CN105368213A - Dustproof scraping-resistant aluminum rod - Google Patents
Dustproof scraping-resistant aluminum rod Download PDFInfo
- Publication number
- CN105368213A CN105368213A CN201510905540.9A CN201510905540A CN105368213A CN 105368213 A CN105368213 A CN 105368213A CN 201510905540 A CN201510905540 A CN 201510905540A CN 105368213 A CN105368213 A CN 105368213A
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- Prior art keywords
- layer
- dust
- resistant
- scratch
- oxidation
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Wood Science & Technology (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Laminated Bodies (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a dustproof scraping-resistant aluminum rod. The dustproof scraping-resistant aluminum rod comprises a rod body; the exterior of the rod body is coated with an anti-oxidation layer, a scraping-resistant layer, and a dustproof layer successively; the anti-oxidation layer is a water-based high temperature-resistant anti-oxidation inorganic paint layer with a thickness ranging from 0.5 to 1mm; the scraping-resistant layer is a nano aluminum oxide paint layer with a thickness ranging from 0.2 to 0.3mm; and the dustproof layer is a polysiloxane polymer layer with a thickness ranging from 0.1 to 0.2mm. Dust prevention performance and scraping resistance are improved effectively via coating the aluminum rod with the anti-oxidation layer, the scraping-resistant layer, and the dustproof layer successively.
Description
Technical field
The present invention relates to a kind of aluminium bar material, especially a kind of aluminium bar material possessing dust-proof anti-scratch function.
Background technology
Aluminium is the profuse metallic element of content on the earth, and its standing stock occupy the 2nd in a metal.To 19 end of the centurys, aluminium is just made oneself too remarkable, and becomes competitive metal in engineering uses, and fashionable for a time.Aviation, build, the carrying out of the large essential industry of car three, demand data characteristic has the common property of Aluminum-aluminum alloy, and this is just conducive to producing and using of this new metal-aluminium greatly.Therefore, the usage quantity of aluminium bar material increases greatly, because metallic aluminium possesses certain ductility, and being subject in transit external force crimp and being easily covered with dust at aluminium, just need to carry out peeling to aluminium bar to the second time processing of aluminium, certain waste is caused to aluminum.
Summary of the invention
Goal of the invention: for the problems referred to above, object of the present invention provides a kind of aluminium bar that effectively can improve dust-proof, anti-scratch ability.
Technical scheme: in order to overcome the above problems, the invention provides a kind of dust-proof anti-scratch type aluminium bar, comprise barred body, described barred body outer compound anti-oxidation layer, scratch-resistant layer, dust layer successively, described anti oxidation layer is water-based high-temperature-resistant oxidation-resistant inorganic paint layer, and its thickness is 0.5-1mm; Described scratch-resistant layer is nano aluminium oxide dope layer, and its thickness is 0.2-0.3mm; Described dust layer is polysiloxane polymer layer, and its thickness is 0.1-0.2mm.
Described water-based high-temperature-resistant oxidation-resistant inorganic paint layer, comprises by weight percentage: aqueous inorganic colloidal sol resin 10-40 part, aluminum oxide 5-10 part, pure aluminium silicate 5-35 part, kaolin 5-20 part, organic synthesis emulsion 0.5-10 part, deionized water 10-35 part, high-temperature stable properties-correcting agent 0.5-3 part.
Described nano oxidized aluminium lamination, comprises by weight percentage: water-borne acrylic resin 15-35 part, nano aluminium oxide 5-20 part, organic synthesis emulsion 0.5-6 part, deionized water 10-20 part.
Described polysiloxane polymer layer, comprises according to weight percent: polysiloxane polymer resin 10-40 part, dust-proofing agent 5-10 part, flatting silica 1-15 part, epoxy resin 20-40 part, organic synthesis emulsion 0.5-5 part.
Its making method for heating after aluminum bar peeling at its surface coated water-based high-temperature-resistant oxidation-resistant inorganic paint layer in stove, and heat-up time is 470-530min, and Heating temperature is 320-400 DEG C; Taken out by aluminium bar after heating, at its surface coated nano aluminium oxide dope layer, dry at 100-200 DEG C of temperature, drying time is 200-350min; Nano oxidized aluminium lamination is after the drying coated with polysiloxane polymer layer, air-dry at normal temperatures, form dust-proof anti-scratch aluminium bar.
