CN105348730A - Polyphenyl ether-modified environmental-friendly plastic used for electric appliance plastic elements - Google Patents

Polyphenyl ether-modified environmental-friendly plastic used for electric appliance plastic elements Download PDF

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CN105348730A
CN105348730A CN201510779098.XA CN201510779098A CN105348730A CN 105348730 A CN105348730 A CN 105348730A CN 201510779098 A CN201510779098 A CN 201510779098A CN 105348730 A CN105348730 A CN 105348730A
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parts
polyphenyl ether
weight
auxiliary agent
polyphenylether
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梁晓燕
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ANHUI GUANGYUAN TECHNOLOGY DEVELOPMENT Co Ltd
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ANHUI GUANGYUAN TECHNOLOGY DEVELOPMENT Co Ltd
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Abstract

Polyphenyl ether-modified environmental-friendly plastic used for electric appliance plastic elements is disclosed and comprises following raw materials by weight: 60-120 parts of polyphenyl ether modified phenolic resin, 15-35 parts of ABS resin, 5-15 parts of polypropylene, 2-8 parts of polyethylene, 1-6 parts of bamboo fiber, 2-8 parts of silicon carbide, 1-4 parts of silica powder, 2-5 parts of nanometer attapulgite, 3-9 parts of light calcium carbonate, 1-5 parts of chitin, 2-6 parts of ethanediol, 3-6 parts of carboxylated polyether, 1-5 parts of polycarbonate, 2-5 parts of butyl acetate, 3-8 parts of zinc stearate, 1-5 parts of chlorinated paraffin and 2-7 parts of auxiliary agents. The plastic is environmental friendly and is excellent in toughness, impact resistance and heat resistance.

Description

The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component
Technical field
The present invention relates to a kind of environmentally-friendly plastic, particularly relate to the polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component.
Background technology
Without any hydrolyzable group in polyphenylene oxide molecular structure, make it have very outstanding water tolerance, it put in people's boiling water after 7200h, its tensile strength, elongation, shock strength all obviously do not decline.Its molecular chain without significant polarity, therefore electrical insulating property also fine river.Containing a large amount of phenolic group aromatic nucleus in the main chain of polyphenylene oxide in addition, and enclose the active site at 2 ortho positions on phenolic group due to 2 methyl, cause molecular chain itself have higher rigidity and intermolecularly have high cohesive force.Sauerstoffatom and phenyl ring are in p-π and grip state altogether, and the kindliness that Sauerstoffatom is provided reduces greatly by the phenyl ring with 2 methyl affects, and therefore polyphenylene oxide has better thermostability and chemical resistance.Because the alkyl in the end group of polyphenylene oxide can participate in the reaction of phenol and formaldehyde, so can be used for modified phenolic resins.With the resol that it is modified, not only can improve the thermotolerance of resol, the chemical resistance that can also improve, water tolerance and electrical insulating property.
Summary of the invention
For solving the technical problem existed in background technology, the present invention proposes the polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component, not only environmental protection, and has excellent toughness, shock resistance and resistance toheat.
The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component that the present invention proposes, its raw material comprises by weight: polyphenylether modified phenolic resin 60-120 part, ABS resin 15-35 part, polypropylene 5-15 part, polyethylene 2-8 part, bamboo fibers 1-6 part, silicon carbide 2-8 part, silicon powder 1-4 part, nano-attapulgite 2-5 part, light calcium carbonate 3-9 part, chitin 1-5 part, ethylene glycol 2-6 part, carboxylated poiyether 3-6 part, polycarbonate 1-5 part, N-BUTYL ACETATE 2-5 part, Zinic stearas 3-8 part, clorafin 1-5 part, auxiliary agent 2-7 part.
Preferably, polyphenylether modified phenolic resin is prepared by following technique: under the condition of alkalescence, phenol and poly formic acid is mixed, is warming up to 85-95 DEG C, insulation 1-3h, be cooled to room temperature and obtain material a, then in material a, add polysulfones and polyphenylene oxide mixes, be warming up to 65-85 DEG C, insulation 2-4h, then add isopropanol, then impregnated glass fiber, after oven dry, obtain polyphenylether modified phenolic resin.
