CN105366860A - Method for pretreating mosquito-repellent incense waste water - Google Patents

Method for pretreating mosquito-repellent incense waste water Download PDF

Info

Publication number
CN105366860A
CN105366860A CN201510951909.XA CN201510951909A CN105366860A CN 105366860 A CN105366860 A CN 105366860A CN 201510951909 A CN201510951909 A CN 201510951909A CN 105366860 A CN105366860 A CN 105366860A
Authority
CN
China
Prior art keywords
mosquito
repellent incense
waste water
wastewater
repellent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510951909.XA
Other languages
Chinese (zh)
Inventor
肖磊
唐剑文
何宜斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Guangzhou Liby Enterprise Group Co Ltd
Original Assignee
Guangzhou Liby Enterprise Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Guangzhou Liby Enterprise Group Co Ltd filed Critical Guangzhou Liby Enterprise Group Co Ltd
Priority to CN201510951909.XA priority Critical patent/CN105366860A/en
Publication of CN105366860A publication Critical patent/CN105366860A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/30Treatment of water, waste water, or sewage by irradiation
    • C02F1/32Treatment of water, waste water, or sewage by irradiation with ultraviolet light
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/66Treatment of water, waste water, or sewage by neutralisation; pH adjustment
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/306Pesticides
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2301/00General aspects of water treatment
    • C02F2301/08Multistage treatments, e.g. repetition of the same process step under different conditions

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physical Water Treatments (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a method for pretreating mosquito-repellent incense waste water. Based on the theory that pyrethroid generates hydrolysis and photolysis under the alkaline condition and the condition of ultraviolet irradiation, ultraviolet irradiation is carried out on the mosquito-repellent incense waste water under the alkaline condition, pesticide is promoted to be decomposed, and the toxicity of the mosquito-repellent incense waste water is lowered. The method comprises the specific operating steps that 1, the mosquito-repellent incense waste water is collected; 2, the mosquito-repellent incense waste water is diluted through alkaline water; 3, ultraviolet irradiation is carried out; 4, the mosquito-repellent incense waste water enters a sewage treatment station to be treated. The method has the advantages that investment cost is low, operation is easy and convenient, the degradation efficiency on pesticide, such as tetrafluoro dimethyl ether and fluorine chlorine ether, in the mosquito-repellent incense pesticide liquid waste water is high, the sewage treatment station can be prevented from impact, it is guaranteed that sewage treatment reaches the standard, and the method is very suitable for earlier pretreatment of mosquito-repellent incense waste water generated in mosquito-repellent incense production enterprises.

