CN105399192A - Treating agent for removing methanal, methyl alcohol and phenol in phenolic resin workshop wastewater - Google Patents
Treating agent for removing methanal, methyl alcohol and phenol in phenolic resin workshop wastewater Download PDFInfo
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- CN105399192A CN105399192A CN201610014055.7A CN201610014055A CN105399192A CN 105399192 A CN105399192 A CN 105399192A CN 201610014055 A CN201610014055 A CN 201610014055A CN 105399192 A CN105399192 A CN 105399192A
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/542—Phosphorus compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
- C02F2101/345—Phenols
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
- C02F2103/34—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
- C02F2103/36—Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
- C02F2103/38—Polymers
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention relates to a treating agent for removing methanal, methyl alcohol and phenol in phenolic resin workshop wastewater, compounded from the following components of 2-tridecanone, 4-sodium parachlorophenoxy, fritillarine, thiodipropionicacid dilauryl ester, rotundic acid, 4-acetoxyl-3-methoxy-(2-allyl)benzene, lobelanidine HCL, 4-octylphenol ethoxylate, 3',4'-dyhydroxy-2-(methylamino)acetophenone hydrochloride, and the like. The treating agent is strong in complexing power with a target substance, quick in complex precipitate forming speed, little in usage amount, and free of damage to a water body, and has a removal rate of 99.9 percent.
Description
Technical field
The present invention relates to a kind for the treatment of agent removing formaldehyde, methyl alcohol and phenol in resol plant effluent, belong to environmental protection technical field.
Background technology
Resol is polymerized under certain condition by phenol and formaldehyde, and it is widely used in bakelite synthetic materials, impregnating material, bonding agent and paint etc.A large amount of high-concentration phenolic wastewaters is produced in resol production process.Due to the chemical substance that phenol is a kind of high poison, severe corrosive, it all has extremely strong toxicity to most biology, can cause protein denaturation, solidify, finally cause bio-tissue exhaustion, until dead.Therefore, be just directly discharged in natural water if these waste water do not add process, the physical environment of depending on for existence to us is caused serious destruction.American National Environmental Protection Agency is one of pollutent phenol and compound thereof being listed in 129 kinds of priority acccess control, and the water pollution control work of China is also classified as the process of phenolic wastewater as one of key problems-solving.
The process of the high-concentration phenolic wastewater produced in resol production process seems simple, and actual have certain complicacy.Because pulmonary edema is except containing except the phenol of high density, also containing a large amount of small molecules resol and other materials such as formaldehyde, methyl alcohol, therefore, some single low-cost processes technique and development thereof is just limited, such as: the techniques such as activated adsorption method, biological dephenolize method.Existing treatment technology mainly contains several as follows:
Biochemical decomposition method, first dilution of sewage hundreds of times must can be carried out biochemical treatment, investment is large, and average treatment one ton of waste water needs 300 yuan, and production cost is high, wastes a large amount of water resources.
Chemical oxidization method, by potassium permanganate or ozone oxidation, its cost is high, and technical requirements is high, is difficult to promote.
Extraction and recovery method, make extraction agent with organic solvent (such as coal tar), percentage extraction is low, the highest less than 90%, and processed waste water still exceeds standard thousands of times containing phenol amount, and also need to carry out biological phenol removal, complex technical process, cost is high, and treatment effect is also undesirable.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art, a kind for the treatment of agent removing formaldehyde, methyl alcohol and phenol in resol plant effluent is provided, it can with the formaldehyde in water, methyl alcohol and phenol effect, form complex compound sediment, remove by filtering, have low toxicity, non-environmental-pollution, clearance is high, applied widely, the advantage that cost is low.
Technology contents of the present invention is: a kind for the treatment of agent removing formaldehyde, methyl alcohol and phenol in resol plant effluent, comprises the component of the following meter of mark by weight:
Methyl n-undecyl ketone 10-18 part,
4-chlorophenoxyacetic acid sodium 15-19 part,
Peiminine 0.6-1.0 part,
The two dodecane ester 8-14 part of thio-2 acid,
Rotundic acid 4-8 part,
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane 16-20 part,
Monocalcium phosphate 10-20 part,
Sessile Lobelia determines hydrochloride 0.5-1.1 part,
4-octylphenol ethoxylate 8-12 part,
3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride 3-5 part,
4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene 15-21 part,
Sodium stearyl fumarate 12-20 part,
Acetyl inulicin 2-4 part,
Tripolyglycerol monostearates 6-12 part,
4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate 8-10 part,
6-acetonyl dihydrosanguinarine 3-7 part.
