CN105367877B - Material for preparing lifting handle, preparation method and application thereof - Google Patents

Material for preparing lifting handle, preparation method and application thereof Download PDF

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Publication number
CN105367877B
CN105367877B CN201510937470.5A CN201510937470A CN105367877B CN 105367877 B CN105367877 B CN 105367877B CN 201510937470 A CN201510937470 A CN 201510937470A CN 105367877 B CN105367877 B CN 105367877B
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Prior art keywords
weight
parts
preparation
handle
mixer
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CN105367877A (en
Inventor
李涛
成保龙
周玲
汪安理
刘松
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Gree Electric Appliances Inc of Zhuhai
Gree Shijiazhuang Small Home Appliances Co Ltd
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Gree Electric Appliances Inc of Zhuhai
Gree Shijiazhuang Small Home Appliances Co Ltd
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Priority to CN201510937470.5A priority Critical patent/CN105367877B/en
Publication of CN105367877A publication Critical patent/CN105367877A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04Homopolymers or copolymers of ethene
    • C08L23/06Polyethene
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/72Measuring, controlling or regulating
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
    • B29B7/00Mixing; Kneading
    • B29B7/30Mixing; Kneading continuous, with mechanical mixing or kneading devices
    • B29B7/58Component parts, details or accessories; Auxiliary operations
    • B29B7/72Measuring, controlling or regulating
    • B29B7/728Measuring data of the driving system, e.g. torque, speed, power, vibration
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00Properties characterising the ingredient of the composition
    • C08L2207/06Properties of polyethylene
    • C08L2207/066LDPE (radical process)

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processing And Handling Of Plastics And Other Materials For Molding In General (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)

Abstract

The invention discloses a material for preparing a handle, a preparation method and application thereof, wherein the preparation method comprises the following steps of S1, mixing 95-105 parts by weight of L DPE, 27-33 parts by weight of LL DPE, 18-22 parts by weight of POE and 0.04-0.06 part by weight of white oil through a mixer to obtain a main material mixture, S2, adding an auxiliary agent into the main material mixture, mixing through the mixer again to obtain a main material mixture and an auxiliary material mixture, and S3, putting the main material mixture and the auxiliary material mixture into a double-screw extruder, blending and modifying to obtain a material for preparing the handle.