Description

A kind of mosquito-repellent incense pretreatment method for wastewater
Technical field
The present invention relates to a kind of mosquito-repellent incense pretreatment method for wastewater, utilize pyrethroid to issue the principle of unboiled water solution and photolysis in alkalescence and UV-irradiation condition, in the basic conditions uv irradiating is carried out to mosquito-repellent incense waste water, promote that agricultural chemicals decomposes, reduce mosquito-repellent incense wastewater toxicity.
Background technology
In the process of producing coiled mosquito-repellent incense, electric mosquito repellent liquid, anti-mosquito incense sheet, discarded former medicine can be produced, the waste water that liquor piping, equipment and container produce is infected with in cleaning, these waste water are as directly entered sewage works without pre-treatment, can impact sewage plant, easily cause discharge to exceed standard, pastille waste water enters in aquatic ecological environment, can have a huge impact aquatic animals and plants, as dead in fishes and shrimps etc.So need first to carry out pre-treatment before pastille waste water enters sewage plant, enter sewage plant again after most farm chemical ingredients of first degrading, reach the operation not affecting sewage plant, the object of wastewater treatment qualified discharge.
Physics, chemistry, biological process etc. are had at present to the treatment process of agricultural chemicals waste water.Physical mainly contains absorption method, sonication, irradiation method etc. at present, absorption method has the material of adsorptivity or biological adsorption mainly through some and carrys out fractionation by adsorption and go out agricultural chemicals, but the material adsorbed has become again danger wastes needs process in addition, and the cost of investment of sorbing material is also higher simultaneously; Namely supersonic method utilizes liquid to produce cavitation effect under ul-trasonic irradiation to carry out degrading pesticide, at present technical comparative maturity, and shortcoming is that investment is large, running cost is high; Irradiation method is the method utilizing ionizing rays decomposing pesticide, does not need to add chemical agent, noresidue, energy consumption are low, but facility investment large, have radiological hazard etc., less use.Chemical method comprises the methods such as oxygenolysis, hydrolysis, coagulation, and wherein oxygenolysis utilizes strong oxidizer to process agricultural chemicals waste water, and running cost is high; Hydrolysis is that agricultural chemicals is unstable and hydrolytic action occurs in alkaline aqueous solution, but effect is general; Coagulation adopts coagulating agent process pastille waste water, and one is that medicament expense is comparatively large, and two is to produce pastille mud, and mud also needs other disposal.Biological process mainly carrys out degrading pesticide by enzymatic reactions such as microorganism, degrading enzyme, engineering bacterias, on the one hand because agricultural chemicals inherently has bio-toxicity, add the high and difficult degradation of concentration, cause Biochemical Treatment poor, at present separation and purification obtained to pesticide degradable enzyme and carried out more deep physiological and biochemical research, but still can not produce on a large scale and practical application.
Summary of the invention
For the treatment process of existing agricultural chemicals waste water, the object of the present invention is to provide a kind of mosquito-repellent incense pretreatment method for wastewater, utilize pyrethroid to issue the principle of unboiled water solution and photolysis in alkalescence and UV-irradiation condition, in the basic conditions uv irradiating is carried out to mosquito-repellent incense waste water, promote that agricultural chemicals decomposes, reduce mosquito-repellent incense wastewater toxicity.
The object of the invention to solve the technical problems realizes by the following technical solutions.According to a kind of mosquito-repellent incense pretreatment method for wastewater that the present invention proposes, comprise the following steps:
1) mosquito-repellent incense waste water is collected;
2) alkaline water dilution;
3) uv irradiating;
4) sewage works process is entered.
Disclosed by the invention is a kind of mosquito-repellent incense pretreatment method for wastewater, and the operation steps that described method is concrete is as follows:
1) the discarded former medicine will produced in coiled mosquito-repellent incense, electric mosquito repellent liquid, anti-mosquito incense sheet production process, cleaning is infected with the wastewater collection of liquor piping, equipment and container generation in the lighttight container of outer wall;
2) finite concentration is diluted to the pastille waste water weakly alkaline of collecting in container or middle strong alkaline water;
3) the UV-irradiation regular hour in container;
4) reacted discharge of wastewater is processed further to sewage works.
The pastille waste collection container of described method both can be bucket also can be fluid-tight pond or groove.
In described method to the dilution water of pastille waste water be pH 7 ~ 10 alkaline water, preferred pH is 8; Drug level is diluted to massfraction 0.01% ~ 0.08%, and preferential weaker concn is 0.03%.
Described method can be potassium hydroxide or sodium hydroxide for regulating the medicine of alkaline water, preferred sodium hydroxide.
Can be xenon lamp, mercury lamp etc. for generation of the light source of UV-light in described method, preferred mercury lamp; Lamp installation directly can be inserted in collection container and also use silica glass protection of pipe, also can be placed on apart from liquid level 5 ~ 10cm place, and preferably direct insertion by light fixture in collection container also uses silica tube glass protection; Uv irradiating duration at 8 ~ 48h, preferred 48h.
The intensity of illumination of the ultraviolet lamp source of described method at 3000 ~ 15000LuX, preferred 8000LuX, power at 5 ~ 10w/L, preferred 8w/L.
By technique scheme, the present invention has following significantly technique effect:
1) utilize pyrethroid to issue the principle of unboiled water solution and photolysis in alkalescence and UV-irradiation condition, in the basic conditions uv irradiating is carried out to mosquito-repellent incense waste water, facilitate agricultural chemicals and decompose, significantly reduce mosquito-repellent incense wastewater toxicity;
2) present method has low in investment cost, easy and simple to handle, to mosquito-repellent incense liquid waste water Pesticides as degradation efficiency highs such as tetrafluoro methyl ether, chlorine fluorine ethers, can prevent sewage plant from being impacted, guarantee sewage disposal is up to standard, is applicable to very much the pre-treatment in early stage of the mosquito-repellent incense waste water that mosquito-repellent incense class manufacturing enterprise produces.
Embodiment
Below by way of concrete preferred embodiment, the present invention is described in further detail, but the present invention is not limited in following embodiment.
embodiment 1
