CN105345236A - Control method for phosphorus content of submerged-arc welding deposited metal - Google Patents

Control method for phosphorus content of submerged-arc welding deposited metal Download PDF

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Publication number
CN105345236A
CN105345236A CN201510912574.0A CN201510912574A CN105345236A CN 105345236 A CN105345236 A CN 105345236A CN 201510912574 A CN201510912574 A CN 201510912574A CN 105345236 A CN105345236 A CN 105345236A
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welding
content
submerged
seam
deposited metal
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CN105345236B (en
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黄治军
胡因洪
张穗忠
牟文广
高俊
胡家国
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Wuhan Iron and Steel Co Ltd
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Wuhan Iron and Steel Group Corp
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B23MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
    • B23KSOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
    • B23K9/00Arc welding or cutting
    • B23K9/18Submerged-arc welding

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Mechanical Engineering (AREA)
  • Arc Welding In General (AREA)
  • Nonmetallic Welding Materials (AREA)

Abstract

The invention discloses a control method for a phosphorus content of a submerged-arc welding deposited metal. According to the control method, welding conditions are as follows: a welding current is 800-900A, a voltage is 29-30V, a welding speed is 42-45cm/min, and a welding wire energy is 34-36J/cm; a matched welding flux is an alkaline sintering welding flux; a phosphorus P seam of the submerged-arc welding deposited metal is predicated according to a formula P<seam>=(2/3P<wire>+1/3P<flux>)+0.001(ln0.010/P<wire>+ln0.020/P<flux>); and the specific P-containing welding wire and welding flux are determined according to the predicted phosphorus P seam value of the submerged-arc welding deposited metal. According to the invention, through the established calculation formula, the P content of the submerged-arc welding seam can be strictly controlled, and the matched phosphorus-containing welding wire and welding flux can be rapidly and accurately selected, without the need of selecting and matching the welding wire and welding flux through tests; and moreover, the predicated controlled P content of the welding seam is identical to an experimental verification result.

Description

A kind of control method of submerged-arc welding deposited metal phosphorus content
Technical field
The present invention relates to a kind of buried arc welding method, belong to a kind of control method of submerged-arc welding deposited metal phosphorus content particularly.
Background technology
Phosphorus in weld seam is one of main harm element.Especially in the weld seam of the welding such as nuclear power structure, high-performance pipeline, the content requirement of phosphorus is strict, but in actual welding, want the Forecast and control of the content of P in submerged arc weld very difficult again, its reason be submerged-arc welding use welding wire and solder flux be welding material, in welding process, welding wire and solder melts form molten bath, molten pool metal carries out complicated metallurgical reaction, along with a series of de-P process, main as following various:
2[Fe 2P]+5(FeO)→P 2O 5+9[Fe],P 2O 5+3(CaO)→(CaO)3·P 2O 5,P 2O 5+4(CaO)→(CaO)4·P 2O 5
Especially for for constantly adapting to high-end product and new steel grade newly developed, when in its weld seam, phosphorus content requires strict, current way determines whether welding wire and sintered flux meet the requirement of P content by carrying out actual welding test.The deficiency of this method be cause the time matching welding wire and solder flux long, and both wasted material and hand labor.
P content in weld seam is generally divided into multiple grade, and as P≤0.025%, 0.015%, 0.010%, 0.008% etc., its change is very trickle, and comparatively accurately predicting and the P content controlled in weld seam are one and significantly work.
For head it off, the applicant, through a large amount of tests, proposing (1) when using identical welding wire and solder flux, obtaining the welding condition of minimum weld seam P content; (2) under this welding condition, namely adopt weld heat input at 34 ~ 36kJ/cm and larger electric current, corresponding relation by the different wlding P content of research and submerged arc weld P content, propose by the P content in welding wire and solder flux, P content in Resistance of Weld Metal carries out the relational expression controlled, whether the P content in the weld seam predicted by relational expression is again met the demands, thus the welding wire of the P content that need mate when determining actual submerged arc welding fast and solder flux, thus serve guarantee effect for obtaining high-performance weld seam.
Summary of the invention
The invention reside in the deficiency overcoming prior art and exist, a kind of calculating formula by setting up is provided, submerged arc weld P content can be predicted, again can fast, accurate selected welding wire and the solder flux that can meet weld seam P content, without the need to carrying out the control method of the submerged-arc welding deposited metal phosphorus content of actual welding test.
Realize the measure of above-mentioned purpose:
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 800 ~ 900A, voltage is 29 ~ 30V, and speed of welding is 42 ~ 45cm/min, and weld heat input is at 34 ~ 36J/cm; The solder flux of coupling is alkalescent sintered flux;
Be applicable to: the P content in component of weld wire is at 0.006 ~ 0.015wt%, and the P content in flux constituent is at 0.008 ~ 0.03wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
When the P content in component of weld wire is at 0.006 ~ 0.015wt%, the P content in flux constituent is when 0.008 ~ 0.03wt%, and submerged-arc welding deposited metal phosphorus is predicted according to following calculating formula:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)
In formula: P seamthe weight percent content of-expression submerged-arc welding deposited metal phosphorus,
P silkthe weight percent content of phosphorus in-expression welding wire,
P agentthe weight percent content of phosphorus in-expression solder flux;
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, determines concrete containing P welding wire and solder flux; As predicted submerged-arc welding deposited metal phosphorus P seamwhen value meets the requirements, then the welding wire containing P used and solder flux are then as welding wire during actual welding and solder flux; As predicted submerged-arc welding deposited metal phosphorus P seamwhen being worth undesirable, then continue to select, until meet the requirements.
It is: selected solder flux before use, will toast 1.5 hours under 350 DEG C of conditions.
Calculating formula of the present invention through being verified in laboratory, adopt the welding wire of different P content select and solder flux weld, the weld seam P content of PREDICTIVE CONTROL and experiment results identical; Through verifying further in engineering welding test, measured value is equally comparatively identical, obtains good result.
The present invention compared with prior art, pass through set up calculating formula, strictly can control submerged arc weld P content, fast, accurately can select again the phosphorous welding wire and solder flux that mate, without the need to carrying out test apolegamy welding wire and solder flux, and the weld seam P content of PREDICTIVE CONTROL and experiment results are coincide; Through verifying further in engineering welding test, measured value is identical equally, obtains good result.
Detailed description of the invention
Below the present invention is described in detail:
What embodiment 1(test was welded is construction(al)steel, and it requires P seamcontent is less than 0.018wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 840A, voltage is 29V, and speed of welding is 43cm/min, and weld heat input is ~ 34J/cm; The solder flux of coupling is alkalescent sintered flux SJ105;
P in component of weld wire silkcontent is 0.01wt%, the P in flux constituent agentcontent is 0.027wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.01wt%, the P in flux constituent agentcontent at 0.027wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.0162wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.01wt%, and the solder flux being 0.027wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.016%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 2(test was welded is petroleum pipe steel, and it requires P agentcontent is less than 0.012wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 880A, voltage is 30V, and speed of welding is 45cm/min, and weld heat input is ~ 35J/cm; The solder flux of coupling is alkalescent sintered flux SJ105;
P in component of weld wire silkcontent is 0.01wt%, the P in flux constituent agentcontent is 0.018wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.01wt%, the P in flux constituent agentcontent at 0.018wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.013wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value is due to undesirable, and actual welds P content is 0.0125wt%, therefore need reselect wlding.Again selecting containing P is the welding wire of 0.01wt%, is the solder flux of 0.013wt% containing P, and calculating weldering P content is 0.0119%, and carry out actual welding checking, the weld seam P content of its actual welding is 0.0117wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 3(test was welded is midium-carbon steel, and it requires P agentcontent is less than 0.01wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 820A, voltage is 30V, and speed of welding is 44cm/min, and weld heat input is ~ 34J/cm; The solder flux of coupling is alkalescent sintered flux SJ101;
P in component of weld wire silkcontent is 0.006wt%, the P in flux constituent agentcontent is 0.008wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.006wt%, the P in flux constituent agentcontent at 0.008wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.008wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.006wt%, and the solder flux being 0.008wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.0083%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 4(test was welded is midium-carbon steel, and it requires P agentcontent is less than 0.01wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 820A, voltage is 30V, and speed of welding is 44cm/min, and weld heat input is ~ 34J/cm; The solder flux of coupling is alkalescent sintered flux SJ101;
P in component of weld wire silkcontent is 0.006wt%, the P in flux constituent agentcontent is 0.015wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.006wt%, the P in flux constituent agentcontent at 0.015wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.010wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.006wt%, and the solder flux being 0.015wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.0097%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 5(test was welded is wheel steel, and it requires P agentcontent is less than 0.015wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 820A, voltage is 30V, and speed of welding is 44cm/min, and weld heat input is ~ 34J/cm; The solder flux of coupling is alkalescent sintered flux SJ101;
P in component of weld wire silkcontent is 0.012wt%, the P in flux constituent agentcontent is 0.018wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.012wt%, the P in flux constituent agentcontent at 0.018wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.0146wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.012wt%, and the solder flux being 0.018wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.0149%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 6(test was welded is bridge steel, and it requires P agentcontent is less than 0.012wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 900A, voltage is 30V, and speed of welding is 45cm/min, and weld heat input is ~ 36J/cm; The solder flux of coupling is alkalescent sintered flux SJ101;
P in component of weld wire silkcontent is 0.011wt%, the P in flux constituent agentcontent is 0.010wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.011wt%, the P in flux constituent agentcontent at 0.010wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.0117wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.011wt%, and the solder flux being 0.010wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.0115%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 7(test was welded is bridge steel, and it requires P agentcontent is less than 0.012wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 820A, voltage is 30V, and speed of welding is 43cm/min, and weld heat input is ~ 34J/cm; The solder flux of coupling is alkalescent sintered flux SJ101;
P in component of weld wire silkcontent is 0.01wt%, the P in flux constituent agentcontent is 0.011wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.010wt%, the P in flux constituent agentcontent at 0.011wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.0114wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.010wt%, and the solder flux being 0.010wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.0114%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 8(test was welded is engineering machinery steel, and it requires P agentcontent is less than 0.018wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 900A, voltage is 30V, and speed of welding is 45cm/min, and weld heat input is ~ 36J/cm; The solder flux of coupling is alkalescent sintered flux SJ101;
P in component of weld wire silkcontent is 0.015wt%, the P in flux constituent agentcontent is 0.019wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.015wt%, the P in flux constituent agentcontent at 0.019wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.0168wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.015wt%, and the solder flux being 0.019wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.0171%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
What embodiment 9(test was welded is engineering machinery steel, and it requires P agentcontent is less than 0.018wt%)
A control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 900A, voltage is 30V, and speed of welding is 45cm/min, and weld heat input is ~ 36J/cm; The solder flux of coupling is alkalescent sintered flux SJ101;
P in component of weld wire silkcontent is 0.01wt%, the P in flux constituent agentcontent is 0.030wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
By the P in component of weld wire silkcontent 0.01wt%, the P in flux constituent agentcontent at 0.030wt%, according to the predicted value P of following formulae discovery submerged-arc welding deposited metal phosphorus seam:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)=0.017wt%
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, its value owing to meeting the requirements, therefore determines that selecting containing P is the welding wire of 0.01wt%, and the solder flux being 0.030wt% containing P carries out actual welding checking, and the weld seam P content of its actual welding is 0.0171%wt%; Predicted value P can be found out seamfine with actual tests welding result uniformity, prove that technical scheme of the present invention is effective.
It should be noted that, selected solder flux has toasted 1.5 hours before weldering under 350 DEG C of conditions.
This detailed description of the invention is only the best and exemplifies, the restricted enforcement not to technical solution of the present invention.

