CN105367038B - A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof - Google Patents

A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof Download PDF

Info

Publication number
CN105367038B
CN105367038B CN201510555594.7A CN201510555594A CN105367038B CN 105367038 B CN105367038 B CN 105367038B CN 201510555594 A CN201510555594 A CN 201510555594A CN 105367038 B CN105367038 B CN 105367038B
Authority
CN
China
Prior art keywords
felt
silica aerogel
glass
glass fiber
nanometers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201510555594.7A
Other languages
Chinese (zh)
Other versions
CN105367038A (en
Inventor
陈照峰
叶信立
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nanjing University of Aeronautics and Astronautics
Original Assignee
Nanjing University of Aeronautics and Astronautics
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nanjing University of Aeronautics and Astronautics filed Critical Nanjing University of Aeronautics and Astronautics
Priority to CN201510555594.7A priority Critical patent/CN105367038B/en
Publication of CN105367038A publication Critical patent/CN105367038A/en
Application granted granted Critical
Publication of CN105367038B publication Critical patent/CN105367038B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Nonwoven Fabrics (AREA)
  • Thermal Insulation (AREA)

Abstract

The invention discloses a kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof, it is characterized in that described glass lightweight felt is formed by the glass fiber horizontal arrangement of surface uniform adhesion silica aerogel particles, felt thickness direction without the glass fibre extended vertically through, a diameter of 1 micron 4 microns of glass fiber, length is 5 millimeters 30 millimeters, the particle diameter of silica aerogel particles is 10 nanometers 100 nanometers, by Venturi effect so that silica aerogel particles uniform adsorption is on glass fiber surface, glass fiber superficial silicon dioxide silica aerogel adhesion layer thickness is 50 nanometers 500 nanometers, the uncovered ratio of fiber surface is 5% 10%, weight ratio of the silica aerogel particles in felt is 0.1% 1%, the unit weight of felt is every cube 5 kilograms 20 kilograms, the compression rebound rate of felt is 20% 30%, the porosity of felt is 70% 90%, the thermal conductivity factor of nanometer titanium dioxide silica aerogel glass lightweight felt is 0.008 0.015W/mK.

