CN105344239A - A method of purifying indoor air by utilization of a household heating radiator - Google Patents

A method of purifying indoor air by utilization of a household heating radiator Download PDF

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Publication number
CN105344239A
CN105344239A CN201510780487.4A CN201510780487A CN105344239A CN 105344239 A CN105344239 A CN 105344239A CN 201510780487 A CN201510780487 A CN 201510780487A CN 105344239 A CN105344239 A CN 105344239A
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air
adsorption
layer
adsorption element
heating radiator
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CN201510780487.4A
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Chinese (zh)
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华玉叶
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Individual
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8637Simultaneously removing sulfur oxides and nitrogen oxides
    • AHUMAN NECESSITIES
    • A61MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61LMETHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
    • A61L9/00Disinfection, sterilisation or deodorisation of air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0027Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions
    • B01D46/0028Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with additional separating or treating functions provided with antibacterial or antifungal means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/30Particle separators, e.g. dust precipitators, using loose filtering material
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/56Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition
    • B01D46/62Filters or filtering processes specially modified for separating dispersed particles from gases or vapours with multiple filtering elements, characterised by their mutual disposition connected in series
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86Catalytic processes
    • B01D53/8668Removing organic compounds not provided for in B01D53/8603 - B01D53/8665
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/206Rare earth metals
    • B01D2255/2065Cerium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2255/00Catalysts
    • B01D2255/20Metals or compounds thereof
    • B01D2255/207Transition metals
    • B01D2255/20715Zirconium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/40Nitrogen compounds
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/12Methods and means for introducing reactants
    • B01D2259/128Solid reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2259/00Type of treatment
    • B01D2259/45Gas separation or purification devices adapted for specific applications
    • B01D2259/4508Gas separation or purification devices adapted for specific applications for cleaning air in buildings
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2279/00Filters adapted for separating dispersed particles from gases or vapours specially modified for specific uses
    • B01D2279/65Filters adapted for separating dispersed particles from gases or vapours specially modified for specific uses for the sterilisation of air

Abstract

A method of purifying indoor air by utilization of a household heating radiator is disclosed. A first adsorption part, a catalyzing part and a second adsorption part are orderly disposed on the heating radiator and/or at a side of the heating radiator. According to the method, by utilization of the present heating radiator as a power source and a heat source, the cost of adding a power source and a heat source is saved and space is saved.

Description

A kind of method utilizing household central heating sheet to purify the air of a room
Technical field
The present invention relates to technical field of air purification, be specifically related to a kind of method utilizing household central heating sheet to purify the air of a room.
Background technology
Haze weather is a kind of atmosphere pollution state, haze is the general statement to suspended particulate substance content overproof various in air, and especially PM2.5 (equivalent aerodynamic diameter is less than or equal to the particle of 2.5 microns) is considered to " arch-criminal " that cause haze weather.Sulfur dioxide, nitrogen oxide and pellet are the main compositions of haze.
In early or mid November, 2015, the city being representative with Shenyang and other places, its haze PM2.5 index reaches surprising 1140, belongs to serious pollution.Under this kind of environment, pollutant not only injures the respiratory system of people, and the organs such as eyes also can be caused to produce burning sensation, the health of damage eyes.
For indoor environment, owing to must carry out ventilation with outdoor, therefore indoor air faces the problem that PM2.5 pollutes equally.Meanwhile, along with the raising of people's living standard, the interpolation of interior decoration, new furniture also significantly increases.But in interior decoration and furniture, inevitably use various glue or paint, thus cause distributing various organic pollution to indoor, the such as material such as formaldehyde, benzene.
At present, for the process of these indoor pollutants, be mostly to adopt various air purifier and charcoal absorption etc., but the increase of these equipment, careat can be taken, increase cost.
Summary of the invention
The object of the invention is to propose a kind of method utilizing household central heating sheet to purify the air of a room, its inventive point is just to utilize radiator, and when heating, the flowing of distribute heat and then formation air, it can be used as power source; Meanwhile, because the operating temperature of radiator is between 30-80 DEG C, it contributes to as thermal source the catalytic efficiency improving catalyst.That is, the present invention adopts indoor heating radiator, it can be used as power source and thermal source to use, realizes the catalytic purification of room air.
For reaching this object, the present invention by the following technical solutions:
Utilize the method that household central heating sheet purifies the air of a room, its above radiator and/or side be sequentially set with the first adsorption element, catalytic member and the second adsorption element.
Described first adsorption element is provided with fibrous filter layer, and described fibrous filter layer is superimposed with paper fiber thing filter course and ultra-fine fibre glass thing filter course.
Described catalytic member is provided with catalyst layer, and described catalyst comprises following component,
A) Al of 10% 2o 3the Ce/Zr composite oxides of load, the mol ratio Ti:Ce:Zr of its each component is 1:0.08:0.08;
B) V of 5% 2o 5/ (MoO 3) 0.4(WO 3) 0.6/ TiO 2composite oxides, wherein the mol ratio of V:Mo:W:Ti is 2:0.4:0.6:1;
C) ZSM-5 molecular sieve of surplus.
Described second adsorption element is provided with adsorption layer, and described adsorption layer is made up of the nano titanium oxide of active carbon and Ag-bearing, and its mixing quality such as, than being 5:1-2:1,4.5:1,4:1,3.5:1,3:1 etc.
The method course of work of the present invention is as follows, and the temperature of radiator is higher than indoor temperature, and air contacts with radiator, be heated backward upper direction, thus produce pressure differential, and then the guiding cool air of bottom contacted with radiator, thus form the flowing of air, air is heated.First the hot-air moved upward enters the first adsorption element, in the first adsorption element, air is successively through paper fiber layer and ultra-fine fibre glass layer, and because described fibrage has tiny space, therefore it retains filtration to the particle in air and macromolecular substances.
Air after filtering enters catalytic member subsequently, in catalytic member, pollutant in air, such as formaldehyde, methacrylaldehyde, toluene, nitrogen oxide and oxysulfide etc., contact with catalyst, because described air is the air of heating, therefore now the activity of catalyst is higher, oxygen generation catalytic oxidation in itself and air, becomes harmless or is easy to other organic matters of absorbing, such as oxycarbide, be easy to the SO absorbing process 2and NO 2.
Air after catalysis, enters the second adsorption element.In air, the organic pollution of catalyzed oxidation is absorbed by active carbon, and is distributed in the silver in active carbon, kills virus to the microorganism in air, thus reduces
Method of the present invention, by utilizing existing radiator as power source and thermal source, saving the cost increasing power source and thermal source, and saving space.Simultaneously, catalyst of the present invention is by choosing specific components A and B component, this catalyst is made to produce cooperative effect, the organic matter degradations such as the formaldehyde in air, benzene can be called carbon dioxide, and be higher valence state by harmful oxysulfide, nitrogen oxide catalytic oxidation, and then with charcoal absorption, various pollutant is reduced to ppm level.The removal of benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, methacrylaldehyde reaches less than 0.01 milligram/cubic metre, significantly reduces the content of microorganisms in room air simultaneously.
Detailed description of the invention
The present invention is described breathing mask of the present invention by following embodiment.
Embodiment 1
Utilize the method that household central heating sheet purifies the air of a room, its above radiator and/or side be sequentially set with the first adsorption element, catalytic member and the second adsorption element.
Described first adsorption element is provided with fibrous filter layer, and described fibrous filter layer sequencing is superimposed with paper fiber thing filter course and ultra-fine fibre glass thing filter course.
Described catalytic member is provided with catalyst layer, prepares catalyst by infusion process, comprises following component,
A) Al of 10% 2o 3the Ce/Zr composite oxides of load, the mol ratio Ti:Ce:Zr of its each component is 1:0.08:0.08;
B) V of 5% 2o 5/ (MoO 3) 0.4(WO 3) 0.6/ TiO 2composite oxides, wherein the mol ratio of V:Mo:W:Ti is 2:0.4:0.6:1;
C) ZSM-5 molecular sieve of surplus.
Described second adsorption layer is made up of the nano titanium oxide of active carbon and Ag-bearing, and its mixing quality is than being 3:1.
For testing its purification function, passing into haze PM2.5 index in indoor is the air of 500, and makes the benzene,toluene,xylene of gas, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein reach 10 milligrams/cubic metre, and dust content is medium.Open radiator, the temperature of radiator is set to 50 DEG C, first adsorption element of the present invention, catalytic member and the second adsorption element are set in sequence in top and the side of radiator, after 1 hour, test IAQ, its haze PM2.5 index decreased is 0, and oxysulfide, nitrogen oxide, benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein reach less than 0.01 milligram/cubic metre.
Comparative example 1
Component A content 15%, not containing B component, all the other conditions are constant, and its PM2.5 value is 70, and oxysulfide, nitrogen oxide, benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein are more than 0.1 milligram/cubic metre.
Comparative example 2
B component content 15%, not containing component A, all the other conditions are constant, and its PM2.5 value is 59, and oxysulfide, nitrogen oxide, benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein are more than 0.1 milligram/cubic metre.
Comparative example 3
The ZSM-5 molecular sieve of component C is replaced with alundum (Al2O3), all the other conditions are constant, its PM2.5 value is 41, and oxysulfide, nitrogen oxide, benzene,toluene,xylene, ethylbenzene, styrene, formaldehyde, acetaldehyde, level of acrolein are more than 0.1 milligram/cubic metre.
Above-described embodiment and comparative example illustrate, there is specific contact between several component of the present invention and between catalyst carrier, omit or replace wherein one or more, all can not reach the certain effects of the application, prove to which create cooperative effect.
Applicant states, the present invention illustrates the catalyst of breathing mask of the present invention and employing by above-described embodiment, but the present invention is not limited to above-mentioned catalyst, does not namely mean that the present invention must rely on above-mentioned detailed catalysts and could implement.Person of ordinary skill in the field should understand, any improvement in the present invention, to equivalence replacement and the interpolation of auxiliary element, the concrete way choice etc. of each raw material of product of the present invention, all drops within protection scope of the present invention and open scope.