Certain mosquito-repellent incense factory produces coiled mosquito-repellent incense, electric mosquito repellent liquid, electric mat; farm chemical ingredients tetrafluoro methyl ether is comprised in its waste water produced; its concentration is 2.3%; by wastewater collection to volume be 250L plastic tank in; by pH be 8 alkaline water 0.08% is diluted to it, inserting an intensity of illumination having quartz glass sleeve to protect is 8000LuX, and power is that the mercury lamp of 2kw irradiates; prolonged exposure 24h, the content measuring tetrafluoro methyl ether after having irradiated decreases 99.6%.
embodiment 2
Certain mosquito-repellent incense factory produces coiled mosquito-repellent incense, electric mosquito repellent liquid, electric mat; farm chemical ingredients tetrafluoro methyl ether is comprised in its waste water produced; its concentration is 3.0%; by wastewater collection to volume be 250L plastic tank in; by pH be 8 alkaline water 0.08% is diluted to it, inserting an intensity of illumination having quartz glass sleeve to protect is 10000LuX, and power is that the xenon lamp of 1.8kw irradiates; prolonged exposure 48h, the content measuring tetrafluoro methyl ether after having irradiated decreases 99.83%.
embodiment 3
Certain mosquito-repellent incense factory produces coiled mosquito-repellent incense, electric mosquito repellent liquid, and comprise farm chemical ingredients tetrafluoro methyl ether in its waste water produced, its concentration is 2.5%, is 2m by wastewater collection to volume 3tank in, by pH be 10 alkaline water 0.07% is diluted to it, on liquid level, placement two intensities of illumination in 8cm place are 12000LuX, and power is that the mercury lamp of 3kw irradiates, prolonged exposure 24h, the content measuring tetrafluoro methyl ether after having irradiated decreases 93%.
embodiment 4
Certain mosquito-repellent incense factory produces coiled mosquito-repellent incense, electric mosquito repellent liquid, electric mat, and comprise farm chemical ingredients tetrafluoro methyl ether in its waste water produced, its concentration is 3.0%, is 2m by wastewater collection to volume 3tank in, by pH be 10 alkaline water 0.06% is diluted to it, on liquid level, placement two intensities of illumination in 10cm place are 12000LuX, and power is that the mercury lamp of 3kw irradiates, prolonged exposure 48h, the content measuring tetrafluoro methyl ether after having irradiated decreases 96%.
embodiment 5
Certain mosquito-repellent incense factory produces electric mosquito repellent liquid, electric mat; farm chemical ingredients chlorine fluorine ether is comprised in its waste water produced; its concentration is 4.5%; by wastewater collection to volume be 250L plastic tank in; by pH be 8 alkaline water 0.08% is diluted to it, inserting an intensity of illumination having quartz glass sleeve to protect is 7000LuX, and power is that the mercury lamp of 1.5kw irradiates; prolonged exposure 24h, the content measuring chlorine fluorine ether after having irradiated decreases 72%.
embodiment 6
Certain mosquito-repellent incense factory produces electric mosquito repellent liquid, electric mat; farm chemical ingredients chlorine fluorine ether is comprised in its waste water produced; its concentration is 4.5%; by wastewater collection to volume be 250L plastic tank in; by pH be 8 alkaline water 0.08% is diluted to it, inserting an intensity of illumination having quartz glass sleeve to protect is 6000LuX, and power is that the mercury lamp of 1.6kw irradiates; prolonged exposure 48h, the content measuring chlorine fluorine ether after having irradiated decreases 97%.
embodiment 7
Certain mosquito-repellent incense factory produces electric mosquito repellent liquid, electric mat; farm chemical ingredients chlorine fluorine ether is comprised in its waste water produced; its concentration is 4.0%; by wastewater collection to volume be 200L plastic tank in; by pH be 10 alkaline water 0.08% is diluted to it, inserting an intensity of illumination having quartz glass sleeve to protect is 8000LuX, and power is that the mercury lamp of 1.5kw irradiates; prolonged exposure 24h, the content measuring chlorine fluorine ether after having irradiated decreases 90%.
embodiment 8
Certain mosquito-repellent incense factory produces coiled mosquito-repellent incense, electric mosquito repellent liquid, electric mat; farm chemical ingredients chlorine fluorine ether is comprised in its waste water produced; its concentration is 4.5%; by wastewater collection to volume be 250L plastic tank in; by pH be 10 alkaline water 0.08% is diluted to it, inserting an intensity of illumination having quartz glass sleeve to protect is 5000LuX, and power is that the mercury lamp of 1kw irradiates; prolonged exposure 48h, the content measuring chlorine fluorine ether after having irradiated decreases 89%.
embodiment 9
Certain mosquito-repellent incense factory produces electric mosquito repellent liquid, electric mat; farm chemical ingredients alkynes third is comprised in its waste water produced; its concentration is 1.5%; by wastewater collection to volume be 250L plastic tank in; by pH be 8 alkaline water 0.08% is diluted to it, inserting an intensity of illumination having quartz glass sleeve to protect is 9000LuX, and power is that the mercury lamp of 2.5kw irradiates; prolonged exposure 24h, the content measuring alkynes third after having irradiated decreases 99%.
embodiment 10
Certain mosquito-repellent incense factory produces coiled mosquito-repellent incense, electric mosquito repellent liquid, electric mat, and comprise farm chemical ingredients alkynes the third in its waste water produced, its concentration is 1.0%, is 3m by wastewater collection to volume 3pond, be that the alkaline water of 8 is diluted to 0.08% to it by pH, on liquid level, placement two intensities of illumination in 10cm place are 12000LuX, and power is that the mercury lamp of 3kw irradiates, and prolonged exposure 48h, the content measuring alkynes third after having irradiated decreases 99%.
embodiment 11
Certain mosquito-repellent incense factory produces electric mosquito repellent liquid, electric mat, and comprise farm chemical ingredients alkynes the third in its waste water produced, its concentration is 1.5%, is 1m by wastewater collection to volume 3pond, be that the alkaline water of 10 is diluted to 0.08% to it by pH, on liquid level, placement two intensities of illumination in 10cm place are 13000LuX, and power is that the mercury lamp of 3kw irradiates, and prolonged exposure 24h, the content measuring alkynes third after having irradiated decreases 99%.
embodiment 12
Certain mosquito-repellent incense factory produces coiled mosquito-repellent incense, electric mosquito repellent liquid, electric mat, and comprise farm chemical ingredients alkynes the third in its waste water produced, its concentration is 2.0%, is 3m by wastewater collection to volume 3pond, be that the alkaline water of 10 is diluted to 0.08% to it by pH, on liquid level, placement three intensities of illumination in 5cm place are 13000LuX, and power is that the mercury lamp of 3.5kw irradiates, and prolonged exposure 48h, the content measuring alkynes third after having irradiated decreases 99%.
The above, it is only preferred embodiment of the present invention, not any pro forma restriction is done to the present invention, therefore everyly do not depart from technical solution of the present invention content, the any simple modification done above embodiment according to technical spirit of the present invention, equivalent variations and modification, all still belong in the scope of technical solution of the present invention.

