CN105394840A - Anti-haze mask - Google Patents

Anti-haze mask Download PDF

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Publication number
CN105394840A
CN105394840A CN201510781216.0A CN201510781216A CN105394840A CN 105394840 A CN105394840 A CN 105394840A CN 201510781216 A CN201510781216 A CN 201510781216A CN 105394840 A CN105394840 A CN 105394840A
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CN
China
Prior art keywords
layer
haze
contact layer
incorporated
top layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510781216.0A
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Chinese (zh)
Inventor
唐靖岚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Wuxi Qingyang Machinery Manufacturing Co Ltd
Original Assignee
Wuxi Qingyang Machinery Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Wuxi Qingyang Machinery Manufacturing Co Ltd filed Critical Wuxi Qingyang Machinery Manufacturing Co Ltd
Priority to CN201510781216.0A priority Critical patent/CN105394840A/en
Publication of CN105394840A publication Critical patent/CN105394840A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D13/00Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches
    • A41D13/05Professional, industrial or sporting protective garments, e.g. surgeons' gowns or garments protecting against blows or punches protecting only a particular body part
    • A41D13/11Protective face masks, e.g. for surgical use, or for use in foul atmospheres
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/02Layered materials
    • AHUMAN NECESSITIES
    • A41WEARING APPAREL
    • A41DOUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D31/00Materials specially adapted for outerwear
    • A41D31/04Materials specially adapted for outerwear characterised by special function or use
    • A41D31/10Impermeable to liquids, e.g. waterproof; Liquid-repellent
    • A41D31/102Waterproof and breathable
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8637Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/89Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
    • B01J23/8933Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8993Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air

Abstract

The invention discloses an anti-haze mask which is provided with a catalyst structure layer. After haze air passes through the mask, PM 2.5 particles, nitric oxide and sulfur oxide are all decreased to an extremely low level, and respiratory health is effectively protected.

