CN105385255A - Weather-proof FEVE (Fluoroethylene Vinyl Ether) ambient temperature curing fluorocarbon coating and preparation method thereof - Google Patents
Weather-proof FEVE (Fluoroethylene Vinyl Ether) ambient temperature curing fluorocarbon coating and preparation method thereof Download PDFInfo
- Publication number
- CN105385255A CN105385255A CN201510828277.8A CN201510828277A CN105385255A CN 105385255 A CN105385255 A CN 105385255A CN 201510828277 A CN201510828277 A CN 201510828277A CN 105385255 A CN105385255 A CN 105385255A
- Authority
- CN
- China
- Prior art keywords
- component
- parts
- feve
- weather
- proof
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses weather-proof FEVE (Fluoroethylene Vinyl Ether) ambient temperature curing fluorocarbon coating and a preparation method thereof. The weather-proof FEVE ambient temperature curing fluorocarbon coating comprises a component A and a component B according to a weight ratio of 1 to (0.2 to 0.5); the component A comprises the following raw materials in parts by weight: 30 to 45 parts of FEVE fluorocarbon resin, 5 to 10 parts of alicyclic epoxy resin, 15 to 35 parts of butyl acetate, 10 to 18 parts of propylene glycol methyl ether acetate, 20 to 40 parts of pigments and fillers, 1 to 2 parts of modified organic bentonite, 1 to 2 parts of calcined kaolin, 1 to 2 parts of sodium sulfonate, 1 to 2 parts of flatting agent, 0.1 to 0.3 part of polyether modified polydimethylsiloxane, 1 to 3 parts of dispersing agent, 1 to 2 parts of anti-fungus agent and 0.2 to 0.5 part of defoaming agent; the component B comprises the following raw materials in parts by weight: 10 to 20 parts of trimer prepolymer of aliphatic isocyanate, 2 to 5 parts of boron trifluoride diethyl etherate and 15 to 20 parts of butyl acetate. The weather-proof FEVE ambient temperature curing fluorocarbon coating disclosed by the invention has good corrosion protection and weather resistance properties, and the preparation method is simple and convenient for actual operation.
Description
Technical field
The present invention relates to fluorocarbon coating technical field, particularly relate to a kind of weather-proof FEVE normal temperature solidifying fluorine-carbon coating and preparation method thereof.
Background technology
Bridge undergos the erosions such as fog, rainwater, daylight, severe cold; especially the environmental attack of high temperature, high humidity, high salt fog is stronger; the heavy corrosion of bridge steel structure must be caused under above-mentioned all rugged environment factors; a lot of bridge steel structure surface rust spots is full of stains or spots; affect bridge stability and reliable operation; shorten work-ing life; the current steel structure surface brushing rust proof paint through bridge of being everlasting is to protect, but the corrosion resistant of current bridge steel structure rust proof paint, weather resistance still can not meet demand.
Summary of the invention
The present invention proposes a kind of weather-proof FEVE normal temperature solidifying fluorine-carbon coating and preparation method thereof, protection against corrosion and weather resistance good, long service life, and preparation method is simple, is convenient to actually operating.
The weather-proof FEVE normal temperature solidifying fluorine-carbon coating of one that the present invention proposes, be made up of component A and B component, the weight ratio of component A and B component is 1:0.2-0.5;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 30-45 part, cycloaliphatic epoxy resin 5-10 part, ethyl acetate 15-35 part, propylene glycol methyl ether acetate 10-18 part, color stuffing 20-40 part, organic modified bentonite 1-2 part, calcined kaolin 1-2 part, sodium sulfonate 1-2 part, flow agent 1-2 part, polyether-modified polydimethylsiloxane 0.1-0.3 part, dispersion agent 1-3 part, mould inhibitor 1-2 part, defoamer 0.2-0.5 part;
The raw material of B component comprises by weight: tripolymer prepolymer 10-20 part of aliphatic isocyanates, boron trifluoride diethyl etherate 2-5 part, N-BUTYL ACETATE 15-20 part.
Preferably, in FEVE fluorocarbon resin, Oil repellent is 30-34%, and hydroxyl value is 60-65mgKOH/g.
