CN105348622A - Multifunctional polyethylene plastics - Google Patents

Multifunctional polyethylene plastics Download PDF

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Publication number
CN105348622A
CN105348622A CN201510983496.3A CN201510983496A CN105348622A CN 105348622 A CN105348622 A CN 105348622A CN 201510983496 A CN201510983496 A CN 201510983496A CN 105348622 A CN105348622 A CN 105348622A
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CN
China
Prior art keywords
accounts
parts
agent
ethylene
polyethylene plastics
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201510983496.3A
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Chinese (zh)
Inventor
凌忠英
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGSHU JIANGSHUN PLASTIC PRODUCT CO LTD
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CHANGSHU JIANGSHUN PLASTIC PRODUCT CO LTD
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Application filed by CHANGSHU JIANGSHUN PLASTIC PRODUCT CO LTD filed Critical CHANGSHU JIANGSHUN PLASTIC PRODUCT CO LTD
Priority to CN201510983496.3A priority Critical patent/CN105348622A/en
Priority to PCT/CN2015/099470 priority patent/WO2017107222A1/en
Publication of CN105348622A publication Critical patent/CN105348622A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/40—Glass
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/5399—Phosphorus bound to nitrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/08—Copolymers of ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L29/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
    • C08L29/14—Homopolymers or copolymers of acetals or ketals obtained by polymerisation of unsaturated acetals or ketals or by after-treatment of polymers of unsaturated alcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L71/00—Compositions of polyethers obtained by reactions forming an ether link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
    • C08L83/04—Polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/04—Antistatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses multifunctional polyethylene plastics. The multifunctional polyethylene plastics comprises polyethylene, filler, an antistatic agent, an anti-aging agent, a toughening agent, a lubricant, a dispersing agent and a coupling agent, wherein the filler adopts glass powder; the antistatic agent adopts fatty alcohol polyoxyethylene ether; the anti-aging agent adopts hexamethylphosphoramide; the toughening agent adopts polyvinyl butyral; the lubricant adopts organic silicone oil; the dispersing agent adopts an ethylene-acrylic acid copolymer; the coupling agent adopts di(dioctylpyrophosphato) ethylene titanate. The multifunctional polyethylene plastics comprises polyethylene, the filler, the antistatic agent, the anti-aging agent, the toughening agent, the lubricant, the dispersing agent and the coupling agent and has the advantages of high hardness, high strength, antistatic performance, aging resistance, scraping resistance, good quality and long service life.

Description

A kind of multi-functional polyethylene plastics
Technical field
The present invention relates to a kind of plastic applications, be specifically related to a kind of multi-functional polyethylene plastics.
Background technology
Polyethylene is called for short PE, and being one of five large synthetic resins, is the kind that in China's synthetic resins, production capacity is maximum, import volume is maximum.Along with the multidirectional development of continuous progress and enterprise of productivity, the vinyon instantly used cannot meet the requirement of the use in market, is therefore badly in need of a kind of novel multi-functional polyethylene to fill up the demand in market.
Summary of the invention
The object of the present invention is to provide one to be made up of polyethylene, weighting agent, static inhibitor, anti-aging agent, toughner, lubricant, dispersion agent and coupling agent, obtained product hardness is large, intensity is high, antistatic, ageing-resistant, Anti-scratching, quality are good, the multi-functional polyethylene plastics of long service life.
Technical scheme of the present invention is, a kind of multi-functional polyethylene plastics, described multi-functional polyethylene plastics are by polyethylene, weighting agent, static inhibitor, anti-aging agent, toughner, lubricant, dispersion agent and coupling agent composition, described weighting agent is glass powder, described static inhibitor is polyoxyethylene aliphatic alcohol ether, described anti-aging agent is HMPA, described toughner is polyvinyl butyral acetal, described lubricant is organic silicone oil, described dispersion agent is ethylene-acrylic acid copolymer, described coupling agent is two (two octyloxy acid esters tetra-sodium ester groups) ethylene titaniums, shared by each composition of described multi-functional polyethylene plastics, parts by weight are respectively: described polyethylene accounts for 98-104 part, described glass powder accounts for 29-33 part, described polyoxyethylene aliphatic alcohol ether accounts for 3-6 part, described HMPA accounts for 4-7 part, described polyvinyl butyral acetal accounts for 10-13 part, described organic silicone oil accounts for 6-9 part, described ethylene-acrylic acid copolymer accounts for 2-5 part, described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 5-8 part.
In a preferred embodiment of the present invention, in described multi-functional polyethylene plastics, shared by each composition, parts by weight are specially: described polyethylene accounts for 99 parts, described glass powder accounts for 30 parts, described polyoxyethylene aliphatic alcohol ether accounts for 4 parts, described HMPA accounts for 5 parts, and described polyvinyl butyral acetal accounts for 11 parts, and described organic silicone oil accounts for 7 parts, described ethylene-acrylic acid copolymer accounts for 3 parts, and described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 6 parts.
In a preferred embodiment of the present invention, in described multi-functional polyethylene plastics, shared by each composition, parts by weight are specially: described polyethylene accounts for 103 parts, described glass powder accounts for 32 parts, described polyoxyethylene aliphatic alcohol ether accounts for 5 parts, described HMPA accounts for 6 parts, and described polyvinyl butyral acetal accounts for 12 parts, and described organic silicone oil accounts for 6-9 part, described ethylene-acrylic acid copolymer accounts for 4 parts, and described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 7 parts.
Of the present invention is a kind of multi-functional polyethylene plastics, be made up of polyethylene, weighting agent, static inhibitor, anti-aging agent, toughner, lubricant, dispersion agent and coupling agent, obtained product hardness is large, intensity is high, antistatic, ageing-resistant, Anti-scratching, quality are good, long service life.
Embodiment
Below preferred embodiment of the present invention is described in detail, can be easier to make advantages and features of the invention be readily appreciated by one skilled in the art, thus more explicit defining is made to protection scope of the present invention.
Of the present invention is a kind of multi-functional polyethylene plastics, described multi-functional polyethylene plastics are by polyethylene, weighting agent, static inhibitor, anti-aging agent, toughner, lubricant, dispersion agent and coupling agent composition, described weighting agent is glass powder, described static inhibitor is polyoxyethylene aliphatic alcohol ether, described anti-aging agent is HMPA, described toughner is polyvinyl butyral acetal, described lubricant is organic silicone oil, described dispersion agent is ethylene-acrylic acid copolymer, described coupling agent is two (two octyloxy acid esters tetra-sodium ester groups) ethylene titaniums, shared by each composition of described multi-functional polyethylene plastics, parts by weight are respectively: described polyethylene accounts for 98-104 part, described glass powder accounts for 29-33 part, described polyoxyethylene aliphatic alcohol ether accounts for 3-6 part, described HMPA accounts for 4-7 part, described polyvinyl butyral acetal accounts for 10-13 part, described organic silicone oil accounts for 6-9 part, described ethylene-acrylic acid copolymer accounts for 2-5 part, described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 5-8 part.
Further, in described multi-functional polyethylene plastics, shared by each composition, parts by weight are specially: described polyethylene accounts for 99 parts, described glass powder accounts for 30 parts, described polyoxyethylene aliphatic alcohol ether accounts for 4 parts, described HMPA accounts for 5 parts, and described polyvinyl butyral acetal accounts for 11 parts, and described organic silicone oil accounts for 7 parts, described ethylene-acrylic acid copolymer accounts for 3 parts, and described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 6 parts.
Further, in described multi-functional polyethylene plastics, shared by each composition, parts by weight are specially: described polyethylene accounts for 103 parts, described glass powder accounts for 32 parts, described polyoxyethylene aliphatic alcohol ether accounts for 5 parts, described HMPA accounts for 6 parts, and described polyvinyl butyral acetal accounts for 12 parts, and described organic silicone oil accounts for 6-9 part, described ethylene-acrylic acid copolymer accounts for 4 parts, and described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 7 parts.
In addition, by regulating the Different Weight number of each composition of product, the product performance height obtained is differed.
Of the present invention is a kind of multi-functional polyethylene plastics, be made up of polyethylene, weighting agent, static inhibitor, anti-aging agent, toughner, lubricant, dispersion agent and coupling agent, obtained product hardness is large, intensity is high, antistatic, ageing-resistant, Anti-scratching, quality are good, long service life.
The foregoing is only the specific embodiment of the present invention; but protection scope of the present invention is not limited thereto; any those of ordinary skill in the art are in the technical scope disclosed by the present invention; the change can expected without creative work or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should limit with claims is as the criterion.