Description

A kind of mouth mask preventing and treating haze
Technical field
The present invention relates to mouth mask technical field, be specifically related to a kind of mouth mask preventing and treating haze.
Background technology
Haze weather is a kind of atmosphere pollution state, haze is the general statement to suspended particulate substance content overproof various in air, and especially PM2.5 (equivalent aerodynamic diameter is less than or equal to the particle of 2.5 microns) is considered to " arch-criminal " that cause haze weather.
Haze, also claims the particle such as dust, sulfuric acid, nitric acid, organic hydrocarbon compounds in gray haze (smog) air that air also can be made muddy.The horizontal visibility of object is called mist or mist (Mist) in this phenomenon of 1000-10000 rice.Formed mist time atmospheric humidity should be saturated (when existing if any a large amount of nuclei of condensation, relative humidity not necessarily reach 100% just may occur saturated).Due to the mist scattering of aqueous water or ice crystal composition light and wavelength relationship not quite, thus mist seems to be creamy white or Bluish white and grey.Sulfur dioxide, nitrogen oxide and pellet are the main compositions of haze.
The harm that haze produces human body is as follows:
(1) on the impact of respiratory system
The constituent of haze is very complicated, comprises hundreds of Atmospheric Chemistry particulate matter.The particulate that the mainly diameter be wherein harmful to health is less than 10 microns, as mineral grain thing, sea salt, sulfate, nitrate, Organic aerosol particle, fuel and automobile exhaust gas etc., it directly can enter and stick in human respiratory tract and alveolar.Especially submicron particle can be deposited in upper and lower respiratory tract and alveolar respectively, causes the illness such as acute rhinitis and acute bronchitis.For chronic respiratory disease patients such as bronchial astehma, chronic bronchitis, obstructive emphysema and COPDs, haze weather can make state of an illness acute attack or acute exacerbation.If be in this environment for a long time also can bring out lung cancer.
(2) on the impact of cardiovascular system
Haze sky is also very serious on the impact of human body cardiovascular and cerebrovascular disease, normal blood circulation can be hindered, cause cardiovascular disease, hypertension, coronary heart disease, cerebral hemorrhage, angina pectoris, miocardial infarction, heart failure etc. may be brought out, make chronic bronchitis occur cor pulmonale etc.
Except haze has an impact to air, the Organic Pollution that finishing, industry and mining, vehicle exhaust produce, such as formaldehyde, oxysulfide, nitrogen oxide etc., also create huge pollution to air, result in the decline of air quality equally, have impact on the healthy of people.
Mostly current place to go air-polluting mode, be by physical absorption forms such as charcoal absorptions, the mode that this place to go is polluted, and takes effect slow, and organic pollution can not be decomposed, significantly can not reduce haze, therefore limited more.
Although there are some means utilizing chemical mode to purify the air of a room, such as utilize various chemical reagent or catalyst etc., it generally needs higher temperature, also more to environment for use restriction.
At present, common mouth mask generally adopts fiber cloth or fiber cloth to be mingled with active carbon layer, carrys out filtered air.
CN104983095A discloses a kind of haze apnea resistance mouth mask, it is characterized in that, comprise case, described case is the housing of middle part protuberance, and described case is provided with induction chamber and air storage chamber from inside to outside successively, the top of described induction chamber is provided with haze screen pack, described induction chamber comprises cylinder, piston, crank and connecting rod, and described cylinder is connected with described crank, and described crank connects described connecting rod, described connecting rod is connected with piston, and described piston is provided with the 3rd one-way vent valve; Described air storage chamber comprises upper end cover and bottom end cover, and described upper end cover is the side near described induction chamber, and described upper end cover and bottom end cover are respectively equipped with the first one-way vent valve and the second one-way vent valve; The top of the outer surface of described case is provided with motor, and described motor is connected with power supply; The downside of described case outer surface is provided with some ventholes.
CN104921345A discloses a kind of anti-PM2.5 mouth mask, comprise mask body, described mask body comprises top layer, intermediate layer and nexine, it is characterized in that: described top layer is first comprehensive fabric, described intermediate layer is the melt-blowing nonwoven of weight every square metre 50g, described nexine is the second cotton fabric, filter course is provided with between described first cotton fabric and melt-blowing nonwoven, be provided with heat-insulation layer between described second cotton fabric and melt-blowing nonwoven, described first cotton fabric is connected by bound edge with between the second cotton fabric.
The haze mouth mask of prior art be all by filter or being used for of adsorbing purifies air, but organic pollution, nitrogen oxide or the oxysulfide in air is not by filtering or Adsorption.
Summary of the invention
The object of the invention is to propose a kind of mouth mask preventing and treating haze, this mouth mask can purify haze air, and by the organic pollution in air, sulfur and nitrogen oxides fast decoupled, the respiratory system of energy available protecting user.
For reaching this object, the present invention by the following technical solutions:
Prevent and treat a mouth mask for haze, it comprises the mask body at least covering wearer mouth, nose, its have contact with wearer's skin in contact layer and the top layer away from the setting of interior contact layer side, be provided with filtration between interior contact layer and top layer; Be arranged at the mounting element of mask body; The marginal texture circumference that the top layer of mask body, interior contact layer contact with each other arranges enclosed construction, thus forming the mezzanine space of an installing filtration, the mezzanine space formed by top layer, interior contact layer, enclosed construction has the slide fastener opening structure of lateral arrangement; Wherein, described filtration at least comprises: nonwoven fabric construct layer; Be incorporated into the catalyst structure layer of nonwoven fabric construct layer; Be incorporated into the glass fiber filters of catalyst structure layer; Be incorporated into the nonwoven layer of glass fiber filters; Described catalyst structure layer contains carbon monoxide-olefin polymeric, it is characterized in that,
Described composition comprises following component,
A) nano-TiO of 6%-20% 2the platinum cerium silver kalium composite oxides of load, the mol ratio Ti:Pt:Ce:Ag:K of its each component is 1:(0.05-0.1): (0.05-0.1): (0.05-0.1): (0.05-0.1);
B) the ferrotitanium molybdenum vanadium oxides composite of the zirconium doping of 3%-8%, the mol ratio of Zr:Fe:Ti:Mo:V is (0.02-0.2): 1:(0.5-1): (0.5-1): (0.5-1), described ferrotitanium molybdenum composite oxides possess the composite oxides crystallite system of Fe-O-Ti, Mo-O-Ti and Fe-O-Mo structure;
C) active carbon of surplus.
The present invention is by choosing specific components A and B component, said composition is made to produce cooperative effect, the control of said composition to haze is efficient reaches 100%, simultaneously active high, can catalytic action be played under room temperature, the organic matter degradations such as the formaldehyde in air, benzene are called carbon dioxide, and be higher valence state by harmful oxysulfide, nitrogen oxide catalytic oxidation, and then with charcoal absorption, various pollutant is reduced to ppm level, make this catalyst produce cooperative effect.The mouth mask that slide fastener opening structure is formed; conveniently put into the catalyst structure layer of anti-PM2.5; be applied to mouth mask; make its temperature at about 25-37 DEG C when breathing; reach best effort scope; haze air is after described mouth mask, PM2.5 particle, organic pollution (formaldehyde, benzene etc.) nitrogen oxide and oxysulfide are all reduced to pole low-level, available protecting respiratory health.
Detailed description of the invention
The present invention is described mouth mask of the present invention by following embodiment.
Embodiment 1
By being simply mixed to get composition, the following component of described composition,
A) nano-TiO of 10% 2the platinum cerium silver kalium composite oxides of load, the mol ratio Ti:Pt:Ce:Ag:K of its each component is 1:0.1:0.1:0.1:0.1;
B) 5% zirconium doping ferrotitanium molybdenum vanadium oxides composite, the mol ratio of Zr:Fe:Ti:Mo:V is 0.1:1:1:1:1, and described ferrotitanium molybdenum composite oxides possess the composite oxides crystallite system of Fe-O-Ti, Mo-O-Ti and Fe-O-Mo structure;
C) active carbon of surplus.
Open slide fastener opening structure, put into described catalyst and form catalyst structure layer.And then prepare mouth mask of the present invention according to following structure.Comprise the mask body at least covering wearer mouth, nose, its have contact with wearer's skin in contact layer and the top layer away from the setting of interior contact layer side, be provided with filtration between interior contact layer and top layer; Be arranged at the mounting element of mask body; The marginal texture circumference that the top layer of mask body, interior contact layer contact with each other arranges enclosed construction, thus forming the mezzanine space of an installing filtration, the mezzanine space formed by top layer, interior contact layer, enclosed construction has the slide fastener opening structure of lateral arrangement; Wherein, described filtration at least comprises: nonwoven fabric construct layer; Be incorporated into the catalyst structure layer of nonwoven fabric construct layer; Be incorporated into the glass fiber filters of catalyst structure layer; Be incorporated into the nonwoven layer of glass fiber filters.
Test when PM2.5 is 350, described contaminated air is passed through described mouth mask with the speed of 1 meter per second close to respiration rate, test the air through mouth mask process, its PM2.5 value is 0, the content of organic pollution, nitrogen oxide and oxysulfide all drops to less than 0.01 milligram/cubic metre, is far smaller than the requirement of the Indoor Air Quality standards that GB/T18883-2002 specifies.
Comparative example 1
Component A content 15%, not containing B component, all the other conditions are constant, and the PM2.5 value after 1 hour is 23, and the content of organic pollution, nitrogen oxide and oxysulfide is more than 0.5 milligram/cubic metre.
Comparative example 2
B component content 15%, not containing component A, all the other conditions are constant, and the PM2.5 value after 1 hour is 27, and the content of organic pollution, nitrogen oxide and oxysulfide is more than 0.5 milligram/cubic metre.
Above-described embodiment and comparative example illustrate, under the condition that room temperature is worn, independent component A and B component, all do not reach the effect of component A and B component coupling, illustrate to there is specific contact between composition A of the present invention and B component, which create cooperative effect.
Applicant states, the present invention illustrates mouth mask of the present invention by above-described embodiment, but the present invention is not limited to above-mentioned specific mouth mask, does not namely mean that the present invention must rely on above-mentioned detailed catalysts and could implement described mouth mask.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.

