CN105361054B - A kind of material bag for reducing catsup and pickled vegetables nitrite - Google Patents
A kind of material bag for reducing catsup and pickled vegetables nitrite Download PDFInfo
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- CN105361054B CN105361054B CN201510793303.8A CN201510793303A CN105361054B CN 105361054 B CN105361054 B CN 105361054B CN 201510793303 A CN201510793303 A CN 201510793303A CN 105361054 B CN105361054 B CN 105361054B
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Abstract
A kind of material bag for reducing catsup and pickled vegetables nitrite disclosed by the invention, belongs to field of vegetable deep-processing.The material bag is made up of absorption bag and spices bag, contain the adsorbent of adsorbable nitrite in absorption bag, contain the spice that can suppress nitrite generation in spices bag, the content of nitrite in catsup and pickled vegetables is effectively reduced by synergy, the effect of increase flavor taste is also acted as simultaneously, the batch that can be used not only for large-scale production line is pickled, for self-employed worker oneself pickle for more convenient safety, possess very strong practicality.
Description
Technical field
The present invention relates to a kind of method for reducing catsup and pickled vegetables nitrite, and in particular to one kind is reduced in catsup and pickled vegetables
The material bag of content of nitrite, belongs to field of vegetable deep-processing.
Background technology
Catsup and pickled vegetables eat the mode of phase as a kind of extension vegetables, can not only increase the flavor and taste of vegetable raw-material,
The nutritive value of raw material can also be increased by fermenting simultaneously, it is deep to be welcome by consumers in general.But sell on the market at present
Mostly there is the too high risk of nitrite in catsup and pickled vegetables commodity, cause consumer to trust purchase simultaneously because quality is uneven
Buy use；And the catsup and pickled vegetables that oneself pickles more bother due to lacking experience of pickling, curing process, equally exist nitrite and contain
Measure too high risk.
Although it is well known that simple low concentration nitrite can be metabolized quickly in human body, due to its appearance
The stable strong carcinogen nitrosamine of generation is easily reacted with aminated compounds, harm to the human body is very big；Wherein, and secondary amine combination
Reaction is particularly rapid.The principle easily combined using nitrite with secondary amine, by being bonded on the material for possessing a large amount of micropores
Small molecule with secondary amine, it can be reacted with free nitrite rapidly, generation is fixed on the Asia in poromerics
Nitramine, so as to reach the effect of stable absorption nitrite.Meanwhile the spices such as garlic, ginger also possesses nitrite certain suppression
Effect processed.
Although there is the application for being used for salted white using chrysanthemum stone, medical stone in the prior art, as CN104719817 is disclosed
A kind of production technology using medical stone salted white, it has main steps that first extracts maifanite leaching solution, then by medical stone
Leachate is added in vegetables and pickled, and the main purpose for changing technique is by contained selenium, strontium, iodine, fluorine and metasilicic acid in medical stone
Etc. distinctive trace element, it is dissolved among salted vegetables, people are during diet, you can element needed for supplement body；
The nitrite among salted vegetables can be adsorbed simultaneously, avoid endangering the body of people.And for example CN102008058, which is disclosed, uses chrysanthemum stone
The method for pickling various vegetables, key step include selected clean chrysanthemum stone processing powdering, then by chrysanthemum stone flour and water
It is mixed to be added in vegetables after chrysanthemum halite water by weight 1: 20 and pickles, the lot of trace containing needed by human body in chrysanthemum stone
Element, and it has stronger adsorptivity and stripping property are various can be immersed to human body beneficial element in dish, is inhaled after food by human body
Receive, supplement needed by human body various elements, while adsorb the Escherichia coli in food, dysentery bacillus, staphylococcus aureus and mercury,
The harmful element such as aluminium, arsenic, cadmium has the function that to prevent and cure diseases, strengthens human immunological competence.But these adsorbents exist
While adsorbing harmful substance, the microorganism needed for fermentation is also adsorbed, have impact on ferment effect.
The content of the invention
The technical problems to be solved by the invention are：For the curing food nitrite mistake of existing commercial type
High danger, while convenient and safe preserved materials are provided for the vast consumer for liking oneself to pickle, having invented one kind can be effective
The material bag of catsup and pickled vegetables nitrite is reduced, while is also equipped with seasoning and proposes fresh effect, to meet that individual pickles or even criticized
Measure the demand pickled.
In order to solve the above technical problems, the technical solution adopted in the present invention is to provide nitrous acid in a kind of reduction catsup and pickled vegetables
The material bag of salt content, absorption bag and a kind of spices that suppresses nitrite generation of the material bag by a kind of absorbable nitrite
Bag composition.
The absorption bag of described a kind of absorbable nitrite, it is characterised in that absorption bag packaging material is permeable materials, is inhaled
The attached one or more included in following material：Silica gel, resin, zeolite powder, activated carbon, sepiolite etc..
The absorption bag of described a kind of absorbable nitrite, it is characterised in that the material that absorption includes can passing through
Reaction bonding fixed absorbent enhancing suction-operated is learned, adsorbent includes following one or more：Proline, hydroxy-proline,
Methyl amimoacetic acid etc..The material of the absorption bag includes resin and hydroxy-proline, and the material of the absorption bag is by ion exchange resin
It is made with hydroxy-proline, the further preferred anion exchange resin of its ion exchange resin.The material of the absorption bag can
To be prepared by the following method, 4- hydroxy-prolines are protected with Boc, are then dissolved in organic solvent（It is preferred that dichloromethane）In,
Anion exchange resin is put into again, and adds DCC and is stirred, and is then taken off Boc protections again, is produced.
Described one kind can suppress spices bag caused by nitrite, it is characterised in that spices bag is matched somebody with somebody comprising following parts by weight
Compare auxiliary material：33 portions of salt, 10 parts of white sugar, 10 parts of garlic granules, 10 parts of ginger powders, 3 portions of pepper powders, 2 portions of aniseed, 2 parts of fennel powders, 2 parts of dimensions
Raw plain C, 1 part of citric acid, 4 parts of acetic acid, 6 parts of white wine.
Described one kind can suppress spices bag caused by nitrite, it is characterised in that be divided into A bags, B bags and C in spices bag
Bag；A bags are wrapped up after being mixed by salt and white sugar and are made, and B bags are wrapped up after being mixed by vitamin C, citric acid and acetic acid and are made, C bags
Dissolved in white wine or wrapped up after scattered by garlic granule, ginger powder, pepper powder, aniseed and fennel powder and be made.
The material bag of described a kind of reduction catsup and pickled vegetables nitrite, it is characterised in that the material bag is applied to most of
Catsup and pickled vegetables are pickled；Absorption bag and the feeding method of spices bag are respectively：Absorption bag is placed directly within curing container；Spices bag can
Injected with pouring into after cold water mixes, also or after directly being mixed with vegetables reinject cold water.
The beneficial effects of the invention are as follows：（1）By the way that this poromerics for possessing absorption nitrite ability is wrapped
Wrap up in and permeability material bag is made, obtain to reduce the absorption bag of content of nitrite by simply immersing.（2）Subsidiary spices bag
Except can season carry it is fresh in addition to, equally possess effect caused by certain suppression nitrite.（3）This reduction catsup and pickled vegetables are sub-
The material bag of nitrate content is widely used, using flexible, convenient and safe.Embodiment
Following examples are intended to illustrate invention, rather than the further limitation to the present invention, should not limit on this basis
Protection scope of the present invention processed.
Embodiment 1.
Adsorb the fabrication processing of bag：
（1）500 suitable g weak-base anion-exchange resins of granular size are chosen, 30 points are soaked in 95% alcohol
Clock, rinsed well afterwards with lot of pure water to alcohol-free smell.
（2）Clean resin is put into 5% HCl solution and soaked 1 hour, is rinsed afterwards with purified water to neutrality, then
Soak 1 hour in 5% NaOH solution, then rinsed again with purified water to neutrality.So it is repeated 2 times, for the last time should be 5%
Carry out in NaOH solution, rinsed afterwards with purified water to neutrality, dried stand-by.
（3）Take 10 g 4- hydroxy-prolines and 12.8 g NaHCO3It is dissolved in 200 ml purified waters, is dripped in ice-water bath
Add 17 g Boc acid anhydrides, reply be stirred at room temperature 12 hours afterwards.
（4）It is extracted with ethyl acetate after the completion of reaction, organic phase is again respectively with 0.2 mol/L HCl, 5%NaHCO3, it is pure
Change water and saturation NaCl extractions are washed, add anhydrous MgSO4Dry, drained after filtering.
（5）The above-mentioned 4- hydroxy-prolines with Boc protections are dissolved in dichloromethane, input weak base type treated before
Anion exchange resin, the DCC for adding 19 g are stirred 12 hours.
（6）Resin particle is filtered out, and rinsed with ethanol, purified water.It is added to afterwards in 92.8 g 30%HCl,
Stirring de- Boc protections in 12 hours.
（7）Resin particle is filtered out, rinsed with large-scale purification water to neutrality, is dried at 40 DEG C.Afterwards will be dry
Dry resin finished is neatly wrapped up with three layers of clean gauze, checks for small opening, is sterilized after loading inner packing, is filled after cooling
Enter outer packing and be put in storage.
Embodiment 2.
The fabrication processing of spices bag：
（1）It is fitted into after taking 33 g salt and the mixing of 10 g white sugar in basic bag packaging bag.
（2）Take 2 g vitamin Cs, 1 g citric acids to be dissolved in 4 g light-coloured vinegars, be fitted into after well mixed in acid material bag packaging bag.
（3）Take 10 g garlic granules, 10 g ginger powders, 3 g pepper powders, 2 g aniseed, 2 g fennel powders to be added in 6 g white wine, stir
Mix and be fitted into after being well mixed in pungent material bag packaging bag.
（4）Above-mentioned three kinds packaged material bags are sterilized at 95 DEG C, rapid ladder water cooling to room temperature, three kinds after drying
Material bag is every kind of to put one bag in big spices bag, and outer packing is loaded after sealing and is put in storage.
Embodiment 3：It is raw material to choose without mildew and rot, no disease and pests harm, the fresh vegetables having no mechanical damage, and cleans, drains, stripping and slicing
After be placed in altar, the absorption bag of embodiment 1 is placed directly within curing container, the spices bag of embodiment 2 is poured into cold water and mixed
Injected after conjunction, or cold water is reinjected after directly being mixed with vegetables；Then the lactic acid bacteria system equivalent to material quality 0.04% is weighed
Agent, 2% glucose solution is dissolved in, 30 DEG C activate 30 minutes；Add the lactobacillus preparation solution activated and sterilized, quality
The saline solution that concentration is 7% was not up to having raw material, clear water envelope altar, fermentation just.
Comparative example 1：In addition to the absorption bag and spices bag that are added without in embodiment 1,2 remaining process with above-mentioned phase
Together.
Comparative example 2：Method according to CN104719817 embodiments 1 prepares salted vegetables.
Content of nitrite is detected by hydrochloric acid-naphthalene-ethylenediamine method during fermentation ends, repeating result of the test confirms, embodiment 3
Salted vegetables finished product content of nitrite reduces 62.4% than comparative example 1, the salted vegetables finished product content of nitrite of comparative example 2
Reduce 34.5% than comparative example 1.Embodiment 3 shortens 2 days than the fermentation period of comparative example 2 simultaneously, and this may be with suction
Enclosure material adsorbs relevant to fermentative microorganism.
Claims (3)
1. a kind of material bag for reducing catsup and pickled vegetables nitrite, it is characterised in that this material bag is by a kind of absorbable nitrous acid
The absorption bag and one kind of salt can suppress spices bag caused by nitrite and form；
The material of the absorption bag is made up of anion exchange resin and hydroxy-proline, and the material that the absorption is wrapped passes through following
Prepared by method, 4- hydroxy-prolines are protected with Boc, are then dissolved in organic solvent, then puts into anion exchange resin, and adds
Enter DCC to be stirred, then take off Boc protections again, produce；
It is described to suppress spices bag caused by nitrite and include following weight auxiliary material：33 portions of salt, 10 parts of white sugar, 10
Part garlic granule, 10 parts of ginger powders, 3 portions of pepper powders, 2 portions of aniseed, 2 parts of fennel powders, 2 parts of vitamin Cs, 1 part of citric acid, 4 parts of acetic acid, 6 parts
White wine.
