CN105349976B - A kind of surface of aluminum plate handling process - Google Patents

A kind of surface of aluminum plate handling process Download PDF

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Publication number
CN105349976B
CN105349976B CN201510747993.3A CN201510747993A CN105349976B CN 105349976 B CN105349976 B CN 105349976B CN 201510747993 A CN201510747993 A CN 201510747993A CN 105349976 B CN105349976 B CN 105349976B
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aluminum plate
aluminium sheet
parts
passivation
treatment
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CN105349976A (en
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张枫
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Henan Xirang Industrial Design Co ltd
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Anhui Feng Hui Metallgesellschaft AG
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/24Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing hexavalent chromium compounds
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/78Pretreatment of the material to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/82After-treatment
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/20Use of solutions containing silanes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)

Abstract

The present invention relates to a kind of surface of aluminum plate handling process, comprise the following steps:(1), aluminium sheet cleaned;(2), aluminium sheet Passivation Treatment;(3), spray-applied primer;(4), spray paint;The method of the present invention is when handling aluminium sheet, first wiped after cleaning using silver oxide and kerosene, the foreign matter of surface of aluminum plate can be removed, the consistency of uniformity and passivation layer when and can enough lifts follow-up passivation, and after handling, the thickness of passivation layer can be increased, greatly promote the Corrosion Protection of aluminium sheet and the flatness of surface of aluminum plate after passivation;Spray paint again after passivation, the anti-corrosive properties of aluminium are further lifted, its aesthetic property can also be lifted, handled before passivation using silver oxide and kerosene, the uniformity of spray painting and the fastness of bonding can be lifted.

