CN105348790A - Environmental-friendly high-hardness high-toughness heat-conducting electroconductive plastic - Google Patents
Environmental-friendly high-hardness high-toughness heat-conducting electroconductive plastic Download PDFInfo
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- C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
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- C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
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Abstract
Environmental-friendly high-hardness high-toughness heat-conducting electroconductive plastic is disclosed. Raw materials of the plastic comprise nylon 66, furfuryl alcohol resin, polyvinyl chloride, polystyrene, titanium magnesium alloy powder, carbon black, calcium oxide, bamboo fiber, barium oxide, methyl laurate, epoxidized vegetable oil, glycerol, polyethylene glycol, polytetrafluoroethylene, sodium allysulfonate, alkyl quaternary ammonium salts, methyl acrylate, n-propyl acrylate, magnesium stearate, didodecanol ester, an antioxidant 1098, an adhesive, a foaming agent, a thickening agent, a dispersing agent, nanometer calcium carbonate and oxidized polypropylene ester. The plastic is high in hardness, good in toughness, heat-conducting and electroconductive.
Description
Technical field
The present invention relates to a kind of heat-conductivity conducting plastics, particularly relate to a kind of environment protection high hardness high tenacity heat-conductivity conducting plastics.
Background technology
Along with the fast development of electronic apparatus industrial technology, electronics is constantly by more powerful function i ntegration to more widgets, and operating frequency sharply increases, the heat run-up of equipment, temperature controls to have become one of vital challenge in design, namely tightens, when operating space is more and more less at framework, how effectively to take away more heats that larger unit power produces, ensure that the running of whole equipment normal table has become the key point of problem.
Because plastics are high at design freedom, the light and cost of easy-formation processing, quality low etc. in advantage, people urgently wish more by plastic applications in electronic apparatus industry.But the thermal conductivity of most of plastics is very little, affect their application, particularly need the occasion of good heat conductive performance at some.
Meanwhile, heat-conducting plastic in use, require that it has excellent conductivity, but existing heat-conducting plastic cannot meet in actual use procedure for the demand while heat conduction with conductivity simultaneously.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes a kind of environment protection high hardness high tenacity heat-conductivity conducting plastics, and hardness is high, good toughness, and has conduction and heat conductivility.
A kind of environment protection high hardness high tenacity heat-conductivity conducting plastics that the present invention proposes, its raw material comprises by weight: nylon66 fiber 45-85 part, furfuryl alcohol resin 30-60 part, polyvinyl chloride 10-50 part, polystyrene 5-15 part, titanium magnesium alloy powder 2-8 part, carbon black 3-9 part, calcium oxide 2-7 part, bamboo fibers 4-9 part, barium oxide 2-8 part, Laurate methyl 4-9 part, epoxidized vegetable oil 2-9 part, glycerol 4-9 part, polyoxyethylene glycol 1-6 part, tetrafluoroethylene 2-6 part, sodium allyl sulfonate 2-5 part, alkyl quaternary ammonium salts 1-3 part, methyl acrylate 2-8 part, n-propyl 1-6 part, Magnesium Stearate 2-5 part, two Lauryl Alcohol ester 3-8 part, oxidation inhibitor 10981-5 part, tackiness agent 2-8 part, whipping agent 3-9 part, thickening material 4-8 part, dispersion agent 1-8 part, nano-calcium carbonate 2-9 part, its chlorinated polypropylene ester 3-6 part.
Preferably, the weight ratio of polyvinyl chloride and polystyrene is 15-45:8-12.
Preferably, carbon black in the weight ratio of calcium oxide be 4-8:3-6.
Preferably, in titanium magnesium alloy powder, the content of titanium is 30-50%, and the content of magnesium is 35-55%.
Preferably, the mass percent of two Lauryl Alcohol ester is 43-50%.