Beneficial effect: compared with prior art, the present invention has the following advantages:
1. good in oxidation resistance: the present invention, by aluminium bar top layer coating antioxidant coating, effectively can prevent aluminium material oxidation, improve the availability of aluminium;
2. anti-scratch effective: the present invention, by anti oxidation layer surface coated scratch-resistant layer, effectively can improve the anti-scratch ability of aluminium bar, avoid it impaired in handling process;
3. dust-proof: the present invention, by scratch-resistant layer surface coated dust layer, effectively can improve the dust-proof effect of aluminium bar, make the processing of aluminium bar second time be can carry out peeling without effects on surface, effectively save material, increase economic efficiency.
Accompanying drawing explanation
Fig. 1 is the structural representation of dust-proof anti-scratch type aluminium bar;
Wherein: 1. barred body, 2. anti oxidation layer, 3. scratch-resistant layer, 4. dust layer.
Embodiment
Below in conjunction with drawings and Examples, embodiments of the present invention are described in further detail.Following examples for illustration of the present invention, but can not be used for limiting the scope of the invention.Orientation or the position relationship of the instruction such as D score, "left", "right", " interior ", " outward ", " front end ", " rear end ", " head ", " afterbody " are based on orientation shown in the drawings or position relationship, only the present invention for convenience of description and simplified characterization, instead of indicate or imply that the device of indication or element must have specific orientation, with specific azimuth configuration and operation, therefore can not be interpreted as limitation of the present invention.In addition, term " first ", " second ", " the 3rd " etc. only for describing object, and can not be interpreted as instruction or hint relative importance.
In describing the invention, it should be noted that, unless otherwise clearly defined and limited, term " installation ", " being connected ", " connection " should be interpreted broadly, and such as, can be fixedly connected with, also can be removably connect, or connect integratedly; Can be mechanical connection, also can be electrical connection; Can be directly be connected, also indirectly can be connected by intermediary.For the ordinary skill in the art, particular case above-mentioned term concrete meaning in the present invention can be understood.
The dust-proof anti-scratch type aluminium bar of one as shown in Figure 1, comprises barred body 1, described barred body 1 outer compound anti-oxidation layer 2, scratch-resistant layer 3, dust layer 4 successively, and described anti oxidation layer 2 is water-based high-temperature-resistant oxidation-resistant inorganic paint layer, and its thickness is 0.5-1mm; Described scratch-resistant layer 3 is nano aluminium oxide dope layer, and its thickness is 0.2-0.3mm; Described dust layer 4 is polysiloxane polymer layer, and its thickness is 0.1-0.2mm; Described water-based high-temperature-resistant oxidation-resistant inorganic paint layer, comprises by weight percentage: aqueous inorganic colloidal sol resin 10-40 part, aluminum oxide 5-10 part, pure aluminium silicate 5-35 part, kaolin 5-20 part, organic synthesis emulsion 0.5-10 part, deionized water 10-35 part, high-temperature stable properties-correcting agent 0.5-3 part; Described nano oxidized aluminium lamination, comprises by weight percentage: water-borne acrylic resin 15-35 part, nano aluminium oxide 5-20 part, organic synthesis emulsion 0.5-6 part, deionized water 10-20 part; Described polysiloxane polymer layer, comprises according to weight percent: polysiloxane polymer resin 10-40 part, dust-proofing agent 5-10 part, flatting silica 1-15 part, epoxy resin 20-40 part, organic synthesis emulsion 0.5-5 part.
Embodiment 1
A kind of dust-proof anti-scratch type aluminium bar, its making method for heating after aluminum bar peeling at its surface coated water-based high-temperature-resistant oxidation-resistant inorganic paint layer in stove, and heat-up time is 475min, Heating temperature is 320 DEG C, wherein, described water-based high-temperature-resistant oxidation-resistant inorganic paint layer thickness is 0.5mm, comprises by weight percentage: aqueous inorganic colloidal sol resin 15 parts, 6 parts, aluminum oxide, pure aluminium silicate 10 parts, kaolin 5 parts, organic synthesis emulsion 0.5 part, deionized water 10 parts, high-temperature stable properties-correcting agent 0.5 part;
Aluminium bar after heating is taken out, at its surface coated nano aluminium oxide dope layer, dry at 100 DEG C of temperature, drying time is 200min, wherein said nano oxidized aluminum layer thickness is 0.2mm, comprises by weight percentage: water-borne acrylic resin 15 parts, nano aluminium oxide 20 parts, organic synthesis emulsion 0.6 part, deionized water 10 parts;
Nano oxidized aluminium lamination is after the drying coated with polysiloxane polymer layer, air-dry at normal temperatures, wherein, described polysiloxane polymer layer thickness is 0.15mm, comprise according to weight percent: polysiloxane polymer resin 10 parts, dust-proofing agent 5 parts, flatting silica 1 part, epoxy resin 20 parts, organic synthesis emulsion 0.5 part.Form dust-proof anti-scratch aluminium bar.