Description

A kind of material, its preparation method and its application for being used to prepare handle
Technical field
The present invention relates to materials processing technology field, in particular to a kind of material for being used to prepare handle, its preparation Method and its application.
Background technology
In the market, existing carton plastic cement handle are broadly divided into three major types, i.e.,:(1) upper and lower handle individually produces, and passes through two Secondary man-made assembly;(2) upper and lower handle one end connection, the other end pass through man-made assembly;(3) integrated handle.
Wherein:It is the production of PE (polyethylene) material that the upper handle of the first handle, which is usually, and lower handle is PP (polypropylene) Material produces, both coordinate, it is necessary to manually be assembled, waste of manpower, and the load-bearing maximum, force of component is only about 25kg.The Two kinds of handles, common used material PP, the more difficult injection molding and hardness due to common PE material injection are higher, using simultaneously few; But because PP material hardnesses are higher, influence packing case accumulation.The third handle is similar with second of handle situation, common PE, PP materials The integrated handle of expecting production is hard, feel is poor and seriously affects the accumulation of Packaging Box, so existing market practical application is less.
The content of the invention
The present invention is intended to provide a kind of material, its preparation method and its application for being used to prepare handle, to solve existing skill The technical problem that handle production cost is high in art or hardness is high.
To achieve these goals, according to an aspect of the invention, there is provided a kind of material for being used to prepare handle Preparation method.The preparation method comprises the following steps:S1, by the LDPE (low density polyethylene (LDPE)) of 95~105 parts by weight, 27~33 The LLDPE (linear low density polyethylene (LLDPE)) of parts by weight, the POE (polyethylene glycol oxide) of 18~22 parts by weight and 0.04~0.06 weight The white oil of part is mixed by mixer, obtains major ingredient mixture;S2, adds after auxiliary agent again by mixer to major ingredient mixture Mixing, obtains main and supplementary materials mixture;S3, is put into double screw extruder blending and modifying by main and supplementary materials mixture, is used to prepare The material of handle.
Further, auxiliary agent is age resister.
Further, age resister includes antioxidant 1010 and antioxidant DLTP.
Further, the additive amount of auxiliary agent is the antioxidant 1010 and 0.13~0.17 weight of 0.04~0.06 parts by weight The antioxidant DLTP of part.
Further, auxiliary agent includes light stabilizer.
Further, the addition of light stabilizer is 0.04~0.06 parts by weight.
Further, in step S1, the mixing velocity of mixer is 1200~2500r/min, incorporation time for 10~ 15S。
Further, in step S2, the mixing velocity of mixer is 1200~2500r/min, incorporation time for 10~ 15S。
According to another aspect of the present invention, there is provided a kind of material for being used to prepare handle.The material passes through any of the above-described The preparation method of kind is prepared.
According to a further aspect of the invention, there is provided a kind of material for being used to prepare handle is in integrated handle is prepared Using.
The material being prepared that applies the technical scheme of the present invention is carried relative to the integration that traditional PE or PP materials produce Hand is soft, and hardness is moderate, and bearing capacity is strong, avoids handle man-made assembly in the prior art, reduces manufacture cost, and Be not in product banking process, due to handle be difficult to packing case caused by deforming scratch with product accumulation it is crooked the problems such as, So that integrated handle product can smoothly be applied among actual production.
Brief description of the drawings
The accompanying drawings which form a part of this application are used for providing a further understanding of the present invention, and of the invention shows Meaning property embodiment and its explanation are used to explain the present invention, do not form inappropriate limitation of the present invention.In the accompanying drawings:
Fig. 1 shows the preparation process flow diagram of the material for being used to prepare handle according to embodiment 1~5.
Embodiment
It should be noted that in the case where there is no conflict, the feature in embodiment and embodiment in the application can phase Mutually combination.Below with reference to the accompanying drawings and the present invention will be described in detail in conjunction with the embodiments.
It is a kind of according to the present invention that typically embodiment there is provided a kind of preparation method for the material for being used to prepare handle. The preparation method comprises the following steps:S1, by the LDPE of 95~105 parts by weight, the LLDPE of 27~33 parts by weight, 18~22 weights Measure the POE of part and the white oil of 0.04~0.06 parts by weight is mixed by mixer, obtain major ingredient mixture;S2, mixes to major ingredient Thing mixes after adding auxiliary agent again by mixer, obtains main and supplementary materials mixture;S3, is put into twin-screw by main and supplementary materials mixture and squeezes Go out machine blending and modifying, obtain being used to prepare the material of handle.
The material being prepared that applies the technical scheme of the present invention is carried relative to the integration that traditional PE or PP materials produce Hand is soft, and hardness is moderate, and bearing capacity is strong, avoids handle man-made assembly in the prior art, reduces manufacture cost, and Be not in product banking process, due to handle be difficult to packing case caused by deforming scratch with product accumulation it is crooked the problems such as, So that integrated handle product can smoothly be applied among actual production.
