CN105360148A - Compound weeding composition containing clodinafop-propargyl and amidosulfuron and application of compound weeding composition - Google Patents
Compound weeding composition containing clodinafop-propargyl and amidosulfuron and application of compound weeding composition Download PDFInfo
- Publication number
- CN105360148A CN105360148A CN201510435181.5A CN201510435181A CN105360148A CN 105360148 A CN105360148 A CN 105360148A CN 201510435181 A CN201510435181 A CN 201510435181A CN 105360148 A CN105360148 A CN 105360148A
- Authority
- CN
- China
- Prior art keywords
- propargyl
- amidosulfuron
- clodinafop
- weeding composition
- compound weeding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a compound weeding composition containing clodinafop-propargyl and amidosulfuron and application of the compound weeding composition. Clodinafop-propargyl and amidosulfuron serve as main effective components of the compound weeding composition, the mass ratio of clodinafop-propargyl to amidosulfuron is 1-99 to 1-99, and the mass percent of clodinafop-propargyl and amidosulfuron in the compound weeding composition accounts for 10-80% of the total mass percent. The compound weeding composition can be used for post-seedling weeding of wheat fields, and especially has a remarkable effect on preventing and killing graminaceous weed and broad-leaved weed in the wheat fields. By means of the compound weeding composition, compared with single agents, on the premise of improving efficacy, weed resistance is delayed, a weeding spectrum is wide, the lasting period is long, and safety is achieved for wheat and succeeding crops.
Description
Technical field
The invention belongs to technical field of pesticide, especially weed killer herbicide field, be specifically related to the binary built Herbicidal combinations of a kind of clodinafop-propargyl and amidosulfuron, this Herbicidal combinations can be applicable to wheat paddock postemergence weed control.
Background technology
Clodinafop-propargyl, has another name called top, chemical name: R-2-[4-(the chloro-3-of 5-fluoro-2-oxygen yl pyridines)-phenoxy group]-propiolic acid, belongs to phenoxy carboxylic acid herbicides, structural formula:
Clodinafop-propargyl is acetyl-CoA carboxylase (ACCase) inhibitor, Uptake and translocation weed killer herbicide, by blade and the leaf sheath absorption of plant corpus, phloem conducts, and accumulates and obtains in meristematic tissue in plant corpus, suppresses acetyl-CoA carboxylase, fatty acid is synthesized stop, the growth division of cell can not normally be carried out, and membranous system etc., containing fat structural deterioration, finally cause Plant death.Be absorbed into weeds Mortality Ratio from clodinafop-propargyl comparatively slow, generally need 1-3 week.
Amidosulfuron, chemical name: 1-(4,6-dimethoxy-2-pyrimidine radicals)-3-(N-methylmethanesulfonamide sulfonyl)-urea; Amino Sulfometuron Methyl, belongs to sulfonylurea herbicide, structural formula:
Amidosulfuron is acetolactate synthestase (ALS) inhibitor.Absorbed by weeds root and leaf, conduct in plant body, namely weeds stop growing, leaf look chlorisis, then withered.Herbicidal effect after dispenser is not subject to weather effect, effect stability.Low toxicity, low-residual, environmentally safe.
Current wheat field herbicide limit by crop safety, herbicide spectrum is also limited, be used alone the generation that a kind of weed killer herbicide single dose can not control weeds of wheat completely effectively, moreover some weed killer herbicide is due to water-soluble large or the field lasting period is oversize, consumption is excessive or the uneven residual hazard all easily caused this season crop or succession crop of dispenser.
Summary of the invention
The object of this invention is to provide a kind of Herbicidal combinations containing clodinafop-propargyl and amidosulfuron.
Another object of the present invention is to provide the application of this Herbicidal combinations in wheat paddock weeding.