Embodiment 2
A kind of dust-proof anti-scratch type aluminium bar, its making method for heating after aluminum bar peeling at its surface coated water-based high-temperature-resistant oxidation-resistant inorganic paint layer in stove, and heat-up time is 500min, Heating temperature is 370 DEG C, wherein, described water-based high-temperature-resistant oxidation-resistant inorganic paint layer thickness is 1mm, comprises by weight percentage: aqueous inorganic colloidal sol resin 20 parts, 10 parts, aluminum oxide, pure aluminium silicate 15 parts, kaolin 15 parts, organic synthesis emulsion 2 parts, deionized water 15 parts, high-temperature stable properties-correcting agent 2 parts;
Aluminium bar after heating is taken out, at its surface coated nano aluminium oxide dope layer, dry at 150 DEG C of temperature, drying time is 270min, wherein said nano oxidized aluminum layer thickness is 0.25mm, comprises by weight percentage: water-borne acrylic resin 20 parts, nano aluminium oxide 25 parts, organic synthesis emulsion 3 parts, deionized water 20 parts;
Nano oxidized aluminium lamination is after the drying coated with polysiloxane polymer layer, air-dry at normal temperatures, wherein, described polysiloxane polymer layer thickness is 0.2mm, comprise according to weight percent: polysiloxane polymer resin 20 parts, dust-proofing agent 15 parts, flatting silica 2 parts, epoxy resin 30 parts, organic synthesis emulsion 2 parts.Form dust-proof anti-scratch aluminium bar.
Embodiment 3
A kind of dust-proof anti-scratch type aluminium bar, its making method for heating after aluminum bar peeling at its surface coated water-based high-temperature-resistant oxidation-resistant inorganic paint layer in stove, and heat-up time is 530min, Heating temperature is 400 DEG C, wherein, described water-based high-temperature-resistant oxidation-resistant inorganic paint layer thickness is 1mm, comprises by weight percentage: aqueous inorganic colloidal sol resin 30 parts, 10 parts, aluminum oxide, pure aluminium silicate 25 parts, kaolin 20 parts, organic synthesis emulsion 10 parts, deionized water 35 parts, high-temperature stable properties-correcting agent 3 parts;
Aluminium bar after heating is taken out, at its surface coated nano aluminium oxide dope layer, dry at 200 DEG C of temperature, drying time is 350min, wherein said nano oxidized aluminum layer thickness is 0.3mm, comprises by weight percentage: water-borne acrylic resin 35 parts, nano aluminium oxide 20 parts, organic synthesis emulsion 6 parts, deionized water 20 parts;
Nano oxidized aluminium lamination is after the drying coated with polysiloxane polymer layer, air-dry at normal temperatures, wherein, described polysiloxane polymer layer thickness is 0.2mm, comprise according to weight percent: polysiloxane polymer resin 40 parts, dust-proofing agent 10 parts, flatting silica 15 parts, epoxy resin 40 parts, organic synthesis emulsion 5 parts.Form dust-proof anti-scratch aluminium bar.
Embodiments of the invention provide in order to example with for the purpose of describing, and are not exhaustively or limit the invention to disclosed form.Many modifications and variations are apparent for the ordinary skill in the art.Selecting and describing embodiment is in order to principle of the present invention and practical application are better described, and enables those of ordinary skill in the art understand the present invention thus design the various embodiments with various amendment being suitable for specific end use.
Claims (5)
1. a dust-proof anti-scratch type aluminium bar, it is characterized in that: comprise barred body (1), described barred body (1) compound anti-oxidation layer (2), scratch-resistant layer (3), dust layer (4) successively outward, described anti oxidation layer (2) is water-based high-temperature-resistant oxidation-resistant inorganic paint layer, and its thickness is 0.5-1mm; Described scratch-resistant layer (3) is nano aluminium oxide dope layer, and its thickness is 0.2-0.3mm; Described dust layer (4) is polysiloxane polymer layer, and its thickness is 0.1-0.2mm.