Alleged auxiliary agent in the present invention, is the additive for improving material property.A kind of typical embodiment party according to the present invention Formula, auxiliary agent are age resister, so as to the anti-aging property of reinforcing material, extend the service life of product.Preferably, it is anti-ageing Agent includes antioxidant 1010 and antioxidant DLTP, and using both oxidants, antioxidant 1010 chemistry is entitled:Four [β- (3,5- di-tert-butyl-hydroxy phenyl) propionic acid] pentaerythritol ester is white crystalline powder, chemical property is stablized, extensive use In the hot procedure of polyvinyl resin, it is possible to increase the service life of plastic products.Anti-oxidant DLTP, also known as thio dipropyl Sour double lauryls, white flock crystalline wafer solid, as auxiliary antioxidant, is widely used in the process of polyethylene, carries The service life of high plastic products.Preferably, the additive amount of auxiliary agent for 0.04~0.06 parts by weight antioxidant 1010 and The antioxidant DLTP of 0.13~0.17 parts by weight.
A kind of typical embodiment according to the present invention, auxiliary agent include light stabilizer, and light stabilizer can shield or absorb purple Hydroperoxides and are resolved into the functions such as inert matter at quenching singlet oxygen by the energy of outside line, high molecular polymer is existed Under the radiation of light, it can exclude or slow down photochemical reaction possibility, prevent or postpone the process of light aging, so that it is high to reach extension The purpose of molecule aggregation Tetramune service life.Preferably, the addition of light stabilizer is 0.04~0.06 parts by weight.
A kind of typical embodiment according to the present invention, in step S1, the mixing velocity of mixer is 1200~2500r/ Min, incorporation time are uniformly mixed the materials such as LDPE, LLDPE, POE for 10~15S, form main mixture.
In step S2, the mixing velocity of mixer is 1200~2500r/min, and incorporation time is 10~15S.Make main mixing Material mixes again with anti-oxidant auxiliary agent, obtains uniformly mixed main materials and auxiliary materials mixture.Main materials and auxiliary materials mixture is squeezed by twin-screw Go out comminutor extrusion, be granulated into modified LDPE --- integrated handle proprietary material.According to a kind of typical embodiment of the present invention, A kind of material for being used to prepare handle is provided.The material is prepared by any of the above-described kind of preparation method.
A kind of typical embodiment according to the present invention, there is provided a kind of material for being used to prepare handle is carried in preparation integration Application in hand.Wherein, which can be molded by injection molding machine all-in-one machine.Integration is prepared using the material of the present invention Handle, the process for eliminating the upper and lower handle of assembling in production product process.Directly integrated handle can be directly sleeved on On packing case, staff labor intensity and productive labor cost are greatly reduced.
Beneficial effects of the present invention are further illustrated below in conjunction with embodiment.
The technological process of following embodiments is as shown in Figure 1.
Embodiment 1
S1, the white oil of the LDPE of 95 parts by weight, the LLDPE of 27 parts by weight, the POE of 18 parts by weight and 0.04 parts by weight is led to Mixer mixing is crossed, obtains major ingredient mixture;The mixing velocity of mixer is 1200r/min, incorporation time 10S;
S2, the antioxidant of antioxidant 1010,0.13 parts by weight to the major ingredient mixture 0.04 parts by weight of addition Mixed after DLTP and 0.04 parts by weight light stabilizer again by mixer, obtain main and supplementary materials mixture;The mixing speed of mixer Spend for 1200r/min, incorporation time 10S;
S3, double screw extruder blending and modifying is put into by the main and supplementary materials mixture, obtains described being used to prepare handle Material.
Embodiment 2
S1, by the white oil of the LDPE of 100 parts by weight, the LLDPE of 30 parts by weight, the POE of 20 parts by weight and 0.05 parts by weight Mixed by mixer, obtain major ingredient mixture;The mixing velocity of mixer is 1500r/min, incorporation time 10S;
S2, the antioxidant 1010 of 0.05 parts by weight and the antioxidant of 0.15 parts by weight are added to the major ingredient mixture Mixed after DLTP again by mixer, obtain main and supplementary materials mixture;The mixing velocity of mixer is 1500r/min, during mixing Between be 10S;
S3, double screw extruder blending and modifying is put into by the main and supplementary materials mixture, obtains described being used to prepare handle Material.
Embodiment 3
S1, by the white oil of the LDPE of 105 parts by weight, the LLDPE of 33 parts by weight, the POE of 22 parts by weight and 0.06 parts by weight Mixed by mixer, obtain major ingredient mixture;The mixing velocity of mixer is 2500r/min, incorporation time 15S;
S2, the antioxidant 1010 of 0.06 parts by weight and the antioxidant of 0.17 parts by weight are added to the major ingredient mixture Mixed after DLTP again by mixer, obtain main and supplementary materials mixture;The mixing velocity of mixer is 2500r/min, during mixing Between be 15S;
S3, double screw extruder blending and modifying is put into by the main and supplementary materials mixture, obtains described being used to prepare handle Material.
Embodiment 4
S1, the white oil of the LDPE of 95 parts by weight, the LLDPE of 33 parts by weight, the POE of 22 parts by weight and 0.06 parts by weight is led to Mixer mixing is crossed, obtains major ingredient mixture;The mixing velocity of mixer is 1200r/min, incorporation time 15S;
S2, the antioxidant 1010 of 0.06 parts by weight and the antioxidant of 0.17 parts by weight are added to the major ingredient mixture Mixed after DLTP again by mixer, obtain main and supplementary materials mixture;The mixing velocity of mixer is 1200r/min, during mixing Between be 15S;
S3, double screw extruder blending and modifying is put into by the main and supplementary materials mixture, obtains described being used to prepare handle Material.
Embodiment 5
S1, by the white oil of the LDPE of 105 parts by weight, the LLDPE of 27 parts by weight, the POE of 18 parts by weight and 0.04 parts by weight Mixed by mixer, obtain major ingredient mixture;The mixing velocity of mixer is 1800r/min, incorporation time 10S;
S2, the antioxidant 1010 and 0.13~0.17 weight of 0.04~0.06 parts by weight are added to the major ingredient mixture Mixed after the antioxidant DLTP of part again by mixer, obtain main and supplementary materials mixture;The mixing velocity of mixer is 2000r/min, incorporation time 15S;
S3, double screw extruder blending and modifying is put into by the main and supplementary materials mixture, obtains described being used to prepare handle Material.
Comparative example
Existing routine handle for injection moldings such as general PE, PP, but existed by the assembly type handle of PE, PP production and held Situation easy to fall off during loads.The integrated handle suppleness produced using general PP is inadequate, and feel is bad and seriously affects production The accumulation of product.The handle purchased in the market in the prior art that specific comparative example uses.
Performance test
The material injection of above-described embodiment and comparative example is integrally changed into handle, which is:Beam overall 35 ± 1mm, 140 ± 3mm of overall length, total high 45 ± 2mm.
Container Handle major function is carrying product and packaging gross weight, therefore uses universal tensile performance testing device, stretching Speed 50mm/min, tensile property test is carried out to handle.
Test result is shown in Table 1, the data in table 1 for a kind of material manufacture into integrated handle and upper and lower assembling handle Tensile property test data, be averaged after test.
1 integrated handle of table and common assembly type handle tensile property contrast test
Stretch maximum, force (N) Tensile strength (Mpa) Break-draw strain (%) Ability to bear (Kg)
Embodiment 1 844.418 20.934 143.207 86
Embodiment 2 854.805 21.191 116.748 87
Embodiment 3 854.035 21.172 122.957 87
Embodiment 4 844.097 20.926 120.245 86
Embodiment 5 874.612 21.682 129.868 89
Comparative example 1 241.596 5.989 29.778 24
Comparative example 2 259.097 6.423 25.47 26
Comparative example 3 254.93 6.32 27.64 26
Comparative example 4 256.792 6.366 28.702 26
Comparative example 5 261.982 6.495 29.759 26
The above results explanation:The integrated handle stretching maximum, force of raw material production of the present invention, tensile strength, break-draw should Become and be significantly larger than conventional sectional formula handle with load-bearing maximum, force.Handle pliability that conventional PE, PP raw material is molded into, stretching Performance cannot meet the needs of existing product.Conventionally, easily occur coming off, break during lower assembly type handle carrying heavier product Split.Conventionally, lower assembly type handle must employee assembling after just can be used, and integrated handle can then remove from assemble this ring Section.
It can be seen from the above description that the above embodiments of the present invention realize following technique effect:
1) solve the problems, such as that integrated handle is difficult to practical application.
2) solve the problems, such as separate type handle coming off when putting forward heavier product.
3) reduce the process of handle above and below man-made assembly in production process, reduce production cost.
The foregoing is only a preferred embodiment of the present invention, is not intended to limit the invention, for the skill of this area For art personnel, the invention may be variously modified and varied.Within the spirit and principles of the invention, that is made any repaiies Change, equivalent substitution, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of preparation method for the material for being used to prepare handle, it is characterised in that comprise the following steps:
S1, by the LDPE of 95~105 parts by weight, the LLDPE of 27~33 parts by weight, 18~22 parts by weight polyethylene glycol oxide and The white oil of 0.04~0.06 parts by weight is mixed by mixer, obtains major ingredient mixture;
S2, adds after auxiliary agent to the major ingredient mixture and is mixed again by mixer, obtain main and supplementary materials mixture;
S3, double screw extruder blending and modifying is put into by the main and supplementary materials mixture, obtains the material for being used to prepare handle.
2. preparation method according to claim 1, it is characterised in that the auxiliary agent is age resister.
3. preparation method according to claim 2, it is characterised in that the age resister includes antioxidant 1010 and resists Oxidant DLTP.
4. preparation method according to claim 3, it is characterised in that the additive amount of the auxiliary agent is 0.04~0.06 weight The antioxidant 1010 of part and the antioxidant DLTP of 0.13~0.17 parts by weight.
5. preparation method according to claim 2, it is characterised in that the auxiliary agent further comprises light stabilizer.
6. preparation method according to claim 5, it is characterised in that the addition of the light stabilizer is 0.04~0.06 Parts by weight.
7. preparation method according to claim 1, it is characterised in that in the step S1, the mixing speed of the mixer It is 10~15s to spend for 1200~2500r/min, incorporation time.
8. preparation method according to claim 7, it is characterised in that in the step S2, the mixing speed of the mixer It is 10~15s to spend for 1200~2500r/min, incorporation time.
9. a kind of material for being used to prepare handle, it is characterised in that pass through preparation such as described in any item of the claim 1 to 8 Method is prepared.
10. application of the material according to claim 9 for being used to prepare handle in integrated handle is prepared.
CN201510937470.5A 2015-12-15 2015-12-15 Material for preparing lifting handle, preparation method and application thereof Active CN105367877B (en)

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Application Number Priority Date Filing Date Title
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CN105367877B true CN105367877B (en) 2018-04-13

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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101696290A (en) * 2009-11-03 2010-04-21 四川剑南春(集团)有限责任公司 High-lubrication wear-resisting polyolefin material, high-lubrication wear-resisting polyolefin pipe and preparation method thereof
CN203294438U (en) * 2013-05-14 2013-11-20 珠海格力电器股份有限公司 Integral type handle and with supporting packing box that uses of this handle

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101696290A (en) * 2009-11-03 2010-04-21 四川剑南春(集团)有限责任公司 High-lubrication wear-resisting polyolefin material, high-lubrication wear-resisting polyolefin pipe and preparation method thereof
CN203294438U (en) * 2013-05-14 2013-11-20 珠海格力电器股份有限公司 Integral type handle and with supporting packing box that uses of this handle

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
低密度聚乙烯提手增加提携强度;无;《上海包装》;19881231;第45页 *

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