Containing a compound weeding composition for clodinafop-propargyl and amidosulfuron, this Herbicidal combinations is with clodinafop-propargyl and amidosulfuron for principle active component, and wherein, the weight ratio of clodinafop-propargyl and amidosulfuron is 1 ~ 99:1 ~ 99; Preferably in this Herbicidal combinations, the weight ratio of clodinafop-propargyl and amidosulfuron is 1 ~ 80:1 ~ 80; In this Herbicidal combinations preferred, the weight ratio of clodinafop-propargyl and amidosulfuron is 1 ~ 60:1 ~ 60 further; Most preferably in this Herbicidal combinations, the weight ratio of clodinafop-propargyl and amidosulfuron is 29 ~ 60:1 ~ 5.
The compound weeding composition containing clodinafop-propargyl and amidosulfuron described in technical solution of the present invention, both clodinafop-propargyl and the amidosulfuron mass percentage in Herbicidal combinations is 1 ~ 80%; Both preferred clodinafop-propargyl and the amidosulfuron mass percentage in Herbicidal combinations is 30 ~ 65%.
In the binary built composition of clodinafop-propargyl of the present invention and amidosulfuron, except the active ingredient such as clodinafop-propargyl and amidosulfuron, the auxiliary agents such as conventional surfactants, thickener, solvent or the solid packing that pesticidal preparations allows can also be added and be mixed with any one formulation that agricultural chemicals allows.Preferably be processed in missible oil, suspending agent, aqueous emulsion, microemulsion, water dispersion granule and wetting powder any one.
Aforementionedly can be applicable to the not special restriction of weeding auxiliary agent of the present invention, include, but are not limited to alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, aluminium-magnesium silicate, dimethylbenzene, methyl naphthalene sulfonate formaldehyde condensate, polyoxyethylene nonylphenol ether, aluminium-magnesium silicate, ethylene glycol, tributyl phosphate, silicone oil, sodium metnylene bis-naphthalene sulfonate, ammonium sulfate, polyvinyl alcohol, kaolin, solvent naphtha and water etc.
Herbicidal combinations of the present invention can be applied in wheat paddock postemergence weed control, particularly has remarkable result preventing and kill off in wheat paddock application in grass family and broad leaved weed.
Herbicidal combinations of the present invention has the following advantages:
1, activity of weeding is high.Herbicidal combinations of the present invention can kill weeds by two kinds of different mechanism, makes Weed Resistance produce speed and reduces, greatly improve the removing activity of weed killer herbicide.
2, herbicidal spectrum is wide, and the lasting period is long.Amidosulfuron has good preventive effect to broad leaved weed in wheat paddock, and clodinafop-propargyl can prevent and treat most of grassy weed.After both mixing, the control to multiple broad leaved weed and grassy weed can be improved.
3, safety is high.Because its using dosage is under control, make medicament under the prerequisite that improve drug effect, it have also been obtained raising to the safety of wheat and succession crop.
Herbicidal combinations of the present invention, is applied to wheat paddock weeding, and it can prevent and kill off various broad leaved weed and grassy weed in wheat paddock, under the prerequisite that improve drug effect, all has safety to wheat and succession crop.
Therefore, Herbicidal combinations of the present invention can be applied in the weed killer herbicide for the preparation of wheat paddock weeding, particularly applies in for the preparation of the weed killer herbicide preventing and kill off grassy weed and broad leaved weed in wheat paddock.
Embodiment
Below in conjunction with embodiment, the invention will be further described, but protection scope of the present invention is not limited thereto:
Embodiment 1
Take clodinafop-propargyl 34g, amidosulfuron 1g, alkylphenol polyoxyethylene 4g, phenethyl phenol polyethenoxy ether 15g, dimethylbenzene is to 100g, and formulation method is conveniently mixed with the missible oil that mass percentage is 35%.
Embodiment 2
Take clodinafop-propargyl 29g, amidosulfuron 1g, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, silicone oil 0.2g, surplus is water, and formulation method is conveniently mixed with the suspending agent that mass percentage is 30%.
Embodiment 3
Take clodinafop-propargyl 59g, amidosulfuron 1g, NNO (methylene two bitter edible plant sodium sulfonate) 5g, ammonium sulfate 3g, polyvinyl alcohol 2g, kaolin is to 100g, and formulation method is conveniently mixed with the water dispersion granule that mass percentage is 60%.