Preferably, the component of the following meter of mark is by weight comprised:
Methyl n-undecyl ketone 14 parts,
17 parts, 4-chlorophenoxyacetic acid sodium,
Peiminine 0.8 part,
The two dodecane ester 11 parts of thio-2 acid,
Rotundic acid 6 parts,
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane 18 parts,
Monocalcium phosphate 15 parts,
Sessile Lobelia determines hydrochloride 0.8 part,
4-octylphenol ethoxylate 10 parts,
3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride 4 parts,
4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene 18 parts,
Sodium stearyl fumarate 16 parts,
Acetyl inulicin 3 parts,
Tripolyglycerol monostearates 9 parts,
4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate 9 parts,
6-acetonyl dihydrosanguinarine 5 parts.
The present invention has following beneficial effect:
(1) methyl n-undecyl ketone, 4-chlorophenoxyacetic acid sodium, peiminine, the two dodecane ester of thio-2 acid, rotundic acid five kinds of materials produce synergy, can with formaldehyde effect, form complex compound sediment; 1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane, monocalcium phosphate, Sessile Lobelia determine hydrochloride, 4-octylphenol ethoxylate, 3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride, five kinds of materials produce synergy, can with methyl alcohol effect, formed complex compound sediment; 4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene, sodium stearyl fumarate, acetyl inulicin, Tripolyglycerol monostearates, 4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate, 6-acetonyl dihydrosanguinarine six kinds of materials produce synergy, can with phenol effect, formed complex compound sediment;
(2) strong with the complex ability of formaldehyde, methyl alcohol and phenol, form complex compound sediment speed fast, clearance can reach more than 99.9%;
(3) hypotoxicity, consumption is few, does not produce harm to water body;
(4) only need dosing and filtering separation device, low for equipment requirements, processing cost is low;
(5) use at any time and add at any time, by the restriction of producing load.
Embodiment
Below in conjunction with specific embodiment, the invention will be further described, but the present invention's scope required for protection is not limited to the described scope of embodiment.
Embodiment 1
Remove a treatment agent for formaldehyde, methyl alcohol and phenol in resol plant effluent, comprise the component of the following meter of mark by weight:
Methyl n-undecyl ketone 12 parts,
16 parts, 4-chlorophenoxyacetic acid sodium,
Peiminine 0.7 part,
The two dodecane ester 9 parts of thio-2 acid,
Rotundic acid 5 parts,
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane 17 parts,
Monocalcium phosphate 14 parts,
Sessile Lobelia determines hydrochloride 0.7 part,
4-octylphenol ethoxylate 9 parts,
3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride 3 parts,
4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene 16 parts,
Sodium stearyl fumarate 15 parts,
Acetyl inulicin 3 parts,
Tripolyglycerol monostearates 8 parts,
4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate 8 parts,
6-acetonyl dihydrosanguinarine 4 parts.
Before process: 1L Formaldehyde in Water Sample 10mg, methyl alcohol 10mg, phenol 10mg, adds present treatment agent 50mg;
After process: all do not detect containing methyl alcohol 0.01mg, formaldehyde and phenol in 1L water sample.
Embodiment 2
Remove a treatment agent for formaldehyde, methyl alcohol and phenol in resol plant effluent, comprise the component of the following meter of mark by weight:
Methyl n-undecyl ketone 15 parts,
18 parts, 4-chlorophenoxyacetic acid sodium,
Peiminine 0.9 part,
The two dodecane ester 12 parts of thio-2 acid,
Rotundic acid 7 parts,
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane 19 parts,
Monocalcium phosphate 16 parts,
Sessile Lobelia determines hydrochloride 0.9 part,
4-octylphenol ethoxylate 11 parts,
3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride 5 parts,
4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene 20 parts,
Sodium stearyl fumarate 17 parts,
Acetyl inulicin 3 parts,
Tripolyglycerol monostearates 10 parts,
4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate 10 parts,
6-acetonyl dihydrosanguinarine 6 parts.
Before process: 1L Formaldehyde in Water Sample 8mg, methyl alcohol 12mg, phenol 12mg, adds present treatment agent 50mg;
After process: in 1L water sample, formaldehyde, methyl alcohol and phenol all do not detect.
Embodiment 3
Remove a treatment agent for formaldehyde, methyl alcohol and phenol in resol plant effluent, comprise the component of the following meter of mark by weight:
Methyl n-undecyl ketone 14 parts,
17 parts, 4-chlorophenoxyacetic acid sodium,
Peiminine 0.8 part,
The two dodecane ester 11 parts of thio-2 acid,
Rotundic acid 6 parts,
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane 18 parts,
Monocalcium phosphate 15 parts,
Sessile Lobelia determines hydrochloride 0.8 part,
4-octylphenol ethoxylate 10 parts,
3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride 4 parts,
4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene 18 parts,
Sodium stearyl fumarate 16 parts,
Acetyl inulicin 3 parts,
Tripolyglycerol monostearates 9 parts,
4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate 9 parts,
6-acetonyl dihydrosanguinarine 5 parts.