Preferably, its raw material comprises by weight: nylon66 fiber 50-80 part, furfuryl alcohol resin 35-55 part, polyvinyl chloride 15-45 part, polystyrene 8-12 part, titanium magnesium alloy powder 3-7 part, carbon black 4-8 part, calcium oxide 3-6 part, bamboo fibers 5-8 part, barium oxide 3-7 part, Laurate methyl 5-8 part, epoxidized vegetable oil 3-8 part, glycerol 5-8 part, polyoxyethylene glycol 2-5 part, tetrafluoroethylene 3-5 part, sodium allyl sulfonate 3-4 part, alkyl quaternary ammonium salts 1.5-2.5 part, methyl acrylate 3-7 part, n-propyl 2-5 part, Magnesium Stearate 3-4 part, two Lauryl Alcohol ester 4-7 part, oxidation inhibitor 10982-4 part, tackiness agent 3-7 part, whipping agent 4-8 part, thickening material 5-7 part, dispersion agent 2-7 part, nano-calcium carbonate 3-8 part, its chlorinated polypropylene ester 4-5 part.
Preferably, its raw material comprises by weight: nylon66 fiber 65 parts, furfuryl alcohol resin 45 parts, polyvinyl chloride 30 parts, polystyrene 10 parts, 5 parts, titanium magnesium alloy powder, carbon black 6 parts, 4.5 parts, calcium oxide, bamboo fibers 6.5 parts, 5 parts, barium oxide, Laurate methyl 6.5 parts, epoxidized vegetable oil 5.5 parts, glycerol 6.5 parts, polyoxyethylene glycol 3.5 parts, tetrafluoroethylene 4 parts, sodium allyl sulfonate 3.5 parts, alkyl quaternary ammonium salts 2 parts, methyl acrylate 5 parts, n-propyl 3.5 parts, Magnesium Stearate 3.5 parts, two Lauryl Alcohol ester 5.5 parts, 10983 parts, oxidation inhibitor, 5 parts, tackiness agent, whipping agent 6 parts, thickening material 6 parts, dispersion agent 4.5 parts, nano-calcium carbonate 5.5 parts, its chlorinated polypropylene ester 4.5 parts.
A kind of environment protection high hardness high tenacity heat-conductivity conducting plastics of the present invention, its raw material comprises: nylon66 fiber, furfuryl alcohol resin, polyvinyl chloride, polystyrene, titanium magnesium alloy powder, carbon black, calcium oxide, bamboo fibers, barium oxide, Laurate methyl, epoxidized vegetable oil, glycerol, polyoxyethylene glycol, tetrafluoroethylene, sodium allyl sulfonate, alkyl quaternary ammonium salts, methyl acrylate, n-propyl, Magnesium Stearate, two Lauryl Alcohol ester, oxidation inhibitor 1098, tackiness agent, whipping agent, thickening material, dispersion agent, nano-calcium carbonate and its chlorinated polypropylene ester, wherein, with nylon66 fiber and furfuryl resin for major ingredient, auxiliaryly add polyvinyl chloride, polystyrene, titanium magnesium alloy powder, carbon black, calcium oxide, bamboo fibers, barium oxide, Laurate methyl, epoxidized vegetable oil, glycerol, polyoxyethylene glycol, tetrafluoroethylene, sodium allyl sulfonate, alkyl quaternary ammonium salts, methyl acrylate, n-propyl, Magnesium Stearate, two Lauryl Alcohol ester, oxidation inhibitor 1098, tackiness agent, whipping agent, thickening material, dispersion agent, nano-calcium carbonate and its chlorinated polypropylene ester are as auxiliary material, and the proportioning of conservative control major ingredient and auxiliary material, makes environment protection high hardness high tenacity heat-conductivity conducting plastics of the present invention have excellent heat conduction and conductivity, and have high rigidity and toughness properties.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In embodiment, the weight part of nylon66 fiber can be 45 parts, 50 parts, 55 parts, 60 parts, 65 parts, 70 parts, 75 parts, 80 parts, 85 parts; The weight part of furfuryl alcohol resin can be 30 parts, 35 parts, 40 parts, 45 parts, 50 parts, 55 parts, 60 parts; The weight part of polyvinyl chloride can be 10 parts, 15 parts, 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts; The weight part of polystyrene can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; The weight part of titanium magnesium alloy powder can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of carbon black can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of calcium oxide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts; The weight part of bamboo fibers can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; Barytic weight part can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of Laurate methyl can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of epoxidized vegetable oil can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of glycerol can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of polyoxyethylene glycol can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of tetrafluoroethylene can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of sodium allyl sulfonate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of alkyl quaternary ammonium salts can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts; The weight part of methyl acrylate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of n-propyl can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of Magnesium Stearate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of two Lauryl Alcohol ester can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts; The weight part of oxidation inhibitor 1098 can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of tackiness agent can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of whipping agent can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of thickening material can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of dispersion agent can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts; The weight part of nano-calcium carbonate can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of its chlorinated polypropylene ester can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts.