Embodiment 4
Take clodinafop-propargyl 60g, amidosulfuron 5g, NNO (methylene two bitter edible plant sodium sulfonate) 6g, sodium lignin sulfonate 4g, kaolin is to 100g, and formulation method is conveniently mixed with the wetting powder that mass percentage is 65%.
Embodiment 5
Take clodinafop-propargyl 3g, amidosulfuron 12g, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, solvent naphtha 20g, water is to 100g, and formulation method is conveniently mixed with the aqueous emulsion that mass percentage is 15%.
Embodiment 6
Take clodinafop-propargyl 5g, amidosulfuron 9g, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, water is to 100g, and formulation method is conveniently mixed with the microemulsion that mass percentage is 14%.
Embodiment 7
Take clodinafop-propargyl 10g, amidosulfuron 50g, NNO (methylene two bitter edible plant sodium sulfonate) 6g, sodium lignin sulfonate 4g, kaolin is to 100g, and formulation method is conveniently mixed with the wetting powder that mass percentage is 60%.
Embodiment 8
Take clodinafop-propargyl 20g, amidosulfuron 31g, methyl naphthalene sulfonate formaldehyde condensate 6g, polyoxyethylene nonylphenol ether 3g, aluminium-magnesium silicate 0.5g, ethylene glycol 7g, tributyl phosphate 2g, silicone oil 0.2g, surplus is water, and formulation method is conveniently mixed with the suspending agent that mass percentage is 51%.
Embodiment 9
Take clodinafop-propargyl 19g, amidosulfuron 60g, NNO (methylene two bitter edible plant sodium sulfonate) 5g, ammonium sulfate 3g, polyvinyl alcohol 2g, kaolin is to 100g, and formulation method is conveniently mixed with the water dispersion granule that mass percentage is 79%.
Embodiment 10
Take clodinafop-propargyl 5g, amidosulfuron 5g, NNO (methylene two bitter edible plant sodium sulfonate) 6g, sodium lignin sulfonate 4g, kaolin is to 100g, and formulation method is conveniently mixed with the wetting powder that mass percentage is 10%.
1), toxicity determination test
Utilize the preparation in embodiment 1 ~ 4, measure its co-toxicity coefficient to wheat paddock common weed barnyard grass.
Test method: be seeded in by the seed of quantitative barnyard grass in the high Disposable paper cup of 9cm respectively, sows 12 seeds in every glass, cultivates in illumination box, when the barnyard grass 5 leaf phase, does composition spray to carry out spraying process in crawler type.Continue in greenhouse after process to cultivate, routine observation respectively processes the preventive effect to weeds, weighs the weeds fresh weight after each process after 30d, calculates its toxicity regression curve and co-toxicity coefficient.Co-toxicity coefficient is greater than 120, and show that two kinds of active principles have synergistic effect, co-toxicity coefficient is less than 80, shows that two kinds of active principles have antagonism.Measurement result is as shown in table 1.
Table 1 toxicity measurement result
As can be seen from the above table, the co-toxicity coefficient after two kinds of active principles are composite is all greater than 120, illustrates that the present invention has obvious synergistic effect.
2), field control effectiveness test
Reagent agent:
4 kinds of re-compounded binary herbicides in embodiment 1 ~ 4.
Contrast medicament:
15% clodinafop-propargyl can wet-milling (commercially available), 50% amidosulfuron water dispersible granules (commercially available).
For studying thing: wheat
Wheat seedling grows fine, robust plant, without other damage by disease and insect.
Prevent and kill off object:
The weeds such as annual bluegrass, Bermuda grass, lamb's-quarters, amaranth, smartweed.
Test method:
According to the area of experimental plot, the good various medicament of precise, and after being watered dilution, utilize knapsack sprayer, carry out even spraying, the Fan spray head that sprinkler selection weed killer herbicide is special.During spraying, liquid be noted evenly to spray application in experimental plot, accomplish the phenomenon not having drain spray, many sprays.