Before process: 1L Formaldehyde in Water Sample 10mg, methyl alcohol 14mg, phenol 14mg adds present treatment agent 50mg;
After process: in 1L water sample, formaldehyde, methyl alcohol and phenol all do not detect.
The above; be only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.
Claims (2)
1. remove a treatment agent for formaldehyde, methyl alcohol and phenol in resol plant effluent, it is characterized in that, comprise the following component counted by weight:
Methyl n-undecyl ketone 10-18 part,
4-chlorophenoxyacetic acid sodium 15-19 part,
Peiminine 0.6-1.0 part,
The two dodecane ester 8-14 part of thio-2 acid,
Rotundic acid 4-8 part,
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane 16-20 part,
Monocalcium phosphate 10-20 part,
Sessile Lobelia determines hydrochloride 0.5-1.1 part,
4-octylphenol ethoxylate 8-12 part,
3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride 3-5 part,
4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene 15-21 part,
Sodium stearyl fumarate 12-20 part,
Acetyl inulicin 2-4 part,
Tripolyglycerol monostearates 6-12 part,
4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate 8-10 part,
6-acetonyl dihydrosanguinarine is about 3-7 part.
2. the treatment agent of formaldehyde, methyl alcohol and phenol in removal resol plant effluent according to claim 1, is characterized in that, comprise the following component counted by weight:
Methyl n-undecyl ketone 14 parts,
17 parts, 4-chlorophenoxyacetic acid sodium,
Peiminine 0.8 part,
The two dodecane ester 11 parts of thio-2 acid,
Rotundic acid 6 parts,
1,3,3-trimethylammonium-2-oxabicyclo [2.2.2] octane 18 parts,
Monocalcium phosphate 15 parts,
Sessile Lobelia determines hydrochloride 0.8 part,
4-octylphenol ethoxylate 10 parts,
3 ', 4 '-dihydroxyl-2-(methylamino) acetophenone hydro-chloride 4 parts,
4-(1,5-dimethyl-4-hexene subunit)-1-tetrahydrotoluene 18 parts,
Sodium stearyl fumarate 16 parts,
Acetyl inulicin 3 parts,
Tripolyglycerol monostearates 9 parts,
4-amino-1-hydroxyl fourth subunit-1,1-bisphosphate 9 parts,
6-acetonyl dihydrosanguinarine 5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610014055.7A CN105399192A (en) | 2016-01-11 | 2016-01-11 | Treating agent for removing methanal, methyl alcohol and phenol in phenolic resin workshop wastewater |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610014055.7A CN105399192A (en) | 2016-01-11 | 2016-01-11 | Treating agent for removing methanal, methyl alcohol and phenol in phenolic resin workshop wastewater |
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| Publication Number | Publication Date |
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| CN105399192A true CN105399192A (en) | 2016-03-16 |
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| CN201610014055.7A Pending CN105399192A (en) | 2016-01-11 | 2016-01-11 | Treating agent for removing methanal, methyl alcohol and phenol in phenolic resin workshop wastewater |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109438183A (en) * | 2018-12-21 | 2019-03-08 | 安徽省新康饲料有限公司 | A kind of synthetic method of bisabolene |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4830671A (en) * | 1971-08-25 | 1973-04-23 | ||
| CN105016450A (en) * | 2015-08-17 | 2015-11-04 | 李海兰 | Treating agent for removing ethyl alcohol, isopropyl alcohol and octyl alcohol in waste water of amino resin workshop |
| CN105084495A (en) * | 2015-08-17 | 2015-11-25 | 李海兰 | Method for removing ethanol, isopropanol and octyl alcohol from amino resin workshop wastewater |
-
2016
- 2016-01-11 CN CN201610014055.7A patent/CN105399192A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4830671A (en) * | 1971-08-25 | 1973-04-23 | ||
| CN105016450A (en) * | 2015-08-17 | 2015-11-04 | 李海兰 | Treating agent for removing ethyl alcohol, isopropyl alcohol and octyl alcohol in waste water of amino resin workshop |
| CN105084495A (en) * | 2015-08-17 | 2015-11-25 | 李海兰 | Method for removing ethanol, isopropanol and octyl alcohol from amino resin workshop wastewater |
Non-Patent Citations (2)
| Title |
|---|
| 张华山 等: "《分子探针与检测试剂》", 31 July 2002 * |
| 赵志刚: "《当代药学辞典》", 30 April 2006 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109438183A (en) * | 2018-12-21 | 2019-03-08 | 安徽省新康饲料有限公司 | A kind of synthetic method of bisabolene |
| CN109438183B (en) * | 2018-12-21 | 2021-09-14 | 安徽省新康饲料有限公司 | Synthesis method of bisabolene |
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