Claims (3)

1. multi-functional polyethylene plastics, it is characterized in that: described multi-functional polyethylene plastics are by polyethylene, weighting agent, static inhibitor, anti-aging agent, toughner, lubricant, dispersion agent and coupling agent composition, described weighting agent is glass powder, described static inhibitor is polyoxyethylene aliphatic alcohol ether, described anti-aging agent is HMPA, described toughner is polyvinyl butyral acetal, described lubricant is organic silicone oil, described dispersion agent is ethylene-acrylic acid copolymer, described coupling agent is two (two octyloxy acid esters tetra-sodium ester groups) ethylene titaniums, shared by each composition of described multi-functional polyethylene plastics, parts by weight are respectively: described polyethylene accounts for 98-104 part, described glass powder accounts for 29-33 part, described polyoxyethylene aliphatic alcohol ether accounts for 3-6 part, described HMPA accounts for 4-7 part, described polyvinyl butyral acetal accounts for 10-13 part, described organic silicone oil accounts for 6-9 part, described ethylene-acrylic acid copolymer accounts for 2-5 part, described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 5-8 part.
2. multi-functional polyethylene plastics according to claim 1, it is characterized in that: in described multi-functional polyethylene plastics, shared by each composition, parts by weight are specially: described polyethylene accounts for 99 parts, described glass powder accounts for 30 parts, described polyoxyethylene aliphatic alcohol ether accounts for 4 parts, described HMPA accounts for 5 parts, described polyvinyl butyral acetal accounts for 11 parts, described organic silicone oil accounts for 7 parts, described ethylene-acrylic acid copolymer accounts for 3 parts, and described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 6 parts.
3. multi-functional polyethylene plastics according to claim 1, it is characterized in that: in described multi-functional polyethylene plastics, shared by each composition, parts by weight are specially: described polyethylene accounts for 103 parts, described glass powder accounts for 32 parts, described polyoxyethylene aliphatic alcohol ether accounts for 5 parts, described HMPA accounts for 6 parts, described polyvinyl butyral acetal accounts for 12 parts, described organic silicone oil accounts for 6-9 part, described ethylene-acrylic acid copolymer accounts for 4 parts, and described two (two octyloxy acid esters tetra-sodium ester groups) ethylene titanium accounts for 7 parts.
CN201510983496.3A 2015-12-24 2015-12-24 Multifunctional polyethylene plastics Pending CN105348622A (en)

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CN201510983496.3A CN105348622A (en) 2015-12-24 2015-12-24 Multifunctional polyethylene plastics
PCT/CN2015/099470 WO2017107222A1 (en) 2015-12-24 2015-12-29 Multifunction polyethylene plastic

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106026001A (en) * 2016-05-12 2016-10-12 石策略 Power cable connector
CN107325391A (en) * 2017-08-29 2017-11-07 阜南县鲲鹏塑业科技有限公司 A kind of ageing-resistant modified poly ethylene plastics

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945723A (en) * 2015-07-31 2015-09-30 苏州新区特氟龙塑料制品厂 Modified high-density polyethylene with high strength for cables

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63246587A (en) * 1987-04-02 1988-10-13 三菱油化株式会社 Feed and drain pipe
EP1882014B1 (en) * 2005-05-12 2009-03-11 Dow Global Technologies Inc. Thermoformed, extruded sheeting with reduced gloss
CN105175867A (en) * 2015-10-16 2015-12-23 太仓市晨洲塑业有限公司 Anti-static high-density polyethylene power cable protection pipe

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104945723A (en) * 2015-07-31 2015-09-30 苏州新区特氟龙塑料制品厂 Modified high-density polyethylene with high strength for cables

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106026001A (en) * 2016-05-12 2016-10-12 石策略 Power cable connector
CN107325391A (en) * 2017-08-29 2017-11-07 阜南县鲲鹏塑业科技有限公司 A kind of ageing-resistant modified poly ethylene plastics

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Application publication date: 20160224