Claims (7)

1. a mosquito-repellent incense pretreatment method for wastewater, is characterized in that, the method comprises the following steps:
1) mosquito-repellent incense waste water is collected;
2) alkaline water dilution;
3) uv irradiating;
4) sewage works process is entered.
2. mosquito-repellent incense pretreatment method for wastewater according to claim 1, is characterized in that: the method specifically comprises the following steps:
1) the discarded former medicine will produced in coiled mosquito-repellent incense, electric mosquito repellent liquid, anti-mosquito incense sheet production process, cleaning is infected with the wastewater collection of liquor piping, equipment and container generation in the lighttight container of outer wall;
2) finite concentration is diluted to the pastille waste water weakly alkaline of collecting in container or middle strong alkaline water;
3) the UV-irradiation regular hour in container;
4) reacted discharge of wastewater is processed further to sewage works.
3. mosquito-repellent incense pretreatment method for wastewater according to claim 1, is characterized in that: step 1) in, pastille waste collection container both can be bucket also can be fluid-tight pond or groove.
4. mosquito-repellent incense pretreatment method for wastewater according to claim 1, is characterized in that: step 2) in, to the dilution water of pastille waste water be pH 7 ~ 10 alkaline water, drug level is diluted to massfraction 0.01% ~ 0.08%.
5. mosquito-repellent incense pretreatment method for wastewater according to claim 3, is characterized in that: can be potassium hydroxide or sodium hydroxide for modulating the medicine of alkaline water.
6. mosquito-repellent incense pretreatment method for wastewater according to claim 1; it is characterized in that: step 4) in; light source for generation of UV-light can be xenon lamp, mercury lamp etc.; lamp installation directly can be inserted in collection container and also use silica tube glass protection; also can be placed on apart from liquid level 5 ~ 10cm place, uv irradiating duration is at 8 ~ 48h.
7. mosquito-repellent incense pretreatment method for wastewater according to claim 5, is characterized in that: the intensity of illumination of described ultraviolet lamp source is at 3000 ~ 15000LuX, and power is at 5 ~ 10w/L.
CN201510951909.XA 2015-12-17 2015-12-17 Method for pretreating mosquito-repellent incense waste water Pending CN105366860A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201510951909.XA CN105366860A (en) 2015-12-17 2015-12-17 Method for pretreating mosquito-repellent incense waste water

