CN105367938A - Novel PVC environment-friendly foamed panel - Google Patents
Novel PVC environment-friendly foamed panel Download PDFInfo
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- CN105367938A CN105367938A CN201510735434.0A CN201510735434A CN105367938A CN 105367938 A CN105367938 A CN 105367938A CN 201510735434 A CN201510735434 A CN 201510735434A CN 105367938 A CN105367938 A CN 105367938A
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- novel pvc
- panel
- pvc environment
- sheet material
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
- C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
- C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
- C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
- C08J9/102—Azo-compounds
- C08J9/103—Azodicarbonamide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2203/00—Foams characterized by the expanding agent
- C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
- C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
- C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08J2327/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
- C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/14—Applications used for foams
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a novel PVC environment-friendly foamed panel. The panel is prepared from, by weight, 120-150 parts of polyvinyl chloride, 60-70 parts of ACR resin, 11-19 parts of foaming control agent, 70-85 parts of modified polypropylene, 4-8 parts of ethylene-vinyl acetate copolymer, 30-50 parts of light calcium carbonate, 4-6 parts of lubricating processing agent, 3-8 parts of polyacrylate and 7-10 parts of silane coupling agent. The problems that the panel surface is not smooth and skin forming thickness is small are solved, production efficiency is effectively improved, the foamed panel has high flame resistance, and the panel can be put under various conditions and has the advantages of dust prevention and light reflection.
Description
Technical field
The invention belongs to polymer composite, particularly relate to a kind of novel PVC environment-friendly foaming sheet material.
Background technology
PVC foam sheet material is as a kind of novel plastic material, due to the production technology of its uniqueness, make it have excellent performance, but China foaming extruded product production kind and quality in growth momentum unlike adaptation, optimizing further about the density of formula, processing condition, device structure parameter and foaming product and performance need, current use mainly there is the unfairness of plate face in PVC foam sheet material, skinning thickness is thin, surface smoothness is not high, the low inferior problem of production efficiency.
Summary of the invention
For solving the problem, the invention discloses a kind of novel environment protection PVC environment-friendly foaming, there is provided a kind of and solve the unfairness of plate face, skinning thickness is thin, effectively enhance productivity, foaming plate has good flame retardant properties simultaneously, can place under various conditions simultaneously, there is dust-proof, reflective characteristic.
In order to achieve the above object, the invention provides following technical scheme: a kind of novel PVC environment-friendly foaming sheet material, comprise the raw material of following parts by weight: polyvinyl chloride 120-150 part, ACR resin 60-70 part, foaming control agent 11-19, modified polypropene 70-85 part, ethylene-vinyl acetate copolymer 4-8 part, makings calcium carbonate 30-50 part, oilness processing aid 4-6 part, polyacrylate 3-8 part, silane coupling agent 7-10 part.
As a preferred embodiment of the present invention, novel PVC environment-friendly foaming sheet material, comprise the raw material of following parts by weight: polyvinyl chloride 135 parts, ACR resin 65 parts, foaming control agent 15, modified polypropene 77 parts, ethylene-vinyl acetate copolymer 7 parts, 44 parts, makings calcium carbonate, oilness processing aid 5 parts, polyacrylate 5 parts, silane coupling agent 8 parts.
As a preferred embodiment of the present invention, described foaming control agent is high molecular weight acrylic polymers, and density domination is at 1.0-1.5g, cm3.
As a preferred embodiment of the present invention, described oilness processing aid is LP-175.
As a preferred embodiment of the present invention, also comprise the raw material of following parts by weight: poly(lactic acid) 0.5-1.5 part, Cellmic C 121 0.2-0.7 part.
The beneficial effect that the present invention possesses: board quality of the present invention is light, thermal distortion load temperature is high, not yielding, modulus in flexure is large, tensile strength is large, jagged shock strength is large, rebound resilience is good, have good toughness, soundproof effect is good, is beneficial to environmental protection simultaneously, can regeneration, can degrade smoothly.
Embodiment
Below with reference to specific embodiment, technical scheme provided by the invention is described in detail, following embodiment should be understood and be only not used in for illustration of the present invention and limit the scope of the invention.
Embodiment one: a kind of novel PVC environment-friendly foaming sheet material, comprise the raw material of following parts by weight: polyvinyl chloride 120 parts, ACR resin 60 parts, high molecular weight acrylic polymers 11, modified polypropene 70 parts, ethylene-vinyl acetate copolymer 4 parts, 30 parts, makings calcium carbonate, oilness processing aid 4 parts, polyacrylate 3 parts, silane coupling agent 7 parts, poly(lactic acid) 0.5 part, Cellmic C 121 0.2 part.
Embodiment two: a kind of novel PVC environment-friendly foaming sheet material, comprise the raw material of following parts by weight: polyvinyl chloride 150 parts, ACR resin 70 parts, high molecular weight acrylic polymers 19, modified polypropene 85 parts, ethylene-vinyl acetate copolymer 8 parts, 50 parts, makings calcium carbonate, oilness processing aid 6 parts, polyacrylate 8 parts, silane coupling agent 10 parts, poly(lactic acid) 1.5 parts, Cellmic C 121 0.7 part.
Embodiment three: a kind of novel PVC environment-friendly foaming sheet material, comprise the raw material of following parts by weight: polyvinyl chloride 135 parts, ACR resin 65 parts, high molecular weight acrylic polymers 15, modified polypropene 77 parts, ethylene-vinyl acetate copolymer 7 parts, 44 parts, makings calcium carbonate, oilness processing aid 5 parts, polyacrylate 5 parts, silane coupling agent 8 parts, poly(lactic acid) 0.5-1.5 part, Cellmic C 121 0.2-0.7 part.
Technique means disclosed in the present invention program is not limited only to the technique means disclosed in above-mentioned embodiment, also comprises the technical scheme be made up of above technical characteristic arbitrary combination.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also make some improvements and modifications, these improvements and modifications are also considered as protection scope of the present invention.
Claims (5)
1. a novel PVC environment-friendly foaming sheet material, it is characterized in that, comprise the raw material of following parts by weight: polyvinyl chloride 120-150 part, ACR resin 60-70 part, foaming control agent 11-19, modified polypropene 70-85 part, ethylene-vinyl acetate copolymer 4-8 part, makings calcium carbonate 30-50 part, oilness processing aid 4-6 part, polyacrylate 3-8 part, silane coupling agent 7-10 part.
2. novel PVC environment-friendly foaming sheet material according to claim 1, it is characterized in that, comprise the raw material of following parts by weight: polyvinyl chloride 135 parts, ACR resin 65 parts, foaming control agent 15, modified polypropene 77 parts, ethylene-vinyl acetate copolymer 7 parts, 44 parts, makings calcium carbonate, oilness processing aid 5 parts, polyacrylate 5 parts, silane coupling agent 8 parts.
3. novel PVC environment-friendly foaming sheet material according to claim 1, is characterized in that: described foaming control agent is high molecular weight acrylic polymers, and density domination is at 1.0-1.5g, cm3.
4. novel PVC environment-friendly foaming sheet material according to claim 1, is characterized in that: described oilness processing aid is LP-175.
5. novel PVC environment-friendly foaming sheet material according to claim 1, is characterized in that, also comprise the raw material of following parts by weight: poly(lactic acid) 0.5-1.5 part, Cellmic C 121 0.2-0.7 part.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510735434.0A CN105367938A (en) | 2015-11-03 | 2015-11-03 | Novel PVC environment-friendly foamed panel |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510735434.0A CN105367938A (en) | 2015-11-03 | 2015-11-03 | Novel PVC environment-friendly foamed panel |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105367938A true CN105367938A (en) | 2016-03-02 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510735434.0A Pending CN105367938A (en) | 2015-11-03 | 2015-11-03 | Novel PVC environment-friendly foamed panel |
Country Status (1)
| Country | Link |
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| CN (1) | CN105367938A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221046A (en) * | 2016-07-28 | 2016-12-14 | 无锡市凯达来塑胶有限公司 | A kind of polrvinyl chloride height bendability floor |
| CN109096670A (en) * | 2017-06-20 | 2018-12-28 | 贵州详务节能建材有限公司 | A kind of macromolecule energy conservation template |
| CN109505143A (en) * | 2018-11-05 | 2019-03-22 | 加通汽车内饰(常熟)有限公司 | A kind of degradable PVC artificial leather of novel environment friendly and its production technology |
| CN109555286A (en) * | 2018-11-29 | 2019-04-02 | 安徽可尔海思塑业有限公司 | A kind of novel SPC solid wooden compound floor |
| CN110343346A (en) * | 2019-08-14 | 2019-10-18 | 淮北市菲美得环保科技有限公司 | A kind of polylactic acid/polyamide/polyvinyl chloride composite foam material and preparation method thereof |
-
2015
- 2015-11-03 CN CN201510735434.0A patent/CN105367938A/en active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106221046A (en) * | 2016-07-28 | 2016-12-14 | 无锡市凯达来塑胶有限公司 | A kind of polrvinyl chloride height bendability floor |
| CN109096670A (en) * | 2017-06-20 | 2018-12-28 | 贵州详务节能建材有限公司 | A kind of macromolecule energy conservation template |
| CN109505143A (en) * | 2018-11-05 | 2019-03-22 | 加通汽车内饰(常熟)有限公司 | A kind of degradable PVC artificial leather of novel environment friendly and its production technology |
| CN109555286A (en) * | 2018-11-29 | 2019-04-02 | 安徽可尔海思塑业有限公司 | A kind of novel SPC solid wooden compound floor |
| CN110343346A (en) * | 2019-08-14 | 2019-10-18 | 淮北市菲美得环保科技有限公司 | A kind of polylactic acid/polyamide/polyvinyl chloride composite foam material and preparation method thereof |
| CN110343346B (en) * | 2019-08-14 | 2021-06-18 | 烟台万华聚氨酯合成材料有限公司 | Polylactic acid/polyamide/polyvinyl chloride composite foaming material and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20160302 |
|
| WD01 | Invention patent application deemed withdrawn after publication |