Description

A kind of surface of aluminum plate handling process
Technical field
The invention belongs to field of metal surface treatment, and in particular to a kind of surface of aluminum plate handling process.
Background technology
Aluminium and aluminium alloy are that current applications are quite varied, one of most economical applicable material.World aluminum yield is from 1956 Year begins to exceed copper yield and occupied always first of non-ferrous metal.The yield and dosage of current aluminium(Calculated by ton)Steel are only second to, into For the second largest metal of mankind's application;And the resource very abundant of aluminium, according to primary Calculation, the mineral reserve storage capacity of aluminium accounts for the earth's crust Form more than the 8% of material.Aluminium is widely used, now needs to be surface-treated when in use.
The content of the invention
It is an object of the invention to provide a kind of surface of aluminum plate handling process, processing, the lifting such as it is passivated to surface of aluminum plate The antiseptic property of aluminium sheet.
A kind of surface of aluminum plate handling process, comprises the following steps:
(1), by surface of aluminum plate be put into soaking compartment using 40 DEG C, mass fraction be 3-4% sodium bicarbonate solution immersion at 60-72s is managed, then wipes surface of aluminum plate using soft cloth, and rinse well using clear water;
(2), by step(1)The surface of aluminum plate handled well is dried at a temperature of 30-40 DEG C, is then uniformly sprayed in surface of aluminum plate Spill silver oxide powder, fountain height 55-62g/m2, then using being moistened with the soft cloth of kerosene to being sprayed with the aluminium sheet of silver oxide powder Wiped, pressure during wiping is 0.35-0.42MPa, and the wiping time is 5-8min;
(3), by step(2)At the sodium bicarbonate solution immersion that the aluminium sheet handled well uses 28 DEG C, mass fraction is 3-4% 3-5min is managed, is then cleaned using deionized water, deionized water temperature is 22-28 DEG C;
(4), the aluminium sheet for handling above-mentioned steps well uses inactivating treatment liquid in 25-32 DEG C of Passivation Treatment 25-33min;
(5), by Passivation Treatment complete aluminium sheet using deionized water rinsing it is clean, dried at 35-40 DEG C;
(6), surface of aluminum plate sprayed using epoxy zinc chromate primer, during spraying, priming paint:Solidifying priming paint agent:The weight of diluent Amount ratio is 7:2:0.2;Dried after spraying at 35 DEG C;
(7) aluminium sheet, is handled into 10-15min at 50-55 DEG C, then spray paint.
Preferably, the inactivating treatment liquid includes treatment fluid A and treatment fluid B, silane coupler mass concentration in treatment fluid A It is water for 1.2-1.5%, mixed amine mass concentration 4.3-5.8%, dimethylformamide mass concentration 1.5-3% surpluses;Treatment fluid B The mass concentration of middle sodium dichromate is 8-15%, and surplus is water, and regulation pH is 4.5-6;In use, first use treatment fluid A processing 10-15min, then using treatment fluid B processing.
Preferably, the finish paint is made up of following component by weight:Urethane acrylate 25-30 parts, hydroxy Acid resin 15-22 parts, aqueous epoxy resins 12-15 parts, ethylene glycol ether acetate 15-20 parts, diluent 50-65 parts, levelling Agent 1-2 parts, curing agent 1-2 parts, defoamer 0.5-1 parts.The paint spraying of the formula through silver peroxide with handling post-passivation Caking property is more preferable on aluminium sheet, can prevent from painting bubble, come off.
The diluent, levelling agent, curing agent and defoamer can use reagent commonly used in the art.
A small amount of conventional dissolving adjuvants can be used when in the present invention prepared by reagent, cosolvent usage amount is less than 5%.
Beneficial effects of the present invention:The present invention method when handling aluminium sheet, first after cleaning using silver oxide with Kerosene is wiped, and can remove the foreign matter of surface of aluminum plate, the cause of uniformity and passivation layer when and can enough lifts follow-up passivation Density, and after handling, the thickness of passivation layer can be increased, greatly promote aluminium sheet Corrosion Protection and passivation after surface of aluminum plate Flatness;Spray paint again after passivation, the anti-corrosive properties of aluminium are further lifted, its aesthetic property can also be lifted, be passivated It is preceding to be handled using silver oxide and kerosene, the uniformity of spray painting and the fastness of bonding can be lifted.
