CN105347832B - Coiled carbon fibers composite ceramics for activated water and preparation method thereof and application - Google Patents
Coiled carbon fibers composite ceramics for activated water and preparation method thereof and application Download PDFInfo
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- CN105347832B CN105347832B CN201510882454.0A CN201510882454A CN105347832B CN 105347832 B CN105347832 B CN 105347832B CN 201510882454 A CN201510882454 A CN 201510882454A CN 105347832 B CN105347832 B CN 105347832B
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Abstract
The present invention is used for the coiled carbon fibers composite ceramics of activated water, including ceramic phase and coiled carbon fibers, and the coiled carbon fibers distribution is attached to ceramic phase.Harmful substance can be changed using coiled carbon fibers and fluctuate the fluctuation for making it become to match to human body.Specifically, oxygen barrier composite ceramics are sintered into micron order coiled carbon fibers and ceramic raw material are compound.The fluctuation being harmful to the human body that the substances such as many chemical substances, elemental chlorine, harmful bacteria generate can be become the fluctuation beneficial to body by this composite ceramics, and make hydrone that the activation that declension vibrates occur, hydrone is set to become smaller molecular cluster, hence it is evident that improve cerebral blood flow；Also have the function of inhibiting bacterial reproduction additionally by its special fluctuation.The present invention is based on fluctuation effects, as long as so addition minimal amount, can change water quality in moment.There is no absorption pollutant in water activation process, also there is no chemical changes etc., therefore do not need later period clean and maintenance, and product of the present invention can be used for a long time.
Description
Technical field
The invention belongs to water treatment fields, and in particular to for the coiled carbon fibers composite ceramics of activated water and its production side
Method and application
Background technique
It drinks water very big to health effect, in addition to because drinking-water the inside is containing impurity, (sludge, disinfection chlorine bleaches, have
Evil drug, chemical substance, heavy metal classes, bacterium class etc.) influence factor other than, the activity (energy of hydrone of hydrone itself
Amount) it is also critically important.The low quality of raw water is filtered purification and is also difficult to completely remove micro harmful drug and chemical substance,
So being not suitable for directly being used as drinking water.
Studies have shown that human brain inside put aside huge information data, these information datas can substance judge be to people
It is beneficial or harmful.It can judge whether drinking water fits to including human body using this super memory function and discernment
It closes.If brain judgement is harmful drinking water and food, cerebral blood flow (CBF) is reduced, to prevent harmful substance from flowing into intracerebral.Such as
Fruit brain is judged as benefit materials, then cerebral blood flow (CBF) is increased by, so that nutrient supply brain, waste is discharged, rises to improve and exempt from
The effect of epidemic disease power.This all substances in the world and immaterial, all with certain natural frequency vibration.Having has human body
The vibration of benefit；Also have the vibration being harmful to the human body and human body it is distinctive fluctuation it is suitable in the case where, brain is judged as being harmful
And start to refuse, cerebral blood flow (CBF) just declines.Especially artificial synthesized chemicals and harmful bacteria class, their fluctuation have
The fluctuation of very big distortion and stress and human body is not suitable, thus brain command reject (CMDR) they, thus cerebral blood flow (CBF) decline.
We investigate influence of the city tap-water to cerebral blood flow (CBF), the results showed that the tap water of most of metropolis is all to brain
Blood flow has a significant impact, and is unsuitable for directly drinking.Mountain area area just can be improved brain blood flow rich in the mineral water of minerals
Amount；As Aspartame artificial sweeteners element, the beverages such as man-made additive or Coca-Cola can then reduce cerebral blood flow (CBF)；On the contrary, rice
Meal, bean curd, vinegar, the daily breads such as beer can increase cerebral blood flow (CBF).Same substance is also more to refine, and more makes brain blood flow
Amount reduces, and mineral salt and rock salt can be such that cerebral blood flow (CBF) improves.Just explanation is beneficial to body for cerebral blood flow (CBF) raising, instead then harmful.
Summary of the invention
The present invention, to the influence of human health and its application method, is changed by research coiled carbon fibers based on substance fluctuation
The principle of change develops a kind of coiled carbon fibers composite ceramics for activated water and preparation method thereof and answering in water process
With.
The technical scheme of the present invention is realized as follows:
For the coiled carbon fibers composite ceramics of activated water, including ceramic phase and coiled carbon fibers, the coiled carbon fibers
Distribution is attached to ceramic phase.
Preferably, the coiled carbon fibers are randomly dispersed in ceramic phase.
Preferably, the ceramic phase is the ceramic of solid fraction form.Ceramic phase can be any solid shape, can also make
At forms such as artwork ornaments, practical ceramic tiles, it might even be possible to directly be combined in the water container of ceramic form, main function is to make
For the carrier for carrying coiled carbon fibers.
Preferably, the mass ratio of the coiled carbon fibers be greater than 0wt%, and be less than or equal to 80%.
It is further preferred that the mass ratio of the coiled carbon fibers is 0.01wt%-80wt%.
Preferably, the diameter of the coiled carbon fibers is 10nm-100 μm.
The production method of the above-mentioned coiled carbon fibers composite ceramics for activated water includes the following steps: to determine firstly, taking
Ceramic raw material is measured, is in mass ratio mixing in the content addition such as ceramic raw material of 0.01wt%~80wt% by coiled carbon fibers
It is uniformly spare；Secondly, mixing material to be fabricated to the ceramic germule of solid fraction form using ceramic molding；Certainly to germule finally
So ceramic is sintered into an inert atmosphere after drying.
Preferably, in above-mentioned production method, the ceramic molding is rolling molding, the shallow lake molding of capillary drop, does
Any forming method in molded, hydrostatic profile, roll-forming.
Preferably, in above-mentioned production method, wherein sintering temperature is 1000-1200 DEG C.
Coiled carbon fibers composite ceramics of the present invention can be used for a long time, the coiled carbon fibers composite ceramic for activated water
Porcelain can add coiled carbon fibers composite ceramics, or the pipe flowed through in water in the application of drinking water treatment in water container
Coiled carbon fibers composite ceramics are installed in road, can also be prepared into coiled carbon fibers composite ceramics container and be contained water.
The coiled carbon fibers composite ceramics for activated water aquaculture water process application, by coiled carbon fibers
Composite ceramics are crossed in water pipe loaded on sink.
Water process principle of the invention is: coiled carbon fibers composite ceramics can be by many chemical substances in water, example
The fluctuation being harmful to the human body as the substances such as chloride ion and harmful bacteria occur is converted into the fluctuation beneficial to human body, and makes
The activation of declension vibration occurs for hydrone, and hydrone is made to become smaller molecular cluster, hence it is evident that improves cerebral blood flow；In addition lead to
Crossing its special fluctuation also has the function of inhibiting bacterial reproduction.
The present invention has the further advantage that
1, by coiled carbon fibers in conjunction with ceramic phase, forming coiled carbon fibers composite ceramics has stable structure, convenient for protecting
Deposit, it is easy to use the advantages that.
2, coiled carbon fibers composite ceramics can activate water, make hydrone that activation-activation of declension vibration occur, make
Hydrone becomes smaller molecular cluster.
3, method for treating water of the invention is physical treatment, and coiled carbon fibers composite ceramics do not adsorb in water treatment procedure
Harmful substance does not chemically react, and chemical form variation will not occur for long-term place in water, therefore can make for a long time
With effect will not decay.
4, because being that fluctuation effect is presented, CMC ceramic bead is not dirty, and effect does not also reduce, and long-time service does not need
Replacement, cleaning, it is particularly convenient.
5, inhibit the harmful bacteria breeding in water, kill bacterium, improve the activity of water, improve organism in water survival condition,
Water environment especially suitable for aquaculture pond improves.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
The present invention is used for the coiled carbon fibers composite ceramics of activated water, including ceramic phase 1 and the (letter of several coiled carbon fibers 3
Claim: CMC), the distribution of coiled carbon fibers 3 is attached to ceramic phase, specifically, the coiled carbon fibers 3 can be randomly dispersed in
In ceramic phase, coiled carbon fibers 3 can also be assembled to be distributed in ceramic phase in certain rule or random pattern, or overlays on ceramics
Phase outer surface.The ceramic phase is the ceramic of solid fraction form.Ceramic phase can be any solid shape, such as it is rectangular, do not advise
Then shape, may be made as the forms such as artwork ornaments, practical ceramic tile, it might even be possible to directly in ceramic form water container combine,
Its main function is the carrier as carrying coiled carbon fibers.The ceramic phase preferably uses ceramic bead structure, has beautiful, easy
With, it is applied widely the advantages that.
In the present invention, the mass ratioes of the coiled carbon fibers is and to be less than or equal to 80% greater than 0wt%.The spiral
Carbon fiber micron order coiled carbon fibers.As long as theoretically the very small amount of the content of coiled carbon fibers can reach good effect
Fruit, and in conjunction with ceramic phase after, it is tangible upper to be attached in ceramic phase, according to the molding of the water of required processing and the narrow body of ceramics
State, mass ratio can be between 0.01wt%~80wt%.Inventor is found by experiment that, coiled carbon fibers composite ceramics
Clearly to the treatment effect of water, cerebral blood flow (CBF) can be improved quickly, and ultrasonic wave can be used in the cerebral blood flow (CBF) that the present invention refers to
The test of blood flow detection instrument can be measured using the ultrasonic measuring method of twocouese blood flow.
The production method of the above-mentioned coiled carbon fibers composite ceramics for activated water, includes the following steps:
It is in mass ratio the content addition of 0.01wt%~80wt% by coiled carbon fibers firstly, taking quantitative ceramic raw material
Enter in ceramic raw material, is uniformly mixed spare；Secondly, mixing material to be fabricated to the ceramics of solid fraction form using ceramic molding
Germule；Ceramic is finally sintered into an inert atmosphere after germule natural drying, and wherein sintering temperature is 1000-1200
℃.The ceramic molding is that rolling forms, capillary drips molding of forming sediment, appointing in dry-pressing formed, hydrostatic profile, roll-forming
A kind of forming method.
Ceramic bead, ceramic particle and ceramics are made by different ceramic raw materials, coiled carbon fibers adding proportion in the present invention
A variety of ceramic composites of different shapes such as cylindrical body, and carry out water and be activated experiment, it is specific as follows:
The preparation of embodiment one, coiled carbon fibers composite ceramic beads: 0.5wt% coiled carbon fibers and the pottery of 99.5wt% are taken
Floor tile powder is first carried out 40 spray drying, then by coiled carbon fibers and the agravic method of floor tile powder by porcelain floor tile powder
It is uniformly mixed, complex is rolled onto using rolling method plus water, diameter reaches 3-5 millimeters of ball, sorts out drying with sieve, so
After be put into oxygen-free atmosphere furnace coiled carbon fibers composite ceramic beads be made with 1180 DEG C of high temperature sinterings.
In an experiment, by adding coiled carbon fibers composite ceramics in 10 liters of tap water that cerebral blood flow (CBF) is 1.8L/min
Pearl, out the cerebral blood flow (CBF) fast lifting of saliva to 7L/min.
The preparation of embodiment two, coiled carbon fibers composite ceramic particle: first choice takes 37wt% red soil and granite powder
Then plus 100wt% water 63wt% after the mud by 0.5wt% more than ball milling to 10000-hole sieve, adds 0.2wt% spiral carbon
Fiber is uniformly mixed, which is dehydrated into mud cake with filter press, mud cake is ground into 2-4 milli through drying, pelletizer
The particle of meter great little, then be sintered by 1050 DEG C of oxygen-free atmosphere furnace.
In an experiment, it takes coiled carbon fibers composite ceramic particle several, is put into internal diameter 17mm, in the cylinder of length 450mm, brain
Blood flow is the tap water of 1.8L/min with the flow rate of 50L/min, and the cerebral blood flow (CBF) of saliva is promoted to 6L/min out.