Preferably, organic modified bentonite adopts following technique to prepare: by weight by 30-50 part wilkinite, 5-15 part glass microballon, it is stir 5-10min in 1-3mol/L hydrochloric acid that 2-7 part cotton short fiber sends into 100-150 part concentration, leave standstill 1-2 days, filter, add 2-8 part sodium-chlor, 0.2-0.8 part Weibull stirs, whipping temp is 40-60 DEG C, churning time is 5-10h, filter, add 2-5 part benzyltriethylammonium chloride, 0.2-0.9 part silane coupling agent stirs 20-40min at 40-60 DEG C, washing, filter, send into 80-95 DEG C of oven for drying, pulverize, obtain organic modified bentonite.
Preferably, in component A, the weight ratio of FEVE fluorocarbon resin, cycloaliphatic epoxy resin, organic modified bentonite is 36-40:6-8:1.4-1.7.
Preferably, in component A, the weight ratio of color stuffing, organic modified bentonite, calcined kaolin is 30-34:1.4-1.7:1.5-1.8.
Preferably, in B component, the tripolymer prepolymer of aliphatic isocyanates, the weight ratio of boron trifluoride diethyl etherate are 14-16:3-4.5.
Preferably, be made up of component A and B component, the weight ratio of component A and B component is 1:0.3-0.45;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 36-40 part, cycloaliphatic epoxy resin 6-8 part, ethyl acetate 25-30 part, propylene glycol methyl ether acetate 12-14 part, color stuffing 30-34 part, organic modified bentonite 1.4-1.7 part, calcined kaolin 1.5-1.8 part, sodium sulfonate 1.5-1.8 part, flow agent 1.4-1.6 part, polyether-modified polydimethylsiloxane 0.15-0.2 part, dispersion agent 1-2 part, mould inhibitor 1.2-1.5 part, defoamer 0.3-0.45 part;
The raw material of B component comprises by weight: tripolymer prepolymer 14-16 part of aliphatic isocyanates, boron trifluoride diethyl etherate 3-4.5 part, N-BUTYL ACETATE 16-18 part.
Disclosed in the present invention also, a kind of preparation method of weather-proof FEVE normal temperature solidifying fluorine-carbon coating, comprises the steps:
S1, preparation component A: FEVE fluorocarbon resin, cycloaliphatic epoxy resin, organic modified bentonite, calcined kaolin, sodium sulfonate, flow agent are dropped in paint mixing tank and mix, add color stuffing to mix, it is 15-30 μm that feeding sand mill is ground to fineness, add mould inhibitor, polyether-modified polydimethylsiloxane solution, dispersion agent, defoamer mix, add ethyl acetate, propylene glycol methyl ether acetate mixes and obtain component A;
S2, preparation B component: the tripolymer prepolymer of aliphatic isocyanates, boron trifluoride diethyl etherate, N-BUTYL ACETATE are mixed and obtain B component;
S3, coating: the component A configured and B component are uniformly mixed and obtain weather-proof FEVE normal temperature solidifying fluorine-carbon coating.
In the present invention, in FEVE fluorocarbon resin, fluorine element electronegativity is large, carbon-fluorine bond can be strong, cycloaliphatic epoxy resin contains a large amount of epoxide group, FEVE fluorocarbon resin, the tripolymer prepolymer of cycloaliphatic epoxy resin and aliphatic isocyanates, boron trifluoride diethyl etherate effect, mutual intersection is cross-linked, the reticulated structure that ambient cure height of formation is crosslinked, there is excellent weathering resistance, humidity resistance, the dispersion agent added, the color stuffing that organic modified bentonite and calcined kaolin make fully disperses in FEVE fluorocarbon resin, corrosion resistant synergy is better played with matrix resin, the color stuffing added, sanitas, mould inhibitor synergy can improve the salt spray resistance of bridge steel structure, wet-heat resisting, resistance to atmospheric exposure and mildew resistance, extends the work-ing life of steel construction, in organic modified bentonite, first wilkinite, glass microballon and cotton short fiber carry out surface active in acid, form punctulate surface, continue under the effect of sodium-chlor and Weibull, sodium ion is just easy to calcium the monovalence hydrogen ion of interlayer, magnesium cation displaces out, and benzyltriethylammonium chloride, silane coupling agent makes material be combined with each other, obtain long-chain and the very good organic modified bentonite of activity, with calcined kaolin, FEVE fluorocarbon resin, cycloaliphatic epoxy resin effect, be coated with film toughness and cross-linking density all good, product anticorrosion erosion and weather resistance very excellent.