Claims (1)

1. utilize the method that household central heating sheet purifies the air of a room, its above radiator and/or side be sequentially set with the first adsorption element, catalytic member and the second adsorption element;
Described first adsorption element is provided with fibrous filter layer, and described fibrous filter layer is superimposed with paper fiber thing filter course and ultra-fine fibre glass thing filter course;
Described catalytic member is provided with catalyst layer, and described catalyst comprises following component,
A) Al of 10% 2o 3the Ce/Zr composite oxides of load, the mol ratio Ti:Ce:Zr of its each component is 1:0.08:0.08;
B) V of 5% 2o 5/ (MoO 3) 0.4(WO 3) 0.6/ TiO 2composite oxides, wherein the mol ratio of V:Mo:W:Ti is 2:0.4:0.6:1;
C) ZSM-5 molecular sieve of surplus;
Described second adsorption filtration adsorption element is provided with adsorption layer, and described adsorption layer is made up of the nano titanium oxide of active carbon and Ag-bearing, and its mixing quality is than being 5:1-2:1.
CN201510780487.4A 2015-11-14 2015-11-14 A method of purifying indoor air by utilization of a household heating radiator Pending CN105344239A (en)

Priority Applications (1)

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CN201510780487.4A CN105344239A (en) 2015-11-14 2015-11-14 A method of purifying indoor air by utilization of a household heating radiator

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Application Number Priority Date Filing Date Title
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2456077Y (en) * 2000-08-14 2001-10-24 李晓华 Heater for warming
CN1724146A (en) * 2005-07-13 2006-01-25 北京化工大学 Preparation for load type nano composite photocatalyst for catalyzing oxidizing degrading organism under sun lighting
CN1778455A (en) * 2004-11-25 2006-05-31 中国科学院生态环境研究中心 Three-efficiency catalyst and its preparation
CN101104133A (en) * 2006-07-12 2008-01-16 北京华夏金安环保科技有限公司 Air purifying method and device thereof
US20120087838A1 (en) * 2010-10-06 2012-04-12 General Electric Company Catalyst and method of manufacture
CN102764643A (en) * 2012-07-16 2012-11-07 中国科学院生态环境研究中心 Vanadium-titanium oxide catalyst, and preparation method and application thereof
CN204006370U (en) * 2014-06-17 2014-12-10 深圳中元宏康科技有限公司 A kind of new and effective indoor air auto-purifying device
CN104406244A (en) * 2014-12-06 2015-03-11 重庆玛格装饰建材有限公司 Air purifying treating device

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2456077Y (en) * 2000-08-14 2001-10-24 李晓华 Heater for warming
CN1778455A (en) * 2004-11-25 2006-05-31 中国科学院生态环境研究中心 Three-efficiency catalyst and its preparation
CN1724146A (en) * 2005-07-13 2006-01-25 北京化工大学 Preparation for load type nano composite photocatalyst for catalyzing oxidizing degrading organism under sun lighting
CN101104133A (en) * 2006-07-12 2008-01-16 北京华夏金安环保科技有限公司 Air purifying method and device thereof
US20120087838A1 (en) * 2010-10-06 2012-04-12 General Electric Company Catalyst and method of manufacture
CN102764643A (en) * 2012-07-16 2012-11-07 中国科学院生态环境研究中心 Vanadium-titanium oxide catalyst, and preparation method and application thereof
CN204006370U (en) * 2014-06-17 2014-12-10 深圳中元宏康科技有限公司 A kind of new and effective indoor air auto-purifying device
CN104406244A (en) * 2014-12-06 2015-03-11 重庆玛格装饰建材有限公司 Air purifying treating device

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