Description

A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof
Technical field
The present invention relates to a kind of glass lightweight felt and preparation method thereof, more particularly to a kind of nanometer titanium dioxide silica aerogel Glass lightweight felt and preparation method thereof.
Technical background
In recent years, energy-conserving and environment-protective turn into the most concerned problem of people, and traditional organic insulation material is inflammable perishable to be lacked The extensive use for limiting it in building field is fallen into, and there is poor thermal insulation property in inorganic heat insulation material, the shortcomings of density is big has Significant limitation.Glass fibre is as the inorganic non-metallic material of another excellent performance, and not only thermal conductivity factor is low but also machine Tool intensity is high, and it forms unorganic glass meltblown, because with good resilience, heat insulating effect is excellent, also has Very excellent damping, sound absorption characteristics, advantageously reduce noise pollution, improve working environment, are widely used in architecture indoor, disappear Sound system, the vehicles, refrigeration plant, the damping of household electrical appliance, sound absorption, noise reduction process, effect are very good.The life of mineral wool Production is broadly divided into flame injection and centrifugal blast, but flame injection energy consumption is higher, is gradually replaced by centrifugal blast technique.In glass In the preparation technology of glass blanket, wet method and dry method are broadly divided into.The blanket unit weight of wet production is higher, general fiber and particle It is compound mainly to use binding agent by fiber solidifying into felt using wet processing dry process felt more.
Aerosil has nano-porous structure, and general aerosil density is relatively low, with special Porous network structure, porosity is more than 90%, and most of gas cell distribution is below 50 nanometers, less than being averaged certainly for air molecule It is difficult to collide by 70 nanometers of journey, between air molecule, with relatively low thermal conductivity factor.The preparation method of aerogel composite Two kinds are broadly divided into, is gel molding in integral and grain forming method respectively.For gel molding in integral, in collosol and gel mistake Enhancing phase is introduced in journey, Monolithic aerogel composite is finally given;For grain forming method, by the nano-pore gas prepared Gel particle powder adds enhancing mutually and in binding agent, and the complex of post forming is made up of molding or moulding by casting.
The Chinese invention patent of Application No. 201310309064.5 discloses a kind of blanket of glass wool and silica airsetting The method of glue mixing felt, the invention is to prepare mineral wool using centrifugal blast technique, sprays resinoid bond, while by dioxy SiClx aeroge slurry is sprayed at blanket of glass wool surface, forms the composite that blanket is superimposed with aeroge, its advantage is to prepare The composite gone out has excellent mechanical performance, good heat-insulating property and sound absorbing capabilities.It has the disadvantage the requirement to equipment Height, virtually adds cost, and the content of aeroge is larger in the aeroge combination mat prepared in addition so that the rigidity of combination mat It is big flexible not enough, limit its application in some fields.
The Chinese invention patent of Application No. 201310309201.5 discloses a kind of dry method mineral wool and silica gas Gel complex material and preparation method thereof, the invention is that aerosil is filled in mineral wool gap, passes through phenol Aerosil and mineral wool are combined by urea formaldehyde binding agent, constitute fiber and Particles dispersed type composite.Profit Mineral wool, sprinkling phenolic resin adhesive and aerosil mixture are prepared with centrifugal blast technique, its advantage is this Composite has excellent mechanical performance, good heat-insulating property and sound absorbing capabilities.It has the disadvantage using phenolic resin bonded Agent and aerosil mixture, the thermal conductivity factor of combination mat slightly has increase while the highest for reducing combination mat uses temperature Degree, limits its application in high-temperature field.
Content in two patents as described above, aerosil combination mat prepared by prior art shared by aeroge compared with Many, equipment requirement is high, considerably increases cost, the rigidity of additional mixing felt is big flexible not enough, and the effect of sound-insulating and heat-insulating is simultaneously paid no attention to Think, therefore a kind of new mixing felt technique of urgent need carrys out the more excellent aeroge Chopped Strand Mat of processability.
The content of the invention
The purpose of the present invention is intended to overcome the deficiencies in the prior art, and there is provided a kind of small flexible big, sound isolating and heat insulating performance of rigidity More excellent nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof.
To realize that the technical scheme that the purpose of the present invention is used is:A kind of nanometer titanium dioxide silica aerogel glass lightweight Felt, it is characterised in that described glass lightweight felt by surface uniform adhesion silica aerogel particles glass fiber level Arrangement is formed, felt thickness direction without the glass fibre extended vertically through, it is a diameter of 1 micron -4 microns of glass fiber, long Spend for 5 millimeters -30 millimeters, in a contact form between filament and filament, greatly reduce overlapping area, so as to increase heat Resistance, significantly reduces the thermal conductivity factor of Chopped Strand Mat.
The particle diameter of silica aerogel particles is 10 nanometers -100 nanometers, glass fiber superficial silicon dioxide silica aerogel Adhesion layer thickness is 50 nanometers -500 nanometers, and the uncovered ratio of fiber surface is 5%-10%, aerosil Weight ratio of the grain in felt is 0.1%-1%, by Venturi effect so that silica aerogel particles uniform adsorption is in glass In the gap being present between glass fibre of glass filament surface rather than monoblock, the flexibility for adding Chopped Strand Mat reduces it Rigidity, makes it have excellent sound absorption qualities, the unit weight of felt is every cube 5 kilograms -20 kilograms, and the compression rebound rate of felt is 20%-30%, the porosity of felt is 70%-90%, and the thermal conductivity factor of the heat-insulated Chopped Strand Mat of aerosil light sound-proof is 0.008-0.015W/mK, in the leading level in the world.
Present invention also offers a kind of preparation method of nanometer titanium dioxide silica aerogel glass lightweight felt, it is characterised in that bag Include following steps:
(1) glass fiber is sprayed into from Venturi tube top, flow is 100 kilograms -300 kilograms, glass fibers per hour Dimension silk descends slowly and lightly in Venturi tube, and Venturi tube length is 3 meters -5 meters, and upper and lower side aperture ratio is 1: 3-5;
(2) one air inlet is set in the contraction section of Venturi tube, silica aerogel particles is sprayed into from air inlet, flow Measure as 0.1 kilogram -0.5 kilogram per hour, glass fiber entrance is 1 with silica aerogel particles entrance spacing - 2 meters of rice;
(3) the ratio between gentle gel flow of flow of adjustment glass fiber, it is to avoid silica aerogel particles are in fiber Silk surface multi-layer pushes away product so that aerosil is uniformly distributed in filament surface;