Embodiment
Below, by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
A kind of weather-proof FEVE normal temperature solidifying fluorine-carbon coating, be made up of component A and B component, the weight ratio of component A and B component is 1:0.2;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 45 parts, cycloaliphatic epoxy resin 5 parts, ethyl acetate 35 parts, propylene glycol methyl ether acetate 10 parts, color stuffing 40 parts, organic modified bentonite 1 part, calcined kaolin 2 parts, sodium sulfonate 1 part, flow agent 2 parts, polyether-modified polydimethylsiloxane 0.1 part, dispersion agent 3 parts, mould inhibitor 1 part, defoamer 0.5 part;
The raw material of B component comprises by weight: the tripolymer prepolymer of aliphatic isocyanates 10 parts, boron trifluoride diethyl etherate 5 parts, N-BUTYL ACETATE 15 parts.
Embodiment 2
A kind of weather-proof FEVE normal temperature solidifying fluorine-carbon coating, be made up of component A and B component, the weight ratio of component A and B component is 1:0.5;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 30 parts, cycloaliphatic epoxy resin 10 parts, ethyl acetate 15 parts, propylene glycol methyl ether acetate 18 parts, color stuffing 20 parts, organic modified bentonite 2 parts, calcined kaolin 1 part, sodium sulfonate 2 parts, flow agent 1 part, polyether-modified polydimethylsiloxane 0.3 part, dispersion agent 1 part, mould inhibitor 2 parts, defoamer 0.2 part;
The raw material of B component comprises by weight: the tripolymer prepolymer of aliphatic isocyanates 20 parts, boron trifluoride diethyl etherate 2 parts, N-BUTYL ACETATE 20 parts.
Embodiment 3
A kind of weather-proof FEVE normal temperature solidifying fluorine-carbon coating, be made up of component A and B component, the weight ratio of component A and B component is 1:0.3;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 40 parts, cycloaliphatic epoxy resin 6 parts, ethyl acetate 30 parts, propylene glycol methyl ether acetate 12 parts, color stuffing 34 parts, organic modified bentonite 1.4 parts, calcined kaolin 1.8 parts, sodium sulfonate 1.5 parts, flow agent 1.6 parts, polyether-modified polydimethylsiloxane 0.15 part, dispersion agent 2 parts, mould inhibitor 1.2 parts, defoamer 0.45 part;
The raw material of B component comprises by weight: the tripolymer prepolymer of aliphatic isocyanates 14 parts, boron trifluoride diethyl etherate 4.5 parts, N-BUTYL ACETATE 16 parts.
In FEVE fluorocarbon resin, Oil repellent is 34%, and hydroxyl value is 60mgKOH/g.
Organic modified bentonite adopts following technique to prepare: by weight 50 parts of wilkinites, 5 parts of glass microballons, 7 parts of cotton short fibers being sent into 100 parts of concentration is stir 5min in 3mol/L hydrochloric acid, leave standstill 2 days, filter, add 2 parts of sodium-chlor, 0.8 part of Weibull stirs, whipping temp is 40 DEG C, churning time is 10h, filter, add 2 parts of benzyltriethylammonium chlorides, 0.9 part of silane coupling agent stirs 40min at 40 DEG C, washing, filters, sends into 80 DEG C of oven for drying, pulverize, obtain organic modified bentonite.
The preparation method of described weather-proof FEVE normal temperature solidifying fluorine-carbon coating comprises the steps:
S1, preparation component A: FEVE fluorocarbon resin, cycloaliphatic epoxy resin, organic modified bentonite, calcined kaolin, sodium sulfonate, flow agent are dropped in paint mixing tank and mix, add color stuffing to mix, it is 15-30 μm that feeding sand mill is ground to fineness, add mould inhibitor, polyether-modified polydimethylsiloxane solution, dispersion agent, defoamer mix, add ethyl acetate, propylene glycol methyl ether acetate mixes and obtain component A;
S2, preparation B component: the tripolymer prepolymer of aliphatic isocyanates, boron trifluoride diethyl etherate, N-BUTYL ACETATE are mixed and obtain B component;
S3, coating: the component A configured and B component are uniformly mixed and obtain weather-proof FEVE normal temperature solidifying fluorine-carbon coating.