Preferably, the weight ratio of phenol, paraformaldehyde, polysulfones, polyphenylene oxide, glass fibre and Virahol is 30-60:20-40:10-30:5-15:2-8:1-5.
Preferably, the raw material of auxiliary agent comprises by weight: Paris white 10-50 part, stearate 2-8 part, mica powder 1-6 part, magnesium hydroxide 3-9 part, organotin 1-6 part, glass fiber powder 2-7 part, methacrylic ester 4-9 part, silane coupling agent KH5702-5 part, lubricant 3-8 part.
Preferably, auxiliary agent is prepared by following technique: by Paris white and stearate, at 50-60 DEG C of temperature lower seal stirring at low speed 10-25min, then mix with mica powder, magnesium hydroxide and glass fiber powder, 45-55 DEG C of sealing stirring at low speed 5-10min, then add organotin, methacrylic ester, silane coupling agent KH570 and lubricant, be warming up to 135-140 DEG C, stirring at low speed 10-20min, discharging, is cooled to room temperature and obtains auxiliary agent.
Preferably, its raw material comprises by weight: polyphenylether modified phenolic resin 65-115 part, ABS resin 18-32 part, polypropylene 8-12 part, polyethylene 3-7 part, bamboo fibers 2-5 part, silicon carbide 3-7 part, silicon powder 2-3 part, nano-attapulgite 3-4 part, light calcium carbonate 4-8 part, chitin 2-4 part, ethylene glycol 3-5 part, carboxylated poiyether 4-5 part, polycarbonate 2-4 part, N-BUTYL ACETATE 3-4 part, Zinic stearas 4-7 part, clorafin 2-4 part, auxiliary agent 3-6 part.
Preferably, its raw material comprises by weight: polyphenylether modified phenolic resin 90 parts, ABS resin 25 parts, polypropylene 10 parts, polyethylene 5 parts, bamboo fibers 3.5 parts, 5 parts, silicon carbide, silicon powder 2.5 parts, nano-attapulgite 3.5 parts, light calcium carbonate 6 parts, chitin 3 parts, ethylene glycol 4 parts, carboxylated poiyether 4.5 parts, polycarbonate 3 parts, N-BUTYL ACETATE 3.5 parts, Zinic stearas 5.5 parts, clorafin 3 parts, auxiliary agent 4.5 parts.
The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component of the present invention, its raw material comprises polyphenylether modified phenolic resin, ABS resin, polypropylene, polyethylene, bamboo fibers, silicon carbide, silicon powder, nano-attapulgite, light calcium carbonate, chitin, ethylene glycol, carboxylated poiyether, polycarbonate, N-BUTYL ACETATE, Zinic stearas, clorafin and auxiliary agent, wherein pass through polyphenylether modified phenolic resin, solve in resole production process and discharge containing phenol, aldehyde, alcohol waste water pollution on the environment, by adding polysulfones, make polyphenylene oxide and polysulfones fully can hold conjunction, modified resol has excellent antiwear heat resisting performance, good toughness, further increase the antiwear heat resisting performance of the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component of the present invention, auxiliary ABS resin, polypropylene, polyethylene, bamboo fibers, silicon carbide, silicon powder, nano-attapulgite, light calcium carbonate, chitin, ethylene glycol, carboxylated poiyether, polycarbonate, N-BUTYL ACETATE, Zinic stearas, clorafin and the auxiliary agent of adding is as auxiliary material, wherein bamboo fibers, silicon carbide, silicon powder, nano-attapulgite, light calcium carbonate and chitin are as filler, while the wear resistance that improve the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component of the present invention and toughness, also improve resistance toheat.
Embodiment
Below in conjunction with specific embodiment, the present invention is described in detail; should understand; embodiment is only for illustration of the present invention, instead of for limiting the present invention, any amendment, equivalent replacement etc. made on basis of the present invention is all in protection scope of the present invention.
In embodiment, the weight part of polyphenylether modified phenolic resin can be 60 parts, 65 parts, 70 parts, 75 parts, 80 parts, 85 parts, 90 parts, 95 parts, 100 parts, 105 parts, 110 parts, 115 parts, 120 parts; The weight part of ABS resin can be 15 parts, 16 parts, 17 parts, 18 parts, 19 parts, 20 parts, 21 parts, 22 parts, 23 parts, 24 parts, 25 parts, 26 parts, 27 parts, 28 parts, 29 parts, 30 parts, 31 parts, 32 parts, 33 parts, 34 parts, 35 parts; Polyacrylic weight part can be 5 parts, 6 parts, 7 parts, 8 parts, 9 parts, 10 parts, 11 parts, 12 parts, 13 parts, 14 parts, 15 parts; Poly weight part can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of bamboo fibers can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of silicon carbide can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of silicon powder can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts; The weight part of nano-attapulgite can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of light calcium carbonate can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of chitin can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of ethylene glycol can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts; The weight part of carboxylated poiyether can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of polycarbonate can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of N-BUTYL ACETATE can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of Zinic stearas can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts; The weight part of clorafin can be 1 part, 2 parts, 3 parts, 4 parts, 5 parts; The weight part of auxiliary agent can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts.
In embodiment, in the raw material of auxiliary agent, the weight part of Paris white can be 10 parts, 15 parts, 20 parts, 25 parts, 30 parts, 35 parts, 40 parts, 45 parts, 50 parts; The weight part of stearate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts; The weight part of mica powder can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of magnesium hydroxide can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts; The weight part of organotin can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts; The weight part of glass fiber powder can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts; The weight part of methacrylic ester can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts; The weight part of silane coupling agent KH570 can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts; The weight part of lubricant can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts.
Embodiment 1
The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component that the present invention proposes, its raw material comprises by weight: polyphenylether modified phenolic resin 90 parts, ABS resin 25 parts, polypropylene 10 parts, polyethylene 5 parts, bamboo fibers 3.5 parts, 5 parts, silicon carbide, silicon powder 2.5 parts, nano-attapulgite 3.5 parts, light calcium carbonate 6 parts, chitin 3 parts, ethylene glycol 4 parts, carboxylated poiyether 4.5 parts, polycarbonate 3 parts, N-BUTYL ACETATE 3.5 parts, Zinic stearas 5.5 parts, clorafin 3 parts, auxiliary agent 4.5 parts.
Polyphenylether modified phenolic resin is prepared by following technique: under the condition of alkalescence, by weight 45 parts of phenol and 30 parts of poly formic acid are mixed, be warming up to 90 DEG C, insulation 2h, is cooled to room temperature and obtains material a, then in material a, interpolation 20 parts of polysulfones and 10 parts of polyphenylene oxide mix, be warming up to 75 DEG C, insulation 3h, then adds 3 parts of isopropanol, then flood 5 parts of glass fibre, after oven dry, obtain polyphenylether modified phenolic resin.
Auxiliary agent is prepared by following technique: by weight by 30 parts of Paris whites and 5 parts of stearate, at 55 DEG C of temperature lower seal stirring at low speed 17.5min, then mix with 3.5 parts of mica powders, 6 parts of magnesium hydroxides and 4.5 parts of glass fiber powders, 50 DEG C of sealing stirring at low speed 7.5min, add 3.5 parts of organotins, 6.5 parts of methacrylic esters, 3.5 parts of silane coupling agent KH570 and 5.5 part lubricants again, be warming up to 137.5 DEG C, stirring at low speed 15min, discharging, is cooled to room temperature and obtains auxiliary agent.
Embodiment 2
The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component that the present invention proposes, its raw material comprises by weight: polyphenylether modified phenolic resin 60 parts, ABS resin 35 parts, polypropylene 5 parts, polyethylene 8 parts, bamboo fibers 1 part, 8 parts, silicon carbide, silicon powder 1 part, nano-attapulgite 5 parts, light calcium carbonate 3 parts, chitin 5 parts, ethylene glycol 2 parts, carboxylated poiyether 6 parts, polycarbonate 1 part, N-BUTYL ACETATE 5 parts, Zinic stearas 3 parts, clorafin 5 parts, auxiliary agent 2 parts.
Polyphenylether modified phenolic resin is prepared by following technique: under the condition of alkalescence, by weight 30 parts of phenol and 40 parts of poly formic acid are mixed, be warming up to 85 DEG C, insulation 3h, is cooled to room temperature and obtains material a, then in material a, interpolation 10 parts of polysulfones and 15 parts of polyphenylene oxide mix, be warming up to 65 DEG C, insulation 4h, then adds 1 part of isopropanol, then flood 8 parts of glass fibre, after oven dry, obtain polyphenylether modified phenolic resin.
Auxiliary agent is prepared by following technique: by weight by 10 parts of Paris whites and 8 parts of stearate, at 50 DEG C of temperature lower seal stirring at low speed 25min, then mix with 1 part of mica powder, 9 parts of magnesium hydroxides and 2 parts of glass fiber powders, 55 DEG C of sealing stirring at low speed 5min, add 6 parts of organotins, 4 parts of methacrylic esters, 5 parts of silane coupling agent KH570 and 3 part lubricants again, be warming up to 140 DEG C, stirring at low speed 10min, discharging, is cooled to room temperature and obtains auxiliary agent.
Embodiment 3
The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component that the present invention proposes, its raw material comprises by weight: polyphenylether modified phenolic resin 120 parts, ABS resin 15 parts, polypropylene 15 parts, polyethylene 2 parts, bamboo fibers 6 parts, 2 parts, silicon carbide, silicon powder 4 parts, nano-attapulgite 2 parts, light calcium carbonate 9 parts, chitin 1 part, ethylene glycol 6 parts, carboxylated poiyether 3 parts, polycarbonate 5 parts, N-BUTYL ACETATE 2 parts, Zinic stearas 8 parts, clorafin 1 part, auxiliary agent 7 parts.
Polyphenylether modified phenolic resin is prepared by following technique: under the condition of alkalescence, by weight 60 parts of phenol and 20 parts of poly formic acid are mixed, be warming up to 95 DEG C, insulation 1h, is cooled to room temperature and obtains material a, then in material a, interpolation 30 parts of polysulfones and 5 parts of polyphenylene oxide mix, be warming up to 85 DEG C, insulation 2h, then adds 5 parts of isopropanol, then flood 2 parts of glass fibre, after oven dry, obtain polyphenylether modified phenolic resin.
Auxiliary agent is prepared by following technique: by weight by 50 parts of Paris whites and 2 parts of stearate, at 60 DEG C of temperature lower seal stirring at low speed 10min, then mix with 6 parts of mica powders, 3 parts of magnesium hydroxides and 7 parts of glass fiber powders, 45 DEG C of sealing stirring at low speed 10min, add 1 part of organotin, 9 parts of methacrylic esters, 2 parts of silane coupling agent KH570 and 8 part lubricants again, be warming up to 135 DEG C, stirring at low speed 20min, discharging, is cooled to room temperature and obtains auxiliary agent.
Embodiment 4
The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component that the present invention proposes, its raw material comprises by weight: polyphenylether modified phenolic resin 65 parts, ABS resin 32 parts, polypropylene 8 parts, polyethylene 7 parts, bamboo fibers 2 parts, 7 parts, silicon carbide, silicon powder 2 parts, nano-attapulgite 4 parts, light calcium carbonate 4 parts, chitin 4 parts, ethylene glycol 3 parts, carboxylated poiyether 5 parts, polycarbonate 2 parts, N-BUTYL ACETATE 4 parts, Zinic stearas 4 parts, clorafin 4 parts, auxiliary agent 3 parts.
Polyphenylether modified phenolic resin is prepared by following technique: under the condition of alkalescence, by weight 55 parts of phenol and 25 parts of poly formic acid are mixed, be warming up to 92 DEG C, insulation 1.5h, is cooled to room temperature and obtains material a, then in material a, interpolation 25 parts of polysulfones and 8 parts of polyphenylene oxide mix, be warming up to 82 DEG C, insulation 2.5h, then adds 4 parts of isopropanol, then flood 3 parts of glass fibre, after oven dry, obtain polyphenylether modified phenolic resin.
Auxiliary agent is prepared by following technique: by weight by 15 parts of Paris whites and 7 parts of stearate, at 52 DEG C of temperature lower seal stirring at low speed 20min, then mix with 2 parts of mica powders, 8 parts of magnesium hydroxides and 3 parts of glass fiber powders, 48 DEG C of sealing stirring at low speed 9min, add 2 parts of organotins, 8 parts of methacrylic esters, 3 parts of silane coupling agent KH570 and 7 part lubricants again, be warming up to 136 DEG C, stirring at low speed 18min, discharging, is cooled to room temperature and obtains auxiliary agent.
Embodiment 5
The polyphenyl ether modified environmentally-friendly plastic of a kind of electrical equipment plastic component that the present invention proposes, its raw material comprises by weight: polyphenylether modified phenolic resin 115 parts, ABS resin 18 parts, polypropylene 12 parts, polyethylene 3 parts, bamboo fibers 5 parts, 3 parts, silicon carbide, silicon powder 3 parts, nano-attapulgite 3 parts, light calcium carbonate 8 parts, chitin 2 parts, ethylene glycol 5 parts, carboxylated poiyether 4 parts, polycarbonate 4 parts, N-BUTYL ACETATE 3 parts, Zinic stearas 7 parts, clorafin 2 parts, auxiliary agent 6 parts.
Polyphenylether modified phenolic resin is prepared by following technique: under the condition of alkalescence, by weight 55 parts of phenol and 25 parts of poly formic acid are mixed, be warming up to 92 DEG C, insulation 1.5h, is cooled to room temperature and obtains material a, then in material a, interpolation 25 parts of polysulfones and 8 parts of polyphenylene oxide mix, be warming up to 82 DEG C, insulation 2.5h, then adds 4 parts of isopropanol, then flood 3 parts of glass fibre, after oven dry, obtain polyphenylether modified phenolic resin.
Auxiliary agent is prepared by following technique: by weight by 45 parts of Paris whites and 3 parts of stearate, at 58 DEG C of temperature lower seal stirring at low speed 15min, then mix with 5 parts of mica powders, 4 parts of magnesium hydroxides and 6 parts of glass fiber powders, 48 DEG C of sealing stirring at low speed 9min, add 2 parts of organotins, 8 parts of methacrylic esters, 3 parts of silane coupling agent KH570 and 7 part lubricants again, be warming up to 136 DEG C, stirring at low speed 18min, discharging, is cooled to room temperature and obtains auxiliary agent.
The above; be only the present invention's preferably embodiment; but protection scope of the present invention is not limited thereto; anyly be familiar with those skilled in the art in the technical scope that the present invention discloses; be equal to according to technical scheme of the present invention and inventive concept thereof and replace or change, all should be encompassed within protection scope of the present invention.

Claims (7)

1. the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component, it is characterized in that, its raw material comprises by weight: polyphenylether modified phenolic resin 60-120 part, ABS resin 15-35 part, polypropylene 5-15 part, polyethylene 2-8 part, bamboo fibers 1-6 part, silicon carbide 2-8 part, silicon powder 1-4 part, nano-attapulgite 2-5 part, light calcium carbonate 3-9 part, chitin 1-5 part, ethylene glycol 2-6 part, carboxylated poiyether 3-6 part, polycarbonate 1-5 part, N-BUTYL ACETATE 2-5 part, Zinic stearas 3-8 part, clorafin 1-5 part, auxiliary agent 2-7 part.
2. the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component according to claim 1, it is characterized in that, polyphenylether modified phenolic resin is prepared by following technique: under the condition of alkalescence, phenol and poly formic acid are mixed, be warming up to 85-95 DEG C, insulation 1-3h, be cooled to room temperature and obtain material a, then in material a, polysulfones is added and polyphenylene oxide mixes, be warming up to 65-85 DEG C, insulation 2-4h, then adds isopropanol, then impregnated glass fiber, obtains polyphenylether modified phenolic resin after oven dry.
3. the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component according to claim 1 and 2, is characterized in that, the weight ratio of phenol, paraformaldehyde, polysulfones, polyphenylene oxide, glass fibre and Virahol is 30-60:20-40:10-30:5-15:2-8:1-5.
4. the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component according to any one of claim 1-3, it is characterized in that, the raw material of auxiliary agent comprises by weight: Paris white 10-50 part, stearate 2-8 part, mica powder 1-6 part, magnesium hydroxide 3-9 part, organotin 1-6 part, glass fiber powder 2-7 part, methacrylic ester 4-9 part, silane coupling agent KH5702-5 part, lubricant 3-8 part.
5. the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component according to any one of claim 1-4, it is characterized in that, auxiliary agent is prepared by following technique: by Paris white and stearate, at 50-60 DEG C of temperature lower seal stirring at low speed 10-25min, then mix with mica powder, magnesium hydroxide and glass fiber powder, 45-55 DEG C of sealing stirring at low speed 5-10min, add organotin, methacrylic ester, silane coupling agent KH570 and lubricant again, be warming up to 135-140 DEG C, stirring at low speed 10-20min, discharging, is cooled to room temperature and obtains auxiliary agent.
6. the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component according to any one of claim 1-5, it is characterized in that, its raw material comprises by weight: polyphenylether modified phenolic resin 65-115 part, ABS resin 18-32 part, polypropylene 8-12 part, polyethylene 3-7 part, bamboo fibers 2-5 part, silicon carbide 3-7 part, silicon powder 2-3 part, nano-attapulgite 3-4 part, light calcium carbonate 4-8 part, chitin 2-4 part, ethylene glycol 3-5 part, carboxylated poiyether 4-5 part, polycarbonate 2-4 part, N-BUTYL ACETATE 3-4 part, Zinic stearas 4-7 part, clorafin 2-4 part, auxiliary agent 3-6 part.
7. the polyphenyl ether modified environmentally-friendly plastic of electrical equipment plastic component according to any one of claim 1-6, it is characterized in that, its raw material comprises by weight: polyphenylether modified phenolic resin 90 parts, ABS resin 25 parts, polypropylene 10 parts, polyethylene 5 parts, bamboo fibers 3.5 parts, 5 parts, silicon carbide, silicon powder 2.5 parts, nano-attapulgite 3.5 parts, light calcium carbonate 6 parts, chitin 3 parts, ethylene glycol 4 parts, carboxylated poiyether 4.5 parts, polycarbonate 3 parts, N-BUTYL ACETATE 3.5 parts, Zinic stearas 5.5 parts, clorafin 3 parts, auxiliary agent 4.5 parts.
CN201510779098.XA 2015-11-13 2015-11-13 Polyphenyl ether-modified environmental-friendly plastic used for electric appliance plastic elements Pending CN105348730A (en)

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CN106046645A (en) * 2016-08-19 2016-10-26 陈苹 Antiskid composite material specially used for computer mouse
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CN106751186A (en) * 2016-12-12 2017-05-31 天长市康宁塑胶科技有限公司 A kind of high hardness high toughness modified plastic rubber material
CN108192346A (en) * 2017-11-26 2018-06-22 天长市荣盛有机硅科技有限公司 A kind of high-toughness wear-resistant heat-resistant silicon rubber material
CN108456396A (en) * 2018-01-24 2018-08-28 合肥铭佑高温技术有限公司 A kind of high-temperature service mating switch and preparation method
CN109135317A (en) * 2018-07-26 2019-01-04 苏州嘉迈德电子科技有限公司 A kind of casing for electric appliances plastics

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Application publication date: 20160224