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201510951909.XA CN105366860A (en) 2015-12-17 2015-12-17 Method for pretreating mosquito-repellent incense waste water

Publications (1)

Publication Number Publication Date
CN105366860A true CN105366860A (en) 2016-03-02

Family

ID=55369571

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201510951909.XA Pending CN105366860A (en) 2015-12-17 2015-12-17 Method for pretreating mosquito-repellent incense waste water

Country Status (1)

Country Link
CN (1) CN105366860A (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838075A (en) * 2009-03-16 2010-09-22 中国科学院生态环境研究中心 Process for effectively treating organophosphorus pesticide wastewater
KR20110006757A (en) * 2009-07-15 2011-01-21 삼득산업(주) Wasted water teatment system at the food waste recycling facilities connected with a communitysewage disposal plant
CN102120631A (en) * 2010-12-07 2011-07-13 北京联合大学生物化学工程学院 Photocatalytic degradation method of pyrethroid pesticide in water

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101838075A (en) * 2009-03-16 2010-09-22 中国科学院生态环境研究中心 Process for effectively treating organophosphorus pesticide wastewater
KR20110006757A (en) * 2009-07-15 2011-01-21 삼득산업(주) Wasted water teatment system at the food waste recycling facilities connected with a communitysewage disposal plant
CN102120631A (en) * 2010-12-07 2011-07-13 北京联合大学生物化学工程学院 Photocatalytic degradation method of pyrethroid pesticide in water

Similar Documents

Publication Publication Date Title
Cheng et al. Advanced treatment of pesticide-containing wastewater using Fenton reagent enhanced by microwave electrodeless ultraviolet
CN106927634B (en) Hospital wastewater treatment system
CN102765785A (en) Device and method for sterilizing and disinfecting wastewater by pulsed liquid-phase discharge plasma
CN101767852A (en) Pulse plasma device for safe disinfection of drinking water
CN103447027A (en) Modified nano TiO2/Ag/bamboo charcoal composite material and method for killing microorganisms in medical sewage by virtue of same
CN108585319A (en) Utilize the method for electron beam irradiation degradation water Venlafaxine
CN201990514U (en) Ultraviolet/Fenton reaction device for removing toxic organic pollutant in water
CN111943311A (en) Method for removing phenylurea herbicide chlortoluron in water by ultraviolet/persulfate combined process
Jing et al. The removal of COD and NH 3-N from atrazine production wastewater treatment using UV/O 3: experimental investigation and kinetic modeling
CN103723803A (en) Method and device for disinfecting, detoxifying and purifying water by using hydroxyl radicals
CN102432095A (en) Method for degrading clopyralid in water by performing electron beam irradiation
CN105366860A (en) Method for pretreating mosquito-repellent incense waste water
CN104162418A (en) Activated carbon loaded titanium dioxide composite photocatalyst and preparation method thereof
CN204281503U (en) Hospital sewage disposal system
CN203820497U (en) Photocatalyst sewage and air odor treatment device
CN214399896U (en) Device for treating bacteriostatic agent in water by adopting persulfate
CN201746368U (en) Pulse plasma device for safe disinfection of drinking water
CN205528320U (en) Buried waste water treatment system for treating sewage
CN204138380U (en) A kind of photocatalysis treatment device
CN210001628U (en) immersion ultraviolet sterilizer
CN103086563B (en) Multistage sunlight photocatalytic landfill leachate treatment technology
CN203513404U (en) Automatic swimming pool silver ion sterilization system
CN102249476B (en) Method for removing phthalates out of water by utilizing UV (ultraviolet)/ozone/chlorella degradation composite process
CN105174363A (en) Photocatalytic oxidating method for efficiently removing antibiotics in water body
CN203513403U (en) Automatic disinfection system for silver ions of spring pool

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20160302