Embodiment 4
A kind of weather-proof FEVE normal temperature solidifying fluorine-carbon coating, be made up of component A and B component, the weight ratio of component A and B component is 1:0.45;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 36 parts, cycloaliphatic epoxy resin 8 parts, ethyl acetate 25 parts, propylene glycol methyl ether acetate 14 parts, color stuffing 30 parts, organic modified bentonite 1.7 parts, calcined kaolin 1.5 parts, sodium sulfonate 1.8 parts, flow agent 1.4 parts, polyether-modified polydimethylsiloxane 0.2 part, dispersion agent 1 part, mould inhibitor 1.5 parts, defoamer 0.3 part;
The raw material of B component comprises by weight: the tripolymer prepolymer of aliphatic isocyanates 16 parts, boron trifluoride diethyl etherate 3 parts, N-BUTYL ACETATE 18 parts.
In FEVE fluorocarbon resin, Oil repellent is 30%, and hydroxyl value is 65mgKOH/g.
Organic modified bentonite adopts following technique to prepare: by weight 30 parts of wilkinites, 15 parts of glass microballons, 2 parts of cotton short fibers being sent into 150 parts of concentration is stir 10min in 1mol/L hydrochloric acid, leave standstill 1 day, filter, add 8 parts of sodium-chlor, 0.2 part of Weibull stirs, whipping temp is 60 DEG C, churning time is 5h, filter, add 5 parts of benzyltriethylammonium chlorides, 0.2 part of silane coupling agent stirs 20min at 60 DEG C, washing, filters, sends into 95 DEG C of oven for drying, pulverize, obtain organic modified bentonite.
The preparation method of described weather-proof FEVE normal temperature solidifying fluorine-carbon coating comprises the steps:
S1, preparation component A: FEVE fluorocarbon resin, cycloaliphatic epoxy resin, organic modified bentonite, calcined kaolin, sodium sulfonate, flow agent are dropped in paint mixing tank and mix, add color stuffing to mix, it is 15-30 μm that feeding sand mill is ground to fineness, add mould inhibitor, polyether-modified polydimethylsiloxane solution, dispersion agent, defoamer mix, add ethyl acetate, propylene glycol methyl ether acetate mixes and obtain component A;
S2, preparation B component: the tripolymer prepolymer of aliphatic isocyanates, boron trifluoride diethyl etherate, N-BUTYL ACETATE are mixed and obtain B component;
S3, coating: the component A configured and B component are uniformly mixed and obtain weather-proof FEVE normal temperature solidifying fluorine-carbon coating.
Embodiment 5
A kind of weather-proof FEVE normal temperature solidifying fluorine-carbon coating, be made up of component A and B component, the weight ratio of component A and B component is 1:0.42;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 38 parts, cycloaliphatic epoxy resin 7.6 parts, ethyl acetate 28 parts, propylene glycol methyl ether acetate 13.6 parts, color stuffing 32 parts, organic modified bentonite 1.6 parts, calcined kaolin 1.75 parts, sodium sulfonate 1.6 parts, flow agent 1.55 parts, polyether-modified polydimethylsiloxane 0.18 part, dispersion agent 1.45 parts, mould inhibitor 1.3 parts, defoamer 0.42 part;
The raw material of B component comprises by weight: the tripolymer prepolymer of aliphatic isocyanates 15 parts, boron trifluoride diethyl etherate 4.2 parts, N-BUTYL ACETATE 17.6 parts.
In FEVE fluorocarbon resin, Oil repellent is 32%, and hydroxyl value is 63mgKOH/g.
Organic modified bentonite adopts following technique to prepare: by weight 45 parts of wilkinites, 12 parts of glass microballons, 5 parts of cotton short fibers being sent into 135 parts of concentration is stir 8min in 2.6mol/L hydrochloric acid, leave standstill 1.5 days, filter, add 5 parts of sodium-chlor, 0.65 part of Weibull stirs, whipping temp is 55 DEG C, churning time is 8h, filter, add 3.6 parts of benzyltriethylammonium chlorides, 0.45 part of silane coupling agent stirs 32min at 56 DEG C, washing, filters, sends into 92 DEG C of oven for drying, pulverize, obtain organic modified bentonite.
The preparation method of described weather-proof FEVE normal temperature solidifying fluorine-carbon coating comprises the steps:
S1, preparation component A: FEVE fluorocarbon resin, cycloaliphatic epoxy resin, organic modified bentonite, calcined kaolin, sodium sulfonate, flow agent are dropped in paint mixing tank and mix, add color stuffing to mix, it is 15-30 μm that feeding sand mill is ground to fineness, add mould inhibitor, polyether-modified polydimethylsiloxane solution, dispersion agent, defoamer mix, add ethyl acetate, propylene glycol methyl ether acetate mixes and obtain component A;
S2, preparation B component: the tripolymer prepolymer of aliphatic isocyanates, boron trifluoride diethyl etherate, N-BUTYL ACETATE are mixed and obtain B component;
S3, coating: the component A configured and B component are uniformly mixed and obtain weather-proof FEVE normal temperature solidifying fluorine-carbon coating.
Spraying application mode is adopted to carry out performance test FEVE normal temperature solidifying fluorine-carbon coating weather-proof described in embodiment 1-5:
The 2240h of resistance to neutral salt spray: paint film is without foaming, non-corroding;
The ultraviolet ageing of resistance to UV 5000h: paint film loss of gloss 1 grade, variable color 1 grade, efflorescence 0 grade, 0 grade, crackle;
Mold test: enclosed space's mould test of 28 days, mildew-resistant rank 0 grade.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (8)
1. a weather-proof FEVE normal temperature solidifying fluorine-carbon coating, is characterized in that, is made up of component A and B component, and the weight ratio of component A and B component is 1:0.2-0.5;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 30-45 part, cycloaliphatic epoxy resin 5-10 part, ethyl acetate 15-35 part, propylene glycol methyl ether acetate 10-18 part, color stuffing 20-40 part, organic modified bentonite 1-2 part, calcined kaolin 1-2 part, sodium sulfonate 1-2 part, flow agent 1-2 part, polyether-modified polydimethylsiloxane 0.1-0.3 part, dispersion agent 1-3 part, mould inhibitor 1-2 part, defoamer 0.2-0.5 part;
The raw material of B component comprises by weight: tripolymer prepolymer 10-20 part of aliphatic isocyanates, boron trifluoride diethyl etherate 2-5 part, N-BUTYL ACETATE 15-20 part.
2. weather-proof FEVE normal temperature solidifying fluorine-carbon coating according to claim 1, is characterized in that, in FEVE fluorocarbon resin, Oil repellent is 30-34%, and hydroxyl value is 60-65mgKOH/g.
3. weather-proof FEVE normal temperature solidifying fluorine-carbon coating according to claim 1 and 2, it is characterized in that, organic modified bentonite adopts following technique to prepare: by weight by 30-50 part wilkinite, 5-15 part glass microballon, it is stir 5-10min in 1-3mol/L hydrochloric acid that 2-7 part cotton short fiber sends into 100-150 part concentration, leave standstill 1-2 days, filter, add 2-8 part sodium-chlor, 0.2-0.8 part Weibull stirs, whipping temp is 40-60 DEG C, churning time is 5-10h, filter, add 2-5 part benzyltriethylammonium chloride, 0.2-0.9 part silane coupling agent stirs 20-40min at 40-60 DEG C, washing, filter, send into 80-95 DEG C of oven for drying, pulverize, obtain organic modified bentonite.
4. the weather-proof FEVE normal temperature solidifying fluorine-carbon coating according to any one of claim 1-3, is characterized in that, in component A, the weight ratio of FEVE fluorocarbon resin, cycloaliphatic epoxy resin, organic modified bentonite is 36-40:6-8:1.4-1.7.
5. the weather-proof FEVE normal temperature solidifying fluorine-carbon coating according to any one of claim 1-4, is characterized in that, in component A, the weight ratio of color stuffing, organic modified bentonite, calcined kaolin is 30-34:1.4-1.7:1.5-1.8.
6. the weather-proof FEVE normal temperature solidifying fluorine-carbon coating according to any one of claim 1-5, is characterized in that, in B component, the tripolymer prepolymer of aliphatic isocyanates, the weight ratio of boron trifluoride diethyl etherate are 14-16:3-4.5.
7. the weather-proof FEVE normal temperature solidifying fluorine-carbon coating according to any one of claim 1-6, is characterized in that, be made up of component A and B component, and the weight ratio of component A and B component is 1:0.3-0.45;
The raw material of component A comprises by weight: FEVE fluorocarbon resin 36-40 part, cycloaliphatic epoxy resin 6-8 part, ethyl acetate 25-30 part, propylene glycol methyl ether acetate 12-14 part, color stuffing 30-34 part, organic modified bentonite 1.4-1.7 part, calcined kaolin 1.5-1.8 part, sodium sulfonate 1.5-1.8 part, flow agent 1.4-1.6 part, polyether-modified polydimethylsiloxane 0.15-0.2 part, dispersion agent 1-2 part, mould inhibitor 1.2-1.5 part, defoamer 0.3-0.45 part;
The raw material of B component comprises by weight: tripolymer prepolymer 14-16 part of aliphatic isocyanates, boron trifluoride diethyl etherate 3-4.5 part, N-BUTYL ACETATE 16-18 part.
8. a preparation method for the weather-proof FEVE normal temperature solidifying fluorine-carbon coating according to any one of claim 1-7, is characterized in that, comprise the steps:
S1, preparation component A: FEVE fluorocarbon resin, cycloaliphatic epoxy resin, organic modified bentonite, calcined kaolin, sodium sulfonate, flow agent are dropped in paint mixing tank and mix, add color stuffing to mix, it is 15-30 μm that feeding sand mill is ground to fineness, add mould inhibitor, polyether-modified polydimethylsiloxane solution, dispersion agent, defoamer mix, add ethyl acetate, propylene glycol methyl ether acetate mixes and obtain component A;
S2, preparation B component: the tripolymer prepolymer of aliphatic isocyanates, boron trifluoride diethyl etherate, N-BUTYL ACETATE are mixed and obtain B component;
S3, coating: the component A configured and B component are uniformly mixed and obtain weather-proof FEVE normal temperature solidifying fluorine-carbon coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510828277.8A CN105385255A (en) | 2015-11-24 | 2015-11-24 | Weather-proof FEVE (Fluoroethylene Vinyl Ether) ambient temperature curing fluorocarbon coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510828277.8A CN105385255A (en) | 2015-11-24 | 2015-11-24 | Weather-proof FEVE (Fluoroethylene Vinyl Ether) ambient temperature curing fluorocarbon coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105385255A true CN105385255A (en) | 2016-03-09 |
Family
ID=55418053
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510828277.8A Pending CN105385255A (en) | 2015-11-24 | 2015-11-24 | Weather-proof FEVE (Fluoroethylene Vinyl Ether) ambient temperature curing fluorocarbon coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105385255A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113025132A (en) * | 2021-04-28 | 2021-06-25 | 安徽菱湖漆股份有限公司 | Water-based organic silicon modified fluorocarbon wind power blade coating and preparation method thereof |
| CN114410224A (en) * | 2021-11-30 | 2022-04-29 | 大唐国信滨海海上风力发电有限公司 | Epoxy grafted fluorocarbon resin based heavy-duty anti-corrosion primer-topcoat coating and preparation method thereof |
| CN114958102A (en) * | 2022-06-23 | 2022-08-30 | 中北大学 | Bottom surface integrated composite coating and preparation method and coating method thereof |
| CN115846174A (en) * | 2022-11-30 | 2023-03-28 | 广东合拓新材料科技有限公司 | Preparation process of high-strength multilayer composite aluminum veneer |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102259881A (en) * | 2011-06-20 | 2011-11-30 | 浙江丰虹新材料股份有限公司 | Method for preparing high-viscosity organic bentonite by virtue of calcium-based bentonite |
| CN102874825A (en) * | 2012-10-17 | 2013-01-16 | 南通南京大学材料工程技术研究院 | Compound modification method for clay |
| CN103045065A (en) * | 2013-01-08 | 2013-04-17 | 海洋化工研究院有限公司 | Fluorocarbon paint for cabinet and preparation method |
| CN103265870A (en) * | 2013-06-14 | 2013-08-28 | 沈阳飞机工业（集团）有限公司 | Expansion type high-temperature resistant heat-insulating coating taking epoxy resin as main film-forming agent |
-
2015
- 2015-11-24 CN CN201510828277.8A patent/CN105385255A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102259881A (en) * | 2011-06-20 | 2011-11-30 | 浙江丰虹新材料股份有限公司 | Method for preparing high-viscosity organic bentonite by virtue of calcium-based bentonite |