Temperature and time control in the present invention in Passivation Treatment step, has very big to the Passivation Treatment effect of aluminium sheet Influenceing, the present invention also demonstrates different temperatures and time control, in the case where changing temperature and time, carries out salt spray test, As a result after display condition changes, the salt spray test time shortens in the range of 100-263h, illustrates that the condition control of the present invention produces Fabulous effect.
Embodiment
Embodiment 1
A kind of surface of aluminum plate handling process, comprises the following steps:
(1), by surface of aluminum plate be put into soaking compartment using 40 DEG C, mass fraction be 3.5% sodium bicarbonate solution immersion at 65s is managed, then wipes surface of aluminum plate using soft cloth, and rinse well using clear water;
(2), by step(1)The surface of aluminum plate handled well is dried at a temperature of 32 DEG C, is then uniformly sprayed in surface of aluminum plate Silver oxide powder, fountain height 58g/m2, then the aluminium sheet for being sprayed with silver oxide powder is carried out using the soft cloth for being moistened with kerosene Wipe, pressure during wiping is 0.4MPa, and the wiping time is 6min;
(3), by step(2)At the sodium bicarbonate solution immersion that the aluminium sheet handled well uses 28 DEG C, mass fraction is 3-4% 3min is managed, is then cleaned using deionized water, deionized water temperature is 25 DEG C;
(4), the aluminium sheet for handling above-mentioned steps well uses inactivating treatment liquid in 28 DEG C of Passivation Treatment 28min;
(5), by Passivation Treatment complete aluminium sheet using deionized water rinsing it is clean, dried at 36 DEG C;
(6), surface of aluminum plate sprayed using epoxy zinc chromate primer, during spraying, priming paint:Solidifying priming paint agent:The weight of diluent Amount ratio is 7:2:0.2;Dried after spraying at 35 DEG C;
(7) aluminium sheet, is handled into 10-15min at 50-55 DEG C, then spray paint.
The inactivating treatment liquid includes treatment fluid A and treatment fluid B, in treatment fluid A silane coupler mass concentration be 1.5%, Mixed amine mass concentration 4.8%, the surplus of dimethylformamide mass concentration 2% are water;The mass concentration of sodium dichromate in treatment fluid B For 12%, surplus is water, and regulation pH is 6;In use, first using treatment fluid A processing 15min, then using treatment fluid B processing.
The finish paint is made up of following component by weight:28 parts of urethane acrylate, 20 parts of Hydroxylated acrylic resin, 12 parts of aqueous epoxy resins, 16 parts of ethylene glycol ether acetate, 55 parts of diluent, 1.2 parts of levelling agent, 1.5 parts of curing agent, defoaming 0.75 part of agent.
Embodiment 2
A kind of surface of aluminum plate handling process, comprises the following steps:
(1), by surface of aluminum plate be put into soaking compartment using 40 DEG C, mass fraction be 3.5% sodium bicarbonate solution immersion at 64s is managed, then wipes surface of aluminum plate using soft cloth, and rinse well using clear water;
(2), by step(1)The surface of aluminum plate handled well is dried at a temperature of 32 DEG C, is then uniformly sprayed in surface of aluminum plate Silver oxide powder, fountain height 59g/m2, then the aluminium sheet for being sprayed with silver oxide powder is carried out using the soft cloth for being moistened with kerosene Wipe, pressure during wiping is 0.4MPa, and the wiping time is 7min;
(3), by step(2)The aluminium sheet handled well uses 28 DEG C, the sodium bicarbonate solution immersion treatment that mass fraction is 4% 3min, then cleaned using deionized water, deionized water temperature is 26 DEG C;
(4), the aluminium sheet for handling above-mentioned steps well uses inactivating treatment liquid in 28 DEG C of Passivation Treatment 30min;
(5), by Passivation Treatment complete aluminium sheet using deionized water rinsing it is clean, dried at 36 DEG C;
(6), surface of aluminum plate sprayed using epoxy zinc chromate primer, during spraying, priming paint:Solidifying priming paint agent:The weight of diluent Amount ratio is 7:2:0.2;Dried after spraying at 35 DEG C;
(7) aluminium sheet, is handled into 10-15min at 50-55 DEG C, then spray paint.
Preferably, the inactivating treatment liquid includes treatment fluid A and treatment fluid B, silane coupler mass concentration in treatment fluid A It is water for 1.5%, mixed amine mass concentration 5%, the surplus of dimethylformamide mass concentration 1.8%;Sodium dichromate in treatment fluid B Mass concentration is 12%, and surplus is water, and regulation pH is 5.5;In use, first using treatment fluid A processing 13min, then using processing Liquid B processing.
The finish paint is made up of following component by weight:30 parts of urethane acrylate, 20 parts of Hydroxylated acrylic resin, 14 parts of aqueous epoxy resins, 18 parts of ethylene glycol ether acetate, 60 parts of diluent, 1.5 parts of levelling agent, 1.6 parts of curing agent, defoaming 0.8 part of agent.