Claims (2)

1. a control method for submerged-arc welding deposited metal phosphorus content, its step:
1) welding condition: welding current is 800 ~ 900A, voltage is 29 ~ 30V, and speed of welding is 42 ~ 45cm/min, and weld heat input is at ~ 35J/cm; The solder flux of coupling is alkalescent sintered flux;
Be applicable to: the P content in component of weld wire is at 0.006 ~ 0.015wt%, and the P content in flux constituent is at 0.008 ~ 0.03wt%;
2) according to the P content in welding wire and flux constituent, to submerged-arc welding deposited metal phosphorus P seampredict, namely
When the P content in component of weld wire is at 0.006 ~ 0.015wt%, the P content in flux constituent is when 0.008 ~ 0.03wt%, and submerged-arc welding deposited metal phosphorus is predicted according to following calculating formula:
P seam=(2/3P silk+ 1/3P agent)+0.001 (ln0.010/P silk+ ln0.020/P agent)
In formula: P seamthe weight percent content of-expression submerged-arc welding deposited metal phosphorus,
P silkthe weight percent content of phosphorus in-expression welding wire,
P agentthe weight percent content of phosphorus in-expression solder flux;
3) according to step 2) in the submerged-arc welding deposited metal phosphorus P that predicts seamvalue, determines welding wire and the solder flux of concrete P content; As predicted submerged-arc welding deposited metal phosphorus P seamwhen value meets the requirements, then the welding wire when welding wire of P content used and solder flux can be used as actual welding and solder flux; As predicted submerged-arc welding deposited metal phosphorus P seamwhen being worth undesirable, then continue to select, until meet the requirements.
2. the control method of a kind of submerged-arc welding deposited metal phosphorus content as claimed in claim 1, is characterized in that: selected solder flux before use, will toast 1.5 hours under 350 DEG C of conditions.
CN201510912574.0A 2015-12-11 2015-12-11 A kind of control method of submerged-arc welding deposited metal phosphorus content Active CN105345236B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS594993A (en) * 1982-07-01 1984-01-11 Nippon Kokan Kk <Nkk> Welding method of tempered type steel pipe
JP2008093715A (en) * 2006-10-13 2008-04-24 Nippon Steel Corp High yield strength and high toughness flux-cored wire for gas-shielded arc welding
CN101559541A (en) * 2009-05-19 2009-10-21 武汉钢铁(集团)公司 Test method and device for weld seam alloying in gas shielded welding
CN103323572A (en) * 2013-05-27 2013-09-25 武汉钢铁(集团)公司 A test method for studying components and properties of submerged-arc welding seams
JP2015085331A (en) * 2013-10-28 2015-05-07 新日鐵住金株式会社 Submerged arc weld metal excellent in ultralow-temperature toughness, and submerged arc welding wire and flux forming the same
JP2015155116A (en) * 2015-03-20 2015-08-27 日本冶金工業株式会社 Thickness increasing method for weld stainless steel

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS594993A (en) * 1982-07-01 1984-01-11 Nippon Kokan Kk <Nkk> Welding method of tempered type steel pipe
JP2008093715A (en) * 2006-10-13 2008-04-24 Nippon Steel Corp High yield strength and high toughness flux-cored wire for gas-shielded arc welding
CN101559541A (en) * 2009-05-19 2009-10-21 武汉钢铁(集团)公司 Test method and device for weld seam alloying in gas shielded welding
CN103323572A (en) * 2013-05-27 2013-09-25 武汉钢铁(集团)公司 A test method for studying components and properties of submerged-arc welding seams
JP2015085331A (en) * 2013-10-28 2015-05-07 新日鐵住金株式会社 Submerged arc weld metal excellent in ultralow-temperature toughness, and submerged arc welding wire and flux forming the same
JP2015155116A (en) * 2015-03-20 2015-08-27 日本冶金工業株式会社 Thickness increasing method for weld stainless steel

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Effective date of registration: 20170711

Address after: 430083 Qingshan District, Hubei, Wuhan factory before the door No. 2

Applicant after: Wuhan iron and Steel Company Limited

Address before: 430080 Wuhan, Hubei Friendship Road, No. 999, Wuchang

Applicant before: Wuhan Iron & Steel (Group) Corp.

GR01 Patent grant
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