Claims (1)

1. prevent and treat a mouth mask for haze, it comprises the mask body at least covering wearer mouth, nose, its have contact with wearer's skin in contact layer and the top layer away from the setting of interior contact layer side, be provided with filtration between interior contact layer and top layer; Be arranged at the mounting element of mask body; The marginal texture circumference that the top layer of mask body, interior contact layer contact with each other arranges enclosed construction, thus forming the mezzanine space of an installing filtration, the mezzanine space formed by top layer, interior contact layer, enclosed construction has the slide fastener opening structure of lateral arrangement; Wherein, described filtration at least comprises: nonwoven fabric construct layer; Be incorporated into the catalyst structure layer of nonwoven fabric construct layer; Be incorporated into the glass fiber filters of catalyst structure layer; Be incorporated into the nonwoven layer of glass fiber filters; Described catalyst structure layer contains carbon monoxide-olefin polymeric, it is characterized in that,
Described composition comprises following component,
A) nano-TiO of 6%-20% 2the platinum cerium silver kalium composite oxides of load, the mol ratio Ti:Pt:Ce:Ag:K of its each component is 1:(0.05-0.1): (0.05-0.1): (0.05-0.1): (0.05-0.1);
B) the ferrotitanium molybdenum vanadium oxides composite of the zirconium doping of 3%-8%, the mol ratio of Zr:Fe:Ti:Mo:V is (0.02-0.2): 1:(0.5-1): (0.5-1): (0.5-1), described ferrotitanium molybdenum composite oxides possess the composite oxides crystallite system of Fe-O-Ti, Mo-O-Ti and Fe-O-Mo structure;
C) active carbon of surplus.
CN201510781216.0A 2015-11-14 2015-11-14 Anti-haze mask Pending CN105394840A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510781216.0A CN105394840A (en) 2015-11-14 2015-11-14 Anti-haze mask

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510781216.0A CN105394840A (en) 2015-11-14 2015-11-14 Anti-haze mask

Publications (1)

Publication Number Publication Date
CN105394840A true CN105394840A (en) 2016-03-16

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Application Number Title Priority Date Filing Date
CN201510781216.0A Pending CN105394840A (en) 2015-11-14 2015-11-14 Anti-haze mask

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6165934A (en) * 1996-07-03 2000-12-26 Low Emissions Technologies Research And Development Partnership Material and system for catalytic reduction of nitrogen oxide in an exhaust stream of a combustion process
CN1630556A (en) * 2002-02-15 2005-06-22 株式会社Ict Catalyst for clarifying exhaust emission from internal combustion engine, method for preparation thereof and method for clarifying exhaust emission from internal combustion engine
CN101411984A (en) * 2008-11-27 2009-04-22 中国科学院生态环境研究中心 Other transitional metals doped ferrotitanium composite oxides catalyst for selectively reducing nitrous oxides by ammonia
CN101721911A (en) * 2008-10-31 2010-06-09 中国石油化工股份有限公司 Composition for desorbing sulfur and nitrogen oxide in fume
CN104687516A (en) * 2014-05-13 2015-06-10 上海博化安防设备有限公司 PM2.5 preventing mask

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6165934A (en) * 1996-07-03 2000-12-26 Low Emissions Technologies Research And Development Partnership Material and system for catalytic reduction of nitrogen oxide in an exhaust stream of a combustion process
CN1630556A (en) * 2002-02-15 2005-06-22 株式会社Ict Catalyst for clarifying exhaust emission from internal combustion engine, method for preparation thereof and method for clarifying exhaust emission from internal combustion engine
CN101721911A (en) * 2008-10-31 2010-06-09 中国石油化工股份有限公司 Composition for desorbing sulfur and nitrogen oxide in fume
CN101411984A (en) * 2008-11-27 2009-04-22 中国科学院生态环境研究中心 Other transitional metals doped ferrotitanium composite oxides catalyst for selectively reducing nitrous oxides by ammonia
CN104687516A (en) * 2014-05-13 2015-06-10 上海博化安防设备有限公司 PM2.5 preventing mask

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Application publication date: 20160316