Claims (3)

1. a kind of surface of aluminum plate handling process, it is characterised in that comprise the following steps:
(1), by surface of aluminum plate be put into soaking compartment using 40 DEG C, mass fraction be 3-4% sodium bicarbonate solution immersion treatment 60-72s, surface of aluminum plate then is wiped using soft cloth, and rinsed well using clear water;
(2), by step(1)The surface of aluminum plate handled well is dried at a temperature of 30-40 DEG C, then uniformly sprays oxygen in surface of aluminum plate Change silver powder, fountain height 55-62g/m2, then the aluminium sheet for being sprayed with silver oxide powder is carried out using the soft cloth for being moistened with kerosene Wipe, pressure during wiping is 0.35-0.42MPa, and the wiping time is 5-8min;
(3), by step(2)The aluminium sheet handled well uses 28 DEG C, the sodium bicarbonate solution immersion treatment 3- that mass fraction is 3-4% 5min, then cleaned using deionized water, deionized water temperature is 22-28 DEG C;
(4), the aluminium sheet for handling above-mentioned steps well uses inactivating treatment liquid in 25-32 DEG C of Passivation Treatment 25-33min;
(5), by Passivation Treatment complete aluminium sheet using deionized water rinsing it is clean, dried at 35-40 DEG C;
(6), surface of aluminum plate sprayed using epoxy zinc chromate primer, during spraying, priming paint:Solidifying priming paint agent:The weight ratio of diluent Example is 7:2:0.2;Dried after spraying at 35 DEG C;
(7) aluminium sheet, is handled into 10-15min at 50-55 DEG C, then spray paint.
2. a kind of surface of aluminum plate handling process according to claim 1, it is characterised in that the inactivating treatment liquid includes place Manage liquid A and treatment fluid B, in treatment fluid A silane coupler mass concentration be 1.2-1.5%, mixed amine mass concentration 4.3-5.8%, Dimethylformamide mass concentration 1.5-3%, surplus are water;The mass concentration of sodium dichromate is 8-15% in treatment fluid B, and surplus is Water, regulation pH are 4.5-6;In use, first using treatment fluid A processing 10-15min, then using treatment fluid B processing.
3. a kind of surface of aluminum plate handling process according to claim 1 or 2, it is characterised in that the finish paint is by weight It is made up of following component:Urethane acrylate 25-30 parts, Hydroxylated acrylic resin 15-22 parts, aqueous epoxy resins 12-15 Part, ethylene glycol ether acetate 15-20 parts, diluent 50-65 parts, levelling agent 1-2 parts, curing agent 1-2 parts, defoamer 0.5-1 Part.
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CN106086844A (en) * 2016-06-18 2016-11-09 安徽昊博健身器材有限公司 A kind of surface treatment method of aluminum
CN106048628A (en) * 2016-06-18 2016-10-26 安徽昊博健身器材有限公司 Surface treatment method for aluminum alloy fastener
CN106086845A (en) * 2016-06-18 2016-11-09 安徽昊博健身器材有限公司 A kind of surface treatment method of 4A01 aluminium alloy
CN108103492A (en) * 2017-12-29 2018-06-01 重庆全茂合渝科技有限公司 A kind of clutch of motorcycle gear shift arm Anticorrosion measure
CN108480169A (en) * 2018-04-26 2018-09-04 宁夏坚盾幕墙工程有限公司 A kind of process of surface treatment of aluminum veneer
CN108816708A (en) * 2018-07-06 2018-11-16 嘉兴市皇能厨卫科技有限公司 A kind of process of surface treatment of aluminium sheet
CN111013988A (en) * 2019-12-20 2020-04-17 江苏佰大铝业科技有限公司 Surface treatment process of aluminum veneer for curtain wall
CN112246570A (en) * 2020-10-22 2021-01-22 海南博展实业有限公司 Surface waterproof treatment method for thin aluminum plate
CN112281197A (en) * 2020-11-03 2021-01-29 湖南昕泰装饰材料有限公司 Method for manufacturing surface-treated aluminum material
CN113198712A (en) * 2021-04-19 2021-08-03 江苏安工幕墙新材料有限公司 Paint-dropping-preventing aluminum plate surface spraying process

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CN104975280A (en) * 2015-07-01 2015-10-14 江西飞达新材料科技股份有限公司 Cold-rolled steel sheet passivating treatment method

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CN103447220A (en) * 2013-08-13 2013-12-18 河南辉龙铝业股份有限公司 Aluminum profile spraying process
CN104148258A (en) * 2014-07-21 2014-11-19 浙江德清森朗装饰材料有限公司 Fluorocarbon aluminum panel manufacturing technique
CN104498920A (en) * 2014-11-28 2015-04-08 安徽华灿彩钢薄板科技有限公司 Color steel plate processing method
CN104975280A (en) * 2015-07-01 2015-10-14 江西飞达新材料科技股份有限公司 Cold-rolled steel sheet passivating treatment method

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