The preparation of embodiment three, coiled carbon fibers composite ceramics cylindrical body: take 23wt% red soil, smolmitza 17wt%,
Granite powder 60wt%, additional 100wt% water more than ball milling to 10000-hole sieve after the mud of 2wt%, are added 1wt%CMC and are stirred
Uniformly, which is dehydrated into mud cake with filter press, 5 millimeters of diameter of mud item is squeezed out with soil kneader, is cut into 5 millimeters long
Mud section, mud section are sintered through dry with 1000 DEG C of oxygen-free atmosphere furnace.
In an experiment, the water of cerebral blood flow (CBF) 0.6L/min is added in 200 liters of container, adds carbon fiber containing spiral inside
The ceramic cylinder of dimension after stirring, measures its cerebral blood flow (CBF) 6L/min.
The application of above-mentioned coiled carbon fibers composite ceramics specifically:, can be in water container in the application of drinking water treatment
Coiled carbon fibers composite ceramics are added, or install coiled carbon fibers composite ceramics in the pipeline that water flows through.Coiled carbon fibers
Composite ceramics will persistently improve water quality.
In addition, coiled carbon fibers composite ceramics of the invention are also highly suitable for being applied in aquaculture water process, cultivating
The application of industry water process crosses coiled carbon fibers composite ceramics in water pipe loaded on sink.
The water that the present invention can be used for any occasion is activated, it is not limited to which above-mentioned application example, examples detailed above are
Relatively conventional, effective use occasion, coiled carbon fibers composite ceramics need to only be contacted with water, necessarily had activated water, improved water
The effect of matter.
The foregoing is merely illustrative of the preferred embodiments of the present invention, is not intended to limit the invention, all in essence of the invention
Within mind and principle, any modification, equivalent replacement, improvement and so on be should all be included in the protection scope of the present invention.
Claims (3)
1. being used for the coiled carbon fibers composite ceramics of activated water, it is characterised in that it is compound to be prepared into coiled carbon fibers by following methods
Ceramic cylinder: 23wt% red soil, smolmitza 17wt%, granite powder 60wt%, additional 100wt% water, ball milling to ten thousand are taken
After hole tails over the mud of 2wt%, 1wt% coiled carbon fibers are added and are uniformly mixed, which is dehydrated with filter press
At mud cake, 5 millimeters of diameter of mud item is squeezed out with soil kneader, is cut into 5 millimeters long of mud section, and mud section uses oxygen-free atmosphere furnace through dry
1000 DEG C are sintered.
2. being used for the coiled carbon fibers composite ceramics of activated water as described in claim 1, it is characterised in that the spiral carbon fiber
The diameter of dimension is 10nm-100 μm.
3. the application described in a kind of claim 1 for the coiled carbon fibers composite ceramics of activated water in drinking water treatment, spy
Sign is, coiled carbon fibers composite ceramics are added in water container, or installs coiled carbon fibers in the pipeline that water flows through and answer
Close ceramics.
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| CN105347832B true CN105347832B (en) | 2019-08-16 |
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| CN106830927B (en) * | 2017-01-26 | 2019-10-18 | 广东东方锆业科技股份有限公司 | A method of drop shallow lake molding prepares zirconia ceramics microballon |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1336248A (en) * | 2000-08-01 | 2002-02-20 | 李裕成 | Making-process of active sintered microfiltering film |
| CN103933661A (en) * | 2014-04-09 | 2014-07-23 | 杨少明 | Health caring annexing agent and application of health caring annexing agent |
| CN205241540U (en) * | 2015-12-03 | 2016-05-18 | 泉州凯佳新材料研究院有限公司 | A spiral carbon fiber composite ceramic for activated water |
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| JP5408837B2 (en) * | 2006-06-16 | 2014-02-05 | ブリヂストンフローテック株式会社 | Water quality improvement structure |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1336248A (en) * | 2000-08-01 | 2002-02-20 | 李裕成 | Making-process of active sintered microfiltering film |
| CN103933661A (en) * | 2014-04-09 | 2014-07-23 | 杨少明 | Health caring annexing agent and application of health caring annexing agent |
| CN205241540U (en) * | 2015-12-03 | 2016-05-18 | 泉州凯佳新材料研究院有限公司 | A spiral carbon fiber composite ceramic for activated water |
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