(4) glass fiber slows down in Venturi tube lower end, tends to parallel whereabouts by longitudinal direction whereabouts, is produced with aerogel particle Raw initiative sharp impacts, make the unstable particle of absorption drop, and the particle dropped enters one with the unadsorbed surface of glass fiber Step is adsorbed;
(5) glass fiber goes out behind Venturi tube bottom, and slow parallel depositions are on a moving belt;
(6) rotating speed of bottom conveyor is adjusted, the thickness of the heat-insulated Chopped Strand Mat of aerosil light sound-proof is controlled.
The beneficial effects of the invention are as follows:(1) by Venturi effect silica aerogel particles uniform adsorption is existed In glass fiber surface rather than the gap being present between glass fibre of monoblock, the flexibility for adding Chopped Strand Mat is reduced Its rigidity, makes it have excellent sound absorption qualities;(2) particle diameter of silica aerogel particles is 10 nanometers -100 nanometers, glass Filametntary a diameter of 1 micron -4 microns of glass, is in the leading level in the world, and vertical direction is arranged without filament in addition, and this is all Its service life is added while the overall thermal conductivity for greatly reducing Chopped Strand Mat, its active time is extended.
Brief description of the drawings
Fig. 1 is the installation drawing for preparing nanometer titanium dioxide silica aerogel glass lightweight felt.
10 be venturi tube inlet section in figure, and 20 be contraction section, and 30 be diffuser, and 40 be air inlet, and 50 be conveyer belt.
Fig. 2 is the sectional view of the heat-insulated Chopped Strand Mat of aerosil light sound-proof.
Fig. 3 is the exterior view of the heat-insulated Chopped Strand Mat of aerosil light sound-proof.
Embodiment
With reference to specific embodiment, the present invention is furture elucidated, it should be understood that these embodiments are merely to illustrate the present invention Rather than limitation the scope of the present invention, after the present invention has been read, various equivalences of the those skilled in the art to the present invention The modification of form falls within the application appended claims and limited.
Embodiment 1
Reference picture 1, is the installation drawing for preparing nanometer titanium dioxide silica aerogel glass lightweight felt, 10 be venturi tube inlet Section, 20 be contraction section, and 30 be diffuser, and 40 be air inlet, and 50 be conveyer belt, Fig. 2 be aerosil light sound-proof every The sectional view of hot Chopped Strand Mat, Fig. 3 is the exterior view of the heat-insulated Chopped Strand Mat of aerosil light sound-proof, and its preparation includes following Several steps:
(1) glass fiber is sprayed into from Venturi tube top, flow is 100 kilograms per hour, and glass fiber is in text Descended slowly and lightly in venturi, Venturi tube length is 3 meters, upper and lower side aperture ratio is 1: 3;
(2) one air inlet is set in the contraction section of Venturi tube, silica aerogel particles is sprayed into from air inlet, flow Measure as 0.1 kilogram per hour, glass fiber entrance is 1 meter with silica aerogel particles entrance spacing;
(3) the ratio between gentle gel flow of flow of adjustment glass fiber, it is to avoid silica aerogel particles are in fiber Silk surface multi-layer pushes away product so that aerosil is uniformly distributed in filament surface;
(4) glass fiber slows down in Venturi tube lower end, tends to parallel whereabouts by longitudinal direction whereabouts, is produced with aerogel particle Raw initiative sharp impacts, make the unstable particle of absorption drop, and the particle dropped enters one with the unadsorbed surface of glass fiber Step is adsorbed;
(5) glass fiber goes out behind Venturi tube bottom, and slow parallel depositions are on a moving belt;
(6) rotating speed of bottom conveyor is adjusted, the thickness of nanometer titanium dioxide silica aerogel glass lightweight felt is controlled.
Prepared nanometer titanium dioxide silica aerogel glass lightweight felt, a diameter of 4 microns of its glass fiber, length is 30 millimeters, the particle diameter of silica aerogel particles is 100 nanometers, and glass fiber superficial silicon dioxide silica aerogel adhesion layer is thick Spend for 50 nanometers, the uncovered ratio of fiber surface is 10%, weight ratio of the silica aerogel particles in felt is 0.1%, the unit weight of felt is 5 kilograms every cube, and the compression rebound rate of felt is 20%, and the porosity of felt is 70%, silica gas The thermal conductivity factor of the heat-insulated Chopped Strand Mat of gel light sound-proof is 0.015W/mK.
Embodiment 2
Reference picture 1, is the installation drawing for preparing nanometer titanium dioxide silica aerogel glass lightweight felt, 10 be venturi tube inlet Section, 20 be contraction section, and 30 be diffuser, and 40 be air inlet, and 50 be conveyer belt, Fig. 2 be aerosil light sound-proof every The sectional view of hot Chopped Strand Mat, Fig. 3 is the exterior view of the heat-insulated Chopped Strand Mat of aerosil light sound-proof, and its preparation includes following Several steps:
(1) glass fiber is sprayed into from Venturi tube top, flow is 300 kilograms per hour, and glass fiber is in text Descended slowly and lightly in venturi, Venturi tube length is 5 meters, upper and lower side aperture ratio is 1: 5;
(2) one air inlet is set in the contraction section of Venturi tube, silica aerogel particles is sprayed into from air inlet, flow Measure as 0.5 kilogram per hour, glass fiber entrance is 2 meters with silica aerogel particles entrance spacing;
(3) the ratio between gentle gel flow of flow of adjustment glass fiber, it is to avoid silica aerogel particles are in fiber Silk surface multi-layer pushes away product so that aerosil is uniformly distributed in filament surface;
(4) glass fiber slows down in Venturi tube lower end, tends to parallel whereabouts by longitudinal direction whereabouts, is produced with aerogel particle Raw initiative sharp impacts, make the unstable particle of absorption drop, and the particle dropped enters one with the unadsorbed surface of glass fiber Step is adsorbed;
(5) glass fiber goes out behind Venturi tube bottom, and slow parallel depositions are on a moving belt;
(6) rotating speed of bottom conveyor is adjusted, the thickness of nanometer titanium dioxide silica aerogel glass lightweight felt is controlled.
Prepared nanometer titanium dioxide silica aerogel glass lightweight felt, a diameter of 1 micron of its glass fiber, length is 5 millimeters, the particle diameter of silica aerogel particles is 10 nanometers, glass fiber superficial silicon dioxide silica aerogel adhesion layer thickness For 500 nanometers, the uncovered ratio of fiber surface is 5%, and weight ratio of the silica aerogel particles in felt is 1%, The unit weight of felt is 20 kilograms every cube, and the compression rebound rate of felt is 30%, and the porosity of felt is 90%, and aerosil is light The thermal conductivity factor of matter sound-insulating and heat-insulating Chopped Strand Mat is 0.008W/mK.
Two embodiments of the present invention are above are only, but the design concept of the present invention is not limited thereto, all profits The change of unsubstantiality is carried out to the present invention with this design, the behavior for invading the scope of protection of the invention all should be belonged to.In every case it is Any type of letter made without departing from the content of technical solution of the present invention, the technical spirit according to the present invention to above example Single modification, equivalent variations and remodeling, still fall within the protection domain of technical solution of the present invention.