2. material bag according to claim 1, it is characterised in that described to suppress in spices bag to be divided into caused by nitrite
A bags, B bags and C bags；A bags are wrapped up after being mixed by salt and white sugar and are made, and B bags wrap after being mixed by vitamin C, citric acid and acetic acid
Wrap up in and be made, C bags, which are dissolved in white wine or wrapped up after scattered by garlic granule, ginger powder, pepper powder, aniseed and fennel powder, to be made.
3. according to the material bag described in claim 1, it is characterised in that absorption bag and the feeding method of spices bag are respectively：Absorption bag
It is placed directly within curing container；Spices bag is injected after pouring into cold water mixing, or reinjects cold water after directly being mixed with vegetables.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510793303.8A CN105361054B (en) | 2015-11-18 | 2015-11-18 | A kind of material bag for reducing catsup and pickled vegetables nitrite |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201510793303.8A CN105361054B (en) | 2015-11-18 | 2015-11-18 | A kind of material bag for reducing catsup and pickled vegetables nitrite |
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| CN105361054B true CN105361054B (en) | 2017-12-22 |
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Families Citing this family (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105707787A (en) * | 2016-03-03 | 2016-06-29 | 杨翠萍 | Low-salt ready-to-eat vegetables and making method thereof |
| CN106262652A (en) * | 2016-08-05 | 2017-01-04 | 句容市仑山湖生态卤制品有限公司 | A kind of slow-releasing composite material and the method pickling air-dried chicken with it |
| CN106551319A (en) * | 2016-10-21 | 2017-04-05 | 山东农业大学 | A kind of shrimp sauce catsup and pickled vegetables and preparation method thereof |
| CN107960635A (en) * | 2017-12-08 | 2018-04-27 | 定远县南德调味品加工厂 | A kind of pot-stewed fowl flavoring and preparation method thereof |
| CN108783330B (en) * | 2018-06-11 | 2021-09-17 | 南京财经大学 | Production method for keeping crispness and selenium of selenium-rich dried turnips |
| CN117398973B (en) * | 2023-12-13 | 2024-02-20 | 河北鑫鹏新材料科技有限公司 | Nitrate industrial wastewater treatment method and adsorbent for treating nitrate wastewater |
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| CN1936548A (en) * | 2006-10-10 | 2007-03-28 | 天津科技大学 | Nitrite quick detecting reagent box and application thereof |
| CN101595952A (en) * | 2009-06-19 | 2009-12-09 | 四川省食品发酵工业研究设计院 | Preparation method of kimchi natural compound nitrite inhibitor |
| CN104366399A (en) * | 2014-11-28 | 2015-02-25 | 四川东坡中国泡菜产业技术研究院 | Method for preparing pickled cabbage through multiple rounds of salting and fermentation |
| CN104719817A (en) * | 2015-03-30 | 2015-06-24 | 内蒙古旺牛食品有限公司 | Production process for pickling pickles by virtue of medical stone |
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2015
- 2015-11-18 CN CN201510793303.8A patent/CN105361054B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1936548A (en) * | 2006-10-10 | 2007-03-28 | 天津科技大学 | Nitrite quick detecting reagent box and application thereof |
| CN101595952A (en) * | 2009-06-19 | 2009-12-09 | 四川省食品发酵工业研究设计院 | Preparation method of kimchi natural compound nitrite inhibitor |
| CN104366399A (en) * | 2014-11-28 | 2015-02-25 | 四川东坡中国泡菜产业技术研究院 | Method for preparing pickled cabbage through multiple rounds of salting and fermentation |
| CN104719817A (en) * | 2015-03-30 | 2015-06-24 | 内蒙古旺牛食品有限公司 | Production process for pickling pickles by virtue of medical stone |
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