Embodiment 1
A kind of environment protection high hardness high tenacity heat-conductivity conducting plastics that the present invention proposes, its raw material comprises by weight: nylon66 fiber 65 parts, furfuryl alcohol resin 45 parts, polyvinyl chloride 30 parts, polystyrene 10 parts, 5 parts, titanium magnesium alloy powder, carbon black 6 parts, 4.5 parts, calcium oxide, bamboo fibers 6.5 parts, 5 parts, barium oxide, Laurate methyl 6.5 parts, epoxidized vegetable oil 5.5 parts, glycerol 6.5 parts, polyoxyethylene glycol 3.5 parts, tetrafluoroethylene 4 parts, sodium allyl sulfonate 3.5 parts, alkyl quaternary ammonium salts 2 parts, methyl acrylate 5 parts, n-propyl 3.5 parts, Magnesium Stearate 3.5 parts, two Lauryl Alcohol ester 5.5 parts, 10983 parts, oxidation inhibitor, 5 parts, tackiness agent, whipping agent 6 parts, thickening material 6 parts, dispersion agent 4.5 parts, nano-calcium carbonate 5.5 parts, its chlorinated polypropylene ester 4.5 parts.
Wherein, in titanium magnesium alloy powder, the content of titanium is 40%, and the content of magnesium is 45%.
Embodiment 2
A kind of environment protection high hardness high tenacity heat-conductivity conducting plastics that the present invention proposes, its raw material comprises by weight: nylon66 fiber 45 parts, furfuryl alcohol resin 60 parts, polyvinyl chloride 10 parts, polystyrene 15 parts, 2 parts, titanium magnesium alloy powder, carbon black 9 parts, 2 parts, calcium oxide, bamboo fibers 9 parts, 2 parts, barium oxide, Laurate methyl 9 parts, epoxidized vegetable oil 2 parts, glycerol 9 parts, polyoxyethylene glycol 1 part, tetrafluoroethylene 6 parts, sodium allyl sulfonate 2 parts, alkyl quaternary ammonium salts 3 parts, methyl acrylate 2 parts, n-propyl 6 parts, Magnesium Stearate 2 parts, mass percent is two Lauryl Alcohol esters 3 parts of 50%, 10985 parts, oxidation inhibitor, 2 parts, tackiness agent, whipping agent 9 parts, thickening material 4 parts, dispersion agent 8 parts, nano-calcium carbonate 2 parts, its chlorinated polypropylene ester 6 parts.
Wherein, in titanium magnesium alloy powder, the content of titanium is 30%, and the content of magnesium is 55%.
Embodiment 3
A kind of environment protection high hardness high tenacity heat-conductivity conducting plastics that the present invention proposes, its raw material comprises by weight: nylon66 fiber 85 parts, furfuryl alcohol resin 30 parts, polyvinyl chloride 50 parts, polystyrene 5 parts, 8 parts, titanium magnesium alloy powder, carbon black 3 parts, 7 parts, calcium oxide, bamboo fibers 4 parts, 8 parts, barium oxide, Laurate methyl 4 parts, epoxidized vegetable oil 9 parts, glycerol 4 parts, polyoxyethylene glycol 6 parts, tetrafluoroethylene 2 parts, sodium allyl sulfonate 5 parts, alkyl quaternary ammonium salts 1 part, methyl acrylate 8 parts, n-propyl 1 part, Magnesium Stearate 5 parts, mass percent is two Lauryl Alcohol esters 8 parts of 43%, 10981 parts, oxidation inhibitor, 8 parts, tackiness agent, whipping agent 3 parts, thickening material 8 parts, dispersion agent 1 part, nano-calcium carbonate 9 parts, its chlorinated polypropylene ester 3 parts.
Wherein, in titanium magnesium alloy powder, the content of titanium is 50%, and the content of magnesium is 35%.
Embodiment 4
A kind of environment protection high hardness high tenacity heat-conductivity conducting plastics that the present invention proposes, its raw material comprises by weight: nylon66 fiber 50 parts, furfuryl alcohol resin 55 parts, polyvinyl chloride 15 parts, polystyrene 12 parts, 3 parts, titanium magnesium alloy powder, carbon black 8 parts, 3 parts, calcium oxide, bamboo fibers 8 parts, 3 parts, barium oxide, Laurate methyl 8 parts, epoxidized vegetable oil 3 parts, glycerol 8 parts, polyoxyethylene glycol 2 parts, tetrafluoroethylene 5 parts, sodium allyl sulfonate 3 parts, alkyl quaternary ammonium salts 2.5 parts, methyl acrylate 3 parts, n-propyl 5 parts, Magnesium Stearate 3 parts, two Lauryl Alcohol ester 7 parts, 10982 parts, oxidation inhibitor, 7 parts, tackiness agent, whipping agent 4 parts, thickening material 7 parts, dispersion agent 2 parts, nano-calcium carbonate 8 parts, its chlorinated polypropylene ester 4 parts.
Wherein, in titanium magnesium alloy powder, the content of titanium is 45%, and the content of magnesium is 38%.
Embodiment 5
A kind of environment protection high hardness high tenacity heat-conductivity conducting plastics that the present invention proposes, its raw material comprises by weight: nylon66 fiber 80 parts, furfuryl alcohol resin 35 parts, polyvinyl chloride 45 parts, polystyrene 8 parts, 7 parts, titanium magnesium alloy powder, carbon black 4 parts, 6 parts, calcium oxide, bamboo fibers 5 parts, 7 parts, barium oxide, Laurate methyl 5 parts, epoxidized vegetable oil 8 parts, glycerol 5 parts, polyoxyethylene glycol 5 parts, tetrafluoroethylene 3 parts, sodium allyl sulfonate 4 parts, alkyl quaternary ammonium salts 1.5 parts, methyl acrylate 7 parts, n-propyl 2 parts, Magnesium Stearate 4 parts, two Lauryl Alcohol ester 4 parts, 10984 parts, oxidation inhibitor, 3 parts, tackiness agent, whipping agent 8 parts, thickening material 5 parts, dispersion agent 7 parts, nano-calcium carbonate 3 parts, its chlorinated polypropylene ester 5 parts.
Wherein, in titanium magnesium alloy powder, the content of titanium is 45%, and the content of magnesium is 38%.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.
Claims (7)
1. environment protection high hardness high tenacity heat-conductivity conducting plastics, it is characterized in that, its raw material comprises by weight: nylon66 fiber 45-85 part, furfuryl alcohol resin 30-60 part, polyvinyl chloride 10-50 part, polystyrene 5-15 part, titanium magnesium alloy powder 2-8 part, carbon black 3-9 part, calcium oxide 2-7 part, bamboo fibers 4-9 part, barium oxide 2-8 part, Laurate methyl 4-9 part, epoxidized vegetable oil 2-9 part, glycerol 4-9 part, polyoxyethylene glycol 1-6 part, tetrafluoroethylene 2-6 part, sodium allyl sulfonate 2-5 part, alkyl quaternary ammonium salts 1-3 part, methyl acrylate 2-8 part, n-propyl 1-6 part, Magnesium Stearate 2-5 part, two Lauryl Alcohol ester 3-8 part, oxidation inhibitor 10981-5 part, tackiness agent 2-8 part, whipping agent 3-9 part, thickening material 4-8 part, dispersion agent 1-8 part, nano-calcium carbonate 2-9 part, its chlorinated polypropylene ester 3-6 part.
2. environment protection high hardness high tenacity heat-conductivity conducting plastics according to claim 1, is characterized in that, the weight ratio of polyvinyl chloride and polystyrene is 15-45:8-12.
3. environment protection high hardness high tenacity heat-conductivity conducting plastics according to claim 1 and 2, is characterized in that, carbon black in the weight ratio of calcium oxide be 4-8:3-6.
4. the environment protection high hardness high tenacity heat-conductivity conducting plastics according to any one of claim 1-3, it is characterized in that, in titanium magnesium alloy powder, the content of titanium is 30-50%, and the content of magnesium is 35-55%.
5. the environment protection high hardness high tenacity heat-conductivity conducting plastics according to any one of claim 1-4, is characterized in that, the mass percent of two Lauryl Alcohol ester is 43-50%.
6. the environment protection high hardness high tenacity heat-conductivity conducting plastics according to any one of claim 1-5, it is characterized in that, its raw material comprises by weight: nylon66 fiber 50-80 part, furfuryl alcohol resin 35-55 part, polyvinyl chloride 15-45 part, polystyrene 8-12 part, titanium magnesium alloy powder 3-7 part, carbon black 4-8 part, calcium oxide 3-6 part, bamboo fibers 5-8 part, barium oxide 3-7 part, Laurate methyl 5-8 part, epoxidized vegetable oil 3-8 part, glycerol 5-8 part, polyoxyethylene glycol 2-5 part, tetrafluoroethylene 3-5 part, sodium allyl sulfonate 3-4 part, alkyl quaternary ammonium salts 1.5-2.5 part, methyl acrylate 3-7 part, n-propyl 2-5 part, Magnesium Stearate 3-4 part, two Lauryl Alcohol ester 4-7 part, oxidation inhibitor 10982-4 part, tackiness agent 3-7 part, whipping agent 4-8 part, thickening material 5-7 part, dispersion agent 2-7 part, nano-calcium carbonate 3-8 part, its chlorinated polypropylene ester 4-5 part.
7. the environment protection high hardness high tenacity heat-conductivity conducting plastics according to any one of claim 1-6, it is characterized in that, its raw material comprises by weight: nylon66 fiber 65 parts, furfuryl alcohol resin 45 parts, polyvinyl chloride 30 parts, polystyrene 10 parts, 5 parts, titanium magnesium alloy powder, carbon black 6 parts, 4.5 parts, calcium oxide, bamboo fibers 6.5 parts, 5 parts, barium oxide, Laurate methyl 6.5 parts, epoxidized vegetable oil 5.5 parts, glycerol 6.5 parts, polyoxyethylene glycol 3.5 parts, tetrafluoroethylene 4 parts, sodium allyl sulfonate 3.5 parts, alkyl quaternary ammonium salts 2 parts, methyl acrylate 5 parts, n-propyl 3.5 parts, Magnesium Stearate 3.5 parts, two Lauryl Alcohol ester 5.5 parts, 10983 parts, oxidation inhibitor, 5 parts, tackiness agent, whipping agent 6 parts, thickening material 6 parts, dispersion agent 4.5 parts, nano-calcium carbonate 5.5 parts, its chlorinated polypropylene ester 4.5 parts.
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| CN106751186A (en) * | 2016-12-12 | 2017-05-31 | 天长市康宁塑胶科技有限公司 | A kind of high hardness high toughness modified plastic rubber material |
| CN108359194A (en) * | 2018-03-29 | 2018-08-03 | 合肥博之泰电子科技有限公司 | A kind of anti-aging conductive plastics and preparation method thereof |
| CN110894356A (en) * | 2019-11-29 | 2020-03-20 | 苏州润佳高分子材料有限公司 | High-strength modified nylon material for automobile |
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| CN106751186A (en) * | 2016-12-12 | 2017-05-31 | 天长市康宁塑胶科技有限公司 | A kind of high hardness high toughness modified plastic rubber material |
| CN108359194A (en) * | 2018-03-29 | 2018-08-03 | 合肥博之泰电子科技有限公司 | A kind of anti-aging conductive plastics and preparation method thereof |
| CN110894356A (en) * | 2019-11-29 | 2020-03-20 | 苏州润佳高分子材料有限公司 | High-strength modified nylon material for automobile |
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Application publication date: 20160224 |