Claims (2)

1. a kind of nanometer titanium dioxide silica aerogel glass lightweight felt, it is characterised in that described glass lightweight felt is uniformly glued by surface The glass fiber horizontal arrangement of Annex II silica aerogel particles is formed, felt thickness direction without the glass fibers extended vertically through Dimension, a diameter of 1 micron -4 microns of glass fiber, length is 5 millimeters -30 millimeters, the particle diameter of silica aerogel particles For 10 nanometers -100 nanometers, glass fiber superficial silicon dioxide silica aerogel adhesion layer thickness is 50 nanometers -500 nanometers, fiber The uncovered ratio in surface is 5%-10%, and weight ratio of the silica aerogel particles in felt is 0.1%-1%, felt Unit weight is every cube 5 kilograms -20 kilograms, and the compression rebound rate of felt is 20%-30%, and the porosity of felt is 70%-90%, dioxy The thermal conductivity factor of SiClx aeroge glass lightweight felt is 0.008-0.015W/mK.
2. a kind of preparation method of nanometer titanium dioxide silica aerogel glass lightweight felt described in claim 1, it is characterised in that bag Include following steps:
(1) glass fiber is sprayed into from Venturi tube top, flow is 100 kilograms -300 kilograms, glass fiber per hour Descended slowly and lightly in Venturi tube, Venturi tube length is 3 meters -5 meters, upper and lower side aperture ratio is 1: 3-5;
(2) one air inlet is set in the contraction section of Venturi tube, silica aerogel particles is sprayed into from air inlet, flow is 0.1 kilogram -0.5 kilogram per hour, glass fiber entrance is 1 meter -2 with silica aerogel particles entrance spacing Rice;
(3) the ratio between gentle gel flow of flow of adjustment glass fiber, it is to avoid silica aerogel particles are in fiber silk table Face multilayer pushes away product so that aerosil is uniformly distributed in filament surface;
(4) glass fiber slows down in Venturi tube lower end, tends to parallel whereabouts by longitudinal direction whereabouts, master is produced with aerogel particle Dynamic property sharp impacts, make the unstable particle of absorption drop, the particle dropped is further sent out with the unadsorbed surface of glass fiber Raw absorption;
(5) glass fiber goes out behind Venturi tube bottom, and slow parallel depositions are on a moving belt;
(6) rotating speed of bottom conveyor is adjusted, the thickness of nanometer titanium dioxide silica aerogel glass lightweight felt is controlled.
CN201510555594.7A 2015-08-31 2015-08-31 A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof Active CN105367038B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510555594.7A CN105367038B (en) 2015-08-31 2015-08-31 A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510555594.7A CN105367038B (en) 2015-08-31 2015-08-31 A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof

Publications (2)

Publication Number Publication Date
CN105367038A CN105367038A (en) 2016-03-02
CN105367038B true CN105367038B (en) 2017-08-15

Family

ID=55369743

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510555594.7A Active CN105367038B (en) 2015-08-31 2015-08-31 A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof

Country Status (1)

Country Link
CN (1) CN105367038B (en)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108215372A (en) * 2018-01-16 2018-06-29 天津摩根坤德高新科技发展有限公司 Nanometer titanium dioxide silica aerogel glass fiber composite mat and preparation method thereof
CN113562980A (en) * 2020-04-29 2021-10-29 河北三楷深发科技股份有限公司 Modified inorganic fiber and application thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103723989A (en) * 2013-07-23 2014-04-16 太仓派欧技术咨询服务有限公司 Dry-process glass cotton and silicon dioxide aerogel composite material and preparation method thereof
CN103722813A (en) * 2013-07-23 2014-04-16 太仓派欧技术咨询服务有限公司 High-efficiency heat-insulated glass cotton felt structure
CN103723995A (en) * 2013-07-23 2014-04-16 太仓派欧技术咨询服务有限公司 Method for preparing felt by mixing glass cotton felt with silicon dioxide aerogel

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103723989A (en) * 2013-07-23 2014-04-16 太仓派欧技术咨询服务有限公司 Dry-process glass cotton and silicon dioxide aerogel composite material and preparation method thereof
CN103722813A (en) * 2013-07-23 2014-04-16 太仓派欧技术咨询服务有限公司 High-efficiency heat-insulated glass cotton felt structure
CN103723995A (en) * 2013-07-23 2014-04-16 太仓派欧技术咨询服务有限公司 Method for preparing felt by mixing glass cotton felt with silicon dioxide aerogel

Also Published As

Publication number Publication date
CN105367038A (en) 2016-03-02

Similar Documents

Publication Publication Date Title
CN110922095B (en) Preparation method of composite silica aerogel felt
CN108863294A (en) A kind of NEW TYPE OF COMPOSITE rock wool aeroge insulation board, composite plate and preparation method thereof
CN108793944A (en) A kind of refractory glass fibre enhancing aeroge composite felt and preparation method thereof
CN103074736A (en) Sound absorption and vibration reduction polyester composite cotton and preparation method of sound absorption and vibration reduction polyester composite cotton
CN103641383B (en) A kind of aviation special-purpose thermal insulation insulated fibre glass composite and preparation method thereof
CN116145882A (en) Mineral fiber type ceiling tile
CN105367038B (en) A kind of nanometer titanium dioxide silica aerogel glass lightweight felt and preparation method thereof
HU224120B1 (en) Man-made vitreous fibre products for use in thermal insulation, and their production
CN104193209A (en) High-performance modified glass bead and surface modification method thereof
CN103723995A (en) Method for preparing felt by mixing glass cotton felt with silicon dioxide aerogel
CN109534781A (en) A kind of refractory glass fibre enhancing aeroge composite felt and preparation method thereof
CN105036797B (en) Multilayered-structure porous ceramic sound-absorbing material and preparing method thereof
CN104370516A (en) Core material prepared by mixing glass fibers and silicon dioxide aerogel and preparation method thereof
CN207028396U (en) A kind of hard polyurethane foam rock wool heat-preservation composite plate
CN108978039B (en) Heat-insulating fiber felt and preparation process thereof
CN203049805U (en) Extruded sheet composite insulation board
CN111517644A (en) Passive room inorganic wallboard and preparation method thereof
CN104630985A (en) Preparation method of super-layer structure superfine glass fiber cotton felt
CN207003887U (en) A kind of microvesicle ceramic thermal insulation stone decoration integrated board
CN103204665A (en) Fiber and particle hybrid inorganic composite material felt and making method thereof
CN113415045B (en) Preparation method of toughened nano porous heat insulation material for ice bag cold insulation
CN107338574B (en) A kind of radiation-resistant ceramics cellucotton composite material
CN108679370B (en) Glass fiber insulation felt and preparation method thereof
CN109056188B (en) Production process of heat-preservation fiber felt
CN210026519U (en) Sound insulation quartz stone plate

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant