CN105331448A - Stripping cleaning agent composition and usage method thereof - Google Patents
Stripping cleaning agent composition and usage method thereof Download PDFInfo
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- CN105331448A CN105331448A CN201410289644.7A CN201410289644A CN105331448A CN 105331448 A CN105331448 A CN 105331448A CN 201410289644 A CN201410289644 A CN 201410289644A CN 105331448 A CN105331448 A CN 105331448A
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Abstract
The invention discloses a stripping cleaning agent composition and a usage method thereof. Wherein, the composition contains D-limonene, polyethylene glycol and a nonionic/anionic surfactant mixture, a weight ratio of D-limonene to the polyethylene glycol to the nonionic/anionic surfactant mixture is 1:0.25-3:0.1-1.5, the nonionic surfactant is a polyoxyethylene type nonionic surfactant, and the anionic surfactant is a long-chain alkyl carboxylic salt anionic surfactant. The stripping cleaning agent composition provided by the invention has the oil sludge cleaning efficacy and also has slime stripping efficacy, can be applied to circulating water systems, especially circulating water systems with oil leakage problem, and has the advantages of good cleaning effect, low cost, small dosage, and excellent stripping and cleaning performance.
Description
Technical field
The present invention relates to a kind of recirculated water and peel off cleansing composition and using method thereof.
Background technology
Water resources has become the important factor of restriction petroleum chemical enterprise development, and water conservation is very urgent.Circulating water system is one and uses water rich and influential family, at present, improve cycles of concentration be recirculated water the most directly, the most effective water-saving method.But if circulating water system leaked substance, need with the displacement of a large amount of fresh waters, not only waste a large amount of fresh waters, and the consumption of water treatment agent also rolls up, cost increases substantially.
Oil leak is a kind of situation that petroleum chemical enterprise's circulating water system often occurs.Oil leak showing as in recirculated water: one be system oil-contg increase, two is that bacterial number exceeds standard greatly.Its harm have following some: one is for bacterial growth provides nutrition, makes bacterium raised growth, and the suspended substance in the bacterium of growth and recirculated water and material form biological clay, are deposited in heat-exchange equipment, affect heat transfer effect, cause corrosion; Two is that the material leaked causes sterilant to lose efficacy, material directly and chlorine and non oxidizing bactericide react, affect the effect of sterilant, thus make bacterium raised growth; Three is some material, as heavy oil spill, adheres on tube wall, cooling tower or heat-exchange equipment, impact heat transfer and cooling; Four is bacterium raised growths, has Degradation to inhibition, Scale inhibitors, thus the inhibition of influential system and scale inhibition effect.
At present, the method solving the leakage of circulating water system oil product mostly is low cycles of concentration and runs, large excretion and large complement, adds the various disadvantageous effects peeled off clean-out system reduction oil leak and bring to circulating water system and heat exchanger surface simultaneously.Low cycles of concentration operation can waste a large amount of fresh water, oily substance residual in circulating water system, and bring disadvantageous effect can to equally circulating water system and heat exchanger surface, circulating water system treatment effect can not get ensureing.
Therefore, one is applicable to oil leak circulating water system, have excellent to peel off, the stripping clean-out system of cleaning and dispersing property urgently develops.
Summary of the invention
The object of the invention is to overcome in prior art and solve the large and halfway weakness of cleaning performance of water resource waste when circulating water system oil product is revealed, and run because the method solving the leakage of circulating water system oil product in prior art mostly is low cycles of concentration, one is waste a large amount of fresh waters, two is the residual oily substance of heat exchanger surface and biological clay, burn into can be brought to conduct heat the defects such as ineffective and microbial growth, provide and a kind ofly peel off cleansing composition and using method thereof.
The invention provides a kind of stripping cleansing composition, wherein, said composition contains D-limonene, polyoxyethylene glycol and nonionic/anionic surfactant mixture, and the weight ratio of described D-limonene, described polyoxyethylene glycol and described nonionic/anionic surfactant mixture is 1:0.25 ~ 3:0.1 ~ 1.5, described nonionogenic tenside is Determination of Polyoxyethylene Non-ionic Surfactants, and described anion surfactant is chain alkyl carboxylate anion tensio-active agent.
Present invention also offers a kind of using method peeling off cleansing composition, this using method is: described stripping cleansing composition is added in circulating water system the blowdown after 12 ~ 48 hours that circulates, and mend with fresh water until the turbidity value of this circulating water system and add the turbidity value before described stripping cleansing composition difference between ± 10%.
According to stripping cleansing composition provided by the invention and using method thereof, on the one hand, though the present inventor finds that D-limonene is water insoluble, but can dissolve each other with arbitrary proportion with water after interpolation nonionic/anionic surfactant mixture, can be applied in thus in aqueous phase, the greasy filth of clean cycle water system heat exchanger surface, can be applicable to the circulating water system that there is oil product and reveal, and solves heat exchanger surface oil product and adheres to and the corrosion that brings and the problem such as ineffective of conducting heat; On the other hand, together with the present invention is composite with polyoxyethylene glycol by D-limonene, nonionic/anionic surfactant mixture, can be loosened the foundry loam of heat exchanger surface, and make it be taken away by current, solves the problems such as corrosion and scaling that biological clay brings to circulating water system and microbial growth.
Other features and advantages of the present invention are described in detail in embodiment part subsequently.
Embodiment
Below the specific embodiment of the present invention is described in detail.Should be understood that, embodiment described herein, only for instruction and explanation of the present invention, is not limited to the present invention.
The invention provides a kind of stripping cleansing composition, wherein, said composition contains D-limonene, polyoxyethylene glycol and nonionic/anionic surfactant mixture, and the weight ratio of described D-limonene, described polyoxyethylene glycol and described nonionic/anionic surfactant mixture is 1:0.25 ~ 3:0.1 ~ 1.5, described nonionogenic tenside is Determination of Polyoxyethylene Non-ionic Surfactants, and described anion surfactant is chain alkyl carboxylate anion tensio-active agent.
According to the present invention, under preferable case, the weight ratio of described D-limonene, described polyoxyethylene glycol and described nonionic/anionic surfactant mixture can be 1:0.75 ~ 2.5:0.25 ~ 1.
According to the present invention, in described nonionic/anionic surfactant mixture, described Determination of Polyoxyethylene Non-ionic Surfactants and described chain alkyl carboxylate anion tensio-active agent and weight ratio can be 1:0.25 ~ 4, be preferably 1:0.5 ~ 2, be more preferably 1:0.75 ~ 1.25.
According to the present invention, described chain alkyl carboxylate anion tensio-active agent can be one or more in the ammonium salt of the sylvite of higher fatty acid, the sodium salt of higher fatty acid and higher fatty acid;
Preferably, described chain alkyl carboxylate anion tensio-active agent is C
12~ C
18sodium carboxylate, particularly, C
12~ C
18sodium carboxylate be sodium laurate, tridecyl carboxylic acid sodium, tetradecyl carboxylic acid sodium, pentadecyl carboxylic acid sodium, hexadecyl carboxylic acid sodium, heptadecyl carboxylic acid sodium and octadecyl carboxylic acid sodium;
More preferably, described chain alkyl carboxylate anion tensio-active agent is one or more in sodium laurate, tetradecyl carboxylic acid sodium and hexadecyl carboxylic acid sodium.
According to the present invention, described Determination of Polyoxyethylene Non-ionic Surfactants is the alkylphenol polyoxyethylene shown in the long-chain fat polyoxyethylenated alcohol shown in formula (I) and/or formula (II);
Wherein, in formula (I), R
3for C
12~ C
18alkyl, polymerization degree n can be the integer of 8 ~ 40, be preferably 8 ~ 35 integer;
More preferably, described long-chain fat polyoxyethylenated alcohol is ethoxylated dodecyl alcohol (n=9) and/or hexadecanol Soxylat A 25-7 (n=13).
Wherein, in formula (II), R
4can be C
8~ C
12alkyl, polymerization degree m can be the integer of 3 ~ 30;
Preferably, R
4for C
8, C
9or C
12alkyl, m is the integer of 9 ~ 12;
More preferably, described alkylphenol polyoxyethylene is selected from polyoxyethylene octylphenol ether (m=9), one or more in polyoxyethylene nonylphenol ether (m=9) and dodecyl phenol polyethenoxy ether (m=9).
According to the present invention, described polyoxyethylene glycol can be selected from PEG-400, PEG-600 and PEG-800 one or more.
According to the present invention, described stripping cleansing composition is the form of the aqueous solution, and the total concn of D-limonene described in this aqueous solution, described polyoxyethylene glycol and described nonionic/anionic surfactant mixture can be 25 ~ 75 % by weight, be preferably 30 ~ 55 % by weight.
Present invention also offers a kind of using method peeling off cleansing composition, this using method is: described stripping cleansing composition is added in circulating water system the blowdown after 12 ~ 48 hours that circulates, and mends with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%.
According to the present invention, the consumption of described stripping cleansing composition can be 10mg/L ~ 50mg/L.Under preferable case, the consumption of described stripping cleansing composition is 10mg/L ~ 30mg/L.
Below will be described the present invention by embodiment.
In following examples and comparative example, cleansing composition is peeled off to employing method preparation of the present invention and carries out the system outline of certain Circulating Water Field (hereinafter referred to as " six follow ") that benchmark test adopts in table 1.
Table 1
| Project | Numerical value |
| Cycles of concentration | N≥3 |
| Possess water yield m 3 | 6000 |
| Quantity of circulating water m 3/h | 12000 |
| Water amount of blowdown m 3/h | 13.3 |
| Other drainage amount m 3/h | 382 |
| The temperature difference DEG C | 5 |
| The main material of equipment | Carbon steel, copper |
Six follow and there is oil leak, and six follow water quality situation in table 2.
Table 2
| Project | Scope | Mean value |
| PH value | 8.7～8.4 | 8.5 |
| Hardness/(mg/L) | 1628～1342 | 1469 |
| Ca 2+/(mg/L) | 1135～862 | 1012 |
| Total alkalinity/(mg/L) | 324～178 | 253 |
| Total iron/(mg/L) | 1.7～0.6 | 1.0 |
| Zn 2+/(mg/L) | 3.2～1.6 | 2.5 |
| Total phosphorus/(mg/L) | 6.5～5.7 | 6.2 |
| Chlorine residue/(mg/L) | 1.0～0.1 | 0.4 |
| COD/(mg/L) | 135～109 | 127 |
| Turbidity/(mg/L) | 25.8～13.7 | 18.4 |
| Heterotrophic bacterium/(individual/mL) | 6.0×10 4～1.2×10 5 | 8.1×10 4 |
| Cycles of concentration | 6.3～2.8 | 4.1 |
In the present invention, with reference to " boiler feed water and cooling water quality analytical procedure national standard " GB/T12151-1989 spectrophotometry turbidity value.
In the present invention, heterotrophic bacterium content is measured with reference to " industrial circulating cooling water water quality analysis method " GB/T14643.1-1993 SPC method.
In the present invention, the laboratory evaluation method of sludge stripping performance adopts Extracellular polymers method.
In the present invention, Extracellular polymers is the important component part of active sludge, and its main organic composition is carbohydrate, nucleic acid and protein.After adhesive mud remover acts on active sludge, the organic composition such as polysaccharide and nucleic acid is scattered in recirculated cooling water, evaluates according to the peeling effect of the organic component content such as polysaccharide and nucleic acid to adhesive mud remover.Concrete operation step is as follows:
(1) active sludge is placed in the centrifugal 5min of 7000r/min on whizzer, abandoning supernatant, by distilled water eccentric cleaning 3 times repeatedly, obtains foundry loam for subsequent use.
(2) in Erlenmeyer flask, the above-mentioned foundry loam of 10g/L, different concns adhesive mud remover is added, with distilled water diluting, with the rotating speed constant temperature 27 DEG C of 150r/min revolution 24h on gyrostat.
(3) take out above-mentioned mixed solution to filter, measure polysaccharide and nucleic acid content in filtrate.Measurement of the polysaccharide content adopts anthrone-sulphuric acid method, and the mensuration of nucleic acid content adopts fixing phosphorus method.
D-limonene used in following examples and comparative example is purchased from Ji'an City Tian Yuan medicinal oil factory, polyoxyethylene glycol is purchased from Licheng District, Jinan City all Hue works business department, and described Determination of Polyoxyethylene Non-ionic Surfactants and described chain alkyl carboxylate anion tensio-active agent are all purchased from the strong imperial fine chemistry industry head factory in Luoyang.
Embodiment 1
Cleansing composition Q1 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 20 % by weight, the polyoxyethylene nonylphenol ether (m=9) of 5 % by weight, the sodium laurate of 5 % by weight, the PEG-400 of 20 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 30mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q1 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 2
Cleansing composition Q2 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 10 % by weight, the polyoxyethylene octylphenol ether (m=9) of 8 % by weight, the tetradecyl carboxylic acid sodium of 7 % by weight, the PEG-600 of 25 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 30mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q2 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 3
Cleansing composition Q3 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 30 % by weight, the dodecyl phenol polyethenoxy ether (m=9) of 2 % by weight, the hexadecyl carboxylic acid sodium of 3 % by weight, the PEG-800 of 15 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 30mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q3 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 4
Cleansing composition Q4 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 25 % by weight, the ethoxylated dodecyl alcohol (n=9) of 7 % by weight, the octadecyl carboxylic acid sodium of 8 % by weight, the PEG-400 of 10 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 30mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q4 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 5
Cleansing composition Q5 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 15 % by weight, the hexadecanol Soxylat A 25-7 (n=13) of 3 % by weight, the sodium laurate of 2 % by weight, the PEG-600 of 30 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 30mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q5 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 6
Cleansing composition Q6 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 20 % by weight, the dodecyl phenol polyethenoxy ether (m=9) of 5 % by weight, the tetradecyl carboxylic acid sodium of 5 % by weight, the PEG-800 of 20 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 10mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q6 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 7
Cleansing composition Q7 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 20 % by weight, the polyoxyethylene nonylphenol ether (m=9) of 5 % by weight, the hexadecyl carboxylic acid sodium of 5 % by weight, the PEG-400 of 20 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 50mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q1 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 8
Cleansing composition Q8 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 15 % by weight, the polyoxyethylene octylphenol ether (m=9) of 4 % by weight, the octadecyl carboxylic acid sodium of 3.5 % by weight, the PEG-600 of 15 % by weight and the deionized water of 62.5 % by weight;
The stripping cleansing composition 40mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 12h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q8 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 9
Cleansing composition Q9 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 30 % by weight, the dodecyl phenol polyethenoxy ether (m=9) of 10 % by weight, the sodium laurate of 5 % by weight, the deionized water of the PEG-800 of 15 % by weight and the PEG-400 of 15 % by weight and 25 % by weight;
The stripping cleansing composition 20mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 48h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q9 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 10
Cleansing composition Q1 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 20 % by weight, the polyoxyethylene nonylphenol ether (m=9) of 2 % by weight, the sodium laurate of 8 % by weight, the PEG-400 of 20 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 30mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q1 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Embodiment 11
Cleansing composition Q1 is peeled off in preparation, wherein, this stripping cleansing composition contains the D-limonene of 20 % by weight, the polyoxyethylene nonylphenol ether (m=9) of 8 % by weight, the sodium laurate of 2 % by weight, the PEG-400 of 20 % by weight and the deionized water of 50 % by weight;
The stripping cleansing composition 30mg/L of above-mentioned preparation is added in circulating water system, be circulated to blowdown after 24h, and mend with fresh water until the turbidity value of this circulating water system and the turbidity value difference that adds before described stripping cleansing composition are between ± 10%;
Test the turbidity before and after the stripping in this stripping cleansing composition Q1 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Comparative example 1
Adopt the compound method identical with embodiment 1 and using method, difference is, this stripping cleansing composition contains the D-limonene of 5 % by weight, the polyoxyethylene nonylphenol ether (m=9) of 10 % by weight, the sodium laurate of 10 % by weight, the PEG-400 of 35 % by weight and the deionized water of 40 % by weight;
Test the turbidity before and after the stripping in this stripping cleansing composition DQ1 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Comparative example 2
Adopt the compound method identical with embodiment 1 and using method, difference is, this stripping cleansing composition contains the D-limonene of 40 % by weight, the polyoxyethylene nonylphenol ether (m=9) of 7 % by weight, the sodium laurate of 8 % by weight, the PEG-400 of 5 % by weight and the deionized water of 40 % by weight;
Test the turbidity before and after the stripping in this stripping cleansing composition DQ2 clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Comparative example 3
Adopt the using method identical with embodiment 1, difference is, adds the myristyl benzyl dimethyl ammonium chloride (1427) of 100mg/L in circulating water system.
Test the oil-contg before and after the greasy filth in this greasy filth cleansing composition (myristyl benzyl dimethyl ammonium chloride, namely 1427) clean cycle water system and heterotrophic bacterium numerical value, the results are shown in Table 3.
Table 3
As can be seen from the data of above embodiment 1-11 and comparative example 1-3, adopt stripping cleansing composition of the present invention to be applied to and exist in the circulating water system of oil product leakage, turbidity value obviously increases relative to comparative example 1-3, heterotrophic bacterium number also obviously increases relative to comparative example 1-3, shows the excellent effect adopting stripping cleansing composition of the present invention to the greasy filth cleaning in circulating water system.Therefore, adopt stripping cleansing composition of the present invention to be applied to exist the circulating water system that oil product is revealed, the greasy filth cleaning performance of the excellent stripping cleansing composition used in comparative example 1-3 of greasy filth cleaning performance.
The sludge stripping performance of the stripping clean-out system used in the stripping cleansing composition prepare embodiment 1-5 and comparative example 3 is evaluated, the concentration of stripping cleansing composition prepared by embodiment 1-5 is 30mg/L, in comparative example 3 use 1427 add concentration for 100mg/L, result is as shown in table 4.
Table 4
| Embodiment | Polysaccharide content/(mg/L) | Nucleic acid content/(mg/L) |
| Embodiment 1 (peeling off cleansing composition Q1) | 25.53 | 4.301 |
| Embodiment 2 (peeling off cleansing composition Q2) | 30.79 | 5.206 |
| Embodiment 3 (peeling off cleansing composition Q3) | 21.32 | 3.605 |
| Embodiment 4 (peeling off cleansing composition Q4) | 19.28 | 3.311 |
| Embodiment 5 (peeling off cleansing composition Q5) | 38.28 | 6.489 |
| Comparative example 3 (peeling off clean-out system 1427) | 14.13 | 2.334 |
From the data of above embodiment 1-5 and comparative example 3, even if be 30mg/L in the concentration of the stripping cleansing composition using embodiment 1-5 to prepare, stripping clean-out system 1427 concentration in use comparative example 3 is in 100mg/L situation, that is, the amount of stripping clean-out system used in comparative example 3 be greater than in embodiment 1-5 peel off cleansing composition amount in this case, adopt stripping cleansing composition of the present invention to be applied to and exist in the circulating water system of oil product leakage, the value of polysaccharide content and nucleic acid content is still better than the polysaccharide content of stripping cleansing composition and the value of nucleic acid content of use in comparative example 3, show to adopt stripping cleansing composition of the present invention to the excellent effect of the stripping in circulating water system.
Therefore, adopt stripping cleansing composition of the present invention, both there is excellent greasy filth cleaning performance, there is again good sludge stripping performance.
More than describe the preferred embodiment of the present invention in detail, but the present invention is not limited to above-mentioned embodiment, within the scope of technical conceive of the present invention, multiple simple variant is carried out to technical scheme of the present invention and all belongs to protection scope of the present invention.It should be noted that in addition, each concrete technical characteristic described in above-mentioned embodiment, in reconcilable situation, can be combined by any suitable mode, in order to avoid unnecessary repetition, the present invention illustrates no longer separately to various possible array mode.In addition, also can carry out arbitrary combination between various different embodiment of the present invention, as long as it is without prejudice to thought of the present invention, it should be considered as content disclosed in this invention equally.
Claims (10)
1. peel off cleansing composition for one kind, it is characterized in that, said composition contains D-limonene, polyoxyethylene glycol and nonionic/anionic surfactant mixture, and the weight ratio of described D-limonene, described polyoxyethylene glycol and described nonionic/anionic surfactant mixture is 1:0.25 ~ 3:0.1 ~ 1.5, described nonionogenic tenside is Determination of Polyoxyethylene Non-ionic Surfactants, and described anion surfactant is chain alkyl carboxylate anion tensio-active agent.
2. stripping cleansing composition according to claim 1, wherein, the weight ratio of described D-limonene, described polyoxyethylene glycol and described nonionic/anionic surfactant mixture is 1:0.75 ~ 2.5:0.25 ~ 1.
3. stripping cleansing composition according to claim 1 and 2, wherein, the weight ratio of described Determination of Polyoxyethylene Non-ionic Surfactants and described chain alkyl carboxylate anion tensio-active agent is 1:0.25 ~ 4, is preferably 1:0.5 ~ 2.
4. stripping cleansing composition according to claim 3, wherein, described chain alkyl carboxylate anion tensio-active agent is one or more in the ammonium salt of the sylvite of higher fatty acid, the sodium salt of higher fatty acid and higher fatty acid, is preferably C
12~ C
18sodium carboxylate, be more preferably in sodium laurate, tetradecyl carboxylic acid sodium and hexadecyl carboxylic acid sodium one or more.
5. stripping cleansing composition according to claim 1 and 2, wherein, described Determination of Polyoxyethylene Non-ionic Surfactants is the alkylphenol polyoxyethylene shown in the long-chain fat polyoxyethylenated alcohol shown in formula (I) and/or formula (II);
Wherein, R
3for C
12~ C
18alkyl, n is the integer of 8 ~ 40, be preferably 8 ~ 35 integer; R
4for C
8~ C
12alkyl, m is the integer of 3 ~ 30;
Preferably, R
4for C
8, C
9or C
12alkyl, m is the integer of 9 ~ 12.
6. stripping cleansing composition according to claim 1 and 2, wherein, described polyoxyethylene glycol be selected from PEG-400, PEG-600 and PEG-800 one or more.
7. stripping cleansing composition according to claim 1 and 2, wherein, described stripping cleansing composition is the form of the aqueous solution, and the total concn of D-limonene described in this aqueous solution, described polyoxyethylene glycol and described nonionic/anionic surfactant mixture is 25 ~ 75 % by weight, be preferably 30 ~ 55 % by weight.
8. according to the using method of the stripping cleansing composition in claim 1-7 described in any one, this using method is: described stripping cleansing composition is added in circulating water system the blowdown after 12 ~ 48 hours that circulates, and mend with fresh water until the turbidity value of this circulating water system and add the turbidity value before described stripping cleansing composition difference between ± 10%.
9. using method according to claim 8, wherein, the consumption of described stripping cleansing composition is 10mg/L ~ 50mg/L.
10. using method according to claim 9, wherein, the consumption of described stripping cleansing composition is 10mg/L ~ 30mg/L.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109722673A (en) * | 2017-10-31 | 2019-05-07 | 中国石油化工股份有限公司 | The method that cleaning agent, cleansing composition and its application and processing have the circulation of leakage oil product |
| CN110301437A (en) * | 2019-07-11 | 2019-10-08 | 北京中天兰清环境科技有限公司 | A kind of sterilization synergy remover for circulating water treatment |
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| CN105331448B (en) | 2018-06-15 |
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