After test, after medicine, 20d, 40d observe weeds death condition respectively, and the activity of weeding of more various medicament.In addition, after medicine, the condition of production (consumption is the consumption of every mu of ground active ingredient) of crop also in 1 ~ 15d, to be observed, whether have poisoning to investigate medicament to crop.
Embodiments of the invention preparation Herbicidal Testing Trials effect sees the following form 2 (after medicine 20d) and table 3 (after medicine 40d)
Table 2 field control effectiveness test result (after medicine 20d)
Table 3 field control effectiveness test result (after medicine 40d)
As can be seen from the above table, Herbicidal combinations of the present invention has expansion herbicidal spectrum, improves the effect of activity of weeding, and extends the lasting period of medicament.
Table 4 medicament is to the security survey result of crop
Wheat in each process community grows fine, and has no any medicine spot, illustrates that various medicament is all safe to wheat.
Claims (10)
1. containing a compound weeding composition for clodinafop-propargyl and amidosulfuron, it is characterized in that: this Herbicidal combinations is with clodinafop-propargyl and amidosulfuron for principle active component, and wherein, the weight ratio of clodinafop-propargyl and amidosulfuron is 1 ~ 99:1 ~ 99.
2. the compound weeding composition containing clodinafop-propargyl and amidosulfuron according to claim 1, is characterized in that: in this Herbicidal combinations, the weight ratio of clodinafop-propargyl and amidosulfuron is 1 ~ 80:1 ~ 80.
3. the compound weeding composition containing clodinafop-propargyl and amidosulfuron according to claim 2, is characterized in that: in this Herbicidal combinations, the weight ratio of clodinafop-propargyl and amidosulfuron is 1 ~ 60:1 ~ 60.
4. the compound weeding composition containing clodinafop-propargyl and amidosulfuron according to claim 3, is characterized in that: in this Herbicidal combinations, the weight ratio of clodinafop-propargyl and amidosulfuron is 29 ~ 60:1 ~ 5.
5. the compound weeding composition containing clodinafop-propargyl and amidosulfuron according to any one of claim 1-4, is characterized in that: both clodinafop-propargyl and the amidosulfuron mass percentage in Herbicidal combinations is 1 ~ 80%.
6. the compound weeding composition containing clodinafop-propargyl and amidosulfuron according to claim 5, is characterized in that: both clodinafop-propargyl and the amidosulfuron mass percentage in Herbicidal combinations is 30 ~ 65%.
7. the compound weeding composition containing clodinafop-propargyl and amidosulfuron according to claim 1, is characterized in that: this compound weeding composition with clodinafop-propargyl and amidosulfuron for the auxiliary agent that principle active component and agricultural chemicals allow is mixed with any one formulation.
8. the compound weeding composition containing clodinafop-propargyl and amidosulfuron according to claim 7, is characterized in that: described formulation be missible oil, suspending agent, aqueous emulsion, microemulsion, water dispersion granule or and wetting powder in any one.