2. dust-proof anti-scratch type aluminium bar according to claim 1, it is characterized in that: described water-based high-temperature-resistant oxidation-resistant inorganic paint layer, comprise by weight percentage: aqueous inorganic colloidal sol resin 10-40 part, aluminum oxide 5-10 part, pure aluminium silicate 5-35 part, kaolin 5-20 part, organic synthesis emulsion 0.5-10 part, deionized water 10-35 part, high-temperature stable properties-correcting agent 0.5-3 part.
3. dust-proof anti-scratch type aluminium bar according to claim 1, it is characterized in that: described nano oxidized aluminium lamination, comprises by weight percentage: water-borne acrylic resin 15-35 part, nano aluminium oxide 5-20 part, organic synthesis emulsion 0.5-6 part, deionized water 10-20 part.
4. dust-proof anti-scratch type aluminium bar according to claim 1, it is characterized in that: described polysiloxane polymer layer, comprise according to weight percent: polysiloxane polymer resin 10-40 part, dust-proofing agent 5-10 part, flatting silica 1-15 part, epoxy resin 20-40 part, organic synthesis emulsion 0.5-5 part.
5. dust-proof anti-scratch type aluminium bar according to claim 1, it is characterized in that: its making method for heating after aluminum bar peeling at its surface coated water-based high-temperature-resistant oxidation-resistant inorganic paint layer in stove, heat-up time is 470-530min, and Heating temperature is 320-400 DEG C; Taken out by aluminium bar after heating, at its surface coated nano aluminium oxide dope layer, dry at 100-200 DEG C of temperature, drying time is 200-350min; Nano oxidized aluminium lamination is after the drying coated with polysiloxane polymer layer, air-dry at normal temperatures, form dust-proof anti-scratch aluminium bar.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510905540.9A CN105368213A (en) | 2015-12-10 | 2015-12-10 | Dustproof scraping-resistant aluminum rod |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510905540.9A CN105368213A (en) | 2015-12-10 | 2015-12-10 | Dustproof scraping-resistant aluminum rod |
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| CN105368213A true CN105368213A (en) | 2016-03-02 |
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| CN201510905540.9A Pending CN105368213A (en) | 2015-12-10 | 2015-12-10 | Dustproof scraping-resistant aluminum rod |
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Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1756656A (en) * | 2003-08-06 | 2006-04-05 | 以利沙控股有限公司 | Multilayer coated corrosion resistant articles and method of production thereof |
| CN1970663A (en) * | 2006-10-19 | 2007-05-30 | 上海大学 | Scrape-wearable nanometer aqueous automobile paint preparation method |
| CN102977553A (en) * | 2012-11-06 | 2013-03-20 | 中科院广州化学有限公司 | Epoxy/silicone polymer composite material, and preparation method and application thereof |
| CN104512064A (en) * | 2013-09-30 | 2015-04-15 | 青岛市首胜实业有限公司 | Aluminum section production method |
| CN104941892A (en) * | 2015-05-27 | 2015-09-30 | 天津固特金属制品有限公司 | Pre-treatment technology for heat-stamping-and-shaping metal product |
-
2015
- 2015-12-10 CN CN201510905540.9A patent/CN105368213A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1756656A (en) * | 2003-08-06 | 2006-04-05 | 以利沙控股有限公司 | Multilayer coated corrosion resistant articles and method of production thereof |
| CN1970663A (en) * | 2006-10-19 | 2007-05-30 | 上海大学 | Scrape-wearable nanometer aqueous automobile paint preparation method |
| CN102977553A (en) * | 2012-11-06 | 2013-03-20 | 中科院广州化学有限公司 | Epoxy/silicone polymer composite material, and preparation method and application thereof |
| CN104512064A (en) * | 2013-09-30 | 2015-04-15 | 青岛市首胜实业有限公司 | Aluminum section production method |
| CN104941892A (en) * | 2015-05-27 | 2015-09-30 | 天津固特金属制品有限公司 | Pre-treatment technology for heat-stamping-and-shaping metal product |
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Application publication date: 20160302 |
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