| CN102874825A (en) * | 2012-10-17 | 2013-01-16 | 南通南京大学材料工程技术研究院 | Compound modification method for clay |
| CN103045065A (en) * | 2013-01-08 | 2013-04-17 | 海洋化工研究院有限公司 | Fluorocarbon paint for cabinet and preparation method |
| CN103265870A (en) * | 2013-06-14 | 2013-08-28 | 沈阳飞机工业（集团）有限公司 | Expansion type high-temperature resistant heat-insulating coating taking epoxy resin as main film-forming agent |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113025132A (en) * | 2021-04-28 | 2021-06-25 | 安徽菱湖漆股份有限公司 | Water-based organic silicon modified fluorocarbon wind power blade coating and preparation method thereof |
| CN114410224A (en) * | 2021-11-30 | 2022-04-29 | 大唐国信滨海海上风力发电有限公司 | Epoxy grafted fluorocarbon resin based heavy-duty anti-corrosion primer-topcoat coating and preparation method thereof |
| CN114410224B (en) * | 2021-11-30 | 2023-10-20 | 大唐国信滨海海上风力发电有限公司 | Heavy-duty anticorrosion primer-topcoat coating based on epoxy grafted fluorocarbon resin and preparation method thereof |
| CN114958102A (en) * | 2022-06-23 | 2022-08-30 | 中北大学 | Bottom surface integrated composite coating and preparation method and coating method thereof |
| CN115846174A (en) * | 2022-11-30 | 2023-03-28 | 广东合拓新材料科技有限公司 | Preparation process of high-strength multilayer composite aluminum veneer |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105385255A (en) | Weather-proof FEVE (Fluoroethylene Vinyl Ether) ambient temperature curing fluorocarbon coating and preparation method thereof | |
| CN110028885B (en) | Solvent-free high-toughness heavy-duty anticorrosive paint and preparation method thereof | |
| CN102618159B (en) | Water-based polyurethane anticorrosive coating for containers and preparation method for coating | |
| CN102391771B (en) | Thick paste quick-drying type weather-resistant and wear-resistant coating for wind turbine blades and preparation method thereof | |
| CN103834282B (en) | A kind of weather-proof anticorrosion carbamide paint and preparation method thereof and using method | |
| CN101955729B (en) | Polysiloxane topcoat for wind power generation equipment | |
| CN101956429B (en) | High flame retardant polyurethane rigid foam outer wall thermal insulation system | |
| KR100997259B1 (en) | Floor finishing and waterproof protective coating for concrete structures | |
| CN103214915A (en) | Anti-corrosive coating for concrete surface and preparation method thereof | |
| CN103820020B (en) | A kind of anti-skidding anticorrosion carbamide paint and preparation method thereof and using method | |
| CN206069753U (en) | A kind of water-proof climate resisting polyurea coating | |
| CN104893532B (en) | A kind of heat reflection fluorochemical urethane finish paint | |
| CN102746756A (en) | Water-based acrylic polyurethane finish and preparation method thereof | |
| CN105567080A (en) | High-temperature-resistant protective paint for ships | |
| CN105623504A (en) | Heat-dissipation anti-corrosive paint for ships | |
| CN106366859A (en) | General anticorrosive paint, general anticorrosive coating and offshore engineering structure containing general anticorrosive coating | |
| CN103483527B (en) | A kind of quick-drying weathering protective topcoat for polyurea coating and preparation method thereof | |
| CN102190942B (en) | Epoxy priming paint used for moisture resisting megawatt wind-power blades and preparation method thereof | |
| CN103897569A (en) | Exterior wall coating and preparation method and application method thereof | |
| CN110964388A (en) | Polyurea modified anti-pollution coating and preparation method and application thereof | |
| CN108219628B (en) | Marine corrosion-resistant aircraft engine deionized water paint and preparation method thereof | |
| CN1704454A (en) | Modified double-component epoxy resin paint | |
| CN109535917B (en) | Protective primer for wind power blade and preparation method thereof | |
| CN108948998A (en) | It is ultrafast to do high setting polyurethane paint and preparation method thereof | |
| CN101255290B (en) | Marine reinforced concrete anticorrosion paint and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160309 |
|
| RJ01 | Rejection of invention patent application after publication |