9. Herbicidal combinations according to claim 1 is for the preparation of the application in wheat paddock weeding.
10. Herbicidal combinations according to claim 1 is for the preparation of the application of preventing and kill off in wheat paddock in grassy weed and broad leaved weed.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510435181.5A CN105360148A (en) | 2015-07-22 | 2015-07-22 | Compound weeding composition containing clodinafop-propargyl and amidosulfuron and application of compound weeding composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510435181.5A CN105360148A (en) | 2015-07-22 | 2015-07-22 | Compound weeding composition containing clodinafop-propargyl and amidosulfuron and application of compound weeding composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105360148A true CN105360148A (en) | 2016-03-02 |
Family
ID=55363241
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201510435181.5A Pending CN105360148A (en) | 2015-07-22 | 2015-07-22 | Compound weeding composition containing clodinafop-propargyl and amidosulfuron and application of compound weeding composition |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105360148A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068472A (en) * | 1991-07-12 | 1993-02-03 | 赫彻斯特股份公司 | Synergistic herbicidal agents |
| WO2004008858A1 (en) * | 2002-07-23 | 2004-01-29 | Syngenta Participations Ag | Herbicidal composition |
| CN101513182A (en) * | 2009-03-26 | 2009-08-26 | 江苏长青农化股份有限公司 | Mixed herbicide of wheat after seedling |
| CN101926349A (en) * | 2010-09-13 | 2010-12-29 | 尹小根 | Weeding composition containing amidosulfuron and atrazine |
-
2015
- 2015-07-22 CN CN201510435181.5A patent/CN105360148A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1068472A (en) * | 1991-07-12 | 1993-02-03 | 赫彻斯特股份公司 | Synergistic herbicidal agents |
| WO2004008858A1 (en) * | 2002-07-23 | 2004-01-29 | Syngenta Participations Ag | Herbicidal composition |
| CN101513182A (en) * | 2009-03-26 | 2009-08-26 | 江苏长青农化股份有限公司 | Mixed herbicide of wheat after seedling |
| CN101926349A (en) * | 2010-09-13 | 2010-12-29 | 尹小根 | Weeding composition containing amidosulfuron and atrazine |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105519531A (en) | Clodinafop-propargyl and beflubutamid containing weeding composition and application thereof | |
| CN105360151A (en) | Weeding composition containing clodinafop-propargyl and flucarbazone-sodium and application of weeding composition | |
| CN105379736B (en) | A kind of compound weeding composition and its application containing clodinafop-propargyl and Flumetsulam | |
| CN104604907A (en) | Dicamba and pyributicarb herbicidal composition and application thereof | |
| CN105379718A (en) | Compound weeding composition containing clodinafop-propargyl and oxyfluorfen and application thereof | |
| CN105379742A (en) | Compound weeding composition containing clodinafop-propargyl and methabenzthiazuron and application thereof | |
| CN104604915A (en) | Dicamba and pyrazosulfuron-ethyl herbicidal composition and application thereof | |
| CN105360123A (en) | Composite weeding composition containing clodinafop-propargyl and indanofan and application of composite weeding composition | |
| CN105360122A (en) | Compound weeding composition containing clodinafop-propargyl and methoxyphenone and application of compound weeding composition | |
| CN105432621A (en) | Weeding composition containing clodinafop-propargyl and flupoxam and application thereof | |
| CN107156130A (en) | A kind of Herbicidal combinations and its application containing the bicyclic ketone of benzo and Diflufenican | |
| CN107242243A (en) | Herbicidal combinations and its application of a kind of careless amine of fluorinated ketones contained sulphur and pyridate | |
| CN105360148A (en) | Compound weeding composition containing clodinafop-propargyl and amidosulfuron and application of compound weeding composition | |
| CN105360138B (en) | A kind of compound weeding composition and its application containing clodinafop-propargyl and prometryn | |
| CN105360149A (en) | Composite weeding composition containing clodinafop-propargyl and ethoxysulfuron and application of composite weeding composition | |
| CN105360147A (en) | Compound weeding composition containing clodinafop-propargyl and halosulfuron-methyl and application of compound weeding composition | |
| CN105379732B (en) | A kind of compound weeding composition and its application containing clodinafop-propargyl and isoxaben | |
| CN105360127A (en) | Compound weeding composition containing clodinafop-propargyl and pyribenzoxim and application of compound weeding composition | |
| CN105379727A (en) | Compound weeding composition containing clodinafop-propargyl and difenzoquat and application thereof | |
| CN105360124A (en) | Weeding composition containing clodinafop-propargyl and flamprop-methyl and application of weeding composition | |
| CN105360126A (en) | Weeding composition containing clodinafop-propargyl and flamprop-isopropyl and application of weeding composition | |
| CN105379743A (en) | Compound weeding composition containing clodinafop-propargyl and triasulfuron and application thereof | |
| CN104604872A (en) | Dicamba and metazachlor herbicidal composition and application thereof | |
| CN104604913A (en) | Herbicide composition containing dicamba and imazosulfuron, and applications thereof | |
| CN105379716A (en) | Compound weeding composition containing clodinafop-propargyl and cinidon-ethyl and application thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160302 |