speed (S.S.) of agitator is: 1000-2000r/min;
Step 2, slowly add in the solvent operated according to step one 6% coupling agent, and dispersed with stirring is even, obtains liquid one;
Illustrate as one, the operating environment of described step 2 is normal temperature, normal pressure and lucifuge;
Step 3, employing polyester filter screen, carry out filter operation to described liquid one, get product a kind of highlighted insulation blending oil;
The resin gloss oil made according to the preferred embodiment, possess high gloss, high levelling, can mate with the coloring material such as mill base, metal(lic)powder, and matched performance is splendid, transparency and the vividness of dispersible pigment color paste can be strengthened greatly, and the arrangement of metal(lic)powder when film-forming can be promoted, thus improve the glossiness of coating, reach excellent decorative effect, and there is higher insulativity simultaneously, can be used for the packages printing field of electronic product component;
The ink physical index of the resin gloss oil produced according to above preferred embodiment preparation program is:
Above-describedly be only the preferred embodiments of the present invention; be understood that; the explanation of above embodiment just understands method of the present invention and core concept thereof for helping; the protection domain be not intended to limit the present invention; all any amendments, equivalent replacement etc. made within thought of the present invention and principle, all should be included within protection scope of the present invention.

Claims (10)

1. a highlighted insulation blending oil, is characterized in that, by mass percentage, its component comprises: the Resin A of 10-30%, 10-40% resin B, 5-10% resin C, 5-40% solvent, 2-6% auxiliary agent; Described Resin A is epoxy resin; Described resin B is vibrin; Described resin C is synthetic resins.
2. the highlighted insulation blending oil of one according to claim 1, it is characterized in that, described epoxy resin is Tao Shi epoxy resin DER671, DER331, DER669e, or shell 1001,1004,828, or national capital chemistry YD-112, YD-11, one in YD-115, YD-119,2209 or combination.
3. the highlighted insulation blending oil of one according to claim 1, it is characterized in that, described vibrin is 7360,3911 of Jiangsu Miki Group, or Japan spin 226,245,360,237,600, or Shenzhen praise contain chemistry saturated polyester 7810, or win wound chemistry EPX201, L411-03, L203 in one or combination.
4. the highlighted insulation blending oil of one according to claim 1, is characterized in that, described synthetic resins is synthetic resins 1201, SK, CA, TC of winning wound chemistry, or speeds one in the SNZ905 of trade or combination in Lip river, Guangzhou.
5. the highlighted insulation blending oil of one according to claim 1, it is characterized in that, described solvent is one in ethylene glycol monobutyl ether, ethylene glycol ethyl ether, pimelinketone, toluene, Virahol, isophorone, propylene glycol monomethyl ether, 1-Methoxy-2-propyl acetate, ethylene glycol ether acetate, mixed dibasic acid ester, propyl carbinol or combination.
6. the highlighted insulation blending oil of one according to claim 1, is characterized in that, described auxiliary agent is one in defoamer, flow agent or coupling agent or combination.
7. the highlighted insulation blending oil of one according to claim 6, is characterized in that,
Described defoamer is BYK055, BYK052, BYK057, BYK-066N, BYK-070, BYK-072, BYK-077, BYK-141, or enlightening height FormaxN, 980,289,900,833,910, or Japanese common prosperity society HS01, AC2300, or Merck KGaA chemistry MOK-6010, or one in Bao Er get organosilicon BD3062 or combination;
Described flow agent is that enlightening is high by 410, KL245,432,450,2500,100, Flow300, or Bi Ke chemistry BYK-358N, BYK-390, BYK-306, BYK-307, BYK-310, BYK-361N, BYK-333, or one in Bao Er get organosilicon BD3340, BD3376, BD3303, BD3032 or combination;
Described coupling agent is KH550, KH560, KH570 of Nanjing chemical industry forward, or Norcent of Tianzhang City Fine Chemical Works TC-F, TC-2, TC-3, TC-114, TC-311, or one in TC-9, TC-70, TC-130, TC-TTS of prosperous safe chemical industry or combination.
8. a preparation method for highlighted insulation blending oil, is characterized in that, this preparation method comprises the steps:
Step one, in described solvent, add described Resin A, resin B, resin C dissolve, turn on agitator average rate is stirred to solid particulate and dissolves completely;
Step 2, in the solvent operated according to step one, slowly add described auxiliary agent, and dispersed with stirring is even, obtains liquid one;
Step 3, employing polyester filter screen, carry out filter operation to described liquid one, get product a kind of highlighted insulation blending oil.
9. the preparation method of a kind of highlighted insulation blending oil according to claim 8, is characterized in that, the operating environment of described step one is light protected environment;
Described Resin A, resin B, resin C are solid;
Under described average rate state, the stir speed (S.S.) of agitator is: 1000-2000r/min.
10. the preparation method of a kind of highlighted insulation blending oil according to claim 8, is characterized in that, the operating environment of described step 2 is normal temperature, normal pressure and lucifuge.
CN201510964747.3A 2015-12-21 2015-12-21 Highlight insulation gold varnish and preparation method there Pending CN105400282A (en)

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Application Number Priority Date Filing Date Title
CN201510964747.3A CN105400282A (en) 2015-12-21 2015-12-21 Highlight insulation gold varnish and preparation method there

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510964747.3A CN105400282A (en) 2015-12-21 2015-12-21 Highlight insulation gold varnish and preparation method there

Publications (1)

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CN105400282A true CN105400282A (en) 2016-03-16

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040115561A1 (en) * 2002-12-13 2004-06-17 Mikhail Laksin Energy curable, water washable printing inks suitable for waterless lithographic printing
CN1548485A (en) * 2003-05-07 2004-11-24 中国印钞造币总公司 Pearlescent UV water-based screen-printing ink
CN102140277A (en) * 2011-04-25 2011-08-03 王泝舟 Baking-curing high hardness water transfer printing ink without adopting varnish protection and printing process
CN103740173A (en) * 2014-01-17 2014-04-23 苏州昭奇凯虹精细化工有限公司 Ink

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040115561A1 (en) * 2002-12-13 2004-06-17 Mikhail Laksin Energy curable, water washable printing inks suitable for waterless lithographic printing
CN1548485A (en) * 2003-05-07 2004-11-24 中国印钞造币总公司 Pearlescent UV water-based screen-printing ink
CN102140277A (en) * 2011-04-25 2011-08-03 王泝舟 Baking-curing high hardness water transfer printing ink without adopting varnish protection and printing process
CN103740173A (en) * 2014-01-17 2014-04-23 苏州昭奇凯虹精细化工有限公司 Ink

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Effective date of registration: 20170928

Address after: Ten 239500 Tan Industrial Park, Quanjiao County, Anhui, Chuzhou

Applicant after: CHUZHOU JINQIAO DEKE NEW MATERIAL CO., LTD.

Address before: 214000, Wuxi, Wuxi, Jiangsu photoelectric new materials science and technology park will be No. 88, shore road, Room 606

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Application publication date: 20160316